CN112876084A - 量子点微晶玻璃及其制备和应用3d打印技术制备量子点微晶玻璃制品的方法 - Google Patents
量子点微晶玻璃及其制备和应用3d打印技术制备量子点微晶玻璃制品的方法 Download PDFInfo
- Publication number
- CN112876084A CN112876084A CN202011564505.2A CN202011564505A CN112876084A CN 112876084 A CN112876084 A CN 112876084A CN 202011564505 A CN202011564505 A CN 202011564505A CN 112876084 A CN112876084 A CN 112876084A
- Authority
- CN
- China
- Prior art keywords
- pbbr
- quantum dot
- glass
- raw material
- temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002096 quantum dot Substances 0.000 title claims abstract description 83
- 239000002241 glass-ceramic Substances 0.000 title claims abstract description 57
- 238000000034 method Methods 0.000 title claims abstract description 19
- 238000010146 3D printing Methods 0.000 title claims abstract description 18
- 238000005516 engineering process Methods 0.000 title claims abstract description 9
- 238000002360 preparation method Methods 0.000 title claims abstract description 7
- JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 claims abstract description 50
- FJDQFPXHSGXQBY-UHFFFAOYSA-L caesium carbonate Chemical compound [Cs+].[Cs+].[O-]C([O-])=O FJDQFPXHSGXQBY-UHFFFAOYSA-L 0.000 claims abstract description 46
- 239000011521 glass Substances 0.000 claims abstract description 39
- 239000002994 raw material Substances 0.000 claims abstract description 33
- 229910000024 caesium carbonate Inorganic materials 0.000 claims abstract description 25
- ZASWJUOMEGBQCQ-UHFFFAOYSA-L dibromolead Chemical compound Br[Pb]Br ZASWJUOMEGBQCQ-UHFFFAOYSA-L 0.000 claims abstract description 19
- 239000011159 matrix material Substances 0.000 claims abstract description 4
- 238000010438 heat treatment Methods 0.000 claims description 33
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 23
- 239000000463 material Substances 0.000 claims description 13
- 238000002844 melting Methods 0.000 claims description 10
- 230000008018 melting Effects 0.000 claims description 10
- 239000000843 powder Substances 0.000 claims description 10
- 238000000137 annealing Methods 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 9
- 239000011347 resin Substances 0.000 claims description 9
- 229920005989 resin Polymers 0.000 claims description 9
- 229910001018 Cast iron Inorganic materials 0.000 claims description 8
- 229910052681 coesite Inorganic materials 0.000 claims description 8
- 229910052906 cristobalite Inorganic materials 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- 239000000377 silicon dioxide Substances 0.000 claims description 8
- 229910052682 stishovite Inorganic materials 0.000 claims description 8
- 229910052905 tridymite Inorganic materials 0.000 claims description 8
- 238000000227 grinding Methods 0.000 claims description 7
- 239000004570 mortar (masonry) Substances 0.000 claims description 7
- 238000001816 cooling Methods 0.000 claims description 4
- 239000000156 glass melt Substances 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 238000007639 printing Methods 0.000 claims description 4
- 239000002002 slurry Substances 0.000 claims description 4
- 238000004321 preservation Methods 0.000 claims description 2
- 238000007873 sieving Methods 0.000 claims description 2
- 239000012855 volatile organic compound Substances 0.000 claims 1
- 238000004020 luminiscence type Methods 0.000 abstract description 5
- 239000006121 base glass Substances 0.000 description 10
- 229910052593 corundum Inorganic materials 0.000 description 8
- 239000010431 corundum Substances 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 238000005303 weighing Methods 0.000 description 5
- 238000002441 X-ray diffraction Methods 0.000 description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
- 239000007788 liquid Substances 0.000 description 3
- 239000006064 precursor glass Substances 0.000 description 3
- LYQFWZFBNBDLEO-UHFFFAOYSA-M caesium bromide Chemical group [Br-].[Cs+] LYQFWZFBNBDLEO-UHFFFAOYSA-M 0.000 description 2
- 239000002159 nanocrystal Substances 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- 238000006862 quantum yield reaction Methods 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 238000003917 TEM image Methods 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 238000000498 ball milling Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000005388 borosilicate glass Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000000295 emission spectrum Methods 0.000 description 1
- 238000011534 incubation Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 229910001502 inorganic halide Inorganic materials 0.000 description 1
- 238000010406 interfacial reaction Methods 0.000 description 1
- 238000001000 micrograph Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000012255 powdered metal Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000005368 silicate glass Substances 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C10/00—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition
- C03C10/16—Halogen containing crystalline phase
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y10/00—Processes of additive manufacturing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y70/00—Materials specially adapted for additive manufacturing
- B33Y70/10—Composites of different types of material, e.g. mixtures of ceramics and polymers or mixtures of metals and biomaterials
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B19/00—Other methods of shaping glass
- C03B19/06—Other methods of shaping glass by sintering, e.g. by cold isostatic pressing of powders and subsequent sintering, by hot pressing of powders, by sintering slurries or dispersions not undergoing a liquid phase reaction
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B25/00—Annealing glass products
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B32/00—Thermal after-treatment of glass products not provided for in groups C03B19/00, C03B25/00 - C03B31/00 or C03B37/00, e.g. crystallisation, eliminating gas inclusions or other impurities; Hot-pressing vitrified, non-porous, shaped glass products
- C03B32/02—Thermal crystallisation, e.g. for crystallising glass bodies into glass-ceramic articles
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B5/00—Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
- C03B5/16—Special features of the melting process; Auxiliary means specially adapted for glass-melting furnaces
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C4/00—Compositions for glass with special properties
- C03C4/12—Compositions for glass with special properties for luminescent glass; for fluorescent glass
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Ceramic Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Manufacturing & Machinery (AREA)
- Geochemistry & Mineralogy (AREA)
- Crystallography & Structural Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Civil Engineering (AREA)
- Composite Materials (AREA)
- Structural Engineering (AREA)
- Glass Compositions (AREA)
Abstract
Description
Cs<sub>2</sub>CO<sub>3</sub> | NaBr | PbBr<sub>2</sub> | |
实施例1 | 9.2% | 13.5% | 2.3% |
实施例2 | 8.4% | 13.8% | 2.8% |
实施例3 | 8.2% | 13.6% | 3.2% |
实施例4 | 8% | 13% | 4% |
实施例5 | 7.8% | 12.6% | 4.6% |
Claims (10)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202011564505.2A CN112876084B (zh) | 2020-12-25 | 2020-12-25 | 量子点微晶玻璃及其制备和应用3d打印技术制备量子点微晶玻璃制品的方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202011564505.2A CN112876084B (zh) | 2020-12-25 | 2020-12-25 | 量子点微晶玻璃及其制备和应用3d打印技术制备量子点微晶玻璃制品的方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN112876084A true CN112876084A (zh) | 2021-06-01 |
CN112876084B CN112876084B (zh) | 2022-12-09 |
Family
ID=76043620
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202011564505.2A Active CN112876084B (zh) | 2020-12-25 | 2020-12-25 | 量子点微晶玻璃及其制备和应用3d打印技术制备量子点微晶玻璃制品的方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN112876084B (zh) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114133141A (zh) * | 2021-12-28 | 2022-03-04 | 海南大学 | 一种钙钛矿量子点微晶玻璃及其制备方法 |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6058738A (en) * | 1997-10-17 | 2000-05-09 | Corning Incorporated | Method of forming glass having integral polarizing and non-polarizing regions |
EP1061056A1 (en) * | 1999-06-15 | 2000-12-20 | Agfa-Gevaert N.V. | A fluoro glass ceramic showing photostimulabe properties |
CN108424001A (zh) * | 2018-04-04 | 2018-08-21 | 武汉理工大学 | 一种CsPbX3纳米晶掺杂含硼玻璃及其制备方法 |
CN109052457A (zh) * | 2018-10-29 | 2018-12-21 | 西南交通大学 | 一种无机钙钛矿纳米片及其制备方法 |
US20190169498A1 (en) * | 2016-08-26 | 2019-06-06 | King Abdullah University Of Science And Technology | Compositions and methods relating to luminescent structures |
CN110294597A (zh) * | 2019-05-28 | 2019-10-01 | 华南农业大学 | 一种宽色域显示用铯铅溴钙钛矿量子点荧光玻璃及其制备方法和应用 |
CN110846715A (zh) * | 2019-11-01 | 2020-02-28 | 南京航空航天大学 | 大尺寸零维Cs4PbBr6/CsPbBr3钙钛矿闪烁晶体及其制备方法 |
CN111960461A (zh) * | 2020-07-20 | 2020-11-20 | 齐鲁工业大学 | 一种可以对激光性能调控的零维钙钛矿Cs4PbBr6微米晶及其制备方法 |
-
2020
- 2020-12-25 CN CN202011564505.2A patent/CN112876084B/zh active Active
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6058738A (en) * | 1997-10-17 | 2000-05-09 | Corning Incorporated | Method of forming glass having integral polarizing and non-polarizing regions |
EP1061056A1 (en) * | 1999-06-15 | 2000-12-20 | Agfa-Gevaert N.V. | A fluoro glass ceramic showing photostimulabe properties |
US20190169498A1 (en) * | 2016-08-26 | 2019-06-06 | King Abdullah University Of Science And Technology | Compositions and methods relating to luminescent structures |
CN108424001A (zh) * | 2018-04-04 | 2018-08-21 | 武汉理工大学 | 一种CsPbX3纳米晶掺杂含硼玻璃及其制备方法 |
CN109052457A (zh) * | 2018-10-29 | 2018-12-21 | 西南交通大学 | 一种无机钙钛矿纳米片及其制备方法 |
CN110294597A (zh) * | 2019-05-28 | 2019-10-01 | 华南农业大学 | 一种宽色域显示用铯铅溴钙钛矿量子点荧光玻璃及其制备方法和应用 |
CN110846715A (zh) * | 2019-11-01 | 2020-02-28 | 南京航空航天大学 | 大尺寸零维Cs4PbBr6/CsPbBr3钙钛矿闪烁晶体及其制备方法 |
CN111960461A (zh) * | 2020-07-20 | 2020-11-20 | 齐鲁工业大学 | 一种可以对激光性能调控的零维钙钛矿Cs4PbBr6微米晶及其制备方法 |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114133141A (zh) * | 2021-12-28 | 2022-03-04 | 海南大学 | 一种钙钛矿量子点微晶玻璃及其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
CN112876084B (zh) | 2022-12-09 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN109987848B (zh) | 一种含CsPbBr3量子点超晶格结构玻璃及其制备方法 | |
CN110194593B (zh) | 一种通过添加氟化物促进全无机钙钛矿量子点在玻璃中析晶的方法 | |
CN108285272A (zh) | 一种CsPb2Br5量子点微晶玻璃材料及其制备方法 | |
CN108423984B (zh) | 一种二价锰掺杂的全无机钙钛矿量子点玻璃及其制备方法和应用 | |
WO2019183840A1 (zh) | 一种二价锰掺杂的全无机钙钛矿量子点玻璃及其制备方法和应用 | |
CN113912291B (zh) | 一种全无机钙钛矿量子点荧光玻璃及其制备方法和应用 | |
JP5842701B2 (ja) | 希土類元素が拡散された酸化物セラミック蛍光材料 | |
CN112876084B (zh) | 量子点微晶玻璃及其制备和应用3d打印技术制备量子点微晶玻璃制品的方法 | |
CN110002762A (zh) | 一种Yb3+和CsPbBr3纳米晶掺杂的硼锗酸盐玻璃、其制备方法和应用 | |
CN111517657B (zh) | 一种Sr2+掺杂CsPbBr3量子点锗硼硅玻璃、制备方法及应用 | |
CN113754411A (zh) | 一种基于3D打印红色釉上彩Ce:YAG荧光陶瓷的制备方法 | |
CN111592227B (zh) | Cs3Sb2Br9钙钛矿纳米晶复合硫系玻璃陶瓷材料及其制备方法 | |
CN111302634A (zh) | Zn2+掺杂卤化铅铯量子点微晶玻璃作为催化剂在光催化水产氢中的应用 | |
CN114735934B (zh) | 一种Cu/Cr掺杂的荧光玻璃 | |
CN114853464B (zh) | 一种高光学质量的绿色荧光陶瓷及其制备方法 | |
CN109942193B (zh) | 一种CsPb1-xTixI3红光微晶玻璃及其制备方法 | |
CN108409148B (zh) | 红外非相干LED激发的上转换NaLuF4玻璃陶瓷及其制备方法 | |
CN113149429B (zh) | 一种含金属纳米颗粒的高硼硅玻璃及其制备方法 | |
CN115124247A (zh) | 一种全无机钙钛矿量子点微晶玻璃材料及制备方法 | |
CN102060442A (zh) | 白光led用荧光微晶玻璃制备方法 | |
CN108585482A (zh) | 一种白光led用荧光玻璃片及其制备方法 | |
CN109180011B (zh) | 一种PbTe/CdTe双量子点共掺硼硅酸盐玻璃及其制备工艺 | |
CN110776255B (zh) | 一种天然矿物-钙长石微晶釉料及其制备方法和使用方法 | |
CN108558204B (zh) | 一种可调控光谱的Eu,Dy掺杂的发光玻璃及其制备方法 | |
CN112062472B (zh) | 一种高硬度Lu2Si2O7透明微晶玻璃及其制备方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant | ||
EE01 | Entry into force of recordation of patent licensing contract |
Application publication date: 20210601 Assignee: GUANGDONG ODIMING PHOTOELECTRIC TECHNOLOGY CO.,LTD. Assignor: Wenzhou University Contract record no.: X2024330000059 Denomination of invention: Quantum dot microcrystalline glass and its preparation and application Method for preparing quantum dot microcrystalline glass products using 3D printing technology Granted publication date: 20221209 License type: Exclusive License Record date: 20240516 |
|
EE01 | Entry into force of recordation of patent licensing contract |