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  • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
  • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
  • C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
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  • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
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  • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
  • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
  • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
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  • C08F4/00—Polymerisation catalysts
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  • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
  • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
  • C08F4/62—Refractory metals or compounds thereof
  • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
  • C08F4/64003—Titanium, zirconium, hafnium or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
  • C08F4/64082—Tridentate ligand
  • C08F4/64141—Dianionic ligand
  • C08F4/64158—ONO
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  • C08F4/00—Polymerisation catalysts
  • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
  • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
  • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
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  • C08F4/00—Polymerisation catalysts
  • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
  • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
  • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
  • C08F4/62—Refractory metals or compounds thereof
  • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
  • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
  • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
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  • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
  • C08F2500/17—Viscosity
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  • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
  • C08F2500/19—Shear ratio or shear ratio index
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  • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
  • C08F2500/27—Amount of comonomer in wt% or mol%
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  • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
  • C08F2500/39—Tensile storage modulus E'; Shear storage modulus G'; Tensile loss modulus E''; Shear loss modulus G''; Tensile complex modulus E*; Shear complex modulus G*

Definitions

• TITLE Ethylene- Alpha- Olefin-Diene Monomer Copolymers Obtained Using Transition Metal Bis(Phenolate) Catalyst Complexes and Homogeneous Process For Production Thereof
• compositions Obtained Using Transition Metal Bis(Phenolate) Catalyst Complexes and Homogeneous Process for Production Thereof’ (attorney docket number 2020EM051).
• This invention relates ethylene-propylene diene monomer copolymers prepared using novel catalyst compounds comprising group 4 bis(phenolate) complexes, compositions comprising such and processes to prepare such copolymers.
• Ethylene/propylene copolymer (EPR) and EPDM are two primary types of elastomers manufactured commercially.
• EPR is a copolymer of ethylene and propylene and can be made with a wide range of Mooney viscosities and crystallinity ranging from amorphous to semi-crystalline.
• a third, non-conjugated diene monomer can be terpolymerized in a controlled manner to maintain a saturated backbone and to facilitate vulcanization.
• the diene containing ethylene terpolymer is referred as to EPDM.
• EPDM rubbers are traditionally produced using conventional Ziegler-Natta catalysts based on transition metals, such as V and Ti (cEPDM).
• cEPDM tends to have broad molecular weight distribution (MWD) and broad composition distribution (CD). cEPDM typically has long chain branching through cationic coupling of pendant double bonds.
• metallocene catalyst systems are attractive for EPDM production (mEPDM), due in part to the broader ethylene range, lower production cost and significant emission reduction.
• Limitation of cEPDM e.g., the Mooney viscosity range of only 20-80 Mooney units and the ENB of maximum of 7%
• mEPDM rubbers have a narrow MWD and CD. Degree of branching depends on the choice of diene. When 5-ethylidene-2-norbornene (ENB) is used, as is frequently the case, very little long chain branching is observed in mEPDM.
• mEPDMs In order to take advantage of metallocene catalyzed polymerization process, mEPDMs generally need further improvement, particularly in shear thinning, melt elasticity or green strength.
• Great efforts have been made on manipulating mEPDM molecular architectures such as introduction of long chain branching and design of molecular weight distribution (MWD) and composition distribution (CD) through blending (in reactor and post reactor).
• MWD molecular weight distribution
• CD composition distribution
• Long chain branching can be achieved in- situ in polymerization reactors through two pathways: terminal branching and diene copolymerization.
• EPR and EPDM markets are dominated by products prepared with Ziegler-Natta (ZN) type catalysts and metallocene type of catalysts. Optimization of these products almost always involve use of complicated multiple reactors/multiple catalyst processes. Hence there is interest in finding new catalyst systems that increase the commercial usefulness of the catalyst and allow the production of polymers having improved properties.
• ZN Ziegler-Natta
• Catalysts for olefin polymerization can be based on bis(phenolate) complexes as catalyst precursors, which are activated typically by an alumoxane or an activator containing a non-coordinating anion.
• bis(phenolate) complexes can be found in the following references:
• KR 2018022137 (LG Chem.) describes transition metal complexes of bis(methylphenyl phenolate)pyridine.
• WO 2016/172110 - (Univation Technologies) describes complexes of tridentate bis(phenolate) ligands that feature a non-cyclic ether or thioether donor.
• This invention relates to ethylene- alpha olefin-diene-monomer copolymers, such as ethylene-propylene-diene monomer copolymers, and blends comprising such copolymers, where the ethylene-propylene-diene-monomer copolymers are prepared in a solution process using bis(phenolate) transition metal catalyst complexes.
• This invention further relates to ethylene- alpha olefin-diene-monomer copolymers, such as ethylene-propylene-diene monomer polymers, and blends comprising such copolymers, where the ethylene-propylene-diene-monomer copolymers are prepared in a solution process using transition metal catalyst complexes of a dianionic, tridentate ligand that features a central neutral heterocyclic Lewis base and two phenolate donors, where the tridentate ligand coordinates to the metal center to form two eight- membered rings.
• This invention also relates to polymers of diene monomer with at least one C2-C20 alpha olefin monomer (such as ethylene-alpha-olefin-diene-monomer copolymers, such as ethylene- propylene-diene-monomer copolymers), and blends comprising such copolymers, where the copolymers are, prepared in a solution process using bis(phenolate) complexes represented by Formula (I): wherein:
• M is a group 3-6 transition metal or Lanthanide
• E and E' are each independently O, S, or NR 9 , where R 9 is independently hydrogen, C1-C40 hydrocarbyl, C1-C40 substituted hydrocarbyl, or a heteroatom-containing group; Q is group 14, 15, or 16 atom that forms a dative bond to metal M;
• A'QA 1 are part of a heterocyclic Lewis base containing 4 to 40 non-hydrogen atoms that links A 2 to A 2 via a 3-atom bridge with Q being the central atom of the 3-atom bridge,
• a 1 and A 1 are independently C, N, or C(R 22 ), where R 22 is selected from hydrogen, C1-C20 hydrocarbyl, C1-C20 substituted hydrocarbyl;
• a 3 - A 2 is a divalent group containing 2 to 40 non-hydrogen atoms that links A to the E-bonded aryl group via a 2-atom bridge;
• ⁇ is a divalent group containing 2 to 40 non-hydrogen atoms that links A to the E'-bonded aryl group via a 2-atom bridge;
• L is a neutral Lewis base
• X is an anionic ligand; n is 1, 2 or 3; m is 0, 1, or 2; n+m is not greater than 4; each of R 1 , R 2 , R 3 , R 4 , R 1 , R 2 , R 3 , and R 4 is independently hydrogen, C1-C40 hydrocarbyl, C1-C40 substituted hydrocarbyl, a heteroatom or a heteroatom-containing group, or one or more of R 1 and R 2 , R 2 and R 3 , R 3 and R 4 , R 1 and R 2 , R 2 and R 3 , R 3 and R 4 may be joined to form one or more substituted hydrocarbyl rings, unsubstituted hydrocarbyl rings, substituted heterocyclic rings, or unsubstituted heterocyclic rings each having 5, 6, 7, or 8 ring atoms, and where substitutions on the ring can join to form additional rings; any two L groups may be joined together to form a bidentate Lewis base; an X group may be joined to an
• This invention also relates to a solution phase method to polymerize olefins comprising contacting a catalyst compound as described herein with an activator, propylene and one or more comonomers. This invention further relates to propylene copolymer compositions produced by the methods described herein.
• Catalyst productivity is a measure of the mass of polymer produced using a known quantity of polymerization catalyst. Typically, “catalyst productivity” is expressed in units of (g of polymer)/(g of catalyst) or (g of polymer)/(mmols of catalyst) or the like. If units are not specified then the “catalyst productivity” is in units of (g of polymer)/(g of catalyst). For calculating catalyst productivity only the weight of the transition metal component of the catalyst is used (i.e. the activator and/or co-catalyst is omitted).
• Catalyst activity is a measure of the mass of polymer produced using a known quantity of polymerization catalyst per unit time for batch and semi-batch polymerizations. Typically, “catalyst activity” is expressed in units of (g of polymer)/(mmol of catalyst)/hour or (kg of polymer )/(mmols of catalyst)/hour or the like. If units are not specified then the “catalyst activity” is in units of (g of polymer)/(mmol of catalyst)/hour. [0024] “Conversion” is the percentage of a monomer that is converted to polymer product in a polymerization, and is reported as % and is calculated based on the polymer yield, the polymer composition, and the amount of monomer fed into the reactor.
• an “olefin,” alternatively referred to as “alkene,” is a linear, branched, or cyclic compound of carbon and hydrogen having at least one double bond.
• alkene is a linear, branched, or cyclic compound of carbon and hydrogen having at least one double bond.
• the olefin present in such polymer or copolymer is the polymerized form of the olefin.
• a copolymer when a copolymer is said to have an "ethylene" content of 35 wt% to 55 wt%, it is understood that the mer unit in the copolymer is derived from ethylene in the polymerization reaction and said derived units are present at 35 wt% to 55 wt%, based upon the weight of the copolymer.
• a “polymer” has two or more of the same or different mer units.
• a “homopolymer” is a polymer having mer units that are the same.
• a “copolymer” is a polymer having two or more mer units that are different from each other.
• a “terpolymer” is a polymer having three mer units that are different from each other.
• copolymer includes terpolymers and the like. “Different” as used to refer to mer units indicates that the mer units differ from each other by at least one atom or are different isomerically.
• An "ethylene polymer” or “ethylene copolymer” is a polymer or copolymer comprising at least 50 mole% ethylene derived units
• a "propylene polymer” or “propylene copolymer” is a polymer or copolymer comprising at least 50 mole% propylene derived units, and so on.
• Ethylene shall be considered an alpha olefin (also referred to as a-olefin).
• C n means hydrocarbon(s) having n carbon atom(s) per molecule, wherein n is a positive integer.
• hydrocarbon means a class of compounds containing hydrogen bound to carbon, and encompasses (i) saturated hydrocarbon compounds, (ii) unsaturated hydrocarbon compounds, and (iii) mixtures of hydrocarbon compounds (saturated and/or unsaturated), including mixtures of hydrocarbon compounds having different values of n.
• a “C m -C y ” group or compound refers to a group or compound comprising carbon atoms at a total number thereof in the range from m to y.
• a C 1 -C 50 alkyl group refers to an alkyl group comprising carbon atoms at a total number thereof in the range from 1 to 50.
• hydrocarbyl radical hydrocarbyl group
• hydrocarbyl hydrocarbyl
• Preferred hydrocarbyls are C 1 -C 100 radicals that may be linear, branched, or cyclic, and when cyclic, aromatic or non-aromatic.
• radicals include, but are not limited to, alkyl groups such as methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, sec-butyl, tert-butyl, pentyl, iso-amyl, hexyl, octyl cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cyclooctyl, and the like, aryl groups, such as phenyl, benzyl naphthalenyl, and the like.
• alkyl groups such as methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, sec-butyl, tert-butyl, pentyl, iso-amyl, hexyl, octyl cyclopropyl, cyclobutyl,
• substituted means that at least one hydrogen atom has been replaced with at least one non hydrogen group, such as a hydrocarbyl group, a heteroatom or heteroatom-containing group, such as halogen (such as Br, Cl, F or I) or at least one functional group such as -NR* 2 , -OR*, -SeR*, -TeR*, -PR*2, -ASR* 2 , -SbR* 2 , -SR*, -BR* 2 , -SiR* 3 , -GeR* 3 , -SnR* , -PbR* , -(CH 2 ) q -SiR* 3 , and the like, where q is 1 to 10 and each R* is independently hydrogen, a hydrocarbyl or halocarbyl radical, and two or more
• substituted hydrocarbyl means a hydrocarbyl radical in which at least one hydrogen atom of the hydrocarbyl radical has been substituted with at least one heteroatom (such as halogen, e.g., Br, Cl, F or I) or heteroatom-containing group (such as a functional group, e.g., -NR* 2 , -OR*, -SeR*, -TeR*, -PR* 2 , -AsR* 2 , -SbR* 2 , -SR*, -BR* 2 , -SiR* 3 , -GeR* 3 , -SnR* , -PbR* 3 , -(CH 2 ) q -SiR* 3 , and the like, where q is 1 to 10 and each R* is independently hydrogen, a hydrocarbyl or halocarbyl radical, and two or more R* may join together to form a substituted -SiR* 3 ,
• aryl or "aryl group” means an aromatic ring (typically made of 6 carbon atoms) and the substituted variants thereof, such as phenyl, 2-methyl-phenyl, xylyl, 4-bromo-xylyl.
• heteroaryl means an aryl group where a ring carbon atom (or two or three ring carbon atoms) has been replaced with a heteroatom, such as N, O, or S.
• aromatic also refers to pseudoaromatic heterocycles which are heterocyclic substituents that have similar properties and structures (nearly planar) to aromatic heterocyclic ligands, but are not by definition aromatic.
• substituted aromatic means an aromatic group having 1 or more hydrogen groups replaced by a hydrocarbyl, substituted hydrocarbyl, heteroatom or heteroatom containing group.
• a "substituted phenolate” is a phenolate group where at least one, two, three, four or five hydrogen atoms in the 2, 3, 4, 5, and/or 6 positions has been replaced with at least one non hydrogen group, such as a hydrocarbyl group, a heteroatom or heteroatom-containing group, such as halogen (such as Br, Cl, F or I) or at least one functional group such as -NR* 2 , -OR*, -SeR*, -TeR*, -PR*2, -ASR* 2 , -SbR* 2 , -SR*, -BR* 2 , -SiR* 3 , -GeR* , -SnR* , -PbR* , -(CH 2 ) q -SiR* 3 , and the like, where q is 1 to 10 and each R* is independently hydrogen, a hydrocarbyl or halocarbyl radical, and two or more R
• a "substituted phenolate" group in the catalyst compounds described herein is represented by the formula: where R 18 is hydrogen, C 1 -C 40 hydrocarbyl (such as C 1 -C 40 alkyl) or C 1 -C 40 substituted hydrocarbyl, a heteroatom or a hetero atom-containing group, E 17 is oxygen, sulfur, or NR 17 , and each of R 17 , R 19 , R 20 , and R 21 is independently selected from hydrogen, C 1 -C 40 hydrocarbyl (such as C 1 -C 40 alkyl) or C 1 -C 40 substituted hydrocarbyl, a heteroatom or a heteroatom-containing group, or two or more of R 18 , R 19 , R 20 , and R 21 are joined together to form a C 4 -C 62 cyclic or polycyclic ring structure, or a combination thereof, and the wavy lines show where the substituted phenolate group forms bonds to the rest of the catalyst compound.
• alkyl substituted phenolate is a phenolate group where at least one, two, three, four or five hydrogen atoms in the 2, 3, 4, 5, and/or 6 positions has been replaced with at least one alkyl group, such as a Ci to C 40 , alternately C 2 to C 20 , alternately C 3 to C 12 alkyl, such as methyl, ethyl, methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, sec-butyl, tert-butyl, pentyl, iso-amyl, hexyl, octyl cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cyclooctyl, adamantanyl and the like including their substituted analogues.
• alkyl group such as a Ci to C 40 , alternately C 2 to C 20 , alternately C 3 to
• An "aryl substituted phenolate” is a phenolate group where at least one, two, three, four or five hydrogen atoms in the 2, 3, 4, 5, and/or 6 positions has been replaced with at least one aryl group, such as a Ci to C 40 , alternately C 2 to C 20 , alternately C 3 to C 12 aryl group, such as phenyl, 4-fluorophenyl, 2-methylphenyl, 2-propylphenyl, 2,6-dimethylphenyl, mesityl, 2-ethylphenyl, naphthalenyl and the like including their substituted analogues.
• aryl group such as a Ci to C 40 , alternately C 2 to C 20 , alternately C 3 to C 12 aryl group, such as phenyl, 4-fluorophenyl, 2-methylphenyl, 2-propylphenyl, 2,6-dimethylphenyl, mesityl, 2-ethylphenyl, naphthalen
• a "group 4 bis(phenolate) catalyst compound” is a complex of a group 4 transition metal (Ti, Zr, or Hf) that is coordinated by a tri- or tetradentate ligand that is dianionic, wherein the anionic donor groups are phenolate anions.
• ring atom means an atom that is part of a cyclic ring structure.
• a benzyl group has six ring atoms and tetrahydrofuran has 5 ring atoms.
• a heterocyclic ring also referred to as a heterocyclic, is a ring having a heteroatom in the ring structure as opposed to a “heteroatom- substituted ring” where a hydrogen on a ring atom is replaced with a heteroatom.
• a heteroatom- substituted ring For example, tetrahydrofuran is a heterocyclic ring and 4-N,N- dimethylamino-phenyl is a heteroatom substituted ring.
• a substituted heterocyclic ring means a heterocyclic ring having 1 or more hydrogen groups replaced by a hydrocarbyl, substituted hydrocarbyl, heteroatom or heteroatom containing group.
• a substituted hydrocarbyl ring means a ring comprised of carbon and hydrogen atoms having 1 or more hydrogen groups replaced by a hydrocarbyl, substituted hydrocarbyl, heteroatom or heteroatom containing group.
• the term “substituted” means that a hydrogen group has been replaced with a hydrocarbyl group, a heteroatom or heteroatom-containing group, such as halogen (such as Br, Cl, F or I) or at least one functional group such as -NR* 2 , -OR*, -SeR*, -TeR*, -PR* 2 , -AsR* 2 , -SbR* 2 , -SR*, -BR* 2 , -SiR* 3 , -GeR* 3 , -SnR* , -PbR* , -(CH 2 ) q -SiR* 3 , and the like, where q is 1 to 10 and each R* is independently hydrogen, a hydrocarbyl or halocarbyl radical, and two or more R* may join together to form
• a tertiary hydrocarbyl group possesses a carbon atom bonded to three other carbon atoms.
• tertiary hydrocarbyl groups are also referred to as tertiary alkyl groups.
• tertiary hydrocarbyl groups include tert-butyl, 2-methylbutan-2-yl, 2-methylhexan-2-yl, 2-phenylpropan-2-yl, 2-cyclohexylpropan-2-yl, 1-methylcyclohexyl, 1-adamantyl, bicyclo[2.2.1]heptan-l-yl and the like.
• Tertiary hydrocarbyl groups can be illustrated by formula A: wherein RA, RB and RC are hydrocarbyl groups or substituted hydrocarbyl groups that may optionally be bonded to one another, and the wavy line shows where the tertiary hydrocarbyl group forms bonds to other groups.
• a cyclic tertiary hydrocarbyl group is defined as a tertiary hydrocarbyl group that forms at least one alicyclic (non-aromatic) ring. Cyclic tertiary hydrocarbyl groups are also referred to as alicyclic tertiary hydrocarbyl groups. When the hydrocarbyl group is an alkyl group, cyclic tertiary hydrocarbyl groups are also referred to as cyclic tertiary alkyl groups or alicyclic tertiary alkyl groups.
• cyclic tertiary hydrocarbyl groups include 1-adamantanyl, 1-methylcyclohexyl, 1-methylcyclopentyl, 1-methylcyclooctyl, 1-methylcyclodecyl, 1-methylcyclododecyl, bicyclo[3.3.1]nonan-l-yl, bicyclo[2.2.1]heptan-l-yl, bicyclo[2.3.3]hexan- 1-yl, bicycle[l.l.l]pentan-l-yl, bicycle[2.2.2]octan-l-yl, and the like. Cyclic tertiary hydrocarbyl groups can be illustrated by formula B:
• RA is a hydrocarbyl group or substituted hydrocarbyl group
• each RD is independently hydrogen or a hydrocarbyl group or substituted hydrocarbyl group
• w is an integer from 1 to about 30, and RA, and one or more RD, and or two or more RD may optionally be bonded to one another to form additional rings.
• a cyclic tertiary hydrocarbyl group contains more than one alicyclic ring, it can be referred to as polycyclic tertiary hydrocarbyl group or if the hydrocarbyl group is an alkyl group, it may be referred to as a polycyclic tertiary alkyl group.
• alkyl radical and “alkyl” are used interchangeably throughout this disclosure.
• alkyl radical is defined to be Ci-Cioo alkyls, that may be linear, branched, or cyclic.
• radicals can include methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, sec -butyl, tert-butyl, pentyl, iso-amyl, hexyl, octyl cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cyclooctyl, and the like including their substituted analogues.
• Substituted alkyl radicals are radicals in which at least one hydrogen atom of the alkyl radical has been substituted with at least a non-hydrogen group, such as a hydrocarbyl group, a heteroatom or heteroatom-containing group, such as halogen (such as Br, Cl, F or I) or at least one functional group such as -NR*2, -OR*, -SeR*, -TeR*, -PR*2, -AsR*2, -SbR*2, -SR*, -BR*2, -SiR*3, -GeR*3, -SnR*3, -PbR*3, -(CFb)q-SiR*3, and the like, where q is 1 to 10 and each R* is independently hydrogen, a hydrocarbyl or halocarbyl radical, and two or more R* may join together to form a substituted or unsubstituted completely saturated, partially unsaturated, or aromatic cyclic or polycyclic
• isomers of a named alkyl, alkenyl, alkoxide, or aryl group exist (e.g., n-butyl, iso-butyl, sec -butyl, and tert-butyl) reference to one member of the group (e.g., n-butyl) shall expressly disclose the remaining isomers (e.g., iso-butyl, sec-butyl, and tert-butyl) in the family.
• alkyl, alkenyl, alkoxide, or aryl group without specifying a particular isomer (e.g., butyl) expressly discloses all isomers (e.g., n-butyl, iso-butyl, sec-butyl, and tertbutyl).
• Mn is number average molecular weight
• Mw is weight average molecular weight
• Mz is z average molecular weight
• wt% is weight percent
• mol% is mole percent.
• Molecular weight distribution also referred to as polydispersity index (PDI)
• PDI polydispersity index
• Me is methyl
• Et is ethyl
• Pr is propyl
• cPr is cyclopropyl
• nPr is n-propyl
• iPr is isopropyl
• Bu is butyl
• nBu is normal butyl
• iBu is isobutyl
• sBu is sec-butyl
• tBu is tert-butyl
• Oct octyl
• Ph is phenyl
• MAO is methylalumoxane
• dme also referred to as DME
• p-tBu is para-tertiary butyl
• TMS is trimethylsilyl
• TIBAL is triisobutylaluminum
• TNOA and TNOAL are tri(n-octyl) aluminum
• p- Me is para-methyl
• Bn is benzyl (i.e., CtbPh)
• a “catalyst system” is a combination comprising at least one catalyst compound and at least one activator.
• Catalyst system means the unactivated catalyst complex (precatalyst) together with an activator and, optionally, a co-activator.
• it means the activated complex and the activator or other charge-balancing moiety.
• the transition metal compound may be neutral as in a precatalyst, or a charged species with a counter ion as in an activated catalyst system.
• catalyst systems are described as comprising neutral stable forms of the components, it is well understood by one of ordinary skill in the art, that the ionic form of the component is the form that reacts with the monomers to produce polymers.
• a polymerization catalyst system is a catalyst system that can polymerize monomers to polymer.
• the catalyst may be described as a catalyst, a catalyst precursor, a pre-catalyst compound, catalyst compound or a transition metal compound, and these terms are used interchangeably.
• anionic ligand is a negatively charged ligand which donates one or more pairs of electrons to a metal ion.
• anionic donor is used interchangeably with “anionic ligand”.
• anionic donors in the context of the present invention include, but are not limited to, methyl, chloride, fluoride, alkoxide, aryloxide, alkyl, alkenyl, thiolate, carboxylate, amido, methyl, benzyl, hydrido, amidinate, amidate, and phenyl. Two anionic donors may be joined to form a dianionic group.
• a “neutral Lewis base or “neutral donor group” is an uncharged (i.e. neutral) group which donates one or more pairs of electrons to a metal ion.
• neutral Lewis bases include ethers, thioethers, amines, phosphines, ethyl ether, tetrahydrofuran, dimethylsulfide, triethylamine, pyridine, alkenes, alkynes, alenes, and carbenes.
• Lewis bases may be joined together to form bidentate or tridentate Lewis bases.
• phenolate donors include Ph-O-, Ph-S-, and Ph-N(R A )- groups, where R A is hydrogen, C 1 -C 40 hydrocarbyl, C 1 -C 40 substituted hydrocarbyl, a heteroatom or a heteroatom-containing group, and Ph is optionally substituted phenyl.
• This invention relates solution processes to produce polymers of diene monomer and alpha olefins (such as ethylene and propylene) using a new catalyst family comprising transition metal complexes of a dianionic, tridentate ligand that features a central neutral donor group and two phenolate donors, where the tridentate ligands coordinate to the metal center to form two eight- membered rings.
• the central neutral donor it is advantageous for the central neutral donor to be a heterocyclic group. It is particularly advantageous for the heterocyclic group to lack hydrogens in the position alpha to the heteroatom.
• the phenolates In complexes of this type it is also advantageous for the phenolates to be substituted with one or more cyclic tertiary alkyl substituents. The use of cyclic tertiary alkyl substituted phenolates is demonstrated to improve the ability of these catalysts to produce high molecular weight polymer.
• Complexes of substituted bis(phenolate) ligands (such as adamantanyl-substituted bis(phenolate) ligands) useful herein form active olefin polymerization catalysts when combined with activators, such as non-coordinating anion or alumoxane activators.
• Useful bis(aryl phenolate)pyridine complexes comprise a tridentate bis(aryl phenolate)pyridine ligand that is coordinated to a group 4 transition metal with the formation of two eight-membered rings.
• This invention also relates to solution processes to produce ethylene-alpha-olefin- diene-monomer copolymers utilizing a metal complex comprising: a metal selected from groups 3-6 or Lanthanide metals, and a tridentate, dianionic ligand containing two anionic donor groups and a neutral Lewis base donor, wherein the neutral Lewis base donor is covalently bonded between the two anionic donors, and wherein the metal-ligand complex features a pair of 8- membered metallocycle rings.
• This invention relates to catalyst systems used in solution processes to prepare ethylene-alpha-olefin-diene-monomer copolymers comprising activator and one or more catalyst compounds as described herein.
• This invention also relates to solution processes (preferably at higher temperatures) to polymerize olefins using the catalyst compounds described herein comprising contacting ethylene, C3-C20 alpha olefin (such as propylene) and one or more diene comonomers with a catalyst system comprising an activator and a catalyst compound described herein.
• the present disclosure also relates to a catalyst system comprising a transition metal compound and an activator compound as described herein, to the use of such activator compounds for activating a transition metal compound in a catalyst system for polymerizing ethylene, C3-C20 alpha olefin (such as propylene) and one or more diene comonomers , and to processes for polymerizing said olefins, the process comprising contacting under polymerization conditions ethylene, C3-C20 alpha olefin (such as propylene) and one or more diene comonomers with a catalyst system comprising a transition metal compound and activator compounds, where aromatic solvents, such as toluene, are absent (e.g.
• detecttable aromatic hydrocarbon solvent means 0.1 mg/m 3 or more as determined by gas phase chromatography.
• detecttable toluene means 0.1 mg/m 3 or more as determined by gas phase chromatography.
• the copolymers produced herein preferably contain 0 ppm (alternately less than 1 ppm) of aromatic hydrocarbon.
• the copolymers produced herein contain 0 ppm (alternately less than 1 ppm) of toluene.
• the catalyst systems used herein preferably contain 0 ppm (alternately less than 1 ppm) of aromatic hydrocarbon.
• the catalyst systems used herein contain 0 ppm (alternately less than 1 ppm) of toluene.
• catalyst “compound”, “catalyst compound”, and “complex” may be used interchangeably to describe a transition metal or Lanthanide metal complex that forms an olefin polymerization catalyst when combined with a suitable activator.
• the catalyst complexes of the present invention comprise a metal selected from groups 3, 4, 5 or 6 or Lanthanide metals of the Periodic Table of the Elements, a tridentate dianionic ligand containing two anionic donor groups and a neutral heterocyclic Lewis base donor, wherein the heterocyclic donor is covalently bonded between the two anionic donors.
• a metal selected from groups 3, 4, 5 or 6 or Lanthanide metals of the Periodic Table of the Elements
• a tridentate dianionic ligand containing two anionic donor groups and a neutral heterocyclic Lewis base donor, wherein the heterocyclic donor is covalently bonded between the two anionic donors.
• the dianionic, tridentate ligand features a central heterocyclic donor group and two phenolate donors and the tridentate ligand coordinates to the metal center to form two eight-membered rings.
• the metal is preferably selected from group 3, 4, 5, or 6 elements.
• the metal, M is a group 4 metal.
• the metal, M is zirconium or hafnium.
• the heterocyclic Lewis base donor features a nitrogen or oxygen donor atom.
• Preferred heterocyclic groups include derivatives of pyridine, pyrazine, pyrimidine, triazine, thiazole, imidazole, thiophene, oxazole, thiazole, furan, and substituted variants of thereof.
• the heterocyclic Lewis base lacks hydrogen(s) in the position alpha to the donor atom.
• Particularly preferred heterocyclic Lewis base donors include pyridine, 3-substituted pyridines, and 4-substituted pyridines.
• the anionic donors of the tridentate dianionic ligand may be arylthiolates, phenolates, or anilides. Preferred anionic donors are phenolates. It is preferred that the tridentate dianionic ligand coordinates to the metal center to form a complex that lacks a mirror plane of symmetry. It is preferred that the tridentate dianionic ligand coordinates to the metal center to form a complex that has a two-fold rotation axis of symmetry; when determining the symmetry of the bis(phenolate) complexes only the metal and dianionic tridentate ligand are considered (i.e. ignore remaining ligands).
• the bis(phenolate) ligands useful in the present invention include dianionic multidentate ligands that feature two anionic phenolate donors.
• the bis(phenolate) ligands are tridentate dianionic ligands that coordinate to the metal M in such a fashion that a pair of 8-membered metallocycle rings are formed.
• the preferred bis(phenolate) ligands wrap around the metal to form a complex with a 2-fold rotation axis, thus giving the complexes C2 symmetry.
• the C2 geometry and the 8-membered metallocycle rings are features of these complexes that make them effective catalyst components for the production of polyolefins, particularly isotactic poly(alpha olefins). If the ligands were coordinated to the metal in such a manner that the complex had mirror-plane (Cs) symmetry, then the catalyst would be expected to produce only atactic poly(alpha olefins); these symmetry-reactivity rules are summarized by Bercaw in Macromolecules 2009, v.42, pp. 8751-8762.
• the pair of 8-membered metallocycle rings of the inventive complexes is also a notable feature that is advantageous for catalyst activity, temperature stability, and isoselectivity of monomer enchainment.
• Related group 4 complexes featuring smaller 6-membered metallocycle rings are known (. Macromolecules 2009, v.42, pp. 8751-8762) to form mixtures of C2 and C s symmetric complexes when used in olefin polymerizations and are thus not well suited to the production of highly isotactic poly(alpha olefins).
• Bis(phenolate) ligands that contain oxygen donor groups are preferably substituted with alkyl, substituted alkyl, aryl, or other groups. It is advantageous that each phenolate group be substituted in the ring position that is adjacent to the oxygen donor atom. It is preferred that substitution at the position adjacent to the oxygen donor atom be an alkyl group containing 1-20 carbon atoms. It is preferred that substitution at the position next to the oxygen donor atom be a non-aromatic cyclic alkyl group with one or more five- or six-membered rings.
• substitution at the position next to the oxygen donor atom be a cyclic tertiary alkyl group. It is highly preferred that substitution at the position next to the oxygen donor atom be adamantan-l-yl or substituted adamantan-l-yl.
• the neutral heterocyclic Lewis base donor is covalently bonded between the two anionic donors via “linker groups” that join the heterocyclic Lewis base to the phenolate groups.
• the “linker groups” are indicated by (A 3 A 2 ) and (A 2 A 3 ) in Formula (I). The choice of each linker group may affect the catalyst performance, such as the tacticity of the poly(alpha olefin) produced.
• Each linker group is typically a C2-C40 divalent group that is two-atoms in length.
• One or both linker groups may independently be phenylene, substituted phenylene, heteroaryl, vinylene, or a non-cyclic two-carbon long linker group.
• the alkyl substituents on the phenylene group may be chosen to optimize catalyst performance.
• one or both phenylenes may be unsubstituted or may be independently substituted with Ci to C20 alkyl, such as methyl, ethyl, propyl, butyl, pentyl, hexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, octadecyl, nonadecyl, eicosyl, or an isomer thereof, such as isopropyl, etc.
• Ci to C20 alkyl such as methyl, ethyl, propyl, butyl, pentyl, hexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl, tridecyl, t
• This invention further relates to catalyst compounds, and catalyst systems comprising such compounds, represented by the Formula (I): wherein:
• M is a group 3, 4, 5, or 6 transition metal or a Lanthanide (such as Hf, Zr or Ti);
• E and E' are each independently O, S, or NR 9 , where R 9 is independently hydrogen, C1-C40 hydrocarbyl, C1-C40 substituted hydrocarbyl, or a heteroatom-containing group, preferably O, preferably both E and E' are O;
• Q is group 14, 15, or 16 atom that forms a dative bond to metal M, preferably Q is C, O, S or N, more preferably Q is C, N or O, most preferably Q is N;
• A'QA 1 are part of a heterocyclic Lewis base containing 4 to 40 non-hydrogen atoms that links A 2 to A 2 via a 3-atom bridge with Q being the central atom of the 3-atom bridge (A'QA 1 combined with the curved line joining A 1 and A 1 represents the heterocyclic Lewis base),
• a 1 and A 1 are independently C, N, or C(R 22 ), where R 22 is selected from hydrogen, C1-C20 hydrocarbyl, and C1-C20 substituted hydrocarbyl.
• a 1 and A 1 are C;
• a 3 - A 2 is a divalent group containing 2 to 40 non-hydrogen atoms that links A to the E-bonded aryl group via a 2-atom bridge, such as ortho-phenylene, substituted ortho- phenylene, ortho-arene, indolene, substituted indolene, benzothiophene, substituted benzothiophene, pyrrolene, substituted pyrrolene, thiophene, substituted thiophene, 1,2-ethylene
• a 2 is a divalent hydrocarbyl group
• This invention is further related to catalyst compounds, and catalyst systems comprising such compounds, represented by the Formula (II): wherein:
• M is a group 3, 4, 5, or 6 transition metal or a Lanthanide (such as Hf, Zr or Ti); E and E' are each independently O, S, or NR 9 , where R 9 is independently hydrogen, C1-C40 hydrocarbyl, C1-C40 substituted hydrocarbyl, or a heteroatom-containing group, preferably O, preferably both E and E' are O; each L is independently a Lewis base; each X is independently an anionic ligand; n is 1, 2 or 3; m is 0, 1, or 2; n+m is not greater than 4; each of R 1 , R 2 , R 3 , R 4 , R 1 , R 2 , R 3 , and R 4 is independently hydrogen, C1-C40 hydrocarbyl, C1-C40 substituted hydrocarbyl, a heteroatom or a heteroatom-containing group, or one or more of R 1 and R 2 , R 2 and R 3 , R 3 and R 4 , R 1 and R 2 , R 2 and R
• the metal, M is preferably selected from group 3, 4, 5, or 6 elements, more preferably group 4. Most preferably the metal, M, is zirconium or hafnium.
• the donor atom Q of the neutral heterocyclic Lewis base is preferably nitrogen, carbon, or oxygen. Preferred Q is nitrogen.
• Non-limiting examples of neutral heterocyclic Lewis base groups include derivatives of pyridine, pyrazine, pyrimidine, triazine, thiazole, imidazole, thiophene, oxazole, thiazole, furan, and substituted variants of thereof.
• Preferred heterocyclic Lewis base groups include derivatives of pyridine, pyrazine, thiazole, and imidazole.
• Each A 1 and A 1 of the heterocyclic Lewis base (in Formula (I)) are independently C, N, or C(R 22 ), where R 22 is selected from hydrogen, C 1 -C 20 hydrocarbyl, and C 1 -C 20 substituted hydrocarbyl.
• Preferably A1 and Al' are carbon.
• Q is carbon
• a 1 and A 1 be selected from nitrogen and C(R 22 ).
• Q nitrogen
• the heterocyclic Lewis base in Formula (I) not have any hydrogen atoms bound to the Al or A 1 atoms.
• the heterocyclic Lewis base (of Formula (I)) represented by A 'QA 1 combined with the curved line joining A 1 and A 1 is preferably selected from the following, with each R 23 group selected from hydrogen, heteroatoms, C 1 -C 20 alkyls, C 1 -C 20 alkoxides, C 1 -C 20 amides, and C 1 -C 20 substituted alkyls.
• E and E’ are each selected from oxygen or NR9, where R9 is independently hydrogen, C 1 -C 40 hydrocarbyl, C 1 -C 40 substituted hydrocarbyl, or a heteroatom- containing group. It is preferred that E and E’ are oxygen. When E and/or E’ are NR 9 it is preferred that R 9 be selected from Ci to C 20 hydrocarbyls, alkyls, or aryls.
• E and E’ are each selected from O, S, or N(alkyl) or N(aryl), where the alkyl is preferably a Ci to C 20 alkyl, such as methyl, ethyl, propyl, butyl, pentyl, hexyl, octyl, nonyl, decyl, undecyl, dodceyl and the like, and aryl is a Ce to C 40 aryl group, such as phenyl, naphthalenyl, benzyl, methylphenyl, and the like.
• alkyl is preferably a Ci to C 20 alkyl, such as methyl, ethyl, propyl, butyl, pentyl, hexyl, octyl, nonyl, decyl, undecyl, dodceyl and the like
• aryl is a Ce to C 40 aryl group, such as phenyl, naphthal
• a 3 — A 2 and A 2 '— A 3 are independently a divalent hydrocarbyl group, such as Ci to C 12 hydrocarbyl group.
• each of R 1 and R 1 is independently a C 1 -C 40 hydrocarbyl, a C 1 -C 40 substituted hydrocarbyl, a heteroatom or a heteroatom-containing group, more preferably, each of R 1 and R 1 is independently a non-aromatic cyclic alkyl group with one or more five- or six-membered rings (such as cyclohexyl, cyclooctyl, adamantanyl, or 1-methylcyclohexyl, or substituted adamantanyl), most preferably a non-aromatic cyclic tertiary alkyl group (such as 1-methylcyclohexyl, adamantanyl, or substituted adamantanyl).
• each of R 1 and R 1 is independently a tertiary hydrocarbyl group. In other embodiments of the invention of Formula (I) or (II), each of R 1 and R 1 is independently a cyclic tertiary hydrocarbyl group. In other embodiments of the invention of Formula (I) or (II), each of R 1 and R 1 is independently a polycyclic tertiary hydrocarbyl group.
• each of R 1 and R 1 is independently a tertiary hydrocarbyl group. In other embodiments of the invention of Formula (I) or (II), each of R 1 and R 1 is independently a cyclic tertiary hydrocarbyl group. In other embodiments of the invention of Formula (I) or (II), each of R 1 and R 1 is independently a polycyclic tertiary hydrocarbyl group.
• the linker groups are each preferably part of an ortho-phenylene group, preferably a substituted ortho-phenylene group. It is preferred for the R 7 and R 7 positions of Formula (II) to be hydrogen, or Ci to C20 alkyl, such as methyl, ethyl, propyl, butyl, pentyl, hexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, octadecyl, nonadecyl, eicosyl, or an isomer thereof, such as iospropyl, etc. For applications targeting polymers with high tacticity it is preferred for the R 7 and R 7 positions of Formula (II) to be
• Q is C, N or O, preferably Q is N.
• a 1 and A 1 are independently carbon, nitrogen, or C(R 22 ), with R 22 selected from hydrogen, Ci to C20 hydrocarbyl, Ci to C20 substituted hydrocarbyl.
• R 22 selected from hydrogen, Ci to C20 hydrocarbyl, Ci to C20 substituted hydrocarbyl.
• a 1 and A 1 are carbon.
• A'QA 1 in Formula (I) is part of a heterocyclic Lewis base, such as a pyridine, pyrazine, pyrimidine, triazine, thiazole, imidazole, thiophene, oxazole, thiazole, furan, or a substituted variant of thereof.
• a heterocyclic Lewis base such as a pyridine, pyrazine, pyrimidine, triazine, thiazole, imidazole, thiophene, oxazole, thiazole, furan, or a substituted variant of thereof.
• A'QA 1 are part of a heterocyclic Lewis base containing 2 to 20 non-hydrogen atoms that links A 2 to A 2 via a 3 -atom bridge with Q being the central atom of the 3-atom bridge.
• each A 1 and A 1 is a carbon atom and the A 'QA 1 fragment forms part of a pyridine, pyrazine, pyrimidine, triazine, thiazole, imidazole, thiophene, oxazole, thiazole, furan, or a substituted variant of thereof group, or a substituted variant thereof.
• Q is carbon, and each A 1 and A 1 is N or C(R 22 ), where R 22 is selected from hydrogen, Ci to C20 hydrocarbyl, Ci to C20 substituted hydrocarbyl, a heteroatom or a heteroatom-containing group.
• R 22 is selected from hydrogen, Ci to C20 hydrocarbyl, Ci to C20 substituted hydrocarbyl, a heteroatom or a heteroatom-containing group.
• the A X QA X fragment forms part of a cyclic carbene, N-heterocyclic carbene, cyclic amino alkyl carbene, or a substituted variant of thereof group, or a substituted variant thereof.
• ⁇ is a linear alkyl or forms part of a cyclic group (such as an optionally substituted ortho-phenylene group, or ortho-arylene group) or a substituted variant thereof.
• a 2' -A 3 is a divalent group containing 2 to 20 non-hydrogen atoms that links A 1
• M is a group 4 metal, such as Hf or Zr.
• E and E' are O.
• R 1 , R 2 , R 3 , R 4 , R 1 , R 2 , R 3 , and R 4 is independently hydrogen, C1-C40 hydrocarbyl, C1-C40 substituted hydrocarbyl, a heteroatom or a heteroatom-containing group, or one or more of R 1 and R 2 , R 2 and R 3 , R 3 and R 4 , R 1 and R 2 , R 2 and R 3 , R 3 and R 4 may be joined to form one or more substituted hydrocarbyl rings, unsubstituted hydrocarbyl rings, substituted heterocyclic rings, or unsubstituted heterocyclic rings each having 5, 6, 7, or 8 ring atoms, and where substitutions on the ring can join to form additional rings, preferably hydrogen, methyl, ethyl, propyl, butyl, pentyl, hexyl, or an isomer thereof.
• R 1 , R 2 , R 3 , R 4 , R 1 , R 2 , R 3 , R 4 , and R 9 are independently selected from methyl, ethyl, propyl, butyl, pentyl, hexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, octadecyl, nonadecyl, eicosyl, heneicosyl, docosyl, tricosyl, tetracosyl, pentacosyl, hexacosyl, heptacosyl, octacosyl, nonacosyl, triacontyl, phenyl, substituted
• R 4 and R 4 is independently hydrogen or a Ci to C3 hydrocarbyl, such as methyl, ethyl or propyl.
• R 9 is hydrogen, C1-C40 hydrocarbyl, C1-C40 substituted hydrocarbyl, or a heteroatom-containing group, preferably hydrogen, methyl, ethyl, propyl, butyl, pentyl, hexyl, or an isomer thereof.
• R 9 is methyl, ethyl, propyl, butyl, Ci to Ce alkyl, phenyl, 2-methylphenyl, 2,6-dimethylphenyl, or 2,4,6- trimethylphenyl .
• each X is, independently, selected from the group consisting of hydrocarbyl radicals having from 1 to 20 carbon atoms (such as alkyls or aryls), hydrides, amides, alkoxides, sulfides, phosphides, halides, alkyl sulfonates, and a combination thereof, (two or more X’s may form a part of a fused ring or a ring system), preferably each X is independently selected from halides, aryls, and Ci to C 5 alkyl groups, preferably each X is independently a hydrido, dimethylamido, diethylamido, methyltrimethylsilyl, neopentyl, phenyl, benzyl, methyl, ethyl, propyl, butyl, pentyl, fluoro, iodo, bromo
• each L is a Lewis base, independently, selected from the group consisting of ethers, thio-ethers, amines, nitriles, imines, pyridines, halocarbons, and phosphines, preferably ethers and thioethers, and a combination thereof, optionally two or more L’s may form a part of a fused ring or a ring system, preferably each L is independently selected from ether and thioether groups, preferably each L is a ethyl ether, tetrahydrofuran, dibutyl ether, or dimethylsulfide group.
• R 1 and R 1 are independently cyclic tertiary alkyl groups.
• n is 1, 2 or 3, typically 2.
• m is 0, 1 or 2, typically 0.
• R 1 and R 1 are not hydrogen.
• M is Hf or Zr, E and E' are O; each of R 1 and R 1 is independently a C1-C40 hydrocarbyl, a C1-C40 substituted hydrocarbyl, a heteroatom or a heteroatom-containing group, each R 2 , R 3 , R 4 , R 2 , R 3 , and R 4 is independently hydrogen, Ci to C20 hydrocarbyl, Ci to C20 substituted hydrocarbyl, a heteroatom or a hetero atom-containing group, or one or more of R 1 and R 2 , R 2 and R 3 , R 3 and R 4 , R 1 and R 2 , R 2 and R 3 , R 3 and R 4 may be joined to form one or more substituted hydrocarbyl rings, unsubstituted hydrocarbyl rings, substituted heterocyclic rings, or unsubstituted heterocyclic rings each having 5, 6, 7, or 8 ring atoms, and where substitution
• each of R 5 , R 6 , R 7 , R 8 , R 5 , R 6 , R 7 , R 8 , R 10 , R 11 and R 12 is independently hydrogen, C1-C40 hydrocarbyl, C1-C40 substituted hydrocarbyl, a heteroatom or a heteroatom-containing group, or one or more adjacent R groups may be joined to form one or more substituted hydrocarbyl rings, unsubstituted hydrocarbyl rings, substituted heterocyclic rings, or unsubstituted heterocyclic rings each having 5, 6, 7, or 8 ring atoms, and where substitutions on the ring can join to form additional rings.
• each of R 5 , R 6 , R 7 , R 8 , R 5 , R 6 , R 7 , R 8 , R 10 , R 11 and R 12 is independently hydrogen, methyl, ethyl, propyl, butyl, pentyl, hexyl, or an isomer thereof.
• each of R 5 , R 6 , R 7 , R 8 , R 5 , R 6 , R 7 , R 8 , R 10 , R 11 and R 12 is are independently selected from methyl, ethyl, propyl, butyl, pentyl, hexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, octadecyl, nonadecyl, eicosyl, heneicosyl, docosyl, tricosyl, tetracosyl, pentacosyl, hexacosyl, heptacosyl, octacosyl, nonacosyl, triacontyl, phen
• M is Hf or Zr, E and E' are O; each of R 1 and R 1 is independently a C 1 -C 40 hydrocarbyl, a C 1 -C 40 substituted hydrocarbyl, a heteroatom or a heteroatom-containing group, each R 1 , R 2 , R 3 , R 4 , R 1 , R 2 , R 3 , and R 4 is independently hydrogen, Ci to C 20 hydrocarbyl, Ci to C 20 substituted hydrocarbyl, a heteroatom or a heteroatom-containing group, or one or more of R 1 and R 2 , R 2 and R 3 , R 3 and R 4 , R 1 and R 2 , R 2 and R 3 , R 3 and R 4 may be joined to form one or more substituted hydrocarbyl rings, unsubstituted hydrocarbyl rings, substituted heterocyclic rings, or unsubstituted heterocyclic rings each having 5, 6, 7, or 8 ring atom
• Preferred embodiment of Formula (I) is M is Zr or Hf, Q is nitrogen, both A 1 and A 1 are carbon, both E and E’ are oxygen, and both R 1 and R 1 are C4-C20 cyclic tertiary alkyls.
• Preferred embodiment of Formula (I) is M is Zr or Hf, Q is nitrogen, both A 1 and A 1 are carbon, both E and E’ are oxygen, and both R 1 and R 1 are adamantan-l-yl or substituted adamantan-l-yl.
• Preferred embodiment of Formula (II) is M is Zr or Hf, both E and E’ are oxygen, and both R 1 and R 1 are C4-C20 cyclic tertiary alkyls.
• Preferred embodiment of Formula (II) is M is Zr or Hf, both E and E’ are oxygen, and both R 1 and R 1 are adamantan-l-yl or substituted adamantan-l-yl.
• Preferred embodiment of Formula (II) is M is Zr or Hf, both E and E’ are oxygen, and each of R 1 , R 1 , R3 and R 3 are adamantan-l-yl or substituted adamantan-l-yl.
• Preferred embodiment of Formula (II) is M is Zr or Hf, both E and E’ are oxygen, both R 1 and R 1 are C4-C20 cyclic tertiary alkyls, and both R 7 and R 7 are C1-C20 alkyls.
• Catalyst compounds that are particularly useful in this invention include one or more of: dimethylzirconium[2',2"'-(pyridine-2,6-diyl)bis(3-adamantan-l-yl)-5-(tert-butyl)-[l,r- biphenyl] -2-olate)], dimethylhafnium[2',2"'-(pyridine-2,6-diyl)bis(3-adamantan-l-yl)-5-(tert- butyl)-[l,l'-biphenyl]-2-olate)], dimethylzirconium[6,6'-(pyridine-2,6- diylbis(benzo[b]thiophene-3,2-diyl))bis(2-adamantan-l-yl)-4-methylphenolate)], dimethylhafnium[6,6'-(pyridine-2,6-diylbis(benzo[b]thiophene-3,
• Catalyst compounds that are particularly useful in this invention include those represented by one or more of the formulas:
• two or more different catalyst compounds are present in the catalyst system used herein. In some embodiments, two or more different catalyst compounds are present in the reaction zone where the process(es) described herein occur. It is preferable to use the same activator for the transition metal compounds, however, two different activators, such as a non-coordinating anion activator and an alumoxane, can be used in combination. If one or more transition metal compounds contain an X group which is not a hydride, hydrocarbyl, or substituted hydrocarbyl, then the alumoxane can be contacted with the transition metal compounds prior to addition of the non-coordinating anion activator.
• two different activators such as a non-coordinating anion activator and an alumoxane
• the two transition metal compounds may be used in any ratio.
• Preferred molar ratios of (A) transition metal compound to (B) transition metal compound fall within the range of (A:B) 1:1000 to 1000:1, alternatively 1:100 to 500:1, alternatively 1:10 to 200:1, alternatively 1:1 to 100:1, and alternatively 1:1 to 75:1, and alternatively 5:1 to 50:1.
• the particular ratio chosen will depend on the exact pre-catalysts chosen, the method of activation, and the end product desired.
• useful mole percents are 10 to 99.9% A to 0.1 to 90% B, alternatively 25 to 99% A to 0.5 to 50% B, alternatively 50 to 99% A to 1 to 25% B, and alternatively 75 to 99% A to 1 to 10% B.
• the bis(phenol) ligands may be prepared using the general methods shown in Scheme 1.
• the formation of the bis(phenol) ligand by the coupling of compound A with compound B (method 1) may be accomplished by known Pd- and Ni-catalyzed couplings, such as Negishi, Suzuki, or Kumada couplings.
• the formation of the bis(phenol) ligand by the coupling of compound C with compound D (method 2) may also be accomplished by known Pd- and Ni- catalyzed couplings, such as Negishi, Suzuki, or Kumada couplings.
• Compound D may be prepared from compound E by reaction of compound E with either an organolithium reagent or magnesium metal, followed by optional reaction with a main-group metal halide (e.g.
• Compound E may be prepared in a non- catalyzed reaction from by the reaction of an aryllithium or aryl Grignard reagent (compound F) with a dihalogenated arene (compound G), such as l-bromo-2-chlorobenzene.
• Compound E may also be prepared in a Pd- or Ni-catalyzed reaction by reaction of an arylzinc or aryl-boron reagent (compound F) with a dihalogenated arene (compound G).
• X halogen compound E where M’ is a group 1, 2, 12, or 13 element or substituted element such as Li, MgCl, MgBr, ZnCl, B(OH)2, B(pinacolate), P is a protective group such as methoxymethyl (MOM), tetrahydropyranyl (THP), t-butyl, allyl, ethoxymethyl, trialkylsilyl, t-butyldimethylsilyl, or benzyl, R is a C1-C40 alkyl, substituted alkyl, aryl, tertiary alkyl, cyclic tertiary alkyl, adamantanyl, or substituted adamantanyl and each X' and X is halogen, such as Cl, Br, F or I.
• M is a group 1, 2, 12, or 13 element or substituted element such as Li, MgCl, MgBr, ZnCl, B(OH)2, B(pin
• the bis(phenol) ligand and intermediates used for the preparation of the bis(phenol) ligand are prepared and purified without the use of column chromatography. This may be accomplished by a variety of methods that include distillation, precipitation and washing, formation of insoluble salts (such as by reaction of a pyridine derivative with an organic acid), and liquid-liquid extraction. Preferred methods include those described in Practical Process Research and Development - A Guide for Organic Chemists by Neal C. Anderson (ISBN: 1493300125X). Synthesis of carbene bis(phenol) ligands
• the substituted bromophenol and an equivalent of dihydropyran is dissolved in methylene chloride and cooled to 0°C.
• a catalytic amount of para-toluenesulfonic acid is added and the reaction stirred for 10 min., then quenched with trimethylamine.
• the mixture is washed with water and brine, then dried over magnesium sulfate, filtered, and concentrated under reduced pressure to give a tetrahydropyran- protected phenol.
• Aryl bromide (compound I) is dissolved in THF and cooled to -78°C. n-Butyllithium is added slowly, followed by trimethoxy borate. The reaction is allowed to stir at ambient temperature until completion. The solvent is removed and the solid boronic ester washed with pentane.
• a boronic acid can be made from the boronic ester by treatment with HC1. The boronic ester or acid is dissolved in toluene with an equivalent of ortho-bromoaniline and a catalytic amount of palladium tetrakistriphenylphosphine. An aqueous solution of sodium carbonated is added and the reaction heated at reflux overnight.
• Transition metal or Lanthanide metal bis(phenolate) complexes are used as catalyst components for olefin polymerization in the present invention.
• the terms “catalyst” and “catalyst complex” are used interchangeably.
• the preparation of transition metal or Lanthanide metal bis(phenolate) complexes may be accomplished by reaction of the bis(phenol) ligand with a metal reactant containing anionic basic leaving groups. Typical anionic basic leaving groups include dialkylamido, benzyl, phenyl, hydrido, and methyl. In this reaction, the role of the basic leaving group is to deprotonate the bis(phenol) ligand.
• Suitable metal reagents also include ZrMe 4 , HfMe 4 , and other group 4 alkyls that may be formed in situ and used without isolation. Preparation of transition metal bis(phenolate) complexes is typically performed in etherial or hydrocarbon solvents or solvent mixtures at temperatures typically ranging from -80°C to 120°C.
• a second method for the preparation of transition metal or Lanthanide bis(phenolate) complexes is by reaction of the bis(phenol) ligand with an alkali metal or alkaline earth metal base (e.g., Na, BuLi, iPrMgBr) to generate deprotonated ligand, followed by reaction with a metal halide (e.g., HfCL, ZrCL) to form a bis(phenolate) complex.
• an alkali metal or alkaline earth metal base e.g., Na, BuLi, iPrMgBr
• a metal halide e.g., HfCL, ZrCL
• Bis(phenoate) metal complexes that contain metal-halide, alkoxide, or amido leaving groups may be alkylated by reaction with organolithium, Grignard, and organoaluminum reagents.
• the alkyl groups are transferred to the bis(phenolate) metal center and the leaving groups are removed.
• Reagents typically used for the alkylation reaction include, but are not limited to, MeLi, MeMgBr, AlMe 3 , Al(iBu) 3 , A10ct 3 , and PhCtbMgCl.
• 2 to 20 molar equivalents of the alkylating reagent are added to the bis(phenolate) complex.
• the alkylations are generally performed in etherial or hydrocarbon solvents or solvent mixtures at temperatures typically ranging from -80°C to 120°C.
• the catalyst systems described herein typically comprises a catalyst complex, such as the transition metal or Lanthanide bis(phenolate) complexes described above, and an activator such as alumoxane or a non-coordinating anion.
• a catalyst complex such as the transition metal or Lanthanide bis(phenolate) complexes described above
• an activator such as alumoxane or a non-coordinating anion.
• These catalyst systems may be formed by combining the catalyst components described herein with activators in any manner known from the literature.
• the catalyst systems may also be added to or generated in solution polymerization or bulk polymerization (in the monomer).
• Catalyst systems of the present disclosure may have one or more activators and one, two or more catalyst components.
• Activators are defined to be any compound which can activate any one of the catalyst compounds described above by converting the neutral metal compound to a catalytically active metal compound cation.
• Non limiting activators include alumoxanes, ionizing activators, which may be neutral or ionic, and conventional-type cocatalysts.
• Preferred activators typically include alumoxane compounds, modified alumoxane compounds, and ionizing anion precursor compounds that abstract a reactive metal ligand making the metal compound cationic and providing a charge balancing non-coordinating or weakly coordinating anion, e.g. a non-coordinating anion.
• Alumoxane Activators include alumoxanes, ionizing activators, which may be neutral or ionic, and conventional-type cocatalysts.
• Preferred activators typically include alumoxane compounds, modified alumoxane compounds, and ionizing anion precursor compounds that abstract a reactive metal ligand making the metal compound cationic and providing a charge balancing non-coordinating or weakly coordinating anion, e.g. a non-
• Alumoxane activators are utilized as activators in the catalyst systems described herein.
• Alumoxanes are generally oligomeric compounds containing -Al(R")-0- sub-units, where R 99 is an alkyl group.
• Examples of alumoxanes include methylalumoxane (MAO), modified methylalumoxane (MMAO), ethylalumoxane and isobutylalumoxane.
• Alkylalumoxanes and modified alkylalumoxanes are suitable as catalyst activators, particularly when the abstractable ligand is an alkyl, halide, alkoxide or amide.
• Alumoxane is a modified methyl alumoxane (MMAO) cocatalyst type 3A (commercially available from Akzo Chemicals, Inc. under the trade name Modified Methylalumoxane type 3A, covered under patent number US Patent No. 5,041,584).
• MMAO modified methyl alumoxane
• Another useful alumoxane is solid polymethylaluminoxane as described in US 9,340,630; US 8,404,880; and US 8,975,209.
• the activator is an alumoxane (modified or unmodified)
• typically the maximum amount of activator is at up to a 5,000-fold molar excess Al/M over the catalyst compound (per metal catalytic site).
• the minimum activator-to-catalyst-compound is a 1:1 molar ratio. Alternate preferred ranges include from 1:1 to 500:1, alternately from 1:1 to 200:1, alternately from 1:1 to 100:1, or alternately from 1:1 to 50:1.
• little or no alumoxane is used in the polymerization processes described herein.
• alumoxane is present at zero mole %, alternately the alumoxane is present at a molar ratio of aluminum to catalyst compound transition metal less than 500:1, preferably less than 300:1, preferably less than 100:1, preferably less than 1:1.
• non-coordinating anion means an anion which either does not coordinate to a cation or which is only weakly coordinated to a cation thereby remaining sufficiently labile to be displaced by a neutral Lewis base. Further, the anion will not transfer an anionic substituent or fragment to the cation so as to cause it to form a neutral transition metal compound and a neutral by-product from the anion.
• Non-coordinating anions useful in accordance with this invention are those that are compatible, stabilize the transition metal cation in the sense of balancing its ionic charge at +1, and yet retain sufficient lability to permit displacement during polymerization.
• NCA is also defined to include multicomponent NCA-containing activators, such as N,N-dimethylanilinium tetrakis(pentafluorophenyl)borate, that contain an acidic cationic group and the non-coordinating anion.
• NCA is also defined to include neutral Lewis acids, such as tris(pentafluorophenyl)boron, that can react with a catalyst to form an activated species by abstraction of an anionic group. Any metal or metalloid that can form a compatible, weakly coordinating complex may be used or contained in the non-coordinating anion. Suitable metals include, but are not limited to, aluminum, gold, and platinum. Suitable metalloids include, but are not limited to, boron, aluminum, phosphorus, and silicon.
• the activator is represented by the Formula (III):
• Z is (L-H) or a reducible Lewis Acid
• L is an neutral Lewis base
• H is hydrogen
• (L-H)+ is a Bronsted acid
• a d is a non-coordinating anion having the charge d
• d is an integer from 1 to 3 (such as 1, 2 or 3), preferably Z is (Ar3C + ), where Ar is aryl or aryl substituted with a heteroatom, a Ci to C40 hydrocarbyl, or a substituted Ci to C40 hydrocarbyl.
• each Q is a fluorinated hydrocarbyl group having 1 to 40 (such as 1 to 20) carbon atoms, more preferably each Q is a fluorinated aryl group, such as a perfluorinated aryl group and most preferably each Q is a pentafluoryl aryl group or perfluoronaphthalenyl group.
• suitable Ad- also include diboron compounds as disclosed in US Patent No. 5,447,895, which is fully incorporated herein by reference.
• Z When Z is the activating cation (L-H), it can be a Bronsted acid, capable of donating a proton to the transition metal catalytic precursor resulting in a transition metal cation, including ammoniums, oxoniums, phosphoniums, sulfoniums, and mixtures thereof, such as ammoniums of methylamine, aniline, dimethylamine, diethylamine, N-methylaniline, N-methyl-4-nonadecyl-N- octadecylaniline, N-methyl-4-octadecyl-N-octadecylaniline, diphenylamine, trimethylamine, triethylamine, N,N-dimethylaniline, methyldiphenylamine, pyridine, p-bromo N,N-dimethylaniline, p-nitro-N,N-dimethylaniline, dioctadecylmethylamine, phospho
• the activator is soluble in non- aromatic-hydrocarbon solvents, such as aliphatic solvents.
• a 20 wt% mixture of the activator compound in n-hexane, isohexane, cyclohexane, methylcyclohexane, or a combination thereof forms a clear homogeneous solution at 25°C, preferably a 30 wt% mixture of the activator compound in n-hexane, isohexane, cyclohexane, methylcyclohexane, or a combination thereof, forms a clear homogeneous solution at 25°C.
• the activators described herein have a solubility of more than 10 mM (or more than 20 mM, or more than 50 mM) at 25°C (stirred 2 hours) in methylcyclohexane.
• the activators described herein have a solubility of more than 1 mM (or more than 10 mM, or more than 20 mM) at 25°C (stirred 2 hours) in isohexane.
• the activators described herein have a solubility of more than 10 mM (or more than 20 mM, or more than 50 mM) at 25°C (stirred 2 hours) in methylcyclohexane and a solubility of more than 1 mM (or more than 10 mM, or more than 20 mM) at 25°C (stirred 2 hours) in isohexane.
• the activator is a non-aromatic -hydrocarbon soluble activator compound.
• Non-aromatic-hydrocarbon soluble activator compounds useful herein include those represented by the Formula (V): wherein:
• R , , and R are independently a Ci to C50 hydrocarbyl group optionally substituted with one or more alkoxy groups, silyl groups, a halogen atoms, or halogen containing groups, wherein R , R , and R together comprise 15 or more carbon atoms;
• Mt is an element selected from group 13 of the Periodic Table of the Elements, such as B or Al; and each Q is independently a hydride, bridged or unbridged dialkylamido, halide, alkoxide, aryloxide, hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, or halosubstituted-hydrocarbyl radical.
• Non-aromatic-hydrocarbon soluble activator compounds useful herein include those represented by the Formula (VI):
• Non-aromatic-hydrocarbon soluble activator compounds useful herein include those represented by the Formula (VII), wherein: E is nitrogen or phosphorous; R 1 is a methyl group; R 2 and R 3 are independently is C4-C50 hydrocarbyl group optionally substituted with one or more alkoxy groups, silyl groups, a halogen atoms, or halogen containing groups wherein R and R together comprise 14 or more carbon atoms; B is boron; and R 4 , R 5 , R 6 , and R 7 are independently hydride, bridged or unbridged dialkylamido, halide, alkoxide, aryloxide, hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, or halosubstituted-hydrocarbyl radical.
• Non-aromatic-hydrocarbon soluble activator compounds useful herein include those represented by the Formula (VII
• N is nitrogen
• R and R are independently is C 6 -C 40 hydrocarbyl group optionally substituted with one or more alkoxy groups, silyl groups, a halogen atoms, or halogen containing groups wherein R and R (if present) together comprise 14 or more carbon atoms;
• R 8 , R 9 , and R 10 are independently a C 4 -C 30 hydrocarbyl or substituted C 4 -C 30 hydrocarbyl group;
• R 4 , R 5 , R 6 , and R 7 are independently hydride, bridged or unbridged dialkylamido, halide, alkoxide, aryloxide, hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, or halosubstituted-hydrocarbyl radical.
• R 4 , R 5 , R 6 , and R are pentafluorophenyl.
• R 4 , R 5 , R 6 , and R 7 are pentafluoronaphthalenyl.
• R 8 and R 10 are hydrogen atoms and R 9 is a C 4 -C 30 hydrocarbyl group which is optionally substituted with one or more alkoxy groups, silyl groups, a halogen atoms, or halogen containing groups.
• R 9 is a C 8 -C 22 hydrocarbyl group which is optionally substituted with one or more alkoxy groups, silyl groups, a halogen atoms, or halogen containing groups.
• R and R are independently a C12-C22 hydrocarbyl group.
• R and R together comprise 15 or more carbon atoms (such as 18 or more carbon atoms, such as 20 or more carbon atoms, such as 22 or more carbon atoms, such as 25 or more carbon atoms, such as 30 or more carbon atoms, such as 35 or more carbon atoms, such as 38 or more carbon atoms, such as 40 or more carbon atoms, such as 15 to 100 carbon atoms, such as 25 to 75 carbon atoms).
• carbon atoms such as 18 or more carbon atoms, such as 20 or more carbon atoms, such as 22 or more carbon atoms, such as 25 or more carbon atoms, such as 30 or more carbon atoms, such as 35 or more carbon atoms, such as 38 or more carbon atoms, such as 40 or more carbon atoms, such as 15 to 100 carbon atoms, such as 25 to 75 carbon atoms).
• R and R ' together comprise 15 or more carbon atoms (such as 18 or more carbon atoms, such as 20 or more carbon atoms, such as 22 or more carbon atoms, such as 25 or more carbon atoms, such as 30 or more carbon atoms, such as 35 or more carbon atoms, such as 38 or more carbon atoms, such as 40 or more carbon atoms, such as 15 to 100 carbon atoms, such as 25 to 75 carbon atoms).
• carbon atoms such as 18 or more carbon atoms, such as 20 or more carbon atoms, such as 22 or more carbon atoms, such as 25 or more carbon atoms, such as 30 or more carbon atoms, such as 35 or more carbon atoms, such as 38 or more carbon atoms, such as 40 or more carbon atoms, such as 15 to 100 carbon atoms, such as 25 to 75 carbon atoms).
• R 8 , R 9 ', and R 10 together comprise 15 or more carbon atoms (such as 18 or more carbon atoms, such as 20 or more carbon atoms, such as 22 or more carbon atoms, such as 25 or more carbon atoms, such as 30 or more carbon atoms, such as 35 or more carbon atoms, such as 38 or more carbon atoms, such as 40 or more carbon atoms, such as 15 to 100 carbon atoms, such as 25 to 75 carbon atoms).
• 15 or more carbon atoms such as 18 or more carbon atoms, such as 20 or more carbon atoms, such as 22 or more carbon atoms, such as 25 or more carbon atoms, such as 30 or more carbon atoms, such as 35 or more carbon atoms, such as 38 or more carbon atoms, such as 40 or more carbon atoms, such as 15 to 100 carbon atoms, such as 25 to 75 carbon atoms).
• R is not a C1-C40 linear alkyl group (alternately R is not an optionally substituted C1-C40 linear alkyl group).
• each of R , R , R , and R is an aryl group (such as phenyl or naphthalenyl), wherein at least one of R A , R 5 , R 6 , and R 7 is substituted with at least one fluorine atom, preferably each of R , R , R , and R is a perfluoroaryl group (such as perfluorophenyl or perfluoronaphthalenyl).
• each Q is an aryl group (such as phenyl or naphthalenyl), wherein at least one Q is substituted with at least one fluorine atom, preferably each Q is a perfluoroaryl group (such as perfluorophenyl or perfluoronaphthalenyl).
• R is a methyl group; R is C6-C50 aryl group; and R is independently C1-C40 linear alkyl or Cs-Cso-aryl group.
• each of R and R is independently unsubstituted or substituted with at least one of halide, C 1 -C 35 alkyl, C 5 -C 15 aryl, C 6 -C 35 arylalkyl, C 6 -C 35 alkylaryl, wherein R 2 , and R 3 together comprise 20 or more carbon atoms.
• each Q is independently a hydride, bridged or unbridged dialkylamido, halide, alkoxide, aryloxide, hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, or halosubstituted-hydrocarbyl radical, provided that when Q is a fluorophenyl group, then R is not a C 1 -C 40 linear alkyl group, preferably R is not an optionally substituted C 1 -C 40 linear alkyl group (alternately when Q is a substituted phenyl group, then R is not a C 1 -C 40 linear alkyl group, preferably R is not an optionally substituted C 1 -C 40 linear alkyl group).
• R is a meta- and/or para-substituted phenyl group, where the meta and para substituents are, independently, an optionally substituted Ci to C 40 hydrocarbyl group (such as a Ce to C 40 aryl group or linear alkyl group, a C 12 to C 30 aryl group or linear alkyl group, or a C 10 to C 20 aryl group or linear alkyl group), an optionally substituted alkoxy group, or an optionally substituted silyl group.
• an optionally substituted Ci to C 40 hydrocarbyl group such as a Ce to C 40 aryl group or linear alkyl group, a C 12 to C 30 aryl group or linear alkyl group, or a C 10 to C 20 aryl group or linear alkyl group
• each Q is a fluorinated hydrocarbyl group having 1 to 30 carbon atoms, more preferably each Q is a fluorinated aryl (such as phenyl or naphthalenyl) group, and most preferably each Q is a perflourinated aryl (such as phenyl or naphthalenyl) group.
• suitable [Mt k+ Q n ] d ⁇ also include diboron compounds as disclosed in US Patent No. 5,447,895, which is fully incorporated herein by reference.
• at least one Q is not substituted phenyl.
• all Q are not substituted phenyl.
• at least one Q is not perfluorophenyl.
• all Q are not perfluorophenyl.
• R is not methyl, R is not Cis alkyl and R is not Cis alkyl, alternately R 1 is not methyl, R 2 is not Cis alkyl and R 3 is not Cis alkyl and at least one Q is not substituted phenyl, optionally all Q are not substituted phenyl.
• Useful cation components in Formulas (III) and (V) to (VIII) include those represented by the formula:
• Useful cation components in Formulas (III) and (V) to (VIII) include those represented by the formulas:
• the anion component of the activators described herein includes those represented by the formula [ Mt k+ Q n ] ⁇ wherein k is 1, 2, or 3; n is 1, 2, 3, 4, 5, or 6 (preferably 1, 2, 3, or 4), (preferably k is 3; n is 4, 5, or 6, preferably when M is B, n is 4); Mt is an element selected from Group 13 of the Periodic Table of the Elements, preferably boron or aluminum, and Q is independently a hydride, bridged or unbridged dialkylamido, halide, alkoxide, aryloxide, hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, and halosubstituted- hydrocarbyl radicals, said Q having up to 20 carbon atoms with the proviso that in not more than 1 occurrence is Q a halide.
• each Q is a fluorinated hydrocarbyl group, optionally having 1 to 20 carbon atoms, more preferably each Q is a fluorinated aryl group, and most preferably each Q is a perfluorinated aryl group.
• at least one Q is not substituted phenyl, such as perfluorophenyl, preferably all Q are not substituted phenyl, such as perfluorophenyl.
• the borate activator comprises tetrakis(heptafluoronaphth-2- yl)borate.
• the borate activator comprises tetrakis(pentafluorophenyl)borate.
• Anions for use in the non-coordinating anion activators described herein also include those represented by Formula 7, below:
• M* is a group 13 atom, preferably B or Al, preferably B; each R 11 is, independently, a halide, preferably a fluoride; each R 12 is, independently, a halide, a Ce to C20 substituted aromatic hydrocarbyl group or a siloxy group of the formula -O-Si-Ra, where Ra is a Ci to C20 hydrocarbyl or hydrocarbylsilyl group, preferably R 12 is a fluoride or a perfluorinated phenyl group; each R 13 is a halide, a Ce to C20 substituted aromatic hydrocarbyl group or a siloxy group of the formula -O-Si-Ra, where Ra is a Ci to C20 hydrocarbyl or hydrocarbylsilyl group, preferably R 13 is a fluoride or a Ce perfluorinated aromatic hydrocarbyl group; wherein R 12 and R 13 can form one or more saturated or unsaturated, substituted or unsubstitute
• Molecular volume is used herein as an approximation of spatial steric bulk of an activator molecule in solution. Comparison of substituents with differing molecular volumes allows the substituent with the smaller molecular volume to be considered “less bulky” in comparison to the substituent with the larger molecular volume. Conversely, a substituent with a larger molecular volume may be considered “more bulky” than a substituent with a smaller molecular volume.
• Molecular volume may be calculated as reported in "A Simple "Back of the Envelope” Method for Estimating the Densities and Molecular Volumes of Liquids and Solids," Journal of Chemical Education, v.71(11), November 1994, pp. 962-964.
• Vs is the sum of the relative volumes of the constituent atoms, and is calculated from the molecular formula of the substituent using Table A below of relative volumes. For fused rings, the Vs is decreased by 7.5% per fused ring.
• the Calculated Total MV of the anion is the sum of the MV per substituent, for example, the MV of perfluorophenyl is 183 A3, and the Calculated Total MV for tetrakis(perfluorophenyl)borate is four times 183 A3, or 732 A3.
• the activators may be added to a polymerization in the form of an ion pair using, for example, [M2HTH]+ [NCA]- in which the di(hydrogenated tallow)methylamine (“M2HTH”) cation reacts with a basic leaving group on the transition metal complex to form a transition metal complex cation and [NCA]-.
• the transition metal complex may be reacted with a neutral NCA precursor, such as B(C6Fs)3, which abstracts an anionic group from the complex to form an activated species.
• Useful activators include di(hydrogenated tallow)methylammonium[tetrakis(pentafluorophenyl)borate] (i.e., [M2HTH]B(C 6 Fs) 4 ) and di(octadecyl)tolylammonium [tetrakis(pentafluorophenyl)borate] (i.e., [DOdTH]B(C6Fs)4).
• di(hydrogenated tallow)methylammonium[tetrakis(pentafluorophenyl)borate] i.e., [M2HTH]B(C 6 Fs) 4
• di(octadecyl)tolylammonium [tetrakis(pentafluorophenyl)borate] i.e., [DOdTH]B(C6Fs)4
• Activator compounds that are particularly useful in this invention include one or more of:
• N,N-di(hydrogenated tallow)methylammonium [tetrakis(perfluorophenyl) borate], N-methyl-4-nonadecyl-N-octadecylanilinium [tetrakis(perfluorophenyl)borate], N-methyl-4-hexadecyl-N-octadecylanilinium [tetrakis(perfluorophenyl)borate], N-methyl-4-tetradecyl-N-octadecylanilinium [tetrakis(perfluorophenyl)borate], N-methyl-4-dodecyl-N-octadecylanilinium [tetrakis(perfluorophenyl)borate], N-methyl-4-decyl-N-octadecylanilinium [tetrakis(perfluorophenyl)borate], N-methyl
• N -octadecyl-N-dodecyl-tolylammonium tetrakis(perfluorophenyl)borate
• N-octadecyl-N-decyl-tolylammonium tetrakis(perfluorophenyl)borate
• N-hexadecyl-N-tetradecyl-tolylammonium tetrakis(perfluorophenyl)borate
• N -hexadecyl-N -dodecyl-tolylammonium [tetrakis(perfluorophenyl)borate] N-hexadecyl-N-decyl-tolylammonium [tetrakis(perfluorophenyl)borate]
• N-tetradecyl-N-dodecyl-tolylammonium tetrakis(perfluorophenyl)borate]
• N-methyl-N-octadecylanilinium tetrakis(perfluorophenyl)borate]
• N-methyl-N-decylanilinium tetrakis(perfluorophenyl)borate
• N-methyl-N-octylanilinium tetrakis(perfluorophenyl)borate
• Preferred activators for use herein also include N-methyl-4-nonadecyl-N- octadecylbenzenaminium tetrakis(pentafluorophenyl)borate, N-methyl-4-nonadecyl-N- octadecylbenzenaminium tetrakis(perfluoronaphthalenyl)borate, N,N-dimethylanilinium tetrakis(perfluoronaphthalenyl)borate, N,N-dimethylanilinium tetrakis(perfluorobiphenyl)borate, N,N-dimethylanilinium tetrakis(perfluorophenyl)borate, N,N-dimethylanilinium tetrakis(3,5- bis(trifluoromethyl)phenyl)
• the activator comprises a triaryl carbenium (such as triphenylcarbenium tetraphenylborate, triphenylcarbenium tetrakis(pentafluorophenyl)borate, triphenylcarbenium tetrakis-(2,3 ,4,6-tetrafluorophenyl)borate, triphenylcarbenium tetrakis(perfluoronaphthalenyl)borate, triphenylcarbenium tetrakis(perfluorobiphenyl)borate, triphenylcarbenium tetrakis(3,5-bis(trifluoromethyl)phenyl)borate).
• a triaryl carbenium such as triphenylcarbenium tetraphenylborate, triphenylcarbenium tetrakis(pentafluorophenyl)borate, triphenylcarbenium tetrakis-(2,3 ,4,
• the activator comprises one or more of trialkylammonium tetrakis(pentafluorophenyl)borate, N,N-dialkylanilinium tetrakis(pentafluorophenyl)borate, dioctadecylmethylammonium tetrakis(pentafluorophenyl)borate, dioctadecylmethylammonium tetrakis(perfluoronaphthalenyl)borate, N,N-dimethyl-(2,4,6-trimethylanilinium) tetrakis(pentafluorophenyl)borate, trialkylammonium tetrakis-(2,3,4,6-tetrafluorophenyl) borate, N,N-dialkylanilinium tetrakis-(2,3,4,6-tetrafluorophenyl)borate, trialkylammonium tetrakis-(2,3,4,
• the typical activator-to-catalyst ratio e.g., all NCA activators-to-catalyst ratio is about a 1 : 1 molar ratio.
• Alternate preferred ranges include from 0.1 : 1 to 100: 1 , alternately from 0.5: 1 to 200:1, alternately from 1:1 to 500:1 alternately from 1:1 to 1000:1.
• a particularly useful range is from 0.5:1 to 10:1, preferably 1:1 to 5:1.
• the catalyst compounds can be combined with combinations of alumoxanes and NCA's (see for example, US 5,153,157; US 5,453,410; EP 0 573 120 Bl; WO 1994/007928; and WO 1995/014044 (the disclosures of which are incorporated herein by reference in their entirety) which discuss the use of an alumoxane in combination with an ionizing activator).
• scavengers or co-activators may be used.
• a scavenger is a compound that is typically added to facilitate polymerization by scavenging impurities. Some scavengers may also act as activators and may be referred to as co-activators.
• a co-activator, that is not a scavenger, may also be used in conjunction with an activator in order to form an active catalyst. In some embodiments a co-activator can be pre-mixed with the transition metal compound to form an alkylated transition metal compound.
• Co-activators can include alumoxanes such as methylalumoxane, modified alumoxanes such as modified methylalumoxane, and aluminum alkyls such trimethylaluminum, tri-isobutylaluminum, triethylaluminum, and tri-isopropylaluminum, tri-n-hexylaluminum, tri-n-octylaluminum, tri-n-decylaluminum or tri-n-dodecylaluminum.
• Co-activators are typically used in combination with Lewis acid activators and ionic activators when the pre-catalyst is not a dihydrocarbyl or dihydride complex. Sometimes co-activators are also used as scavengers to deactivate impurities in feed or reactors.
• Aluminum alkyl or organoaluminum compounds which may be utilized as scavengers or co-activators include, for example, trimethylaluminum, triethylaluminum, triisobutylaluminum, tri-n-hexylaluminum, tri-n-octylaluminum, and dialkyl zinc, such as diethyl zinc.
• Chain transfer agents may be used in the compositions and or processes described herein.
• Useful chain transfer agents are typically hydrogen, alkylalumoxanes, a compound represented by the formula AIR3, ZnR2 (where each R is, independently, a Ci-Cs aliphatic radical, preferably methyl, ethyl, propyl, butyl, penyl, hexyl octyl or an isomer thereof) or a combination thereof, such as diethyl zinc, trimethylaluminum, triisobutylaluminum, trioctylaluminum, or a combination thereof.
• Solution polymerization processes may be used to carry out the polymerization reactions disclosed herein in any suitable manner known to one having ordinary skill in the art.
• the polymerization processes may be carried out in continuous polymerization processes.
• the term “batch” refers to processes in which the complete reaction mixture is withdrawn from the polymerization reactor vessel at the conclusion of the polymerization reaction.
• one or more reactants are introduced continuously to the reactor vessel and a solution comprising the polymer product is withdrawn concurrently or near concurrently.
• a solution polymerization means a polymerization process in which the polymer is dissolved in a liquid polymerization medium, such as an inert solvent or monomer(s) or their blends.
• a solution polymerization is typically homogeneous.
• a homogeneous polymerization is one where the polymer product is dissolved in the polymerization medium.
• Such systems are preferably not turbid as described in J. Vladimir Oliveira, C. Dariva and J. C. Pinto, Ind. Eng. Chem. Res. v.29, 2000, 4627.
• catalyst components, solvent, monomers and hydrogen are fed under pressure to one or more reactors.
• Temperature control in the reactor can generally be obtained by balancing the heat of polymerization and with reactor cooling by reactor jackets or cooling coils to cool the contents of the reactor, auto refrigeration, pre-chilled feeds, vaporization of liquid medium (diluent, monomers or solvent) or combinations of all three.
• Adiabatic reactors with pre-chilled feeds can also be used.
• the monomers are dissolved/dispersed in the solvent either prior to being fed to the first reactor or dissolve in the reaction mixture.
• the solvent and monomers are generally purified to remove potential catalyst poisons prior entering the reactor.
• the feedstock may be heated or cooled prior to feeding to the first reactor. Additional monomers and solvent may be added to the second reactor, and it may be heated or cooled.
• the catalysts/activators can be fed in the first reactor or split between two reactors. In solution polymerization, polymer produced is molten and remains dissolved in the solvent under reactor conditions, forming a polymer solution (also referred as to effluent).
• the solution polymerization process of this invention uses stirred reactor system comprising one or more stirred polymerization reactors.
• the reactors should be operated under conditions to achieve a thorough mixing of the reactants.
• the first polymerization reactor preferably operates at lower temperature.
• the residence time in each reactor will depend on the design and the capacity of the reactor.
• the catalysts/activators can be fed into the first reactor only or split between two reactors.
• a loop reactor and plug flow reactors are can be employed for current invention.
• the polymer solution is then discharged from the reactor as an effluent stream and the polymerization reaction is quenched, typically with coordinating polar compounds, to prevent further polymerization.
• the polymer solution On leaving the reactor system the polymer solution is passed through a heat exchanger system on route to a devolatilization system and polymer finishing process.
• the lean phase and volatiles removed downstream of the liquid phase separation can be recycled to be part of the polymerization feed.
• a polymer can be recovered from the effluent of either reactor or the combined effluent, by separating the polymer from other constituents of the effluent.
• Conventional separation means may be employed.
• polymer can be recovered from effluent by coagulation with a non-solvent such as isopropyl alcohol, acetone, or n-butyl alcohol, or the polymer can be recovered by heat and vacuum stripping the solvent or other media with heat or steam.
• a non-solvent such as isopropyl alcohol, acetone, or n-butyl alcohol
• One or more conventional additives such as antioxidants can be incorporated in the polymer during the recovery procedure.
• Other methods of recovery such as by the use of lower critical solution temperature (LCST) followed by devolatilization are also envisioned.
• LCST lower critical solution temperature
• Suitable diluents/solvents for conducting the polymerization reaction include non coordinating, inert liquids.
• the reaction mixture for the solution polymerization reactions disclosed herein may include at least one hydrocarbon solvent.
• hydrocarbon solvent examples include straight and branched-chain hydrocarbons, such as isobutane, butane, pentane, isopentane, hexanes, isohexane, heptane, octane, dodecane, and mixtures thereof; cyclic and alicyclic hydrocarbons, such as cyclohexane, cycloheptane, methylcyclohexane, methylcycloheptane, and mixtures thereof, such as can be found commercially (IsoparTM); halogenated and perhalogenated hydrocarbons, such as perfluorinated C4-C10 alkanes, chlorobenzene, and mixtures thereof; and aromatic and alkyl-substituted aromatic compounds
• Suitable solvents also include liquid olefins which may act as monomers or co-monomers including ethylene, propylene, 1 -butene, 1 -hexene, 1-pentene, 3-methyl-l-pentene, 4-methyl- 1-pentene, 1-octene, 1-decene, and mixtures thereof.
• the solvent is not aromatic, preferably aromatics are present in the solvent at less than 1 wt%, preferably less than 0.5 wt%, preferably less than 0.1 wt% based upon the weight of the solvents.
• olefinic feed can be polymerized using polymerization methods and solution polymerization conditions disclosed herein.
• Suitable olefinic feeds may include any C2-C40 alkene, which may be straight chain or branched, cyclic or acyclic, and terminal or non-terminal, optionally containing heteroatom substitution.
• the olefinic feed may comprise a C2-C20 alkene, particularly linear alpha olefins, such as, for example, ethene, propene, 1 -butene, 1-pentene, 1 -hexene, 1-octene, 1-decene, or 1-dodecene.
• Suitable olefinic monomers may include ethylenically unsaturated monomers, diolefins having 4 to 18 carbon atoms, conjugated or nonconjugated dienes, polyenes, vinyl monomers and cyclic olefins.
• Non-limiting olefinic monomers may also include norbornene, norbornadiene, isobutylene, isoprene, vinylbenzocyclobutane, styrene, alkyl substituted styrene, ethylidene norbornene, dicyclopentadiene, cyclopentene, and cyclohexene. Any single olefinic monomer or any mixture of olefinic monomers may undergo polymerization according to the disclosure herein.
• Preferred diolefin monomers useful in this invention include any hydrocarbon structure, preferably C5 to C30, having at least two unsaturated bonds wherein at least one of the unsaturated bonds is readily incorporated into a polymer.
• the second bond may partially take part in polymerization to form cross-linked polymers but normally provides at least some unsaturated bonds in the polymer product suitable for subsequent functionalization (such as with maleic acid or maleic anhydride), curing or vulcanization in post polymerization processes.
• diolefins examples include, but are not limited to butadiene, pentadiene, hexadiene, heptadiene, octadiene, nonadiene, decadiene, undecadiene, dodecadiene, tridecadiene, tetradecadiene, pentadecadiene, hexadecadiene, heptadecadiene, octadecadiene, nonadecadiene, icosadiene, heneicosadiene, docosadiene, tricosadiene, tetracosadiene, pentacosadiene, hexacosadiene, heptacosadiene, octacosadiene, nonacosadiene, triacontadiene, and polybutadienes having a molecular weight (Mw) of less than 1000 g/mol.
• Mw mole
• Examples of straight chain acyclic dienes include, but are not limited to 1,4-hexadiene and 1,6-octadiene.
• Examples of branched chain acyclic dienes include, but are not limited to 3, 7 -dimethyl- 1,6-octadiene, and 3,7-dimethyl-l,7-octadiene.
• Examples of single ring alicyclic dienes include, but are not limited to 1,4-cyclohexadiene, 1,5-cyclooctadiene, and 1,7-cyclododecadiene.
• multi-ring alicyclic fused and bridged ring dienes include, but are not limited to tetrahydroindene; norbornadiene; methyl-tetrahydroindene; dicyclopentadiene; bicyclo-(2.2.1)-hepta-2, 5-diene; and alkenyl-, alkylidene-, cycloalkenyl-, and cylcoalkyliene norbornenes [including, e.g., 5-methylene-2-norbornene, 5-ethylidene-2- norbornene, 5-propenyl-2-norbornene, 5-isopropylidene-2-norbomene, 5-(4-cyclopentenyl)-2- norbornene, 5-cyclohexylidene-2-norbornene, and 5-vinyl-2-norbomene].
• cycloalkenyl-substituted alkenes include, but are not limited to vinyl cyclohexene, allyl cyclohexene, vinyl cyclooctene, 4-vinyl cyclohexene, allyl cyclodecene, vinyl cyclododecene, and tetracyclo (A-l l,12)-5,8-dodecene.
• Diolefin monomers useful in this invention include any C4-C40 hydrocarbon structure, preferably C5 to C30 hydrocarbon structure, having at least two unsaturated bonds wherein at one (, optionally at least two) unsaturated bond can readily be incorporated into polymers to form cross-linked or crosslinkable polymers.
• dienes examples include alpha, omega-dienes (such as butadiene, 1,4-pentadiene, 1,5-hexadiene, 1,6-heptadiene, 1,7-octadiene, 1,8-nonadiene, 1,9-decadiene, 1,10-undecadiene, 1,11-dodecadiene, 1,12-tridecadiene, and 1,13-tetradecadiene) and certain multi-ring alicyclic fused and bridged ring dienes (such as tetrahydroindene; divinylbenzene, norborndiene; methyl-tetrahydroindene; dicyclopentadiene; bicyclo-(2.2.1)- hepta-2, 5-diene; and alkenyl-, alkylidene-, cycloalkenyl-, and cylcoalkyliene norbornenes [including, e.g., 5-methylene-2-norbomene, 5-eth
• Preferred diene monomers include C6-C20 dienes that have only one unsaturated group that is reactive with the transition metal catalyst.
• Preferred diene monomers include acylic C6-C20 dienes that have only one vinyl group. Examples of preferred diene monomers that have only one unsaturated group that is reactive with the transition metal catalyst include 5-ethylidene-2-norbomene, 7-methyl-l,6-octadiene, and 1,4-hexadiene.
• Preferred polymerizations can be run at any temperature and/or pressure suitable to obtain the desired polymers.
• Solution polymerization conditions suitable for use in the polymerization processes disclosed herein include temperatures ranging from about 0°C to about 300°C, or from about 20°C to about 200°C, or from about 35°C to about 180°C, or from about 80°C to about 160°C, or from about 100°C to about 140°C, or from about 70°C to about 120°C, or from about 90°C to about 120°C, or from about 80°C to about 130°C, or from about 90°C to about 150°.
• Pressures may range from about 0.1 MPa to about 15 MPa, or from about 0.2 MPa to about 12 MPa, or from about 0.5 MPa to about 10 MPa, or from about 1 MPa to about 7 MPa.
• Polymerization run times may range up to about 300 minutes, particularly in a range from about 5 minutes to about 250 minutes, or from about 10 minutes to about 120 minutes.
• hydrogen may be included in the reactor vessel in the solution polymerization processes.
• the hydrogen gas may influence the properties of the resulting polyolefins, such as altering the melt flow index or molecular weight, compared to an analogous polymerization reaction conducted without the hydrogen.
• the amount of hydrogen gas that is present may also alter these properties as well.
• the concentration of hydrogen gas in the reaction mixture may range up to about 5,000 ppm, or up to about 4,000 ppm, or up to about 3,000 ppm, or up to about 2,000 ppm, or up to about 1,000 ppm, or up to about 500 ppm, or up to about 400 ppm, or up to about 300 ppm, or up to about 200 ppm, or up to about 100 ppm, or up to about 50 ppm, or up to about 10 ppm, or up to about 1 ppm.
• hydrogen gas may be present in the reactor vessel at a partial pressure of about 0.007 to 345 kPa, or about 0.07 to 172 kPa, or about 0.7 to 70 kPa. In some embodiments hydrogen is not added.
• the polymerization 1) is conducted at temperatures of 70°C or higher (preferably 80°C or higher, preferably 85°C or higher, preferably 100°C or higher, preferably 110°C or higher); 2) is conducted at a pressure of atmospheric pressure to 10 MPa (preferably from 0.35 to 10 MPa, preferably from 0.45 to 6 MPa, preferably from 0.5 to 4 MPa); 3) is conducted in an aliphatic hydrocarbon solvent (such as, isobutane, butane, pentane, isopentane, hexanes, isohexane, heptane, octane, dodecane, and mixtures thereof; cyclic and alicyclic hydrocarbons, such as cyclohexane, cycloheptane, methylcyclohexane, methylcycloheptane, and mixtures thereof; preferably where aromatics (such as toluene) are preferably present in the solvent at less than 1
• the one or more olefinic monomers present in the reaction mixtures disclosed herein comprise at least ethylene and propylene.
• the one or more olefinic monomers may comprise ethylene, propylene, and a diene monomer.
• Suitable diene monomers that may be present may include, for example, dicyclopentadiene, 5-ethylidene-2-norbomene, or 5-vinylidene-2- norbornene.
• the invention relates to homogeneous polymerization processes where diene monomer and alpha olefin monomer(s) (such as ethylene and or propylene), and optional comonomer, are contacted with a catalyst system comprising an activator and at least one catalyst compound, as described above.
• the catalyst compound and activator may be combined in any order, and are combined typically prior to contacting with the monomers.
• Polymerization processes of this invention can be carried out in any manner known in the art. Any suspension, homogeneous, bulk, solution, slurry, or gas phase polymerization process known in the art can be used. Such processes can be run in a batch, semi-batch, or continuous mode. Homogeneous polymerization processes are preferred.
• a homogeneous polymerization process is preferably a process where at least 90 wt% of the product is soluble in the reaction media.
• the process is a solution process.
• no solvent or diluent is present or added in the reaction medium (except for the small amounts used as the carrier for the catalyst system or other additives, or amounts typically found with the monomer; e.g., propane in propylene), and the polymerization is run in a bulk process.
• a "reaction zone” also referred to as a "polymerization zone” is a vessel where polymerization takes place, for example a batch reactor. When multiple reactors are used in either series or parallel configuration, each reactor is considered as a separate polymerization zone. For a multi-stage polymerization in both a batch reactor and a continuous reactor, each polymerization stage is considered as a separate polymerization zone. In a preferred embodiment, the polymerization occurs in one reaction zone. Room temperature is 23°C unless otherwise noted.
• additives may also be used in the polymerization, as desired, such as one or more scavengers, hydrogen, aluminum alkyls, silanes, or chain transfer agents (such as alkylalumoxanes, a compound represented by the formula AIR3 or ZnR2 (where each R is, independently, a Ci-Cs aliphatic radical, preferably methyl, ethyl, propyl, butyl, penyl, hexyl octyl or an isomer thereof) or a combination thereof, such as diethyl zinc, methylalumoxane, trimethylaluminum, triisobutylaluminum, trioctylaluminum, or a combination thereof).
• scavengers hydrogen, aluminum alkyls, silanes, or chain transfer agents
• alkylalumoxanes a compound represented by the formula AIR3 or ZnR2 (where each R is, independently, a Ci-Cs aliphatic radical
• This invention also relates to compositions of matter produced by the methods described herein.
• the processes described herein may be used to produce polymers of olefins or mixtures of olefins.
• Polymers that may be prepared include copolymers of diene with a C2-C20 alpha olefin, copolymers of ethylene and diene monomer, copolymers of propylene and diene monomer, terpolymers of ethylene and C3-C20 alpha olefin and diene monomer, terpolymers of propylene and and C4-C20 alpha olefin and diene monomer.
• Polymers that may be prepared include copolymer of ethylene and 5-ethylidene-2-norbornene, terpolymer of ethylene propylene and 5- ethylidene-2-norbomene, terpolymer of ethylene and butene with 5-ethylidene-2-norbomene, terpolymer of ethylene and propylene with dicyclopentadiene, terpolymer of ethylene and proplyene with 1,4-hexadiene, terpolymer of ethylene and hexene with 5-ethylidene-2-norbornene, terpolymer of ethylene and octene with 5-ethylidene-2-norbornene.
• the polymers are ethylene propylene diene terpolymers.
• Polymers that may be prepared also include terpolymers of ethylene and alpha-olefin with C3-C20 olefins (such as dienes), such as terpolymers of ethylene and propylene with 5-ethylidene-2-norbornene, ethylene and butene with 5-ethylidene-2- norbornene, ethylene and propylene with dicyclopentadiene, ethylene and proplyene with 1,4-hexadiene, ethylene and hexene with 5-ethylidene-2-norbomene, ethylene and octene with 5 -ethylidene-2-norbornene .
• the ethylene and alpha-olefin or ethylene, alpha-olefin and diene copolymers preferably has an Mw of 100,000 to 2,000,000 g/mol, preferably 150,000 to 1,000,000 g/mol, more preferably 200,000 to 500,000 g/mol, as measured by size exclusion chromatography, as described below in the Test method section below, and/or an Mw/Mn of 2 to 100, preferably 2.5 to 80, more preferably 3 to 60, more preferably 3 to 50 as measured by size exclusion chromatography, and/or a Mz/Mw of 2 to 50, preferably 2.5 to 30, more preferably 3 to 20, more preferably 3 to 25.
• the Mw referred to herein, and for purposes of the claims attached hereto, is obtained from GPC using a light scattering detector as described in the Test method section below.
• the ethylene alpha-olefin or ethylene alpha-olefin and diene copolymers (such as the polymers produced from diene monomer and alpha olefin monomer(s)) have rheological characteristics of high Mooney EPDM observed by Rubber process analyzer (RPA) measurement of the molten polymer performed on a dynamic (oscillatory) rotational rheometer. Unless stated otherwise, the RPA experiment is performed at 125°C.
• the phase or loss angle d is the inverse tangent of the ratio of G" (the loss modulus) to G' (the storage modulus).
• G" the loss modulus
• G' the storage modulus
• the phase angle of the ethylene copolymer is 45 degree or less, preferably 40 degree or less, more preferably 35 degree or less.
• the phase angle is between 10 degrees and 45 degrees, alternatively between 15 degrees and 40 degrees.
• the tan (d) of ethylene copolymer is 1 or less, 0.8 or less, 0.7 or less.
• phase angle of the inventive ethylene copolymers is less than 45 degree in a range of the complex shear modulus from 50,000 Pa to 1,000,000 Pa.
• the ethylene alpha-olefin or ethylene alpha-olefin and diene copolymers of this invention preferably have significant shear induced viscosity thinning.
• Shear thinning is characterized by the decrease of the complex viscosity with increasing shear rate.
• One way to quantify the shear thinning is to use a ratio of complex viscosity at a frequency of 0.245 rad/s to the complex viscosity at a frequency of 128 rad/s. This ratio is referred to as a shear thinning ratio or a complex viscosity ratio.
• the shear thinning ratio of the inventive polymer is 50 or more, more preferably 60 or more, more preferably 70 or more, alternately 75 or more, even more preferably 100 or more when the complex viscosity is measured at 125°C using RPA.
• the shear thinning ratio of the inventive polymer is from 50 to 500, or from 60 to 400, or from 70 to 340, or from 150 to 340, or from 220 to 340, or from 225 to 335.
• the inventive polymers may have a complex viscosity at 0.1 rad/sec and a temperature of 125°C of at least 100,000 Pa.sec (or at least 200,000 Pa.s, or at least 500,000 Pa.s, or at least 1,000,000 Pa.s, or at least 1,500,000 Pa.s, or at least 2,000,000 Pa.s, or at least 3,000,000 Pa.s, preferably from 50,000 to 4,500,000 Pa.sec, preferably from 100,000 to 4,500,000 Pa.sec, preferably from 500,000 to 4,500,000 Pa.s, alternately from 50,000 to 1,000,000 Pa.sec, preferably from 100,000 to 1,000,000 Pa.sec).
• the complex viscosity is measured using RPA using the procedure described in the Test methods section.
• the units abbreviated as Pa.s and Pa.sec both indicate Pascal x seconds.
• the ethylene and alpha-olefin or ethylene, alpha-olefin and diene copolymers may have Mooney viscosity ML (1 + 4 at 125°C) ranging from a low of any one of about 20, 30 and 40 MU (Mooney units) to a high of any one of about 70, 80, 90, 100, 110, 120, 130, 140, 150, 160, 170, and 180 MU.
• Mooney viscosity in terms of MST (5+4 at 200°C) may range from a low of any one of about 10, 20, and 30 MU to a high of any one of about 40, 50, 60, 70 80, 90, and 100 MU.
• the ethylene and alpha-olefin or ethylene, alpha-olefin and diene copolymers may have MLRA ranging from a low of any one of about 300, 400, 500, 600, and 700 mu* sec to a high of any one of about, 800, 900, 1000, 1150, 1200, 1250, 1300, 1350, 1400, 1450, 1500, 1550, 1600, 1650, 1700, 1750, 1800, 1850, 1900, 1950, and 2000 mu*sec.
• MLRA maybe within the range of about 500 to about 2000 mu* sec, or from about 500 to about 1500 mu* sec, or from about 600 to about 1200 mu*sec, etc.
• MLRA may be at least 500 mu*sec, or at least 600 mu*sec, or at least 700 mu*sec.
• the ethylene and alpha-olefin or ethylene, alpha-olefin and diene copolymers may has a MLRA of greater than 176.88*EXP(0.0179*ML), wherein ML is the Mooney viscosity.
• cMLRA may be within the range of about 400 to about 2000 mu* sec, or from about 500 to about 1500 mu* sec, or from about 700 to about 1200 mu*sec, etc. In certain embodiments, cMLRA may be at least 400 mu*sec (without a necessary upper boundary), or at least 500 mu*sec, or at least 600 mu*sec.
• the inventive polymer (such as the ethylene alpha-olefin or ethylene alpha-olefin and diene copolymer) in some embodiments has an ethylene content of 30 wt% or more, 40 wt% or more, 50 wt% or more, 60 wt% or more, 70 wt% or more.
• the ethylene content is in a range of 30 wt% to 80 wt%.
• the ethylene content is in a range of 50 wt% to 80 wt%.
• the ethylene content is in a range of 60 wt% to 80 wt%.
• the polymer composition has a diene content of 15 wt% or less, such as 10 wt% or less. In yet further embodiments, the polymer composition has a diene content of 0.1 to 50 wt%, preferably 1 wt% to 20 wt%, preferably 2 to 15 wt %, more preferably 5 to 10 wt%. Alternatively, the diene content is from 4 to 12 wt%.
• the inventive polymer (such as the ethylene alpha-olefin or ethylene alpha-olefin and diene copolymer) in some embodiments has long chain branched architecture.
• the degree of long chain branched can be determined by a branching index (g’vis) measured using GPC-4D.
• the branching index, g’ viS is 0.98 or less, or 0.94 or less, or 0.90 or less, or 0.88 or less.
• the branching index, g’ v is, is from 0.80 to 0.98, alternatively is from 0.82 to 0.97, alternatively from 0.84 to 0.96, alternatively from 0.85 to 0.95, alternatively from 0.87 to 0.94.
• the polymer composition is characterized as a reactor blend of two or more of the following: a first low molecular weight polymer (such as an ethylene copolymer) and a second high molecular weight polymer (such as an ethylene polymer) with each of the polymers having units derived from diene monomer and one or more C2-C20 alpha olefin.
• a first low molecular weight polymer such as an ethylene copolymer
• a second high molecular weight polymer such as an ethylene polymer
• the first copolymer may have ethylene content within the range of about 20 wt% to about 60 wt%
• the second copolymer may have ethylene content within the range of about 40 wt% to about 80 wt%, wherein the second copolymer has at least 5 wt% greater ethylene content than the first copolymer.
• the ratio of Mw of the second copolymer to Mw of the first copolymer is at least any one of about 1.5, 2, 3, 4, or 5.
• the ethylene content in the first and the second ethylene copolymer are different. The difference is at least 5 wt%, preferably 10 wt%.
• the ethylene content of the first ethylene copolymer is higher than the ethylene content of the second copolymer by at least of 5 wt%.
• the ethylene distribution of the inventive ethylene copolymer can be determined according to the description of Molecular Weight and Composition Distribution in the Test Methods section below.
• Ethylene content in each portion of the blend (e.g., in each of the first and second copolymers) can be controlled according to polymerization processes of various embodiments. For instance, two or more catalyst systems may be used to create the reactor blend, and the catalysts may be selected such that they produce polymers having different ethylene content.
• ethylene content in each fraction of the blend can be controlled through monomer concentration according to each catalyst’s kinetic response of ethylene insertion rate.
• ethylene monomer feed to each zone may be varied to accomplish the differential in ethylene content among the fractions of the blend.
• the catalyst used for oil oligomer production can be also used to produce ethylene copolymer in a separated polymerization zone.
• the amount of first polymer (such as the ethylene copolymer) relative to the in-reactor blend may vary widely depending on the nature of the polymers and the intended use of the final polymer blend.
• one advantage of the process of the invention is the ability to be able to produce a reactor polymer blend in which the first ethylene copolymer comprise more than 30 wt%, such as more than 40 wt% of the total reactor blend.
• the ratio of the two copolymers in the blend can be manipulated according to processes for producing such blends according to various embodiments. For instance, where two catalysts are used for producing the blend, the concentration ratio of the two catalysts can result in different amounts of the first and second ethylene copolymers of the blend.
• the ethylene copolymer having lower molecular weight is of 50 or less, more preferably 40 or less , 30 or less and 20 or less wt% of the total blend.
• Catalyst concentration in each of one or more polymerization zones can be adjusted through catalyst feed rate to the reactor.
• the molar ratio of the first catalyst feed rate to the second catalyst feed rate is in a range of 0.05 to 20.
• the polymer composition may be characterized as a reactor blend comprising two ethylene copolymers (a first and a second ethylene copolymer).
• the first ethylene copolymer has a Mooney viscosity (1+4 at 125°C) of 10 mu or less and the second ethylene copolymer has a Mooney viscosity (1+4 at 125°C) of 20 mu or more.
• the final product has a tan d of 1.2 or less measured at a frequency of 10 rad/sec and a temperature of 125°C.
• the polymer composition may be characterized as a reactor blend comprising two polymers (a first and a second polymer).
• the first polymer has a Mooney viscosity (1+4 at 125°C) of 10 mu or less and the second polymer has a Mooney viscosity (1+4 at 125°C) of 20 mu or more.
• the final product has a tan d of 1.2 or less measured at a frequency of 10 rad/sec and a temperature of 125°C.
• the polymer (such as the ethylene-propylene diene terpolymer) produced herein is combined with one or more additional polymers prior to being formed into a film, molded part or other article.
• additional polymers include polyethylene, polypropylene, random copolymer of propylene and ethylene, and/or butene, and/or hexene, polybutene, LDPE, LLDPE, HDPE, ethylene vinyl acetate, ethylene methyl acrylate, copolymers of acrylic acid, polymethylmethacrylate or any other polymers polymerizable by a high-pressure free radical process, polyvinylchloride, polybutene- 1, isotactic polybutene, ABS resins, ethylene-propylene rubber (EPR), vulcanized EPR, additional EPDM, block copolymer, styrenic block copolymers, polyamides, polycarbonates, PET resins, cross linked polyethylene, copolymers of
• the copolymer produced herein (preferably ethylene- propylene-diene monomer) is present in the above blends, at from 10 to 99 wt%, based upon the weight of the polymers in the blend, preferably 20 to 95 wt%, even more preferably at least 30 to 90 wt%, even more preferably at least 40 to 90 wt%, even more preferably at least 50 to 90 wt%, even more preferably at least 60 to 90 wt%, even more preferably at least 70 to 90 wt%.
• the blends described above may be produced by mixing the polymers of the invention with one or more polymers (as described above), by connecting reactors together in series or parallel to make reactor blends or by using more than one catalyst in the same reactor system to produce multiple species of polymers.
• the polymers can be mixed together prior to being put into the extruder or may be mixed in an extruder.
• the blends may be formed using conventional equipment and methods, such as by dry blending the individual components and subsequently melt mixing in a mixer, or by mixing the components together directly in a mixer, such as, for example, a Banbury mixer, a Haake mixer, a Brabender internal mixer, or a single or twin-screw extruder, which may include a compounding extruder and a side-arm extruder used directly downstream of a polymerization process, which may include blending powders or pellets of the resins at the hopper of the film extruder. Additionally, additives may be included in the blend, in one or more components of the blend, and/or in a product formed from the blend, such as a film, as desired.
• a mixer such as, for example, a Banbury mixer, a Haake mixer, a Brabender internal mixer, or a single or twin-screw extruder, which may include a compounding extruder and a side-arm extruder used directly downstream of a polymerization
• additives are well known in the art, and can include, for example: fillers; antioxidants (e.g., hindered phenolics such as IRGANOXTM 1010 or IRGANOXTM 1076 available from BASF); phosphites (e.g., IRGAFOSTM 168 available from BASF); anti-cling additives; tackifiers, such as polybutenes, terpene resins, aliphatic and aromatic hydrocarbon resins, alkali metal and glycerol stearates, and hydrogenated rosins; UV stabilizers; heat stabilizers; anti-blocking agents; release agents; anti static agents; pigments; colorants; dyes; waxes; silica; fillers; talc; and the like.
• antioxidants e.g., hindered phenolics such as IRGANOXTM 1010 or IRGANOXTM 1076 available from BASF
• phosphites e.g., IRGAFOSTM
• End uses include polymer products and products having specific end-uses.
• Exemplary end uses are films, film-based products, diaper backsheets, housewrap, wire and cable coating compositions, articles formed by molding techniques, e.g., injection or blow molding, extrusion coating, foaming, casting, and combinations thereof.
• End uses also include products made from films, e.g., bags, packaging, and personal care films, pouches, medical products, such as for example, medical films and intravenous (IV) bags.
• the inventive polymer (such as the ethylene copolymer) of some embodiments may be formulated and/or processed with any one or more various additives (e.g., curatives or cross- linking agents, fillers, process oils, and the like) to form rubber compounds suitable for making articles of manufacture.
• various additives e.g., curatives or cross- linking agents, fillers, process oils, and the like
• rubber compounds according to some such embodiments include, in addition to the copolymer composition, any components suitable for an EPDM rubber formulation.
• any of various known additives fillers, plasticizers, compatibilizers, cross-linkers, and the like
• the (such as the ethylene copolymer) may be present in the rubber compound in at least partially cross-linked form (that is, at least a portion of the polymer chains of the devolatilized elastomer composition are cross-linked with each other, e.g., as a result of a curing process typical for EPDM rubbers).
• an at least partially cross-linked rubber compound made by mixing a formulation comprising: (a) an ethylene copolymer (e.g., in accordance with any of the above-described embodiments of ethylene copolymers; (b) one or more vulcanization activators; (c) one or more vulcanizing agents; and (d) optionally, one or more further additives.
• a formulation comprising: (a) an ethylene copolymer (e.g., in accordance with any of the above-described embodiments of ethylene copolymers; (b) one or more vulcanization activators; (c) one or more vulcanizing agents; and (d) optionally, one or more further additives.
• Suitable vulcanization activators include one or more of zinc oxide, stearic acid, and the like. These activators may be mixed in amounts ranging from about 0 to 20 phr. As used herein, “phr” means parts per hundred parts rubber, where the “rubber” is taken as the ethylene copolymer in the formulation. Thus, for activator to be formulated with ethylene copolymer at 15 phr, one would add 15 g activator to 100 g ethylene copolymer. Unless specified otherwise, phr should be taken as phr on a weight basis. Different vulcanization activators may be employed in different amounts.
• the vulcanization activator includes zinc oxide
• the zinc oxide may be employed at amounts ranging from 1 to 20 phr, such as 2.5 to 10 phr (e.g., about 5 phr)
• stearic acid may preferably be employed in amounts ranging from 0.1 to 5 phr, such as 0.1 to 2.0 phr (e.g., about 1.0 or 1.5 phr).
• multiple vulcanization activators may be utilized (e.g., both ZnO and stearic acid).
• Any vulcanizing agent known in the art may be used. Of particular note are curing agents as described in Col. 19, line 35 to Col. 20, line 30 of US Patent No.
• the further additives (used in any compound and/or in an at least partially cross-linked rubber compound according to various embodiments) may be chosen from any known additives useful for EPDM formulations, and include, among others, one or more of:
• Process oil such as API Group I, II, or III base oils, including aromatic, naphthenic, paraffinic, and/or isoparaffinic process oil (examples including SunparTM 2280 (available from HollyFrontier Refining & Marketing LLC, Tulsa, Oklahoma); as well as FlexonTM 876, CORETM 600 base stock oil, FlexonTM 815, and CORETM 2500 base stock oil, available from ExxonMobil Chemical Company, Baytown, Texas. Process oil may be present in the formulation at 1-150 phr (when present), and preferred process oils have viscosity at 40°C ranging from 80 to 600 CSt.
• API Group I, II, or III base oils including aromatic, naphthenic, paraffinic, and/or isoparaffinic process oil (examples including SunparTM 2280 (available from HollyFrontier Refining & Marketing LLC, Tulsa, Oklahoma); as well as FlexonTM 876, CORETM 600 base stock oil, FlexonTM 815, and
• a paraffinic or isoparaffinic oil e.g., having aromatic and/or heteroatom content less than 1 wt% total, preferably less than 0.1 wt% total
• white oils may be particularly preferred.
• Many API Group II and/or III base oils may satisfy such applications.
• Vulcanization accelerators present in the formulation at 0 to 15 phr total, such as 1-5, or 2-4 phr, with examples including one or more of: thiazoles such as 2-mercaptobenzothiazole or mercaptobenzothiazyl disulfide (MBTS); guanidines such as diphenylguanidine; sulfenamides such as N-cyclohexylbenzothiazolsulfenamide; dithiocarbamates such as zinc dimethyl dithiocarbamate, zinc diethyl dithiocarbamate, zinc dibenzyl dithiocarbamate (ZBEC); and zincdibutyldithiocarbamate, thioureas such as 1,3-diethylthiourea, thiophosphates and others.
• thiazoles such as 2-mercaptobenzothiazole or mercaptobenzothiazyl disulfide (MBTS)
• guanidines such as
• Processing aids e.g., polyethylene glycol or zinc soap.
• Carbon black e.g., having particle size from 20 nm to 600 nm and structure having DBPA (dibutyl phthalate absorption number) within the range from 0 to 150, as measured by the DBP method described in ASTM D2414, which may be present in the formulation at 0 - 500 phr, preferably 0 - 200 phr, such as within the range of 50-150 phr.
• DBPA dibutyl phthalate absorption number
• Mineral fillers (talc, calcium carbonate, clay, silica, aluminum trihydrate, and the like), which may be present in the formulation from 0 to 200 phr, preferably from 20 to 100 phr, such as in the range of 30 to 60 phr.
• additives such as antioxidants, stabilizers, anticorrosion agents, UV absorbers, antistatics, slip agents, moisture absorbents (e.g., calcium oxide), and pigments, dyes and other colorants.
• the at least partially cross-linked rubber compounds of some embodiments are formed by mixing the above-described formulations.
• Mixing in these embodiments may include any one or more of typical mixing processes for EPDM compositions, such as open mill mixing, mixing using internal mixers or kneaders, and extrusion (e.g., through an extruder, such as a twin-screw or other multi-screw extruder).
• the compound viscosity (Mooney Viscosity of the compound) of at least partially cross-linked rubber compounds in accordance with some embodiments is within the range from 70 to 95 MU, preferably 75 to 93 MU, or 80 to 92 MU, such as from 82 to 90 MU (ML, 1+4 @ 100°C), with ranges from any of the foregoing lows to any of the foregoing highs also contemplated in various embodiments.
• This invention further relates to:
• a polymerization process comprising contacting in a homogeneous phase diene monomer and at least one C3 to C40 alpha olefin comonomer (such as ethylene, a diene, and an alpha-olefin comonomer selected from C3 to C40 alpha olefins) with a catalyst system comprising activator and catalyst compound represented by the Formula (I): wherein: M is a group 3, 4, 5, or 6 transition metal or a Lanthanide;
• E and E' are each independently O, S, or NR 9 where R 9 is independently hydrogen, a C1-C40 hydrocarbyl, a C1-C40 substituted hydrocarbyl or a heteroatom-containing group;
• Q is group 14, 15, or 16 atom that forms a dative bond to metal M;
• A'QA 1 are part of a heterocyclic Lewis base containing 4 to 40 non-hydrogen atoms that links A 2 to A 2 via a 3-atom bridge with Q being the central atom of the 3-atom bridge,
• a 1 and A 1 are independently C, N, or C(R 22 ), where R 22 is selected from hydrogen, C1-C20 hydrocarbyl, C1-C20 substituted hydrocarbyl;
• a 3 - A 2 is a divalent group containing 2 to 40 non-hydrogen atoms that links A to the E-bonded aryl group via a 2-atom bridge;
• ⁇ A is a divalent group containing 2 to 40 non-hydrogen atoms that links A to the E'-bonded aryl group via a 2-atom bridge;
• L is a Lewis base;
• X is an anionic ligand;
• n is 1, 2 or 3;
• m is 0, 1, or 2; n+m is not greater than 4;
• each of R 1 , R 2 , R 3 , R 4 , R 1 , R 2 , R 3 , and R 4 is independently hydrogen, a C1-C40 hydrocarbyl, a C1-C40 substituted hydrocarbyl, a heteroatom or a hetero atom-containing group, and one or more of R 1 and R 2 , R 2 and R 3 , R 3 and R 4 , R 1 ' and R 2 , R 2 and R 3 , R 3 and R 4 may be joined to form one or more substituted hydrocarbyl rings, unsubstituted hydrocarbyl rings, substituted heterocyclic rings, or unsubstituted heterocyclic rings each having 5, 6, 7, or 8 ring atoms, and where substitutions on the ring can join to form additional rings; any two L groups may
• M is a group 3, 4, 5, or 6 transition metal or a Lanthanide
• E and E' are each independently O, S, or NR 9 , where R 9 is independently hydrogen, a C 1 -C 40 hydrocarbyl, a C 1 -C 40 substituted hydrocarbyl, or a hetero atom-containing group; each L is independently a Lewis base; each X is independently an anionic ligand; n is 1, 2 or 3; m is 0, 1, or 2; n+m is not greater than 4; each of R 1 , R 2 , R 3 , R 4 , R 1 , R 2 , R 3 , and R 4 is independently hydrogen, C 1 -C 40 hydrocarbyl, C 1 -C 40 substituted hydrocarbyl, a heteroatom or a heteroatom-containing group, or one or more of R 1 and R 2 , R 2 and R 3 , R 3 and R 4 , R 1 and R 2 , R 2 and R 3 , R 3 and R 4 may be joined to form one or more substituted hydrocarbyl rings, unsubstituted hydrocarbyl
• each X is, independently, selected from the group consisting of substituted or unsubstituted hydrocarbyl radicals having from 1 to 20 carbon atoms, hydrides, amides, alkoxides, sulfides, phosphides, halides, and a combination thereof, (two X’s may form a part of a fused ring or a ring system).
• each L is, independently, selected from the group consisting of: ethers, thioethers, amines, phosphines, ethyl ether, tetrahydrofuran, dimethylsulfide, triethylamine, pyridine, alkenes, alkynes, alenes, and carbenes and a combinations thereof, optionally two or more L’s may form a part of a fused ring or a ring system).
• Z is (L-H) or a reducible Lewis Acid
• L is an neutral Lewis base
• H is hydrogen
• (L-H) + is a Bronsted acid
• a d is a non-coordinating anion having the charge d
• d is an integer from 1 to 3.
• R 1 , R 2 , and R 3 are independently a Ci to C50 hydrocarbyl group optionally substituted with one or more alkoxy groups, silyl groups, a halogen atoms, or halogen containing groups, wherein R 1 , R 2 , and R 3 together comprise 15 or more carbon atoms;
• Mt is an element selected from group 13 of the Periodic Table of the Elements; and each Q is independently a hydride, bridged or unbridged dialkylamido, halide, alkoxide, aryloxide, hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, or halosubstituted- hydrocarbyl radical.
• the activator is one or more of: N-methyl-4-nonadecyl-N-octadecylbenzenaminium tetrakis(pentafluorophenyl)borate, N-methyl-4-nonadecyl-N-octadecylbenzenaminium tetrakis(perfluoronaphthalenyl)borate, dioctadecylmethylammonium tetraJds(pentafluorophenyl)borate, dioctadecylmethylammonium tetrakis(perfluoronaphthalenyl)borate, N,N-dimethylanilinium tetrakis(pentafluorophenyl)borate, triphenylcarbenium tetrakis(pentafluorophenyl)borate, trimethylammonium tetraJds(perfluoron
• N,N-diethylanilinium tetrakis-(2,3,4,6-tetrafluorophenyl)borate N,N-dimethyl-(2,4,6-trimethylanilinium) tetrakis-(2,3,4,6-tetrafluorophenyl)borate, tropillium tetrakis-(2,3 ,4,6-tetrafluorophenyl)borate, triphenylcarbenium tetrakis-(2,3 ,4,6-tetrafluorophenyl)borate, triphenylphosphonium tetrakis-(2,3 ,4,6-tetrafluorophenyl)borate, triethylsilylium tetrakis-(2,3,4,6-tetrafluorophenyl)borate, benzene(diazonium) tetrakis-(2,3,4,6-tetrafluorophenyl)borate,
• a polymerization process comprising contacting in a homogeneous phase ethylene, a C3-C8 alpha olefin, and 5-ethylidene-2-norbomene with a catalyst system comprising an activator and group 4 bis(phenolate) catalyst compound, wherein the polymerization process takes place at a temperature of 70°C or higher; and obtaining a polymer having:
• Rubber process analyzer Dynamic shear melt rheological data was measured using the ATD ® 1000 Rubber Process Analyzer from Alpha Technologies. A sample of approximately 4.5 gm weight is mounted between the parallel plates of the ATDTM 1000. A nitrogen stream was circulated through the sample oven during the experiments. The test temperature is 125°C, the applied strain is 14 % and the frequency was varied from 0.1 rad/s to 385 rad/s. The complex modulus (G*), complex viscosity (h*) and the phase angle (5) are measured at each frequency. A sinusoidal shear strain is applied to the material. If the strain amplitude is sufficiently small the material behaves linearly.
• the resulting steady-state stress will also oscillate sinusoidally at the same frequency but will be shifted by a phase angle d with respect to the strain wave.
• d For viscoelastic materials, 0 ⁇ d ⁇ 90.
• Complex viscosity, loss modulus (G”) and storage modulus (G’) as function of frequency are provided by the small amplitude oscillatory shear test using RPA.
• Dynamic viscosity is also referred to as complex viscosity or dynamic shear viscosity.
• the phase or the loss angle (d) is the inverse tangent of the ratio of G" (shear loss modulus) to G' (shear storage modulus).
• Shear Thinning Ratio Shear-thinning is a rheological response of polymer melts, where the resistance to flow (viscosity) decreases with increasing shear rate.
• the complex shear viscosity is generally constant at low shear rates (Newtonian region) and decreases with increasing shear rate. In the low shear-rate region, the viscosity is termed the zero shear viscosity, which is often difficult to measure for polydisperse and/or LCB polymer melts.
• the polymer chains are oriented in the shear direction, which reduces the number of chain entanglements relative to their un-deformed state. This reduction in chain entanglement results in lower viscosity.
• Shear thinning is characterized by the decrease of complex dynamic viscosity with increasing frequency of the sinusoidally applied shear.
• Shear thinning ratio is defined as a ratio of the complex shear viscosity at frequency of 0.245 rad/sec to that at frequency of 128 rad/sec.
• Mooney Large viscosity (ML) and Mooney Relaxation Area (MLRA) are measured using a Mooney viscometer according to ASTM D-1646, modified as detailed in the following description. A sample is placed on either side of the rotor. The cavity is filled by pneumatically lowering the upper platen. The upper and lower platens are electrically heated and controlled at 125°C. The torque to turn the rotor at 2 rpm is measured by a torque transducer. Mooney viscometer is operated at an average shear rate of 2 s-1. The sample is pre-heated for 1 minute after the platens are closed. The motor is then started and the torque is recorded for a period of 4 minutes.
• the torque limit of the Mooney viscometer is about 100 Mooney units. Mooney viscosity values greater than about 100 Mooney unit cannot generally be measured under these conditions.
• a non-standard rotor design is employed with a change in Mooney scale that allows the same instrumentation on the Mooney viscometer to be used for more viscous polymers.
• This rotor that is both smaller in diameter and thinner than the standard Mooney Large (ML) rotor is termed MST — Mooney Small Thin.
• MST Mooney Large
• the test is also run at different time and temperature. The pre-heat time is changed from the standard 1 minute to 5 minutes and the test is run at 200°C instead of the standard 125°C.
• MST MST
• the MST rotor should be prepared as follows: a. The rotor should have a diameter of 30.48+/-0.03 mm and a thickness of 2.8+/-0.03 mm (tops of serrations) and a shaft of 11 mm or less in diameter. b.
• the rotor should have a serrated face and edge, with square grooves of 0.8 mm width and depth of 0.25-0.38 mm cut on 1.6 mm centers.
• the serrations will consist of two sets of grooves at right angles to each other (form a square crosshatch).
• the rotor shall be positioned in the center of the die cavity such that the centerline of the rotor disk coincides with the centerline of the die cavity to within a tolerance of +/-0.25 mm. A spacer or a shim may be used to raise the shaft to the midpoint.
• the wear point (cone shaped protuberance located at the center of the top face of the rotor) shall be machined off flat with the face of the rotor.
• the MLRA data is obtained from the Mooney viscosity measurement when the rubber relaxes after the rotor is stopped.
• the MLRA is the integrated area under the Mooney torque- relaxation time curve from 1 to 100 seconds.
• the MLRA is a measure of chain relaxation in molten polymer and can be regarded as a stored energy term which suggests that, after the removal of an applied strain, the longer or branched polymer chains can store more energy and require longer time to relax. Therefore, the MLRA value of a bimodal rubber (the presence of a discrete polymeric fraction with very high molecular weight and distinct composition) or a long chain branched rubber are larger than a broad or a narrow molecular weight rubber when compared at the same Mooney viscosity values.
• Mooney Relaxation Area is dependent on the Mooney viscosity of the polymer, and increases with increasing Mooney viscosity.
• a corrected MLRA (cMLRA) parameter is used, where the MLRA of the polymer is normalized to a reference of 80 Mooney viscosity.
• cMLRA corrected MLRA
• the formula for cMLRA is provided below where MLRA and ML are the Mooney Relaxation Area and Mooney viscosity of the polymer sample measured at 125°C.
• Molecular weight and composition distribution (GPC-IR): The distribution and the moments of molecular weight (e.g., Mn, Mw, Mz ) and the comonomer distribution (C2, C3, Ce, etc.), are determined with a high temperature Gel Permeation Chromatography (PolymerChar GPC-IR) equipped with a multiple-channel band filter based infrared detector ensemble IR5, an 18-angle light scattering detector and a viscometer. A broad-band channel is used to measure the polymer concentration while two narrow-band channels are used for characterizing composition. Three Agilent PLgel lOpm Mixed-B LS columns are used to provide polymer separation.
• TCB Aldrich reagent grade 1,2,4-trichlorobenzene
• BHT butylated hydroxytoluene
• the TCB mixture is filtered through a 0.1 micrometer Teflon filter and degassed with an online degasser before entering the GPC instrument.
• the nominal flow rate is 1.0 mL/min and the nominal injection volume is 200 microliter.
• the whole system including transfer lines, columns, detectors are contained in an oven maintained at 145°C. Given amount of polymer sample is weighed and sealed in a standard vial with 10 microliter flow marker (Heptane) added to it.
• Heptane microliter flow marker
• polymer After loading the vial in the autosampler, polymer is automatically dissolved in the instrument with 8 mL added TCB solvent. The polymer is dissolved at 160°C with continuous shaking for about 1 hour for most PE samples or 2 hour for PP samples.
• the TCB densities used in concentration calculation are 1.463 g/ml at room temperature and 1.284 g/ml at 145°C.
• the sample solution concentration is from 0.2 to 2.0 mg/ml, with lower concentrations being used for higher molecular weight samples.
• the mass recovery is calculated from the ratio of the integrated area of the concentration chromatography over elution volume and the injection mass which is equal to the pre-determined concentration multiplied by injection loop volume.
• the molecular weight (IR MW) is determined by combining universal calibration relationship with the column calibration which is performed with a series of mono-dispersed polystyrene (PS) standards. The molecular weight is calculated at each elution volume with following equation.
• log ⁇ logM x PS
• K and a are the coefficients in the Mark-Houwink equation.
• the variables with subscript “X” stand for the test sample while those with subscript “PS” stand for polystyrene.
• c arc determined based on the composition of linear ethylene/propylene copolymer and linear ethylene -propylene-diene terpolymers using a standard calibration procedure.
• the comonomer composition is determined by the ratio of the IR detector intensity corresponding to C3 ⁇ 4 and CH 3 channel calibrated with a series of PE and PP homo/copolymer standards whose nominal value are predetermined by NMR.
• the LS detector is the 18-angle Wyatt Technology High Temperature DAWN HELEOSII.
• the LS molecular weight (M) at each point in the chromatogram is determined by analyzing the LS output using the Zimm model for static light scattering ⁇ Light Scattering from Polymer Solutions ; Huglin, M. B., Ed.; Academic Press, 1972.):
• AR(9) is the measured excess Rayleigh scattering intensity at scattering angle Q
• c is the polymer concentration determined from the IR5 analysis
• A2 is the second virial coefficient
• R(q) is the form factor for a monodisperse random coil
• K 0 is the optical constant for the system: where NA is Avogadro’s number, and (dn/dc) is the refractive index increment for the system.
• a high temperature Agilent (or Viscotek Corporation) viscometer which has four capillaries arranged in a Wheatstone bridge configuration with two pressure transducers, is used to determine specific viscosity.
• One transducer measures the total pressure drop across the detector, and the other, positioned between the two sides of the bridge, measures a differential pressure.
• the specific viscosity, q s for the solution flowing through the viscometer is calculated from their outputs.
• the intrinsic viscosity, [h] qs/c, where c is concentration and is determined from the IR5 broadband channel output.
• the viscosity MW at each point is calculated as
• K PS M K PS M a * +1 /w , where a ps is 0.67 and Kps is 0.000175.
• the average intrinsic viscosity, [q] avg , of the sample is calculated by: where the summations are over the chromatographic slices, i, between the integration limits.
• Ethylene content is determined using FTIR according the ASTM D3900 and is not corrected for diene content.
• ENB is determined using FTIR according to ASTM D6047. The content of other diene if present can be obtained using C13 NMR.
• the comonomer content and sequence distribution of the polymers can be measured using 13 C nuclear magnetic resonance (NMR) by methods well known to those skilled in the art.
• NMR 13 C nuclear magnetic resonance
• Comonomer content of discrete molecular weight ranges can be measured using methods well known to those skilled in the art, including Fourier Transform Infrared Spectroscopy (FTIR) in conjunction with samples by GPC, as described in Wheeler and Willis, Applied Spectroscopy, 1993, v. 47, pp. 1128-1130.
• FTIR Fourier Transform Infrared Spectroscopy
• Peak melting point, Tm, (also referred to as melting point), peak crystallization temperature, Tc, (also referred to as crystallization temperature), glass transition temperature (Tg), heat of fusion (AHf or Hf), and percent crystallinity were determined using the following DSC procedure according to ASTM D3418-03. Differential scanning calorimetric (DSC) data were obtained using a TA Instruments model Q200 machine. Samples weighing approximately 5-10 mg were sealed in an aluminum hermetic sample pan. The DSC data were recorded by first gradually heating the sample to 200°C at a rate of 10°C/minute.
• the sample was kept at 200°C for 2 minutes, then cooled to -90°C at a rate of 10°C/minute, followed by an isothermal for 2 minutes and heating to 200°C at 10°C/minute. Both the first and second cycle thermal events were recorded. Areas under the endothermic peaks were measured and used to determine the heat of fusion and the percent of crystallinity. The percent crystallinity is calculated using the formula, [area under the melting peak (Joules/gram) / B (Joules/gram)] * 100, where B is the heat of fusion for the 100% crystalline homopolymer of the major monomer component.
• THF for organometallic synthesis was freshly distilled from sodium benzophenone ketyl. Toluene and hexanes for organometallic synthesis were dried over MS 4A.
• 2-(Adamantan-l-yl)-4-(tert-butyl)phenol was prepared from 4-tert-butylphenol (Merck) and adamantanol-1 (Aldrich) as described in Organic Letters , 2015, V.17(9), 2242-2245.
• Ethylene, propylene, hydrogen and ENB feeds were combined into one stream and then mixed with a pre chilled isohexane stream that had been cooled to at least 0°C. The mixture was then fed to the reactor through a single line. Solutions of tri(n-octyl)aluminum (TNOA) were added to the combined solvent and monomer stream just before they entered the reactor. Catalyst solution was fed to the reactor using an ISCO syringe pump through a separated line. [0260] Isohexane (used as solvent) and monomers (e.g., ethylene and propylene) were purified over beds of alumina and molecular sieves.
• TNOA tri(n-octyl)aluminum
• Toluene for preparing catalyst solutions was purified by the same technique. 5-ethylidene-2-norbornene (ENB) was purified over beds of alumina.
• the complex Cat-Zr was used for Examples 1 to 12.
• the catalyst solution was prepared by combining Cat-Zr (ca. 20 mg) with N,N-dimethylanilinium tetrakis(pentafluorophenyl) borate at a molar ratio of about 1:1 in 900 ml of toluene.
• Solution of tri-n-octyl aluminum (TNOA) 25 wt % in hexane, Sigma Aldrich
• the polymer produced in the reactor exited through a back pressure control valve that reduced the pressure to atmospheric. This caused the unconverted monomers in the solution to flash into a vapor phase which was vented from the top of a vapor liquid separator.
• the liquid phase comprising mainly polymer and solvent, was collected for polymer recovery.
• the collected samples were first stabilized with IR1076 (available from BASF), then steam-dried in a hood to evaporate most of the solvent, and then further dried in a vacuum oven at a temperature of about 90°C for about 12 hours. The vacuum oven dried samples were weighed to obtain yields.
• Activation of the complexes was performed using either dimethylanilinium tetrakis(perfluorophenyl)borate (Activator Al, Boulder Scientific or W.R. Grace), or dimethylanilinium tetrakis(perfluoronaphthalen-2-yl)borate (Activator A2, W.R. Grace).
• A2 dimethylanilinium tetrakis(perfluoronaphthalen-2-yl)borate
• TNOAL tri-n-octylaluminum
• Solvents, polymerization grade toluene and/or isohexanes were supplied by ExxonMobil Chemical Co. and are purified by passing through a series of columns: two 500 cc Oxyclear cylinders in series from Labclear (Oakland, Calif.), followed by two 500 cc columns in series packed with dried 3 A mole sieves (8-12 mesh; Aldrich Chemical Company), and two 500 cc columns in series packed with dried 5 A mole sieves (8-12 mesh; Aldrich Chemical Company).
• EMB 5-ethylidene-2-norbornene
• Polymerization grade propylene was purified by passage through a series of columns: 2,250 cc OXICLEAR cylinder from Labclear followed by a 2,250 cc column packed with 3 A molecular sieves (8-12 mesh; Aldrich Chemical Company), then two 500 cc columns in series packed with 5 A molecular sieves (8-12 mesh; Aldrich Chemical Company), then a 500 cc column packed with SELEXSORB CD (BASF), and finally a 500 cc column packed with SELEXSORB COS (BASF).
• Ethylene was allowed to enter (through the use of computer controlled solenoid valves) the autoclaves during polymerization to maintain reactor gauge pressure (+/- 2 psig). Reactor temperature was monitored and typically maintained within +/-1°C. Polymerizations were halted by addition of approximately 50 psi CO2 gas to the autoclave for approximately 30 seconds. The polymerizations were quenched after a predetermined cumulative amount of ethylene had been added (maximum quench value of 20 psi) or for a maximum of 30 minutes polymerization time (maximum quench time). Afterwards, the reactors were cooled and vented.
• Isohexane, and ENB (5.0, 11.25, 16.9, 25.3, or 38.0 pL) and scavenger (TnOAl, 0.5 pmol)
• Reactor temperature was monitored and typically maintained within +/-1°C. Polymerizations were halted by addition of approximately 50 psi CO2 gas to the autoclave for approximately 30 seconds. The polymerizations were quenched after a predetermined cumulative pressure drop had occurred (maximum quench value of 8 psi) or for a maximum of 30 minutes polymerization time (maximum quench time). Afterwards, the reactors were cooled and vented. While still under an inert atmosphere, the polymers were stabilized with the addition of a 100 uL solution of Irganox 1076 in toluene (prepared by dissolving 2.5 g of Irganox 1076 in a total of 20 ml toluene).
• polymer sample solutions were prepared by dissolving polymer in 1,2,4-trichlorobenzene (TCB, 99+% purity from Sigma- Aldrich) containing 2,6-di-tert-butyl-4- methylphenol (BHT, 99% from Aldrich) at 165°C in a shaker oven for approximately 3 hours.
• the typical concentration of polymer in solution was between 0.1 to 0.9 mg/mL with a BHT concentration of 1.25 mg BHT/mL of TCB. Samples were cooled to 135°C for testing.
• PDI polydispersity
• DSC Differential Scanning Calorimetry
• ENB content of the polymers was determined as follows: The 'H solution NMR was performed on a 5mm probe at a field of at least 500 MHz in tetrachloroethane-d2 solvent (or a 80:20 v/v ortho-dichlorobenzene and CeDe mixture) at 120°C with a flip angle of 30°, 15 second delay and 512 transients. Signals were integrated and the ENB weight percent was reported. [0281] For calculation of ENB in ethylene-ENB copolymers:
• Iminor Integral of minor ENB species from 4.6-5.12 ppm
• Imajor Integral of major ENB species from 5.2-5.4 ppm
• Iminor Integral of minor ENB species from 4.6-5.12 ppm
• Ialiph (Integral of -CEhCHiCEb)- from 0-3 ppm)
• Ethylene-ENB copolymerizations Standard condition include, 0.08 umol pre-catalyst, 0.088 umol activator, 0.5 umol TNOAL used as scavenger, 100 psi ethylene with uptake, 100°C reactor temperature. Polymerizations were quenched after 20 psi ethylene uptake or after 30 minutes.
• Table B Propylene-ENB copolymerizations. Standard condition include, 0.16 umol pre-catalyst, 0.176 umol activator, 0.5 umol TNOAL used as scavenger, 100 psi propylene, 100°C reactor temperature. Polymerizations were quenched after 8 psi pressure loss or after 30 minutes.
• compositions, an element or a group of elements are preceded with the transitional phrase “comprising”, it is understood that we also contemplate the same composition or group of elements with transitional phrases “consisting essentially of,” “consisting of”, “selected from the group of consisting of,” or “is” preceding the recitation of the composition, element, or elements and vice versa.

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