CN112203828B - 用于光固化过程的大分子单体和组合物 - Google Patents

用于光固化过程的大分子单体和组合物 Download PDF

Info

Publication number
CN112203828B
CN112203828B CN201980036486.5A CN201980036486A CN112203828B CN 112203828 B CN112203828 B CN 112203828B CN 201980036486 A CN201980036486 A CN 201980036486A CN 112203828 B CN112203828 B CN 112203828B
Authority
CN
China
Prior art keywords
central core
composition
photopolymerizable
group
compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201980036486.5A
Other languages
English (en)
Chinese (zh)
Other versions
CN112203828A (zh
Inventor
迈克尔·亚伦·沃恩
普拉巴乔特·塞尼
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Poly Med Inc
Original Assignee
Poly Med Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Poly Med Inc filed Critical Poly Med Inc
Publication of CN112203828A publication Critical patent/CN112203828A/zh
Application granted granted Critical
Publication of CN112203828B publication Critical patent/CN112203828B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/06—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from hydroxycarboxylic acids
    • C08G63/08—Lactones or lactides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
    • B29C64/10—Processes of additive manufacturing
    • B29C64/106—Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material
    • B29C64/124—Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B33—ADDITIVE MANUFACTURING TECHNOLOGY
    • B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y10/00—Processes of additive manufacturing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B33—ADDITIVE MANUFACTURING TECHNOLOGY
    • B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y70/00—Materials specially adapted for additive manufacturing
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/01—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to unsaturated polyesters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/02—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polycarbonates or saturated polyesters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/64—Polyesters containing both carboxylic ester groups and carbonate groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/91—Polymers modified by chemical after-treatment
    • C08G63/912—Polymers modified by chemical after-treatment derived from hydroxycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
    • C08G75/02—Polythioethers
    • C08G75/04—Polythioethers from mercapto compounds or metallic derivatives thereof
    • C08G75/045—Polythioethers from mercapto compounds or metallic derivatives thereof from mercapto compounds and unsaturated compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2033/00—Use of polymers of unsaturated acids or derivatives thereof as moulding material
    • B29K2033/04—Polymers of esters
    • B29K2033/12—Polymers of methacrylic acid esters, e.g. PMMA, i.e. polymethylmethacrylate
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2067/00—Use of polyesters or derivatives thereof, as moulding material
    • B29K2067/04—Polyesters derived from hydroxycarboxylic acids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2081/00—Use of polymers having sulfur, with or without nitrogen, oxygen or carbon only, in the main chain, as moulding material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2096/00—Use of specified macromolecular materials not provided for in a single one of main groups B29K2001/00 - B29K2095/00, as moulding material
    • B29K2096/02—Graft polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2096/00—Use of specified macromolecular materials not provided for in a single one of main groups B29K2001/00 - B29K2095/00, as moulding material
    • B29K2096/04—Block polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/0002—Condition, form or state of moulded material or of the material to be shaped monomers or prepolymers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Optics & Photonics (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Biological Depolymerization Polymers (AREA)
CN201980036486.5A 2018-04-19 2019-04-05 用于光固化过程的大分子单体和组合物 Active CN112203828B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201862660146P 2018-04-19 2018-04-19
US62/660,146 2018-04-19
PCT/US2019/026098 WO2019204061A1 (en) 2018-04-19 2019-04-05 Macromers and compositions for photocuring processes

Publications (2)

Publication Number Publication Date
CN112203828A CN112203828A (zh) 2021-01-08
CN112203828B true CN112203828B (zh) 2023-06-09

Family

ID=68239891

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201980036486.5A Active CN112203828B (zh) 2018-04-19 2019-04-05 用于光固化过程的大分子单体和组合物

Country Status (6)

Country Link
US (4) US11639416B2 (https=)
EP (1) EP3781384A4 (https=)
JP (3) JP7438129B2 (https=)
CN (1) CN112203828B (https=)
CA (1) CA3097530A1 (https=)
WO (1) WO2019204061A1 (https=)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA3096216A1 (en) 2018-04-06 2019-10-10 Poly-Med, Inc. Methods and compositions for photopolymerizable additive manufacturing
EP3781384A4 (en) * 2018-04-19 2022-01-26 Poly-Med Inc. MACROMERS AND COMPOSITIONS FOR PHOTOCURING PROCESSES
US20240368352A1 (en) * 2021-06-24 2024-11-07 Poly-Med, Inc. Methods and compositions comprising chain transfer agents in absorbable photopolymerizable formulations

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003000766A1 (en) * 2001-06-22 2003-01-03 Venkatram Prasad Shastri Functionalized degradable polymers
CN1910217A (zh) * 2004-01-15 2007-02-07 伊诺科雷技术有限公司 可生物降解的多嵌段共聚物
CN103180125A (zh) * 2010-10-27 2013-06-26 尤金·吉勒 用于制作三维物体的工艺和设备
CN104136488A (zh) * 2012-03-30 2014-11-05 湛新比利时股份有限公司 可辐射固化的(甲基)丙烯酸酯化的化合物
CN105384941A (zh) * 2015-12-07 2016-03-09 江南大学 一种可降解的光敏性磷酸酯基共聚物
KR20180025117A (ko) * 2016-08-30 2018-03-08 아주대학교산학협력단 융점이 조절된 폴리에스테르계 공중합체를 포함하는 바이오 잉크, 이를 포함하는 생체적합 구조체 및 이의 제조방법

Family Cites Families (53)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4223040A (en) 1974-11-26 1980-09-16 Carroll John M Lauric acid for the prevention and treatment of mycobacterial diseases
EP0210637B1 (en) 1985-07-31 1991-09-11 E.I. Du Pont De Nemours And Company Optical coating composition
JP2613929B2 (ja) 1988-10-19 1997-05-28 松下電工株式会社 三次元形状の形成方法および装置
JPH0733844A (ja) 1993-07-23 1995-02-03 Sagami Chem Res Center 脂肪族ポリエステルを主成分とするゲルおよび温度変化に応答する薬物放出制御材料
JP3220968B2 (ja) 1994-08-26 2001-10-22 花王株式会社 透明な液状整髪剤組成物
US5744148A (en) 1996-09-20 1998-04-28 Chesebrough-Pond's Usa Co., Division Of Conopco, Inc. Stabilization of an unstable retinoid in oil-in-water emulsions for skin care compositions
JP4803853B2 (ja) 1996-09-23 2011-10-26 ジェンザイム・コーポレーション カーボネートまたはジオキサノン結合を含む重合可能な生体分解性のポリマー
ZA978537B (en) * 1996-09-23 1998-05-12 Focal Inc Polymerizable biodegradable polymers including carbonate or dioxanone linkages.
USRE38722E1 (en) 1997-02-19 2005-04-12 Ultradent Products, Inc. Polymerizable isolation barriers containing reflective materials and methods for forming and using such barriers
US6305936B1 (en) 1997-02-19 2001-10-23 Ultradent Products, Inc. Polymerizable isolation barriers with reduced polymerization strength and methods for forming and using such barriers
US6162241A (en) 1997-08-06 2000-12-19 Focal, Inc. Hemostatic tissue sealants
US6200646B1 (en) 1999-08-25 2001-03-13 Spectra Group Limited, Inc. Method for forming polymeric patterns, relief images and colored polymeric bodies using digital light processing technology
JP2001213908A (ja) 1999-11-11 2001-08-07 Mitsubishi Chemicals Corp 紫外線硬化性樹脂組成物及び該組成物に基づく被膜を有するインクジェット用被記録材
US7074424B2 (en) 2000-11-28 2006-07-11 Genzyme Corporation Polyalkylene glycol viscosity-enhancing polymeric formulations
JP4141120B2 (ja) 2001-08-16 2008-08-27 富士フイルム株式会社 平版印刷版用原版
AU2003207467A1 (en) 2002-01-07 2003-07-24 Abbott Gmbh And Co. Kg Crystallization of amino acids using ultrasonic agitation
JP3680132B2 (ja) 2002-02-26 2005-08-10 独立行政法人産業技術総合研究所 伸縮性の（エラスティックな）性質を有する生分解性材料およびこの材料から形成される人工血管
JP2003252939A (ja) * 2002-03-01 2003-09-10 Fuji Photo Film Co Ltd 光重合性組成物
JP3651674B2 (ja) 2002-03-22 2005-05-25 財団法人生産技術研究奨励会 生体吸収性多孔質担体の製造方法
US20030198824A1 (en) 2002-04-19 2003-10-23 Fong John W. Photocurable compositions containing reactive polysiloxane particles
JP4214729B2 (ja) 2002-07-25 2009-01-28 コニカミノルタホールディングス株式会社 硬化性白インク組成物
US20040152800A1 (en) * 2002-10-09 2004-08-05 Shalaby Shalaby W. Photo-crosslinkable, crystalline, polyaxial, absorbable polyester for rapid prototyping
JP2005055682A (ja) 2003-08-05 2005-03-03 Canon Inc 光量調節部材の製造方法、光量調節部材、光量調節装置及び撮影装置
WO2005049105A2 (en) 2003-11-10 2005-06-02 Angiotech International Ag Medical implants and anti-scarring agents
US20050148512A1 (en) 2003-11-10 2005-07-07 Angiotech International Ag Medical implants and fibrosis-inducing agents
WO2006031388A2 (en) * 2004-08-20 2006-03-23 Hyperbranch Medical Technology, Inc. Dentritic polymers, crosslinked gels, and their uses in orthopedic applications
US8821559B2 (en) 2004-08-27 2014-09-02 Codman & Shurtleff, Inc. Light-based implants for treating Alzheimer's disease
EP1801140A1 (en) 2005-12-22 2007-06-27 Mnemoscience GmbH Macro-diacrylate
JP5541594B2 (ja) 2006-11-07 2014-07-09 ディーエスエム アイピー アセッツ ビー．ブイ． 生体分子部分を含むカルバメート、チオカルバメートまたはカルバミド
US8384630B2 (en) 2007-05-31 2013-02-26 Nthdegree Technologies Worldwide Inc Light emitting, photovoltaic or other electronic apparatus and system
EP2050720A1 (de) 2007-10-16 2009-04-22 Mondi Business Paper Services AG Laser- und thermisch beschreibbare Oberflächenbeschichtung für Materialien
JP5415029B2 (ja) 2008-07-01 2014-02-12 株式会社リコー 紫外線硬化型インクジェット記録用インク及びカラー画像形成装置
US8257787B2 (en) 2009-12-30 2012-09-04 The Procter & Gamble Company Method of using a carrier sheet in a continuous high internal phase emulsion foam forming process
CN102005532A (zh) 2010-10-15 2011-04-06 陈林 高效反射led封装结构及其封装方法
US8851649B2 (en) 2011-05-13 2014-10-07 Eckart Gmbh UV ink jet printing ink composition
JP2013018920A (ja) 2011-07-13 2013-01-31 Seiko Epson Corp インクセットおよび記録物
WO2013146081A1 (ja) 2012-03-30 2013-10-03 出光興産株式会社 樹脂組成物及びその硬化物ならびにそれを用いた光半導体用反射材
EP2956823B2 (en) 2013-02-12 2019-07-03 CARBON3D, Inc. Continuous liquid interphase printing
US20150002926A1 (en) 2013-06-27 2015-01-01 Motorola Mobility Llc Reflective Mold Apparatus and Methods for UV Curing
AU2014305915B2 (en) 2013-08-07 2019-08-15 Reva Medical, Inc. Polymeric biomaterials derived from monomers comprising hydroxyacids and phenol compounds and their medical uses
WO2015118777A1 (ja) 2014-02-07 2015-08-13 堺化学工業株式会社 六角板状酸化亜鉛粒子、その製造方法、化粧料、フィラー、樹脂組成物、赤外線反射材及び塗料組成物
GB201409451D0 (en) 2014-05-28 2014-07-09 Ipabc Ltd Antimicrobial preparations, methods for preparing the same and uses thereof to combat microorganisms
KR102305509B1 (ko) 2014-07-22 2021-09-28 씨-나노 테크놀로지 리미티드 배터리용 전극 조성물
US20160177026A1 (en) 2014-12-19 2016-06-23 Poly-Med, Inc. Absorbable copolymers with improved thermal stability
JP6475328B2 (ja) 2015-06-08 2019-02-27 富士フイルム株式会社 ３次元印刷用活性光線硬化型インクジェットインクセット、３次元印刷方法、及び、３次元印刷システム
US10435573B2 (en) 2015-11-03 2019-10-08 3D Systems, Inc. Biocompatible inks for 3D printing
US10501572B2 (en) * 2015-12-22 2019-12-10 Carbon, Inc. Cyclic ester dual cure resins for additive manufacturing
JP6819671B2 (ja) 2016-03-18 2021-01-27 株式会社リコー 活性エネルギー線硬化型組成物、立体造形物の製造方法、及び立体造形物の製造装置
KR102143953B1 (ko) 2016-03-24 2020-08-12 주식회사 엘지화학 이차전지의 양극 형성용 조성물 및 이를 이용하여 제조한 이차전지용 양극 및 이차전지
CN106818334B (zh) 2016-12-29 2020-07-14 杭州福斯特应用材料股份有限公司 一种高反光可降解地膜
KR101822151B1 (ko) 2017-06-28 2018-01-25 비즈텍코리아 주식회사 3d 프린팅용 광경화성 폴리실록산 조성물 및 이를 포함하는 치과용 조형물
CA3096216A1 (en) 2018-04-06 2019-10-10 Poly-Med, Inc. Methods and compositions for photopolymerizable additive manufacturing
EP3781384A4 (en) * 2018-04-19 2022-01-26 Poly-Med Inc. MACROMERS AND COMPOSITIONS FOR PHOTOCURING PROCESSES

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003000766A1 (en) * 2001-06-22 2003-01-03 Venkatram Prasad Shastri Functionalized degradable polymers
CN1910217A (zh) * 2004-01-15 2007-02-07 伊诺科雷技术有限公司 可生物降解的多嵌段共聚物
CN103180125A (zh) * 2010-10-27 2013-06-26 尤金·吉勒 用于制作三维物体的工艺和设备
CN104136488A (zh) * 2012-03-30 2014-11-05 湛新比利时股份有限公司 可辐射固化的(甲基)丙烯酸酯化的化合物
CN105384941A (zh) * 2015-12-07 2016-03-09 江南大学 一种可降解的光敏性磷酸酯基共聚物
KR20180025117A (ko) * 2016-08-30 2018-03-08 아주대학교산학협력단 융점이 조절된 폴리에스테르계 공중합체를 포함하는 바이오 잉크, 이를 포함하는 생체적합 구조체 및 이의 제조방법

Also Published As

Publication number Publication date
JP7688683B2 (ja) 2025-06-04
WO2019204061A1 (en) 2019-10-24
JP2021522362A (ja) 2021-08-30
JP2024008974A (ja) 2024-01-19
US12577347B2 (en) 2026-03-17
US20250011530A1 (en) 2025-01-09
US20260103561A1 (en) 2026-04-16
EP3781384A1 (en) 2021-02-24
US20230287171A1 (en) 2023-09-14
US20210115188A1 (en) 2021-04-22
CA3097530A1 (en) 2019-10-24
US11639416B2 (en) 2023-05-02
CN112203828A (zh) 2021-01-08
JP2025126174A (ja) 2025-08-28
EP3781384A4 (en) 2022-01-26
JP7438129B2 (ja) 2024-02-26
US12065539B2 (en) 2024-08-20

Similar Documents

Publication Publication Date Title
JP7688683B2 (ja) 光硬化プロセスのためのマクロマー及び組成物
JP7836642B2 (ja) 生体材料のための３ｄプリンティング用組成物
US10183477B2 (en) Absorbant and reflecting biocompatible dyes for highly accurate medical implants
CN103975014A (zh) 利用乙烯基酯和乙烯基碳酸酯的硫醇-烯聚合反应
EP2925377B1 (en) Absorbant and reflecting biocompatible dyes for highly accurate medical implants
CN106456831A (zh) 适用于印刷的树脂组合物和使用其的印刷方法
CN114502358B (zh) 可固化聚合物组合物
CN113402870A (zh) 一种光固化树脂及其制备方法和应用
US20250100225A1 (en) Continuous digital light processing additive manufacturing of implants
US12486412B2 (en) Polyesters, polymer compositions, and methods of using thereof
US20190210355A1 (en) Absorbant and reflecting biocompatible dyes for highly accurate medical implants
EP4363225A1 (en) Methods and compositions comprising chain transfer agents in absorbable photopolymerizable formulations
Green Controlled fabrication of three-dimensional structures using photopolymerization

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant