CN113278169A - 交联引发剂和促进剂的初级混合物 - Google Patents
交联引发剂和促进剂的初级混合物 Download PDFInfo
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- CN113278169A CN113278169A CN202110200363.XA CN202110200363A CN113278169A CN 113278169 A CN113278169 A CN 113278169A CN 202110200363 A CN202110200363 A CN 202110200363A CN 113278169 A CN113278169 A CN 113278169A
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- crosslinking
- radical initiator
- polyethylene
- mixture
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Images
Classifications
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/14—Peroxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0025—Crosslinking or vulcanising agents; including accelerators
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/101—Esters; Ether-esters of monocarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/22—Compounds containing nitrogen bound to another nitrogen atom
- C08K5/23—Azo-compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3415—Five-membered rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/441—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2312/00—Crosslinking
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- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
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- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Graft Or Block Polymers (AREA)
- General Chemical & Material Sciences (AREA)
- Adhesives Or Adhesive Processes (AREA)
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| CN201380058834.1A CN104797637A (zh) | 2012-09-12 | 2013-09-06 | 交联引发剂和促进剂的初级混合物 |
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| CN109563214A (zh) * | 2016-08-31 | 2019-04-02 | 陶氏环球技术有限责任公司 | 改性聚乙烯 |
| JP2018127510A (ja) * | 2017-02-06 | 2018-08-16 | Nok株式会社 | 過酸化物架橋ゴム用遅延剤マスターバッチとその製造方法 |
| KR102581351B1 (ko) * | 2018-11-05 | 2023-09-20 | 주식회사 엘지화학 | 폴리에틸렌 수지의 물성 예측 방법 및 폴리에틸렌 수지의 제조 방법 |
| KR102676757B1 (ko) * | 2018-12-21 | 2024-06-18 | 주식회사 엘지화학 | 폴리에틸렌 수지의 물성 예측 방법 및 폴리에틸렌 수지의 제조 방법 |
| KR102286151B1 (ko) * | 2019-12-24 | 2021-08-06 | (주)티에스씨 | 저독성 난연 폴리올레핀계 절연 수지 조성물, 절연전선 및 절연전선의 제조방법 |
| GB202311215D0 (en) * | 2023-07-21 | 2023-09-06 | Colormatrix Holdings Inc | Polymeric materials |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4212787A (en) * | 1977-05-26 | 1980-07-15 | Mitsui Petrochemical Industries Ltd. | Thermoplastic elastomer composition, blends of the composition with olefin plastic, and foamed products of the composition and the blends |
| US5252676A (en) * | 1991-06-24 | 1993-10-12 | Nippon Oil & Fats Co., Ltd. | Ethylene polymer crosslinking composition |
| CN1478118A (zh) * | 2000-10-03 | 2004-02-25 | ���з��ɹ�˾ | 含有氮氧化物、促进剂和任选自由基引发剂的组合物 |
| US20040195550A1 (en) * | 2003-04-03 | 2004-10-07 | Atofina | Composition comprising a nitroxide, a promoter and optionally a free-radical initiator |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1025672A (en) | 1961-10-12 | 1966-04-14 | Furukawa Electric Co Ltd | Method of manufacturing electric wires covered with cross-linked polyethylene |
| US4101512A (en) | 1976-08-23 | 1978-07-18 | General Cable Corporation | Dispersion of antioxidant in cross-linkable polyethylene |
| JPS53149241A (en) | 1977-06-02 | 1978-12-26 | Mitsui Petrochem Ind Ltd | Production of thermoplastic elastomer composition |
| JPS53145857A (en) * | 1977-05-26 | 1978-12-19 | Mitsui Petrochem Ind Ltd | Preparation of thermoplastic elastomer composition |
| JPS6081490A (ja) | 1983-10-13 | 1985-05-09 | Tokyo Tatsuno Co Ltd | ポンプ装置 |
| JPH0676518B2 (ja) | 1986-02-28 | 1994-09-28 | 三井石油化学工業株式会社 | 熱可塑性エラストマー |
| JPH0651796B2 (ja) | 1985-07-18 | 1994-07-06 | 三井石油化学工業株式会社 | 微粒状架橋非晶質共重合体及びその製造法 |
| JPH0379650A (ja) | 1990-03-26 | 1991-04-04 | Mitsui Petrochem Ind Ltd | 熱可塑性エラストマーの製造方法 |
| JP2672079B2 (ja) | 1995-08-28 | 1997-11-05 | 三井石油化学工業株式会社 | 熱可塑性エラストマーの製造法 |
| JPH11181174A (ja) | 1997-12-19 | 1999-07-06 | Asahi Chem Ind Co Ltd | オレフィン系熱可塑性エラストマー組成物の製造方法 |
| US6303666B1 (en) | 1998-07-30 | 2001-10-16 | Mitsui Chemicals, Inc. | Process for the production of expanded olefinic thermoplastic elastomer products |
| FR2822472A1 (fr) * | 2001-03-23 | 2002-09-27 | Atofina | Compostion de reticulation et composition reticulable |
| US7160958B2 (en) | 2005-05-09 | 2007-01-09 | Geo Specialty Chemicals, Inc. | Method of increasing the absorption rate of peroxides into polymer particles |
| ATE533814T1 (de) * | 2008-01-17 | 2011-12-15 | Basf Se | Modifizierte olefinpolymere |
| CN101608031A (zh) | 2009-04-24 | 2009-12-23 | 无锡丰力塑化科技有限公司 | 一种快速硅烷交联聚乙烯专用料的制备方法 |
| FR2972560A1 (fr) | 2011-03-08 | 2012-09-14 | Nexans | Cable electrique a moyenne ou haute tension |
| JP6051796B2 (ja) * | 2012-11-08 | 2016-12-27 | 株式会社リコー | 画像形成装置、センシング方法、プログラム及び記録媒体 |
-
2012
- 2012-09-12 FR FR1258569A patent/FR2995313B1/fr active Active
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2013
- 2013-09-06 EP EP13765378.8A patent/EP2895536B1/fr not_active Revoked
- 2013-09-06 PL PL13765378T patent/PL2895536T3/pl unknown
- 2013-09-06 KR KR1020157009338A patent/KR20150058307A/ko not_active Ceased
- 2013-09-06 WO PCT/FR2013/052059 patent/WO2014041287A1/fr not_active Ceased
- 2013-09-06 ES ES13765378.8T patent/ES2635002T3/es active Active
- 2013-09-06 JP JP2015530482A patent/JP6471093B2/ja active Active
- 2013-09-06 CN CN202110200363.XA patent/CN113278169A/zh active Pending
- 2013-09-06 KR KR1020187033766A patent/KR102087536B1/ko active Active
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-
2015
- 2015-03-12 SA SA515360130A patent/SA515360130B1/ar unknown
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4212787A (en) * | 1977-05-26 | 1980-07-15 | Mitsui Petrochemical Industries Ltd. | Thermoplastic elastomer composition, blends of the composition with olefin plastic, and foamed products of the composition and the blends |
| US5252676A (en) * | 1991-06-24 | 1993-10-12 | Nippon Oil & Fats Co., Ltd. | Ethylene polymer crosslinking composition |
| CN1478118A (zh) * | 2000-10-03 | 2004-02-25 | ���з��ɹ�˾ | 含有氮氧化物、促进剂和任选自由基引发剂的组合物 |
| US20040195550A1 (en) * | 2003-04-03 | 2004-10-07 | Atofina | Composition comprising a nitroxide, a promoter and optionally a free-radical initiator |
Non-Patent Citations (2)
| Title |
|---|
| 《电线电缆手册》编写组, 国防工业出版社 * |
| ISMAIL GHASEMI, ET AL.: "The Effect of Co-agent on the Peroxide Cross-linking of LDPE" * |
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| Publication number | Publication date |
|---|---|
| ES2635002T3 (es) | 2017-10-02 |
| CN104797637A (zh) | 2015-07-22 |
| WO2014041287A1 (fr) | 2014-03-20 |
| US10808051B2 (en) | 2020-10-20 |
| PL2895536T3 (pl) | 2017-10-31 |
| SA515360130B1 (ar) | 2016-01-27 |
| EP2895536B1 (fr) | 2017-06-14 |
| EP2895536A1 (fr) | 2015-07-22 |
| JP6471093B2 (ja) | 2019-02-13 |
| US20150239997A1 (en) | 2015-08-27 |
| JP2015527475A (ja) | 2015-09-17 |
| KR20150058307A (ko) | 2015-05-28 |
| KR102087536B1 (ko) | 2020-03-10 |
| KR20180127550A (ko) | 2018-11-28 |
| FR2995313B1 (fr) | 2015-08-21 |
| FR2995313A1 (fr) | 2014-03-14 |
| BR112015005497B1 (pt) | 2021-11-03 |
| BR112015005497A2 (pt) | 2017-07-04 |
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