CN1125025C - 催化剂、其制备方法和使用其制备乙酸乙烯酯的方法 - Google Patents

催化剂、其制备方法和使用其制备乙酸乙烯酯的方法 Download PDF

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Publication number
CN1125025C
CN1125025C CN98123285A CN98123285A CN1125025C CN 1125025 C CN1125025 C CN 1125025C CN 98123285 A CN98123285 A CN 98123285A CN 98123285 A CN98123285 A CN 98123285A CN 1125025 C CN1125025 C CN 1125025C
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CN
China
Prior art keywords
palladium
compound
carrier
solution
alkali metal
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Expired - Fee Related
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CN98123285A
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English (en)
Chinese (zh)
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CN1221731A (zh
Inventor
B·赫佐格
R·斯泰恩
K－H·伦凯尔
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Celanese GmbH
Celanese AG
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Celanese AG
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Publication of CN1221731A publication Critical patent/CN1221731A/zh
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0205—Impregnation in several steps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/52—Gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/58—Platinum group metals with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0236—Drying, e.g. preparing a suspension, adding a soluble salt and drying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
    • C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
    • C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN98123285A 1997-12-11 1998-12-10 催化剂、其制备方法和使用其制备乙酸乙烯酯的方法 Expired - Fee Related CN1125025C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19754991.8 1997-12-11
DE19754991A DE19754991C2 (de) 1997-12-11 1997-12-11 Katalysator, Verfahren zur Herstellung des Katalysators und Verfahren zur Herstellung von Vinylacetat unter Einsatz des Katalysators

Publications (2)

Publication Number Publication Date
CN1221731A CN1221731A (zh) 1999-07-07
CN1125025C true CN1125025C (zh) 2003-10-22

Family

ID=7851507

Family Applications (1)

Application Number Title Priority Date Filing Date
CN98123285A Expired - Fee Related CN1125025C (zh) 1997-12-11 1998-12-10 催化剂、其制备方法和使用其制备乙酸乙烯酯的方法

Country Status (14)

Country Link
US (2) US5972824A (fr)
EP (1) EP0922490B1 (fr)
JP (1) JP4073565B2 (fr)
KR (1) KR100553113B1 (fr)
CN (1) CN1125025C (fr)
BR (1) BR9805329B1 (fr)
CA (1) CA2255327C (fr)
CZ (1) CZ294541B6 (fr)
DE (2) DE19754991C2 (fr)
ES (1) ES2226061T3 (fr)
ID (1) ID21462A (fr)
MY (1) MY117424A (fr)
SG (1) SG75902A1 (fr)
TW (1) TW491837B (fr)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB9810928D0 (en) 1998-05-22 1998-07-22 Bp Chem Int Ltd Catalyst and process
DE19828491A1 (de) * 1998-06-26 1999-12-30 Degussa Formkörper auf Basis von Siliciumdioxid
DE19843693A1 (de) * 1998-09-24 2000-03-30 Degussa Trägerkatalysator für die Produktion von Vinylacetatmonomer
US6303537B1 (en) * 1999-11-17 2001-10-16 Celanese International Corporation Vinyl acetate catalyst comprising metallic palladium and gold and prepared utilizing sonication
US6420308B1 (en) * 2000-07-07 2002-07-16 Saudi Basic Industries Corp Highly selective shell impregnated catalyst of improved space time yield for production of vinyl acetate
US6794332B2 (en) * 2000-07-07 2004-09-21 Saudi Basic Industries Corporation Highly selective shell impregnated catalyst of improved space time yield for production of vinyl acetate
CN1281322C (zh) * 2001-03-30 2006-10-25 国际壳牌研究有限公司 制备含viii族金属的催化剂的方法和该催化剂用于制备烯基羧酸酯的用途
JP4421201B2 (ja) * 2002-03-27 2010-02-24 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー 触媒を調製する方法、触媒、および触媒の使用
TW201240725A (en) * 2003-12-19 2012-10-16 Celanese Int Corp Layered support material for catalysts
US7465823B2 (en) * 2004-03-17 2008-12-16 Celanese International Corporation Utilization of acetic acid reaction heat in other process plants
DE102004050585A1 (de) * 2004-10-15 2006-04-20 Degussa Ag Mikroreaktor und Verfahren zur Synthese von Vinylacetat-Monomer (VAM) in der Gasphase
PL382741A1 (pl) * 2004-12-20 2007-12-10 Celanese International Corporation Zmodyfikowane materiały podłoża dla katalizatorów
US8227369B2 (en) * 2005-05-25 2012-07-24 Celanese International Corp. Layered composition and processes for preparing and using the composition
US8168562B2 (en) * 2006-02-02 2012-05-01 Lyondell Chemical Technology, L.P. Preparation of palladium-gold catalysts
CN112642491B (zh) * 2019-10-10 2023-01-24 中国石油化工股份有限公司 乙烯法合成醋酸乙烯的催化剂

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1994008715A1 (fr) * 1992-10-14 1994-04-28 Hoechst Celanese Corporation Procede de preparation d'un catalyseur d'acetate de vinyle
WO1997036678A1 (fr) * 1996-04-01 1997-10-09 Hoechst Celanese Corporation Procede de preparation de catalyseur pour l'acetate de vinyle au moyen de borate de metal alcalin

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4048096A (en) * 1976-04-12 1977-09-13 E. I. Du Pont De Nemours And Company Surface impregnated catalyst
DE4120492A1 (de) * 1991-06-21 1992-12-24 Hoechst Ag Verfahren zur herstellung von vinylacetat
US5194417A (en) * 1991-12-05 1993-03-16 Quantum Chemical Corporation Pretreatment of palladium-gold catalysts useful in vinyl acetate synthesis
US5332710A (en) * 1992-10-14 1994-07-26 Hoechst Celanese Corporation Vinyl acetate catalyst preparation method
IN188013B (fr) * 1995-05-23 2002-08-10 Hoechst Celanese Corp
DE19613791C2 (de) * 1996-04-04 2002-01-31 Celanese Chem Europe Gmbh Katalysator, Verfahren zu seiner Herstellung und Verfahren zur Herstellung von Vinylacetat

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1994008715A1 (fr) * 1992-10-14 1994-04-28 Hoechst Celanese Corporation Procede de preparation d'un catalyseur d'acetate de vinyle
WO1997036678A1 (fr) * 1996-04-01 1997-10-09 Hoechst Celanese Corporation Procede de preparation de catalyseur pour l'acetate de vinyle au moyen de borate de metal alcalin

Also Published As

Publication number Publication date
DE19754991C2 (de) 2000-03-23
ID21462A (id) 1999-06-17
BR9805329B1 (pt) 2009-05-05
CA2255327A1 (fr) 1999-06-11
BR9805329A (pt) 1999-11-23
TW491837B (en) 2002-06-21
KR19990062910A (ko) 1999-07-26
CA2255327C (fr) 2007-05-22
CZ405098A3 (cs) 1999-06-16
EP0922490A1 (fr) 1999-06-16
DE59811750D1 (de) 2004-09-09
CZ294541B6 (cs) 2005-01-12
CN1221731A (zh) 1999-07-07
JPH11244697A (ja) 1999-09-14
ES2226061T3 (es) 2005-03-16
US6107513A (en) 2000-08-22
US5972824A (en) 1999-10-26
EP0922490B1 (fr) 2004-08-04
KR100553113B1 (ko) 2006-07-03
JP4073565B2 (ja) 2008-04-09
MY117424A (en) 2004-06-30
SG75902A1 (en) 2000-10-24
DE19754991A1 (de) 1999-06-24

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Granted publication date: 20031022

Termination date: 20131210