CN111212894A - 水性喷雾组合物 - Google Patents
水性喷雾组合物 Download PDFInfo
- Publication number
- CN111212894A CN111212894A CN201880066497.3A CN201880066497A CN111212894A CN 111212894 A CN111212894 A CN 111212894A CN 201880066497 A CN201880066497 A CN 201880066497A CN 111212894 A CN111212894 A CN 111212894A
- Authority
- CN
- China
- Prior art keywords
- composition
- silicone
- perfume
- functionalized
- acetate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 121
- 239000007921 spray Substances 0.000 title claims abstract description 32
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 78
- 239000002304 perfume Substances 0.000 claims abstract description 56
- 239000004744 fabric Substances 0.000 claims abstract description 23
- 239000000839 emulsion Substances 0.000 claims abstract description 18
- 239000002245 particle Substances 0.000 claims abstract description 16
- -1 methoxy, ethoxy, hydroxy, propoxy Chemical group 0.000 claims description 49
- 239000004615 ingredient Substances 0.000 claims description 28
- 238000005507 spraying Methods 0.000 claims description 14
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 10
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 10
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 10
- 125000000524 functional group Chemical group 0.000 claims description 8
- 239000000796 flavoring agent Substances 0.000 claims description 7
- 125000004104 aryloxy group Chemical group 0.000 claims description 6
- 239000001257 hydrogen Substances 0.000 claims description 6
- 229910052739 hydrogen Inorganic materials 0.000 claims description 6
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 6
- 230000003716 rejuvenation Effects 0.000 claims description 5
- 229920000642 polymer Polymers 0.000 claims description 4
- 230000008569 process Effects 0.000 claims description 4
- 125000003118 aryl group Chemical group 0.000 claims description 3
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims description 3
- 125000004356 hydroxy functional group Chemical group O* 0.000 claims description 2
- 125000004183 alkoxy alkyl group Chemical group 0.000 claims 1
- 150000001412 amines Chemical class 0.000 claims 1
- 229920000858 Cyclodextrin Polymers 0.000 description 31
- OOCCDEMITAIZTP-QPJJXVBHSA-N (E)-cinnamyl alcohol Chemical compound OC\C=C\C1=CC=CC=C1 OOCCDEMITAIZTP-QPJJXVBHSA-N 0.000 description 18
- 239000000463 material Substances 0.000 description 18
- 229940022663 acetate Drugs 0.000 description 15
- 150000001299 aldehydes Chemical class 0.000 description 15
- 239000010457 zeolite Substances 0.000 description 15
- GAWWVVGZMLGEIW-GNNYBVKZSA-L zinc ricinoleate Chemical compound [Zn+2].CCCCCC[C@@H](O)C\C=C/CCCCCCCC([O-])=O.CCCCCC[C@@H](O)C\C=C/CCCCCCCC([O-])=O GAWWVVGZMLGEIW-GNNYBVKZSA-L 0.000 description 15
- 235000019645 odor Nutrition 0.000 description 14
- HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical compound O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 description 14
- 229940100530 zinc ricinoleate Drugs 0.000 description 14
- 150000001875 compounds Chemical class 0.000 description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- IGODOXYLBBXFDW-UHFFFAOYSA-N alpha-Terpinyl acetate Chemical compound CC(=O)OC(C)(C)C1CCC(C)=CC1 IGODOXYLBBXFDW-UHFFFAOYSA-N 0.000 description 12
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 11
- 229940097362 cyclodextrins Drugs 0.000 description 10
- 239000003205 fragrance Substances 0.000 description 10
- 150000003839 salts Chemical class 0.000 description 10
- 239000004875 Anti-Odour Agent Substances 0.000 description 9
- OOCCDEMITAIZTP-UHFFFAOYSA-N allylic benzylic alcohol Natural products OCC=CC1=CC=CC=C1 OOCCDEMITAIZTP-UHFFFAOYSA-N 0.000 description 9
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 8
- 239000003921 oil Substances 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- WHGYBXFWUBPSRW-FOUAGVGXSA-N beta-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO WHGYBXFWUBPSRW-FOUAGVGXSA-N 0.000 description 7
- KJPRLNWUNMBNBZ-QPJJXVBHSA-N (E)-cinnamaldehyde Chemical compound O=C\C=C\C1=CC=CC=C1 KJPRLNWUNMBNBZ-QPJJXVBHSA-N 0.000 description 6
- JAVZALBKNIHSLL-UHFFFAOYSA-N 1-cyclohexylethyl acetate Chemical compound CC(=O)OC(C)C1CCCCC1 JAVZALBKNIHSLL-UHFFFAOYSA-N 0.000 description 6
- CRPUJAZIXJMDBK-UHFFFAOYSA-N camphene Chemical compound C1CC2C(=C)C(C)(C)C1C2 CRPUJAZIXJMDBK-UHFFFAOYSA-N 0.000 description 6
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 6
- KSMVZQYAVGTKIV-UHFFFAOYSA-N decanal Chemical compound CCCCCCCCCC=O KSMVZQYAVGTKIV-UHFFFAOYSA-N 0.000 description 6
- UWKAYLJWKGQEPM-LBPRGKRZSA-N linalyl acetate Chemical compound CC(C)=CCC[C@](C)(C=C)OC(C)=O UWKAYLJWKGQEPM-LBPRGKRZSA-N 0.000 description 6
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 6
- NSRPTJUYGXZXEC-UHFFFAOYSA-N 2-cyclohexylethyl propanoate Chemical compound CCC(=O)OCCC1CCCCC1 NSRPTJUYGXZXEC-UHFFFAOYSA-N 0.000 description 5
- 229910021536 Zeolite Inorganic materials 0.000 description 5
- 125000000217 alkyl group Chemical group 0.000 description 5
- 125000000129 anionic group Chemical group 0.000 description 5
- 230000008901 benefit Effects 0.000 description 5
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 5
- 125000002791 glucosyl group Chemical group C1([C@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 description 5
- 150000002576 ketones Chemical class 0.000 description 5
- 230000007246 mechanism Effects 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 239000003094 microcapsule Substances 0.000 description 5
- 238000006467 substitution reaction Methods 0.000 description 5
- RUVINXPYWBROJD-ONEGZZNKSA-N trans-anethole Chemical compound COC1=CC=C(\C=C\C)C=C1 RUVINXPYWBROJD-ONEGZZNKSA-N 0.000 description 5
- XMGQYMWWDOXHJM-JTQLQIEISA-N (+)-α-limonene Chemical compound CC(=C)[C@@H]1CCC(C)=CC1 XMGQYMWWDOXHJM-JTQLQIEISA-N 0.000 description 4
- FTMSYMOBBRINAR-UHFFFAOYSA-N 1-cyclohexylethyl butanoate Chemical compound CCCC(=O)OC(C)C1CCCCC1 FTMSYMOBBRINAR-UHFFFAOYSA-N 0.000 description 4
- 229920001450 Alpha-Cyclodextrin Polymers 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 229920004482 WACKER® Polymers 0.000 description 4
- XCPQUQHBVVXMRQ-UHFFFAOYSA-N alpha-Fenchene Natural products C1CC2C(=C)CC1C2(C)C XCPQUQHBVVXMRQ-UHFFFAOYSA-N 0.000 description 4
- HFHDHCJBZVLPGP-RWMJIURBSA-N alpha-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO HFHDHCJBZVLPGP-RWMJIURBSA-N 0.000 description 4
- 229940043377 alpha-cyclodextrin Drugs 0.000 description 4
- 125000004429 atom Chemical group 0.000 description 4
- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 description 4
- UAHWPYUMFXYFJY-UHFFFAOYSA-N beta-myrcene Chemical compound CC(C)=CCCC(=C)C=C UAHWPYUMFXYFJY-UHFFFAOYSA-N 0.000 description 4
- 238000009835 boiling Methods 0.000 description 4
- QMVPMAAFGQKVCJ-UHFFFAOYSA-N citronellol Chemical compound OCCC(C)CCC=C(C)C QMVPMAAFGQKVCJ-UHFFFAOYSA-N 0.000 description 4
- JOZKFWLRHCDGJA-UHFFFAOYSA-N citronellol acetate Chemical compound CC(=O)OCCC(C)CCC=C(C)C JOZKFWLRHCDGJA-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000003995 emulsifying agent Substances 0.000 description 4
- 229930003935 flavonoid Natural products 0.000 description 4
- 150000002215 flavonoids Chemical class 0.000 description 4
- 235000017173 flavonoids Nutrition 0.000 description 4
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- WTEVQBCEXWBHNA-YFHOEESVSA-N neral Chemical compound CC(C)=CCC\C(C)=C/C=O WTEVQBCEXWBHNA-YFHOEESVSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 3
- WTEVQBCEXWBHNA-UHFFFAOYSA-N Citral Natural products CC(C)=CCCC(C)=CC=O WTEVQBCEXWBHNA-UHFFFAOYSA-N 0.000 description 3
- 239000001116 FEMA 4028 Substances 0.000 description 3
- PXRCIOIWVGAZEP-UHFFFAOYSA-N Primaeres Camphenhydrat Natural products C1CC2C(O)(C)C(C)(C)C1C2 PXRCIOIWVGAZEP-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 150000001241 acetals Chemical class 0.000 description 3
- 235000011175 beta-cyclodextrine Nutrition 0.000 description 3
- 229960004853 betadex Drugs 0.000 description 3
- 229930006739 camphene Natural products 0.000 description 3
- ZYPYEBYNXWUCEA-UHFFFAOYSA-N camphenilone Natural products C1CC2C(=O)C(C)(C)C1C2 ZYPYEBYNXWUCEA-UHFFFAOYSA-N 0.000 description 3
- 125000002091 cationic group Chemical group 0.000 description 3
- WTEVQBCEXWBHNA-JXMROGBWSA-N citral A Natural products CC(C)=CCC\C(C)=C\C=O WTEVQBCEXWBHNA-JXMROGBWSA-N 0.000 description 3
- 239000000284 extract Substances 0.000 description 3
- 235000019634 flavors Nutrition 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- GDSRMADSINPKSL-HSEONFRVSA-N gamma-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO GDSRMADSINPKSL-HSEONFRVSA-N 0.000 description 3
- 229940080345 gamma-cyclodextrin Drugs 0.000 description 3
- HIGQPQRQIQDZMP-UHFFFAOYSA-N geranil acetate Natural products CC(C)=CCCC(C)=CCOC(C)=O HIGQPQRQIQDZMP-UHFFFAOYSA-N 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- UWKAYLJWKGQEPM-UHFFFAOYSA-N linalool acetate Natural products CC(C)=CCCC(C)(C=C)OC(C)=O UWKAYLJWKGQEPM-UHFFFAOYSA-N 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- ZRSNZINYAWTAHE-UHFFFAOYSA-N p-methoxybenzaldehyde Chemical compound COC1=CC=C(C=O)C=C1 ZRSNZINYAWTAHE-UHFFFAOYSA-N 0.000 description 3
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 3
- 125000001453 quaternary ammonium group Chemical group 0.000 description 3
- GRWFGVWFFZKLTI-IUCAKERBSA-N (-)-α-pinene Chemical compound CC1=CC[C@@H]2C(C)(C)[C@H]1C2 GRWFGVWFFZKLTI-IUCAKERBSA-N 0.000 description 2
- BAHYRRKWDPFEOG-FNCQTZNRSA-N (1e,6e)-1,7-diphenylhepta-1,6-dien-4-one Chemical compound C=1C=CC=CC=1/C=C/CC(=O)C\C=C\C1=CC=CC=C1 BAHYRRKWDPFEOG-FNCQTZNRSA-N 0.000 description 2
- HLCSDJLATUNSSI-JXMROGBWSA-N (2e)-3,7-dimethylocta-2,6-dienenitrile Chemical compound CC(C)=CCC\C(C)=C\C#N HLCSDJLATUNSSI-JXMROGBWSA-N 0.000 description 2
- GQVMHMFBVWSSPF-SOYUKNQTSA-N (4E,6E)-2,6-dimethylocta-2,4,6-triene Chemical compound C\C=C(/C)\C=C\C=C(C)C GQVMHMFBVWSSPF-SOYUKNQTSA-N 0.000 description 2
- QMVPMAAFGQKVCJ-SNVBAGLBSA-N (R)-(+)-citronellol Natural products OCC[C@H](C)CCC=C(C)C QMVPMAAFGQKVCJ-SNVBAGLBSA-N 0.000 description 2
- KAAGZQABSGXCIB-UHFFFAOYSA-N 1,3-bis(2,4-dimethylcyclohexyl)propan-2-one Chemical compound CC1C(CCC(C1)C)CC(=O)CC1C(CC(CC1)C)C KAAGZQABSGXCIB-UHFFFAOYSA-N 0.000 description 2
- JMSUNAQVHOHLMX-UHFFFAOYSA-N 1-cyclohexylethanol Chemical compound CC(O)C1CCCCC1 JMSUNAQVHOHLMX-UHFFFAOYSA-N 0.000 description 2
- RIFKADJTWUGDOV-UHFFFAOYSA-N 1-cyclohexylethanone Chemical compound CC(=O)C1CCCCC1 RIFKADJTWUGDOV-UHFFFAOYSA-N 0.000 description 2
- NFAVNWJJYQAGNB-UHFFFAOYSA-N 2-methylundecanal Chemical compound CCCCCCCCCC(C)C=O NFAVNWJJYQAGNB-UHFFFAOYSA-N 0.000 description 2
- WRMNZCZEMHIOCP-UHFFFAOYSA-N 2-phenylethanol Chemical compound OCCC1=CC=CC=C1 WRMNZCZEMHIOCP-UHFFFAOYSA-N 0.000 description 2
- PRNCMAKCNVRZFX-UHFFFAOYSA-N 3,7-dimethyloctan-1-ol Chemical compound CC(C)CCCC(C)CCO PRNCMAKCNVRZFX-UHFFFAOYSA-N 0.000 description 2
- WWJLCYHYLZZXBE-UHFFFAOYSA-N 5-chloro-1,3-dihydroindol-2-one Chemical compound ClC1=CC=C2NC(=O)CC2=C1 WWJLCYHYLZZXBE-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- UYWQUFXKFGHYNT-UHFFFAOYSA-N Benzylformate Chemical compound O=COCC1=CC=CC=C1 UYWQUFXKFGHYNT-UHFFFAOYSA-N 0.000 description 2
- JOZKFWLRHCDGJA-LLVKDONJSA-N Citronellyl acetate Natural products CC(=O)OCC[C@H](C)CCC=C(C)C JOZKFWLRHCDGJA-LLVKDONJSA-N 0.000 description 2
- 241000207199 Citrus Species 0.000 description 2
- JUWUWIGZUVEFQB-UHFFFAOYSA-N Fenchyl acetate Chemical compound C1CC2C(C)(C)C(OC(=O)C)C1(C)C2 JUWUWIGZUVEFQB-UHFFFAOYSA-N 0.000 description 2
- GLZPCOQZEFWAFX-UHFFFAOYSA-N Geraniol Chemical compound CC(C)=CCCC(C)=CCO GLZPCOQZEFWAFX-UHFFFAOYSA-N 0.000 description 2
- KGEKLUUHTZCSIP-UHFFFAOYSA-N Isobornyl acetate Natural products C1CC2(C)C(OC(=O)C)CC1C2(C)C KGEKLUUHTZCSIP-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- NFLGAXVYCFJBMK-UHFFFAOYSA-N Menthone Chemical compound CC(C)C1CCC(C)CC1=O NFLGAXVYCFJBMK-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 239000001940 [(1R,4S,6R)-1,7,7-trimethyl-6-bicyclo[2.2.1]heptanyl] acetate Substances 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- VYBREYKSZAROCT-UHFFFAOYSA-N alpha-myrcene Natural products CC(=C)CCCC(=C)C=C VYBREYKSZAROCT-UHFFFAOYSA-N 0.000 description 2
- 125000003277 amino group Chemical group 0.000 description 2
- 229920003180 amino resin Polymers 0.000 description 2
- 229940011037 anethole Drugs 0.000 description 2
- QUKGYYKBILRGFE-UHFFFAOYSA-N benzyl acetate Chemical compound CC(=O)OCC1=CC=CC=C1 QUKGYYKBILRGFE-UHFFFAOYSA-N 0.000 description 2
- JGQFVRIQXUFPAH-UHFFFAOYSA-N beta-citronellol Natural products OCCC(C)CCCC(C)=C JGQFVRIQXUFPAH-UHFFFAOYSA-N 0.000 description 2
- 229960003237 betaine Drugs 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000003575 carbonaceous material Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- GQVMHMFBVWSSPF-UHFFFAOYSA-N cis-alloocimene Natural products CC=C(C)C=CC=C(C)C GQVMHMFBVWSSPF-UHFFFAOYSA-N 0.000 description 2
- NEHNMFOYXAPHSD-UHFFFAOYSA-N citronellal Chemical compound O=CCC(C)CCC=C(C)C NEHNMFOYXAPHSD-UHFFFAOYSA-N 0.000 description 2
- 235000000484 citronellol Nutrition 0.000 description 2
- 235000020971 citrus fruits Nutrition 0.000 description 2
- 229910052681 coesite Inorganic materials 0.000 description 2
- 229910052906 cristobalite Inorganic materials 0.000 description 2
- WTWBUQJHJGUZCY-UHFFFAOYSA-N cuminaldehyde Chemical compound CC(C)C1=CC=C(C=O)C=C1 WTWBUQJHJGUZCY-UHFFFAOYSA-N 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- XSNQECSCDATQEL-UHFFFAOYSA-N dihydromyrcenol Chemical compound C=CC(C)CCCC(C)(C)O XSNQECSCDATQEL-UHFFFAOYSA-N 0.000 description 2
- 229930008394 dihydromyrcenol Natural products 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- CBOQJANXLMLOSS-UHFFFAOYSA-N ethyl vanillin Chemical compound CCOC1=CC(C=O)=CC=C1O CBOQJANXLMLOSS-UHFFFAOYSA-N 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- HIGQPQRQIQDZMP-DHZHZOJOSA-N geranyl acetate Chemical compound CC(C)=CCC\C(C)=C\COC(C)=O HIGQPQRQIQDZMP-DHZHZOJOSA-N 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- 238000010409 ironing Methods 0.000 description 2
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 2
- VAMXMNNIEUEQDV-UHFFFAOYSA-N methyl anthranilate Chemical compound COC(=O)C1=CC=CC=C1N VAMXMNNIEUEQDV-UHFFFAOYSA-N 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- HIGQPQRQIQDZMP-FLIBITNWSA-N neryl acetate Chemical compound CC(C)=CCC\C(C)=C/COC(C)=O HIGQPQRQIQDZMP-FLIBITNWSA-N 0.000 description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- GJQIMXVRFNLMTB-UHFFFAOYSA-N nonyl acetate Chemical compound CCCCCCCCCOC(C)=O GJQIMXVRFNLMTB-UHFFFAOYSA-N 0.000 description 2
- HFPZCAJZSCWRBC-UHFFFAOYSA-N p-cymene Chemical compound CC(C)C1=CC=C(C)C=C1 HFPZCAJZSCWRBC-UHFFFAOYSA-N 0.000 description 2
- QNGNSVIICDLXHT-UHFFFAOYSA-N para-ethylbenzaldehyde Natural products CCC1=CC=C(C=O)C=C1 QNGNSVIICDLXHT-UHFFFAOYSA-N 0.000 description 2
- RUVINXPYWBROJD-UHFFFAOYSA-N para-methoxyphenyl Natural products COC1=CC=C(C=CC)C=C1 RUVINXPYWBROJD-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 2
- SATCULPHIDQDRE-UHFFFAOYSA-N piperonal Chemical compound O=CC1=CC=C2OCOC2=C1 SATCULPHIDQDRE-UHFFFAOYSA-N 0.000 description 2
- 229920000570 polyether Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000003380 propellant Substances 0.000 description 2
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 2
- WBHHMMIMDMUBKC-XLNAKTSKSA-N ricinelaidic acid Chemical compound CCCCCC[C@@H](O)C\C=C\CCCCCCCC(O)=O WBHHMMIMDMUBKC-XLNAKTSKSA-N 0.000 description 2
- 229960003656 ricinoleic acid Drugs 0.000 description 2
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 description 2
- 229910000077 silane Inorganic materials 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 229920005573 silicon-containing polymer Polymers 0.000 description 2
- 229910052682 stishovite Inorganic materials 0.000 description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
- 239000011885 synergistic combination Substances 0.000 description 2
- 235000007586 terpenes Nutrition 0.000 description 2
- 229910052905 tridymite Inorganic materials 0.000 description 2
- 239000000341 volatile oil Substances 0.000 description 2
- 150000003751 zinc Chemical class 0.000 description 2
- IHPKGUQCSIINRJ-UHFFFAOYSA-N β-ocimene Natural products CC(C)=CCC=C(C)C=C IHPKGUQCSIINRJ-UHFFFAOYSA-N 0.000 description 2
- NFLGAXVYCFJBMK-RKDXNWHRSA-N (+)-isomenthone Natural products CC(C)[C@H]1CC[C@@H](C)CC1=O NFLGAXVYCFJBMK-RKDXNWHRSA-N 0.000 description 1
- WTARULDDTDQWMU-RKDXNWHRSA-N (+)-β-pinene Chemical compound C1[C@H]2C(C)(C)[C@@H]1CCC2=C WTARULDDTDQWMU-RKDXNWHRSA-N 0.000 description 1
- WTARULDDTDQWMU-IUCAKERBSA-N (-)-Nopinene Natural products C1[C@@H]2C(C)(C)[C@H]1CCC2=C WTARULDDTDQWMU-IUCAKERBSA-N 0.000 description 1
- NFLGAXVYCFJBMK-IUCAKERBSA-N (-)-isomenthone Chemical compound CC(C)[C@@H]1CC[C@H](C)CC1=O NFLGAXVYCFJBMK-IUCAKERBSA-N 0.000 description 1
- 239000001563 (1,5,5-trimethyl-6-bicyclo[2.2.1]heptanyl) acetate Substances 0.000 description 1
- PXLKJWMSFPYVNB-UHFFFAOYSA-N (1-methyl-4-propan-2-ylcyclohexyl) acetate Chemical compound CC(C)C1CCC(C)(OC(C)=O)CC1 PXLKJWMSFPYVNB-UHFFFAOYSA-N 0.000 description 1
- PCWPQSDFNIFUPO-VDQKLNDWSA-N (1S,3R,5R,6S,8R,10R,11S,13R,15R,16S,18R,20R,21S,23R,25R,26S,28R,30R,31S,33R,35R,36R,37S,38R,39S,40R,41S,42R,43S,44R,45S,46R,47S,48R,49S)-37,39,41,43,45,47,49-heptakis(2-hydroxyethoxy)-5,10,15,20,25,30,35-heptakis(hydroxymethyl)-2,4,7,9,12,14,17,19,22,24,27,29,32,34-tetradecaoxaoctacyclo[31.2.2.23,6.28,11.213,16.218,21.223,26.228,31]nonatetracontane-36,38,40,42,44,46,48-heptol Chemical compound OCCO[C@H]1[C@H](O)[C@@H]2O[C@H]3O[C@H](CO)[C@@H](O[C@H]4O[C@H](CO)[C@@H](O[C@H]5O[C@H](CO)[C@@H](O[C@H]6O[C@H](CO)[C@@H](O[C@H]7O[C@H](CO)[C@@H](O[C@H]8O[C@H](CO)[C@@H](O[C@H]1O[C@@H]2CO)[C@@H](O)[C@@H]8OCCO)[C@@H](O)[C@@H]7OCCO)[C@@H](O)[C@@H]6OCCO)[C@@H](O)[C@@H]5OCCO)[C@@H](O)[C@@H]4OCCO)[C@@H](O)[C@@H]3OCCO PCWPQSDFNIFUPO-VDQKLNDWSA-N 0.000 description 1
- 239000001414 (2E)-2-(phenylmethylidene)octanal Substances 0.000 description 1
- MTDAKBBUYMYKAR-SNVBAGLBSA-N (3r)-3,7-dimethyloct-6-enenitrile Chemical compound N#CC[C@H](C)CCC=C(C)C MTDAKBBUYMYKAR-SNVBAGLBSA-N 0.000 description 1
- 229940098795 (3z)- 3-hexenyl acetate Drugs 0.000 description 1
- 239000001605 (5-methyl-2-propan-2-ylcyclohexyl) acetate Substances 0.000 description 1
- 239000001244 (E)-1-(2,6,6-trimethyl-1-cyclohex-2-enyl)pent-1-en-3-one Substances 0.000 description 1
- VPKMGDRERYMTJX-XEHSLEBBSA-N (e)-1-[(1r)-2,6,6-trimethylcyclohex-2-en-1-yl]pent-1-en-3-one Chemical compound CCC(=O)\C=C\[C@H]1C(C)=CCCC1(C)C VPKMGDRERYMTJX-XEHSLEBBSA-N 0.000 description 1
- FVFXAIJIVWGZOP-UHFFFAOYSA-N 1,3-bis(2,3-dimethylcyclohexyl)propan-2-one Chemical compound CC1C(CCCC1C)CC(=O)CC1C(C(CCC1)C)C FVFXAIJIVWGZOP-UHFFFAOYSA-N 0.000 description 1
- HUVAPJWKIJOFQP-UHFFFAOYSA-N 1,3-bis(2-methyl-5-propan-2-ylcyclohexyl)propan-2-one Chemical compound CC1C(CC(CC1)C(C)C)CC(=O)CC1C(CCC(C1)C(C)C)C HUVAPJWKIJOFQP-UHFFFAOYSA-N 0.000 description 1
- BDDZRTBJSGYWDG-UHFFFAOYSA-N 1,3-bis(3,3,5-trimethylcyclohexyl)propan-2-one Chemical compound CC1(CC(CC(C1)C)CC(=O)CC1CC(CC(C1)C)(C)C)C BDDZRTBJSGYWDG-UHFFFAOYSA-N 0.000 description 1
- RUHOAHWSRPNSCJ-UHFFFAOYSA-N 1,3-bis(3-methylcyclohexyl)propan-2-one Chemical compound C1C(C)CCCC1CC(=O)CC1CC(C)CCC1 RUHOAHWSRPNSCJ-UHFFFAOYSA-N 0.000 description 1
- XAZCFCWYPIWHER-UHFFFAOYSA-N 1,3-bis(4-ethylcyclohexyl)propan-2-one Chemical compound C(C)C1CCC(CC1)CC(=O)CC1CCC(CC1)CC XAZCFCWYPIWHER-UHFFFAOYSA-N 0.000 description 1
- AMOVIIVWTHHHTN-UHFFFAOYSA-N 1,3-bis(4-propan-2-ylcyclohexyl)propan-2-one Chemical compound C(C)(C)C1CCC(CC1)CC(=O)CC1CCC(CC1)C(C)C AMOVIIVWTHHHTN-UHFFFAOYSA-N 0.000 description 1
- VXQSQYJXVGOUFT-UHFFFAOYSA-N 1,3-bis(4-tert-butylcyclohexyl)propan-2-one Chemical compound C(C)(C)(C)C1CCC(CC1)CC(=O)CC1CCC(CC1)C(C)(C)C VXQSQYJXVGOUFT-UHFFFAOYSA-N 0.000 description 1
- WEEGYLXZBRQIMU-UHFFFAOYSA-N 1,8-cineole Natural products C1CC2CCC1(C)OC2(C)C WEEGYLXZBRQIMU-UHFFFAOYSA-N 0.000 description 1
- JESIHYIJKKUWIS-UHFFFAOYSA-N 1-(4-Methylphenyl)ethanol Chemical compound CC(O)C1=CC=C(C)C=C1 JESIHYIJKKUWIS-UHFFFAOYSA-N 0.000 description 1
- QUMXDOLUJCHOAY-UHFFFAOYSA-N 1-Phenylethyl acetate Chemical compound CC(=O)OC(C)C1=CC=CC=C1 QUMXDOLUJCHOAY-UHFFFAOYSA-N 0.000 description 1
- VDJZEAAAOZDPLZ-UHFFFAOYSA-N 2,4-dimethyl-2,4-bis(4-methylcyclohexyl)pentan-3-one Chemical compound CC1CCC(CC1)C(C)(C)C(=O)C(C)(C)C1CCC(CC1)C VDJZEAAAOZDPLZ-UHFFFAOYSA-N 0.000 description 1
- YZKBSTAFLMICGB-UHFFFAOYSA-N 2,6-dimethyl-3,5-bis(4-methylcyclohexyl)heptan-4-one Chemical compound CC1CCC(CC1)C(C(C)C)C(=O)C(C(C)C)C1CCC(CC1)C YZKBSTAFLMICGB-UHFFFAOYSA-N 0.000 description 1
- BEARMGATPGLSKG-UHFFFAOYSA-N 2,6-dimethyloct-7-en-2-yl acetate Chemical compound C=CC(C)CCCC(C)(C)OC(C)=O BEARMGATPGLSKG-UHFFFAOYSA-N 0.000 description 1
- IEORSVTYLWZQJQ-UHFFFAOYSA-N 2-(2-nonylphenoxy)ethanol Chemical compound CCCCCCCCCC1=CC=CC=C1OCCO IEORSVTYLWZQJQ-UHFFFAOYSA-N 0.000 description 1
- VVUMWAHNKOLVSN-UHFFFAOYSA-N 2-(4-ethoxyanilino)-n-propylpropanamide Chemical compound CCCNC(=O)C(C)NC1=CC=C(OCC)C=C1 VVUMWAHNKOLVSN-UHFFFAOYSA-N 0.000 description 1
- 239000001278 2-(5-ethenyl-5-methyloxolan-2-yl)propan-2-ol Substances 0.000 description 1
- SJWKGDGUQTWDRV-UHFFFAOYSA-N 2-Propenyl heptanoate Chemical compound CCCCCCC(=O)OCC=C SJWKGDGUQTWDRV-UHFFFAOYSA-N 0.000 description 1
- PEKSDVSZJRGEDW-UHFFFAOYSA-N 2-ethoxy-1-(2-ethoxy-1-hydroxyethoxy)ethanol Chemical compound CCOCC(O)OC(O)COCC PEKSDVSZJRGEDW-UHFFFAOYSA-N 0.000 description 1
- JRMALCOZOZIWLB-UHFFFAOYSA-N 2-methyl-1-(4-methylcyclohexyl)butan-1-one Chemical compound CCC(C)C(=O)C1CCC(C)CC1 JRMALCOZOZIWLB-UHFFFAOYSA-N 0.000 description 1
- DUAYDERMVQWIJD-UHFFFAOYSA-N 2-n,2-n,6-trimethyl-1,3,5-triazine-2,4-diamine Chemical compound CN(C)C1=NC(C)=NC(N)=N1 DUAYDERMVQWIJD-UHFFFAOYSA-N 0.000 description 1
- GNTQOKGIVMJHQG-UHFFFAOYSA-N 2-propan-2-yloxypyridine-3-carbaldehyde Chemical compound CC(C)OC1=NC=CC=C1C=O GNTQOKGIVMJHQG-UHFFFAOYSA-N 0.000 description 1
- JRTBBCBDKSRRCY-UHFFFAOYSA-N 3,7-dimethyloct-6-en-3-ol Chemical compound CCC(C)(O)CCC=C(C)C JRTBBCBDKSRRCY-UHFFFAOYSA-N 0.000 description 1
- OAFJAALOFJVHMK-UHFFFAOYSA-N 4-cyclohexyl-4-methylpentan-2-one Chemical compound CC(=O)CC(C)(C)C1CCCCC1 OAFJAALOFJVHMK-UHFFFAOYSA-N 0.000 description 1
- QDTDKYHPHANITQ-UHFFFAOYSA-N 7-methyloctan-1-ol Chemical compound CC(C)CCCCCCO QDTDKYHPHANITQ-UHFFFAOYSA-N 0.000 description 1
- LJSJTXAZFHYHMM-UHFFFAOYSA-N 7-methyloctyl acetate Chemical compound CC(C)CCCCCCOC(C)=O LJSJTXAZFHYHMM-UHFFFAOYSA-N 0.000 description 1
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 1
- 235000017491 Bambusa tulda Nutrition 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 241000218645 Cedrus Species 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 235000005979 Citrus limon Nutrition 0.000 description 1
- 244000131522 Citrus pyriformis Species 0.000 description 1
- 241000218631 Coniferophyta Species 0.000 description 1
- NOTFZGFABLVTIG-UHFFFAOYSA-N Cyclohexylethyl acetate Chemical compound CC(=O)OCCC1CCCCC1 NOTFZGFABLVTIG-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- WEEGYLXZBRQIMU-WAAGHKOSSA-N Eucalyptol Chemical compound C1C[C@H]2CC[C@]1(C)OC2(C)C WEEGYLXZBRQIMU-WAAGHKOSSA-N 0.000 description 1
- 244000004281 Eucalyptus maculata Species 0.000 description 1
- 241000134874 Geraniales Species 0.000 description 1
- GLZPCOQZEFWAFX-YFHOEESVSA-N Geraniol Natural products CC(C)=CCC\C(C)=C/CO GLZPCOQZEFWAFX-YFHOEESVSA-N 0.000 description 1
- 239000005792 Geraniol Substances 0.000 description 1
- JTCIUOKKVACNCK-YHYXMXQVSA-N Hexyl tiglate Natural products CCCCCCOC(=O)C(\C)=C/C JTCIUOKKVACNCK-YHYXMXQVSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000004439 Isononyl alcohol Substances 0.000 description 1
- BRHDDEIRQPDPMG-UHFFFAOYSA-N Linalyl oxide Chemical compound CC(C)(O)C1CCC(C)(C=C)O1 BRHDDEIRQPDPMG-UHFFFAOYSA-N 0.000 description 1
- 229920002774 Maltodextrin Polymers 0.000 description 1
- 239000005913 Maltodextrin Substances 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- DRECWIUVUNQXEU-UHFFFAOYSA-N OCC1OC(CC(O1)=O)=O Chemical compound OCC1OC(CC(O1)=O)=O DRECWIUVUNQXEU-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- VONGZNXBKCOUHB-UHFFFAOYSA-N Phenylmethyl butanoate Chemical compound CCCC(=O)OCC1=CC=CC=C1 VONGZNXBKCOUHB-UHFFFAOYSA-N 0.000 description 1
- 244000082204 Phyllostachys viridis Species 0.000 description 1
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 1
- 240000008670 Pinus densiflora Species 0.000 description 1
- 235000000405 Pinus densiflora Nutrition 0.000 description 1
- 241000209504 Poaceae Species 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 229920000388 Polyphosphate Polymers 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- WTARULDDTDQWMU-UHFFFAOYSA-N Pseudopinene Natural products C1C2C(C)(C)C1CCC2=C WTARULDDTDQWMU-UHFFFAOYSA-N 0.000 description 1
- 241000220317 Rosa Species 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 240000001949 Taraxacum officinale Species 0.000 description 1
- 235000005187 Taraxacum officinale ssp. officinale Nutrition 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 240000006909 Tilia x europaea Species 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- JNWQKXUWZWKUAY-XYLIHAQWSA-N [(e)-hex-3-enyl] (e)-2-methylbut-2-enoate Chemical compound CC\C=C\CCOC(=O)C(\C)=C\C JNWQKXUWZWKUAY-XYLIHAQWSA-N 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 238000004887 air purification Methods 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- HMKKIXGYKWDQSV-KAMYIIQDSA-N alpha-Amylcinnamaldehyde Chemical compound CCCCC\C(C=O)=C\C1=CC=CC=C1 HMKKIXGYKWDQSV-KAMYIIQDSA-N 0.000 description 1
- GUUHFMWKWLOQMM-NTCAYCPXSA-N alpha-hexylcinnamaldehyde Chemical compound CCCCCC\C(C=O)=C/C1=CC=CC=C1 GUUHFMWKWLOQMM-NTCAYCPXSA-N 0.000 description 1
- 229940072717 alpha-hexylcinnamaldehyde Drugs 0.000 description 1
- UZFLPKAIBPNNCA-BQYQJAHWSA-N alpha-ionone Chemical compound CC(=O)\C=C\C1C(C)=CCCC1(C)C UZFLPKAIBPNNCA-BQYQJAHWSA-N 0.000 description 1
- UZFLPKAIBPNNCA-UHFFFAOYSA-N alpha-ionone Natural products CC(=O)C=CC1C(C)=CCCC1(C)C UZFLPKAIBPNNCA-UHFFFAOYSA-N 0.000 description 1
- GUUHFMWKWLOQMM-UHFFFAOYSA-N alpha-n-hexylcinnamic aldehyde Natural products CCCCCCC(C=O)=CC1=CC=CC=C1 GUUHFMWKWLOQMM-UHFFFAOYSA-N 0.000 description 1
- MVNCAPSFBDBCGF-UHFFFAOYSA-N alpha-pinene Natural products CC1=CCC23C1CC2C3(C)C MVNCAPSFBDBCGF-UHFFFAOYSA-N 0.000 description 1
- 150000004645 aluminates Chemical class 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000001153 anti-wrinkle effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 210000004666 bacterial spore Anatomy 0.000 description 1
- 239000011425 bamboo Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- YNKMHABLMGIIFX-UHFFFAOYSA-N benzaldehyde;methane Chemical compound C.O=CC1=CC=CC=C1 YNKMHABLMGIIFX-UHFFFAOYSA-N 0.000 description 1
- KYZHGEFMXZOSJN-UHFFFAOYSA-N benzoic acid isobutyl ester Natural products CC(C)COC(=O)C1=CC=CC=C1 KYZHGEFMXZOSJN-UHFFFAOYSA-N 0.000 description 1
- 229940007550 benzyl acetate Drugs 0.000 description 1
- CADWTSSKOVRVJC-UHFFFAOYSA-N benzyl(dimethyl)azanium;chloride Chemical compound [Cl-].C[NH+](C)CC1=CC=CC=C1 CADWTSSKOVRVJC-UHFFFAOYSA-N 0.000 description 1
- 229930006722 beta-pinene Natural products 0.000 description 1
- 229920000704 biodegradable plastic Polymers 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- FZJUFJKVIYFBSY-UHFFFAOYSA-N bourgeonal Chemical compound CC(C)(C)C1=CC=C(CCC=O)C=C1 FZJUFJKVIYFBSY-UHFFFAOYSA-N 0.000 description 1
- RECUKUPTGUEGMW-UHFFFAOYSA-N carvacrol Chemical compound CC(C)C1=CC=C(C)C(O)=C1 RECUKUPTGUEGMW-UHFFFAOYSA-N 0.000 description 1
- HHTWOMMSBMNRKP-UHFFFAOYSA-N carvacrol Natural products CC(=C)C1=CC=C(C)C(O)=C1 HHTWOMMSBMNRKP-UHFFFAOYSA-N 0.000 description 1
- 235000007746 carvacrol Nutrition 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 235000010980 cellulose Nutrition 0.000 description 1
- 229910001919 chlorite Inorganic materials 0.000 description 1
- 229910052619 chlorite group Inorganic materials 0.000 description 1
- QBWCMBCROVPCKQ-UHFFFAOYSA-N chlorous acid Chemical compound OCl=O QBWCMBCROVPCKQ-UHFFFAOYSA-N 0.000 description 1
- 229960005233 cineole Drugs 0.000 description 1
- KJPRLNWUNMBNBZ-UHFFFAOYSA-N cinnamic aldehyde Natural products O=CC=CC1=CC=CC=C1 KJPRLNWUNMBNBZ-UHFFFAOYSA-N 0.000 description 1
- 229940117916 cinnamic aldehyde Drugs 0.000 description 1
- NPFVOOAXDOBMCE-PLNGDYQASA-N cis-3-Hexenyl acetate Natural products CC\C=C/CCOC(C)=O NPFVOOAXDOBMCE-PLNGDYQASA-N 0.000 description 1
- RRGOKSYVAZDNKR-ARJAWSKDSA-M cis-3-hexenylacetate Chemical compound CC\C=C/CCCC([O-])=O RRGOKSYVAZDNKR-ARJAWSKDSA-M 0.000 description 1
- 229930003633 citronellal Natural products 0.000 description 1
- 235000000983 citronellal Nutrition 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000013270 controlled release Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- BADXJIPKFRBFOT-UHFFFAOYSA-N dimedone Chemical compound CC1(C)CC(=O)CC(=O)C1 BADXJIPKFRBFOT-UHFFFAOYSA-N 0.000 description 1
- 235000019329 dioctyl sodium sulphosuccinate Nutrition 0.000 description 1
- POLCUAVZOMRGSN-UHFFFAOYSA-N dipropyl ether Chemical compound CCCOCCC POLCUAVZOMRGSN-UHFFFAOYSA-N 0.000 description 1
- YHAIUSTWZPMYGG-UHFFFAOYSA-L disodium;2,2-dioctyl-3-sulfobutanedioate Chemical compound [Na+].[Na+].CCCCCCCCC(C([O-])=O)(C(C([O-])=O)S(O)(=O)=O)CCCCCCCC YHAIUSTWZPMYGG-UHFFFAOYSA-L 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- HFJRKMMYBMWEAD-UHFFFAOYSA-N dodecanal Chemical compound CCCCCCCCCCCC=O HFJRKMMYBMWEAD-UHFFFAOYSA-N 0.000 description 1
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 235000012489 doughnuts Nutrition 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- HJKVPZJVBHWFCQ-BDXSIMOUSA-N estra-1,3,5(10)-trien-3-ol Chemical compound C1CC2=CC(O)=CC=C2[C@@H]2[C@@H]1[C@@H]1CCC[C@@]1(C)CC2 HJKVPZJVBHWFCQ-BDXSIMOUSA-N 0.000 description 1
- 229940073505 ethyl vanillin Drugs 0.000 description 1
- 210000000416 exudates and transudate Anatomy 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- QOLIPNRNLBQTAU-UHFFFAOYSA-N flavan Chemical group C1CC2=CC=CC=C2OC1C1=CC=CC=C1 QOLIPNRNLBQTAU-UHFFFAOYSA-N 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- IVJISJACKSSFGE-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine Chemical compound O=C.NC1=NC(N)=NC(N)=N1 IVJISJACKSSFGE-UHFFFAOYSA-N 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- 238000013467 fragmentation Methods 0.000 description 1
- 238000006062 fragmentation reaction Methods 0.000 description 1
- LCWMKIHBLJLORW-UHFFFAOYSA-N gamma-carene Natural products C1CC(=C)CC2C(C)(C)C21 LCWMKIHBLJLORW-UHFFFAOYSA-N 0.000 description 1
- 229940113087 geraniol Drugs 0.000 description 1
- FQMZVFJYMPNUCT-UHFFFAOYSA-N geraniol formate Natural products CC(C)=CCCC(C)=CCOC=O FQMZVFJYMPNUCT-UHFFFAOYSA-N 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- LHGVFZTZFXWLCP-UHFFFAOYSA-N guaiacol Chemical compound COC1=CC=CC=C1O LHGVFZTZFXWLCP-UHFFFAOYSA-N 0.000 description 1
- JTCIUOKKVACNCK-BJMVGYQFSA-N hexyl (e)-2-methylbut-2-enoate Chemical compound CCCCCCOC(=O)C(\C)=C\C JTCIUOKKVACNCK-BJMVGYQFSA-N 0.000 description 1
- 150000004678 hydrides Chemical class 0.000 description 1
- WPFVBOQKRVRMJB-UHFFFAOYSA-N hydroxycitronellal Chemical compound O=CCC(C)CCCC(C)(C)O WPFVBOQKRVRMJB-UHFFFAOYSA-N 0.000 description 1
- WYXXLXHHWYNKJF-UHFFFAOYSA-N isocarvacrol Natural products CC(C)C1=CC=C(O)C(C)=C1 WYXXLXHHWYNKJF-UHFFFAOYSA-N 0.000 description 1
- 238000004900 laundering Methods 0.000 description 1
- 229940089454 lauryl aldehyde Drugs 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 229940035034 maltodextrin Drugs 0.000 description 1
- GXHFUVWIGNLZSC-UHFFFAOYSA-N meldrum's acid Chemical compound CC1(C)OC(=O)CC(=O)O1 GXHFUVWIGNLZSC-UHFFFAOYSA-N 0.000 description 1
- 229930007503 menthone Natural products 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229940102398 methyl anthranilate Drugs 0.000 description 1
- YAHNYLGSSPTTAG-UHFFFAOYSA-N methyl n-(3,4-dichlorophenyl)carbamodithioate Chemical compound CSC(=S)NC1=CC=C(Cl)C(Cl)=C1 YAHNYLGSSPTTAG-UHFFFAOYSA-N 0.000 description 1
- 229940115425 methylbenzyl acetate Drugs 0.000 description 1
- 239000004530 micro-emulsion Substances 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 229930008383 myrcenol Natural products 0.000 description 1
- DUNCVNHORHNONW-UHFFFAOYSA-N myrcenol Chemical compound CC(C)(O)CCCC(=C)C=C DUNCVNHORHNONW-UHFFFAOYSA-N 0.000 description 1
- YLYBTZIQSIBWLI-UHFFFAOYSA-N n-octyl acetate Natural products CCCCCCCCOC(C)=O YLYBTZIQSIBWLI-UHFFFAOYSA-N 0.000 description 1
- 239000006199 nebulizer Substances 0.000 description 1
- 229920000847 nonoxynol Polymers 0.000 description 1
- 125000006353 oxyethylene group Chemical group 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229940067107 phenylethyl alcohol Drugs 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229940081310 piperonal Drugs 0.000 description 1
- 239000010773 plant oil Substances 0.000 description 1
- 239000001738 pogostemon cablin oil Substances 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 150000003141 primary amines Chemical group 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
- GRWFGVWFFZKLTI-UHFFFAOYSA-N rac-alpha-Pinene Natural products CC1=CCC2C(C)(C)C1C2 GRWFGVWFFZKLTI-UHFFFAOYSA-N 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000010671 sandalwood oil Substances 0.000 description 1
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 1
- 229940057950 sodium laureth sulfate Drugs 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- SXHLENDCVBIJFO-UHFFFAOYSA-M sodium;2-[2-(2-dodecoxyethoxy)ethoxy]ethyl sulfate Chemical compound [Na+].CCCCCCCCCCCCOCCOCCOCCOS([O-])(=O)=O SXHLENDCVBIJFO-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 150000003505 terpenes Chemical class 0.000 description 1
- 125000001302 tertiary amino group Chemical group 0.000 description 1
- 150000003573 thiols Chemical class 0.000 description 1
- NPFVOOAXDOBMCE-UHFFFAOYSA-N trans-3-hexenyl acetate Natural products CCC=CCCOC(C)=O NPFVOOAXDOBMCE-UHFFFAOYSA-N 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- MWOOGOJBHIARFG-UHFFFAOYSA-N vanillin Chemical compound COC1=CC(C=O)=CC=C1O MWOOGOJBHIARFG-UHFFFAOYSA-N 0.000 description 1
- FGQOOHJZONJGDT-UHFFFAOYSA-N vanillin Natural products COC1=CC(O)=CC(C=O)=C1 FGQOOHJZONJGDT-UHFFFAOYSA-N 0.000 description 1
- 235000012141 vanillin Nutrition 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
- ZFNVDHOSLNRHNN-UHFFFAOYSA-N xi-3-(4-Isopropylphenyl)-2-methylpropanal Chemical compound O=CC(C)CC1=CC=C(C(C)C)C=C1 ZFNVDHOSLNRHNN-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
- C11D3/3738—Alkoxylated silicones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
- C11D17/0017—Multi-phase liquid compositions
- C11D17/0021—Aqueous microemulsions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0043—For use with aerosol devices
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
- C11D3/3742—Nitrogen containing silicones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/005—Compositions containing perfumes; Compositions containing deodorants
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
- D06M15/6436—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing amino groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
- D06M23/06—Processes in which the treating agent is dispersed in a gas, e.g. aerosols
-
- C11D2111/12—
Abstract
一种水性织物喷雾组合物，其包含：a.1‑10重量％的硅酮，其中所述硅酮为乳液的形式，所述乳液具有100至30μm的粒径，b.游离香料，具有1nm至30μm的乳液粒径。
Description
技术领域
本发明的领域为织物喷雾剂。
背景技术
用户的生活日益忙碌，他们洗衣的时间有限。在另一方面，经历洗衣过程的衣物中大约40％并不脏，可以再穿着。该实践导致水的不必要的使用，这可以在世界上的缺水地区是特别成问题。
之前已经公开了多种织物清新喷雾剂。EP1495102公开了提供活性材料的控释的组合物。WO 200161100公开了一种用于控制织物中的褶皱的组合物。然而，这些组合物仅涉及清新的特定方面，不是向用户提供信任以再穿着的充分的应对机制。
需要使衣物复原(rejuvenate)和使其回到“刚洗状态(just washed state)”，由此向用户提供信任以再穿着衣物的消费品。对于“刚洗状态”，用户提示是衣物的外观和感觉的协同组合。当寻求复原时，用户想要衣物回到新购买状态的外观和感觉。
发明内容
根据本发明的一个方面，提供了一种水性织物喷雾组合物，其包含：
a.1-10重量％的硅酮，其中所述硅酮为乳液的形式，所述乳液具有100nm至30μm的粒径，
b.游离香料，其具有1nm至30μm的乳液粒径。
根据本发明的另一个方面，提供了一种使织物复原或使衣服回到“刚洗”状态的方法，其包括将根据本发明的组合物喷雾到所述织物或衣服上的步骤。
根据本发明的另一个方面，提供了根据本发明的组合物用于使衣服复原或使衣服回到“刚洗状态”的用途。
根据本发明的组合物提供益处，如颜色复原，织物更厚、更新的感觉，增强的香味，针对未来褶痕的保护，纤维保护和原纤维出现的减少。
在没有热的情况下除去褶痕的能力对于包含具有低沸点的挥发性香料成分的组合物特别有益。这些挥发性成分通常是清新的提示，期望这些尽可能长地保持在织物上。在例如230摄氏度下熨烫会导致这些香料成分中的许多挥发。
具体实施方式
通过阅读以下详细说明和附加的权利要求，这些和其它方面、特征和优点将对本领域普通技术人员变得显而易见。为了避免疑问，本发明的一个方面的任何特征可用于本发明的任何其它方面。词语“包含”旨在表示“包括”，但不一定“由...组成”或“由...构成”。换句话说，所列步骤或选项不需要是穷举性的。应注意以下说明书中给出的实施例旨在阐述本发明，而非旨在将本发明限于那些实施例本身。类似地，除非另有说明，否则所有百分比都是重量/重量百分比。除非是在操作和比较实施例中或在另外明确指出的情况下，否则本说明书中指示材料的量或反应条件、材料的物理特性和/或用途的所有数值都应理解为由词语“约”修饰。以格式“x至y”表示的数值范围应理解为包括x和y。当对于特定特征以“x至y”的格式描述多个优选范围时，应理解也设想组合不同端点的所有范围。
水性组合物
本发明的组合物为水性织物喷雾剂。优选地，至少60重量％的组合物为水，更优选至少70重量％。
硅酮
本发明的组合物包含硅酮。
按喷雾组合物的重量计，硅酮可以以选自小于10％、小于8％和小于6％的含量存在。按喷雾组合物的重量计，硅酮可以以选自：大于0.5％、大于1％和大于1.5％的含量存在。合适地，按衣物清新组合物的重量计，硅酮在喷雾组合物中以选自：约0.5％至约10％，优选约0.5％至约8％，更优选约0.5％至约6％的量存在。
硅酮及其化学性质在例如The Encyclopaedia of Polymer Science，第11卷，第765页中描述。
适合于本发明的硅酮为织物软化硅酮。这样的硅酮的非限制性实例包括：
·非官能化硅酮，如聚二甲基硅氧烷(PDMS)，
·官能化硅酮，如烷基(或烷氧基)官能化的、环氧烷官能化的、氨基官能化的、苯基官能化的、羟基官能化的、聚醚官能化的、丙烯酸酯官能化的、硅烷(siliconhydride)官能化的、羧基官能化的、磷酸盐官能化的、硫酸盐官能化的、膦酸盐官能化的、磺酸盐(sulphonic)官能化的、甜菜碱官能化的、季氮官能化的、及其混合物。
·具有一个或多个不同类型的官能团如烷基、环氧烷、氨基、苯基、羟基、聚醚、丙烯酸酯、硅烷、羧基、磷酸盐、磺酸盐、膦酸盐、甜菜碱、季氮及其混合物的共聚物、接枝共聚物和嵌段共聚物。
合适的非官能化硅酮具有通式：
R1-Si(R3)2-O-[-Si(R3)2-O-]x-Si(R3)2-R2
R1＝氢、甲基、甲氧基、乙氧基、羟基、丙氧基和芳氧基基团。
R2＝氢、甲基、甲氧基、乙氧基、羟基、丙氧基和芳氧基基团。
R3＝烷基、芳基、羟基或羟基烷基基团，及其混合物。
合适的官能化硅酮可以是阴离子、阳离子或非离子官能化硅酮。
官能化硅酮上的官能团优选地位于硅酮上的悬垂位置(pendent positions)，即，组合物包含其中官能团位于除了硅酮链末端之外的位置的官能化硅酮。术语“末端位置”和“在硅酮链的末端”用于指硅酮链的末端。
当硅酮实质上是直链时，硅酮链上存在两个末端。在该情况下，阴离子硅酮优选地不含位于硅酮的末端位置上的官能团。
当硅酮实质上是支链时，末端位置被认为是最长直链硅酮链的两个末端。优选地，没有官能团位于最长直链硅酮链的末端上。
优选的官能化硅酮为包含在硅酮上的链中位置处的阴离子基团的那些。优选地，官能化硅酮的官能团位于距离硅酮上的末端位置至少五个Si原子。优选地，官能团沿着硅酮链随机分布。
为了最好的性能，优选的是硅酮选自：羧基官能化硅酮；阴离子官能化硅酮；非官能化硅酮；及其混合物。更优选地，硅酮选自：羧基官能化硅酮；氨基官能化硅酮；聚二甲基硅氧烷(PDMS)及其混合物。这些材料各自的优选特征在本文中概述。最优选地，硅酮选自氨基官能化硅酮；聚二甲基硅氧烷(PDMS)及其混合物。
羧基官能化硅酮可以作为羧酸或碳酸根阴离子存在，优选地具有按硅酮聚合物的重量计至少1mol％，优选至少2mol％的羧基含量。优选地，羧基位于悬垂位置，更优选地位于距离硅酮上的末端位置至少五个Si原子。优选地，羧基沿着硅酮链随机分布。合适的羧基官能化硅酮的实例包括来自Wacker Chemie的FC 220和来自Shin Etsu的X22-3701E。
氨基官能化硅酮是指含有至少一个伯胺、仲胺或叔胺基团或季铵基团的硅酮。伯胺、仲胺、叔胺和/或季胺基团优选地位于悬垂位置，更优选地位于距离硅酮上的末端位置至少五个Si原子。优选地，氨基沿着硅酮链随机分布。合适的氨基官能化硅酮的实例包括来自Wacker Chemie的FC222和来自Wacker Chemie的EC218。
聚二甲基硅酮(PDMS)聚合物具有通式：
R1-Si(CH3)2-O-[-Si(CH3)2-O-]x-Si(CH3)2-R2
R1＝氢、甲基、甲氧基、乙氧基、羟基、丙氧基和芳氧基基团。
R2＝氢、甲基、甲氧基、乙氧基、羟基、丙氧基和芳氧基基团。
一种合适的PDMS聚合物的合适实例为来自Wacker Chemie的E22。
硅酮聚合物的分子量优选地为1,000至500,000，更优选2,000至250,000，甚至更优选5,000至200,000。
本发明的硅酮为乳液的形式。硅酮优选地在加入本发明的组合物之前乳化。硅酮组合物通常从制造商以乳液的形式供应。
乳液的平均粒径在约100nm至30μm，更优选150nm至20μm范围内。这可以被称为微乳液。粒径测量为体积平均直径D[4,3]，这可以使用来自Malvern instruments的MalvernMastersizer 2000测量。
硅酮乳液的粒径将向织物提供颜色复原。
游离香料
本发明的组合物包含游离香料。
按喷雾组合物的重量计，游离香料可以以选自：小于10％、小于8％和小于5％的含量存在。按喷雾组合物的重量计，游离香料可以以选自：大于0.0001％、大于0.001％和大于0.01％的含量存在。合适地，按衣物清新组合物的重量计，游离香料在喷雾组合物中以选自约0.0001％至约10％，优选约0.001％至约8％，更优选约0.01％至约5％的量存在。
有用的香料组分可以包括天然和合成来源两者的材料。它们包括单一化合物和混合物。这样的组分的具体实例可见于现有文献，例如Fenaroli's Handbook of FlavorIngredients，1975,CRC Press；M.B.Jacobs的Synthetic Food Adjuncts,1947，VanNostrand编辑；或S.Arctander的Perfume and Flavor Chemicals，1969,Montclair,N.J.(USA)。这些物质对于加香、调味和/或芳香化消费品领域的技术人员是熟知的。
已知多种多样的化学品用于香料用途，包括材料如醛、酮、酯等。更通常，已知包含各种化学组分的复杂混合物的天然存在的植物和动物油和分泌液用作香料，这样的材料可以在本文中使用。典型的香料可以包括，例如，含有异国材料如檀香油、麝猫油和广霍香油的木质/土质基质。香料也可以具有清淡的花香味，例如玫瑰或紫罗兰提取物。进一步，可以配制香料以提供期望的水果气味，例如酸橙、柠檬或柑橘。
有用的香料组分和组合物的特别实例为茴香脑(anetole)、苯甲醛、乙酸苄酯、苄醇、甲酸苄酯、乙酸异冰片酯、莰烯、顺式柠檬醛(橙花醛)、香茅醛、香茅醇、乙酸香茅酯、对伞花烃、癸醛、二氢芳樟醇、二氢月桂烯醇、二甲基苯甲醇、桉树脑、香叶醛、香叶醇、乙酸香叶酯、香叶基腈、乙酸顺-3-己烯酯、羟基香茅醛、d-柠檬烯、里哪醇、里哪醇氧化物、乙酸里哪酯、丙酸里哪酯、邻氨基苯甲酸甲酯、α-甲基紫罗酮、甲基壬基乙醛、乙酸甲基苯基原(carbinyl)酯、左旋-乙酸薄荷酯、薄荷酮、异薄荷酮、月桂烯、乙酸月桂烯酯、月桂烯醇、橙花醇、乙酸橙花酯、乙酸壬酯、苯乙醇、α-蒎烯、β-蒎烯、γ-萜品烯、α-萜品醇、β-萜品醇、乙酸萜品酯、Vertenex(乙酸对叔丁基环己酯)、戊基肉桂醛、水杨酸异戊酯、β-石竹烯、雪松烯、肉桂醇、香豆素(couramin)、乙酸二甲基苄基原(carbinyl)酯、乙基香草醛、丁香酚、异丁香酚、乙酸三环癸烯酯(flor acetate)、洋茉莉醛(heliotrophine)、水杨酸3-顺-己烯酯、水杨酸己酯、铃兰醛(lilial)(对叔丁基-α-甲基氢化肉桂醛)、γ-甲基紫罗酮、橙花叔醇、广藿香醇、苯基己醇、β-蛇床烯、乙酸三氯甲基苯基原(carbinyl)酯、柠檬酸三乙酯、香草醛、藜芦醛、α-雪松烯、β-雪松烯、C15H24倍半萜烯、二苯酮、水杨酸苄酯、巴西酸乙二醇酯、佳乐麝香(galaxolide)(1,3,4,6,7,8-六氢-4,6,6,7,8,8-六甲基环戊-γ-2-苯并吡喃)、己基肉桂醛、新铃兰醛(lyral)(4-(4-羟基-4-甲基戊基)-3-环己烯-10-甲醛)、甲基柏木酮、二氢茉莉酮酸甲酯、甲基-β-萘基酮、葵子麝香、茚酮麝香(musk idanone)、酮麝香、西藏麝香、二甲苯麝香、橙花素和乙酸苯乙基苯酯。
本发明组合物的游离香料组合物包含释香(blooming)香料成分。释香香料组分定义为沸点低于250℃且LogP大于2.5。优选地，本发明的游离香料组合物包含至少10重量％的释香香料成分，更优选地至少20重量％的释香香料成分，最优选地至少25重量％的释香香料成分。优选地，本发明的游离香料组合物包含小于58重量％的释香香料成分，更优选地小于50重量％的释香香料成分，最优选地小于45重量％的释香香料成分。合适地，本发明组合物的游离香料组合物包含10至58重量％的释香香料成分，优选地20至50重量％的释香香料成分，更优选地25至45重量％的释香香料成分。
合适的释香香料成分的实例包括：别罗勒烯(Allo-ocimene)、庚酸烯丙酯、反式茴香脑、丁酸苄酯、莰烯、香芹酚、惕各酸顺式-3-己烯酯、香茅醇、乙酸香茅酯、香茅腈、乙酸环己基乙酯、癸醛(癸醛)、二氢月桂烯醇、乙酸二氢月桂烯酯、3,7-二甲基-1-辛醇、乙酸葑酯、乙酸香叶酯、甲酸香叶酯、香叶基腈、异丁酸顺式-3-己烯酯、新戊酸己酯、惕各酸己酯、α-紫罗酮、乙酸异冰片酯、苯甲酸异丁酯、乙酸异壬酯、异壬醇、乙酸异胡薄荷酯(isopulegylacetate)、月桂醛、乙酸里哪酯、Lorysia、D-柠檬烯、Lymolene、(-)-L-乙酸薄荷酯、甲基胡椒酚(草蒿脑)、甲基正壬基乙醛、甲基辛基乙醛、β-月桂烯、乙酸橙花酯、乙酸壬酯、壬醛、对-伞花烃、α-蒎烯、β-蒎烯、α-萜品烯、γ-萜品烯、萜品油烯(Terpineolene)、α-乙酸萜品酯、四氢里哪醇、四氢月桂烯醇、2-十一碳烯醛、Verdox(乙酸邻叔丁基环已酯)、和Vertenex(乙酸4-叔丁基环己酯)。
其它有用的香料成分包括直接(substantive)香料组分。直接香料组分定义为沸点大于250℃且LogP大于2.5。优选地，游离香料组合物进一步包含直接香料成分。
沸点是在标准压力(760mm Hg)下测量的。优选地，香料组合物将包含释香和直接香料组分的混合物。香料组合物可以包含其它香料组分。
已经报道了许多香料成分的logP；例如，可获自Daylight Chemical InformationSystems,Inc.(Daylight CIS),Irvine,Calif.的Pomona92数据库包含许多，以及对原始文献的引用。然而，logP值最方便地通过同样可获自Daylight CIS的“CLOGP”程序计算。当其可在Pomona 92数据库中获得时，该程序还列出了实验性logP值。“计算的logP”(ClogP)是通过Hansch和Leo的片断方法测定(参见，A Leo，Comprehensive Medicinal Chemistry，第4卷，C.Hansch,P.G.Sammens,J.B.Taylor和C.A.Ramsden编著，第295页，Pergamon Press,1990，通过引入并入本文)。该片断方法是基于每种香料成分的化学结构并考虑原子的数量和类型、原子连接、和化学键合。
在选择本文的香料成分时，使用最可靠和广泛用于估计该物理化学性质的ClogP而非实验性logP值。
在游离油香料组合物中存在多种香料组分是常见的。在用于本发明的组合物中，设想存在三种或更多种，优选地四种或更多种，更优选地五种或更多种，最优选地六种或更多种不同的香料组分。可以应用300种香料组分的上限。
本发明的游离香料为乳液的形式。乳液的粒径可以在约1nm至30微米，优选约100nm至约20微米的范围内。粒径测量为体积平均直径D[4,3]，这可以使用来自Malverninstruments的Malvern Mastersizer 2000测量。
不希望受到理论的束缚，据信具有该乳液粒径的游离香料将与硅酮乳液相互作用，以在被喷雾的物品上提供改善的香料寿命。
在本发明的组合物中，游离油香料形成乳液。所述乳液可以在组合物之外或原位形成。当原位形成时，优选地与游离油香料一起加入至少一种乳化剂，以稳定所述乳液。优选地，乳化剂为阴离子的或非离子的。用于游离油香料的合适的阴离子乳化剂的实例为烷基芳基磺酸盐，例如十二烷基苯磺酸钠，烷基硫酸盐，例如月桂基硫酸钠，烷基醚硫酸盐，例如月桂基醚硫酸钠nEO，其中n为1至20，烷基酚醚硫酸盐，例如辛基苯酚醚硫酸盐nEO，其中n为1至20，和磺基琥珀酸盐，例如二辛基磺基琥珀酸钠。用作用于游离油香料的乳化剂的合适的非离子表面活性剂的实例为烷基酚乙氧基化物，例如壬基酚乙氧基化物nEO，其中n为1至50，醇乙氧基化物，例如月桂醇nEO，其中n为1至50，酯乙氧基化物，例如单硬脂酸聚氧乙烯酯，其中氧乙烯单元的数量为1至30，和PEG-40氢化蓖麻油。
异味成分
本发明的组合物优选地包含抗异味成分。异味成分可以是在传统游离香料成分之外。
按衣物清新组合物的重量计，抗异味剂可以以选自：小于20％、小于10％和小于5％的含量存在。合适地，按衣物清新组合物的重量计，抗异味剂在衣物清新组合物中以选自约0.01％至约5％，优选约0.1％至约3％，更优选约0.5％至约2％的范围内的量存在。
可以使用任何合适的抗异味剂。实际上，抗异味作用可以通过有效地“捕获(trap)”、“吸收”或“破坏”气味分子以由此从衣物分离或除去气味或充当“异味冲消剂(counteractant)”的任何化合物或产品实现。
气味控制剂可以选自：未络合环糊精；气味阻断剂；反应性醛；类黄酮；沸石；活性碳；蓖麻油酸锌或其溶液与取代的单环有机化合物的混合物；及其混合物。
如上所述，合适的抗异味剂为环糊精，合适地是水溶性未络合环糊精。合适地，按衣物清新组合物的重量计，环糊精以选自0.01％至5％，0.1％至4％，和0.5％至2％的含量存在。
如本文使用的术语“环糊精”包括任何已知环糊精，如含有六至十二个葡萄糖单元的未取代环糊精，尤其是α-环糊精、β-环糊精、γ-环糊精和/或其衍生物和/或其混合物。α-环糊精由六个葡萄糖单元组成，β-环糊精由七个葡萄糖单元组成，和γ-环糊精由排列成甜甜圈形环的八个葡萄糖单元组成。
优选地，环糊精为高度水溶性的，如α-环糊精和/或其衍生物，γ-环糊精和/或其衍生物，衍生化β-环糊精，和/或其混合物。环糊精的衍生物主要由其中OH基团中的一些转变成OR基团的分子组成。环糊精衍生物包括，例如，具有短链烷基的那些，如甲基化环糊精和乙基化环糊精，其中R为甲基或乙基；具有羟烷基取代基团的那些，如羟丙基环糊精和/或羟乙基环糊精，其中R为-CH2-CH(OH)-CH3或-CH2CH2-OH基团；支链环糊精，如麦芽糖-键合的环糊精；阳离子环糊精，如含有2-羟基-3-(二甲基氨基)丙基醚的那些，其中R为CH2-CH(OH)-CH2-N(CH3)2，其在低pH下是阳离子性的；季铵，例如氯化2-羟基-3-(三甲基铵基)丙基醚基团，其中R为CH2-CH(OH)-CH2-N+(CH3)3Cl-；阴离子环糊精，如羧甲基环糊精、环糊精硫酸盐和环糊精琥珀酸盐；两性环糊精，如羧甲基/季铵环糊精；其中至少一个吡喃葡萄糖单元具有3-6-脱水-环麦芽糖结构的环糊精，例如单-3-6-脱水环糊精。
高度水溶性的环糊精为在室温下具有在100ml的水中至少约10g，优选地在100ml的水中至少约20g，更优选地在室温下在100ml的水中至少约25g的水溶解度的那些。溶解的未络合环糊精的可用性对于有效和高效的气味控制性能是必要的。当沉积在表面上，尤其是织物上时，溶解的水溶性环糊精可以显示出比非水溶性环糊精更有效的气味控制性能。
适用于本文的优选水溶性环糊精衍生物的实例为羟丙基α-环糊精、甲基化α-环糊精、甲基化β-环糊精、羟乙基β-环糊精和羟丙基β-环糊精。羟烷基环糊精衍生物优选地具有约1至约14，更优选约1.5至约7的取代度，其中每个环糊精的OR基团的总数定义为取代度。甲基化环糊精衍生物通常具有约1至约18，优选约3至约16的取代度。一种已知的甲基化β-环糊精为七-2,6-二-O-甲基-β-环糊精，通常称为DIMEB，其中对于葡萄糖单元具有约2个甲基，取代度为约14。一种优选的更可商购的甲基化β-环糊精为随机甲基化β-环糊精，通常称为RAMEB，具有不同的取代度，通常为约12.6。RAMEB比DIMEB更优选，因为DIMEB比RAMEB更影响优选表面活性剂的表面活性。优选的环糊精可获自例如Cerestar U.S.A.,Inc.和WackerChemicals(U.S.A.),Inc。
在实施方式中，使用环糊精的混合物。“气味阻断剂”可以用作抗异味剂以减轻异味的影响。异味阻断剂的非限制性实例包括4-环己基-4-甲基-2-戊酮、4-乙基环己基甲基酮、4-异丙基环己基甲基酮、环己基甲基酮、3-甲基环己基甲基酮、4-叔丁基环己基甲基酮、2-甲基-4-叔丁基环己基甲基酮、2-甲基-5-异丙基环己基甲基酮、4-甲基环己基异丙基酮、4-甲基环己基仲丁基酮、4-甲基环己基异丁基酮、2,4-二甲基环己基甲基酮、2,3-二甲基环己基甲基酮、2,2-二甲基环己基甲基酮、3,3-二甲基环己基甲基酮、4,4-二甲基环己基甲基酮、3,3,5-三甲基环己基甲基酮、2,2,6-三甲基环己基甲基酮、1-环己基-1-甲酸乙酯、1-环己基-1-乙酸乙酯、1-环己基-1-丙酸乙酯、1-环己基-1-异丁酸乙酯、1-环己基-1-正丁酸乙酯、1-环己基-1-乙酸丙酯、1-环己基-1-正丁酸丙酯、1-环己基-2-甲基-1-乙酸丙酯、2-环己基-2-乙酸丙酯、2-环己基-2-丙酸丙酯、2-环己基-2-异丁酸丙酯、2-环己基-2-正丁酸丙酯、5,5-二甲基-1,3-环己烷二酮(双甲酮)、2,2-二甲基-1,3-二噁烷-4,6-二酮(Meldrum酸)、螺-[4.5]-6,10-二氧杂-7,9-二氧代癸烷、螺-[5.5]-1,5-二氧杂-2,4-二氧代十一烷、2,2-羟甲基-1,3-二噁烷-4,6-二酮和1,3-环己基二酮。气味阻断剂更详细地公开在US4,009,253；US4,187,251；US4,719,105；US5,441,727；和US5,861,371中，其通过引用并入本文。
反应性醛可用作抗异味剂以减轻异味的影响。合适的反应性醛的实例包括I类醛和II类醛。I类醛的实例包括大茴香醛、o-烯丙基-香草醛、苯甲醛、枯茗醛、乙基茴香醛(ethylaubepin)、乙基香草醛、胡椒醛、甲苯基醛和香草醛。II类醛的实例包括3-(4'-叔丁基苯基)丙醛、2-甲基-3-(4-叔丁基苯基)丙醛、2-甲基-3-(4'-异丙基苯基)丙醛、2,2-二甲基-3-(4-乙基苯基)丙醛、肉桂醛、α-戊基-肉桂醛和α-己基肉桂醛。这些反应性醛更详细地描述在US5,676,163中。当使用时，反应性醛可以包括至少两种醛的组合，其中一种醛选自无环脂族醛、非萜烯脂族醛、非萜烯脂环族醛、萜烯醛、被芳族基团取代的脂族醛、和双官能醛；且第二醛种选自具有与芳香环共轭的醛官能团的α不饱和的醛，和其中醛基在芳环上的醛。这种至少两种醛的组合在WO00/49120中更详细地描述。如本文使用的术语“反应性醛”进一步涵盖作为(i)醛与醇，(ii)酮与醇，或(iii)醛与相同的或不同的醛的反应产物的除味材料。这样的除味材料可以是：(a)通过将醛与甲醇反应产生的缩醛或半缩醛；(b)通过将酮与甲醇反应产生的缩酮或半缩酮；(c)至少两种醛的环状三缩醛或混合环状三缩醛，或任何这些缩醛、半缩醛、缩酮、半缩酮或环状三缩醛的混合物。这些除味香料材料更详细地描述在WO 01/07095中，其通过引用并入本文。
类黄酮也可以用作抗异味剂。类黄酮是基于C6-C3-C6黄烷骨架的化合物。类黄酮可见于典型的精油。这样的油包括从针叶树和草(例如雪松、日本扁柏、桉树、日本红松、蒲公英、低条纹竹和陇牛儿苗科)通过干馏提取的精油，并且可以含有萜类物质，例如α-蒎烯、β-蒎烯、月桂烯、phencone和莰烯。还包括茶叶提取物。这样的材料的描述可以见于JP02284997和JP 04030855，。
金属盐也可用作抗异味剂以实现异味控制益处。实例包括脂肪酸的金属盐。蓖麻油酸是优选的脂肪酸。锌盐是优选的金属盐。蓖麻油酸的锌盐是特别优选的。可商购的产品是来自Evonik的TEGO Sorb A30。合适的金属盐的进一步细节提供如下。
沸石可以用作抗异味剂。一类有用的沸石的特征在于“中间”硅酸盐/铝酸盐沸石。中间沸石(intermediate zeolite)的特征在于SiO2/AlO2摩尔比小于约10。优选地，SiO2/AlO2的摩尔比范围为约2至约10。中间沸石可具有优于“高”沸石的优点。中间沸石对胺类气味具有更高的亲和力，它们对于气味吸收是更高重量效率的，因为它们具有更大的表面积，并且它们比高沸石更耐湿并且在水中保留更高的气味吸收能力。适用于本文的广泛的中间沸石可以作为
CP301-68、
300-63、
CP300-35和
CP300-56商购自PQ Corporation，和作为
系列沸石商购自Conteka。可从TheUnion Carbide Corporation和UOP获得的以商品名
和
销售的沸石材料也是优选的。这样的材料对于含硫气味(例如硫醇类(thiols)、硫醇类(mercaptans))的控制优于中间沸石。合适地，沸石材料具有小于约10微米的粒度，并且在衣物清新组合物中以小于衣物清新组合物的1重量％的水平存在。
活性炭是另一种合适的抗异味剂。合适的碳材料是用于有机分子和/或用于空气净化目的的已知吸收剂。通常，这样的碳材料被称为“活性”碳或“活性”炭。这样的碳可以以以下商品名从商业来源获得：如Calgon-Type
Type
Type
Type
和Type 
合适地，活性炭优选具有小于约10微米的粒度，并且在衣物清新组合物中以小于衣物清新组合物的约1重量％的水平存在。
示例性的抗异味剂如下。
ODOBANTM是由Warner Robins,Ga的Clean Central Corp.制造和分发。其活性成分是烷基(C14 50％，C12 40％和C16 10％)二甲基苄基氯化铵，其是抗细菌季铵化合物。烷基二甲基苄基氯化铵是与水和异丙醇一起在溶液中。Clean Control Corp.的另一种产品是BIOODOUR CONTROLTM，其包含水、细菌孢子、烷基酚乙氧基化物和丙二醇。
ZEOCRYSTAL FRESH AIR MISTTM是由Crestwood,Ill的Zeo Crystal Corp.(a/k/aAmerican Zeolite Corporation)制造和分发。该液体包含亚氯酸盐、氧、钠、碳酸盐和柑橘提取物，并且可包含沸石。
气味控制剂可以包括如US2005/0113282A1中描述的异味冲消剂(counteractant)，其通过引用并入本文。特别地，这种异味冲消剂可以包括蓖麻油酸锌或其溶液和如在第17段第2页描述的取代的单环有机化合物的混合物，其中所述取代的单环有机化合物择一地或组合地是以下中的一种或多种：
1-环己基乙-1-基丁酸酯；
1-环己基乙-1-基乙酸酯；
1-环己基乙-1-醇；
1-(4'-甲基乙基)环己基乙-1-基丙酸酯；和
2'-羟基-1'-乙基(2-苯氧基)乙酸酯。
如第38-49段公开的异味冲消剂的协同组合是合适的，例如，所述组合物包含：
(i)约10至约90重量份的至少一种含有取代的单环有机化合物的材料，其为：
(a)1-环己基乙-1-基丁酸酯，其具有以下结构：
(b)1-环己基乙-1-基乙酸酯，其具有以下结构：
(c)1-环己基乙-1-醇，其具有以下结构：
(d)1-(4'-甲基乙基)环己基乙-1-基丙酸酯，其具有以下结构：
和
(e)2'-羟基-1'-乙基(2-苯氧基)乙酸酯，其具有以下结构：
和
(ii)约90至约10重量份的含有蓖麻油酸锌的组合物，其为蓖麻油酸锌和/或含有大于约30重量％的蓖麻油酸锌的蓖麻油酸锌溶液。优选地，前述含有蓖麻油酸锌的组合物为约50重量％的蓖麻油酸锌和约50重量％的至少一种1-羟基-2-乙氧基乙基醚的混合物。更具体地，可用于与蓖麻油酸锌组分组合的优选组合物为以下的混合物：
(A)1-环己基乙-1-基丁酸酯；
(B)1-环己基乙-1-基乙酸酯；和
(C)1-(4'-甲基乙基)环己基乙-1-基丙酸酯。
更优选地，前述含有蓖麻油酸锌的混合物的组分的重量比为其中含有蓖麻油酸锌的组合物:1-环己基乙-1-基丁酸酯:1-环己基乙-1-基乙酸酯:1-(4'-甲基乙基)环己基烷-1-基丙酸酯为约2:1:1:1。
可用于与蓖麻油酸锌组分或溶液组合的另一种优选的组合物为以下的混合物：
(A)1-环己基乙-1-基乙酸酯；和
(B)1-(4'-甲基乙基)环己基乙-1-基丙酸酯。
更优选地，前述含有蓖麻油酸锌的混合物的组分的重量比为其中含有蓖麻油酸锌的组合物:1-环己基乙-1-基乙酸酯:1-(4'-甲基乙基)环己基乙-1-基丙酸酯为约3:1:1。
本发明的抗异味材料在组合物中可以是“游离的”，或者它们可以被包封。合适的包封材料可以包括，但不限于，氨基塑料、蛋白质、聚氨酯、聚丙烯酸酯、聚甲基丙烯酸酯、多糖、聚酰胺、聚烯烃、树胶、硅酮、脂质、改性纤维素、多磷酸盐、聚苯乙烯、聚酯或其组合。
特别优选的包封材料为氨基塑料，如三聚氰胺甲醛或脲甲醛。本发明的微胶囊可以为脆性微胶囊和/或水分活化微胶囊。脆性是指当施加力时，香料微胶囊将破裂。水分活化是指香料在水的存在下释放。
在本文中描述为气味控制剂的任何材料也可能归类为本文所述的另一种组分的情况下，就本发明的目的而言，这样的材料应归类为气味控制剂。
其它任选成分
其它任选成分可以存在于本发明的水性喷雾组合物中。例如，水性喷雾组合物可以进一步包含：着色剂/染料、防腐剂、粘度控制剂、包含有益剂的微胶囊、结构化剂/分散剂、溶剂、用于加工助剂的消泡剂等。
喷雾组合物
组合物为织物喷雾组合物。这是指所述组合物适于喷雾到织物上。它们可以通过任何合适的喷雾设备喷雾。
优选地，在喷雾机构可人工操作以从喷嘴排出一定剂量的所述组合物的意义上，喷雾设备是可人工操作的喷雾设备。喷雾机构可以通过致动器操作。致动器可以为推动致动器或拉动致动器。致动器可以包含触发器。喷雾机构可以包含可手操作泵。任选地，所述泵为以下之一：正位移泵；自引发泵；往复泵。合适的喷雾设备包括触发式喷雾器、连续/半连续喷雾器、手指泵喷雾器、振动筛网设备输出喷雾器。
优选地，喷雾设备可在不使用推进剂的情况下操作。实际上，优选无推进剂的喷雾设备。这允许喷雾剂保持产品的完整性和纯度、不受推进剂污染且是环境优选的。
优选地，喷雾设备是加压的。这可以改善喷雾持续时间和速度。优选地，喷雾设备是通过与容纳组合物的储器分开的气体室加压。气体优选地为空气或氮气。喷雾设备可以包括容纳组合物和加压剂的外容器，其中组合物通过容纳(优选地，密闭地密封的)在柔性小袋中而与加压剂分隔。这保持整个制剂的完整性，使得仅分配纯(即，排除加压剂)组合物。优选的系统为所谓的“罐中袋(bag-in-can)”(或BOV、阀上袋(bag-on-valve)技术)。或者，喷雾设备可以包括活塞式屏障机构，例如Crown Holding的EarthSafe。
优选地，喷雾设备包含可生物降解的塑料材料。
喷雾机构可以进一步包含雾化器，其配置成将所述液体剂量分解成液滴，从而促进形成雾形式的所述细气雾剂。方便地，所述雾化器可以包含以下中的至少一个：涡流室和侧向分散室。合适地，雾化器起到混合空气与水性织物喷雾组合物的作用。
当喷雾时，制剂的粒径优选地为不超过300μm，优选地不超过250μm，优选地不超过150μm，优选地不超过125μm，优选地不超过100μm。当喷雾时，制剂的粒径优选地为至少5μm，优选地至少10μm，优选地至少15μm，优选地至少20μm，优选地至少30μm，优选地至少40μm。合适地，喷雾包含平均直径在优选地5至300μm、更优选10至250μm、最优选15至150μm范围内的液滴。该尺寸允许均匀分布和在足够润湿织物，而没有由于过量定量加料一些成分而导致的潜在织物损坏之间的平衡。液滴尺寸可以在Malvern Spraytec instrument上测量，峰最大值对应于平均液滴尺寸。参数液滴尺寸为体积平均直径D[4,3]。
合适地，在致动后，喷雾具有在至少0.4秒范围内的持续时间。优选地，喷雾具有至少0.8秒的持续时间。较长的持续时间通过使每次致动喷雾设备的覆盖最大化而使努力最小化。这对于设计成用于衣物的全部区域上的产品是重要的因素。优选地，喷雾持续时间与致动直接相关，使得只要致动器被激活(例如，只要压着按钮或触发器)，喷雾排出持续。
喷雾储器可以是非加压的、人工或机械预加压的设备。上述也是可移动的/可再装填的储器。
根据本发明的进一步的方面，提供了一种用于根据上述方面的衣物清新产品的更换储器，所述更换储器预装填有一定体积的所述衣物清新组合物用于补充所述产品。合适的“再装填套件”包括一个或多个储器。在多于一个储器，例如两个、三个、四个、五个或更多个储器的情况下，每个储器的内容物(水性织物喷雾组合物)可以与其它储器相同或不同。
剂量
方便地，衣物清新组合物作为液体提供，并且所述喷雾机构可操作以排出至少0.1ml，优选至少0.2ml，更优选至少0.25ml，更优选至少0.3ml，更优选至少0.35ml，更优选至少0.35ml，更优选至少0.4ml，更优选至少0.45ml，和最优选至少0.5ml的剂量。
合适地，剂量不超过2ml，优选不超过1.8ml，优选不超过1.6ml，更优选不超过1.5ml，更优选不超过1.4ml，更优选不超过1.3ml，和最优选不超过1.2ml。
合适地，剂量为0.1至2ml的所述液体衣物清新组合物，优选0.2至1.8ml，更优选0.25至1.6ml，更优选0.25至1.5ml，和最优选0.25至1.2ml。
已经发现这些剂量在实现期望的衣物清新作用(例如抗皱褶)而没有难看的和浪费的大液滴形成的方面特别有效。
使用方法
在本发明的一个方面，提供了一种使织物复原或使衣服回到“刚洗”状态的方法。“刚洗”状态旨在表示新近洗涤的衣物的外观、感觉和气味，对于一些衣物，洗衣过程将包括熨烫(例如，衬衫)。根据本发明的方法包括将本发明的组合物喷雾到衣物上的步骤。
组合物的用途
在本发明的一个方面，提供了根据本发明的组合物的用途。所述组合物可用于使衣服复原或使衣物回到“刚洗”状态。
复原指所述组合物可用于使经处理的衣物看起来和感觉上更年轻或更新。这包括使衣物恢复到新购买状态的外观和感觉，其可以包括：更少的褪色或更厚的感觉或分裂纤维保护或原纤维的粘住，等等，特别是颜色复原。
回到“刚洗状态”指组合物可用于使衣物看上去、感觉上和闻起来是新近洗涤的。这包括提供刚性和脆性(crispness)的感觉，或除去不想要的褶痕，颜色复原，等等。
实施例制剂
制备方法：
向容器中装入水，并保持在20℃±5℃。向容器中加入硅酮乳液和次要成分，同时搅拌。通过混合熔融的非离子表面活性剂(45℃)与游离油香料和抗异味技术产生预混物，同时将该混合物保持在45℃。然后将预混物加入到容器中，同时混合。
Claims (14)
1.一种水性织物喷雾组合物，其包含：
a.1-10重量％的硅酮，其中所述硅酮为乳液的形式，所述乳液具有100nm至30μm的粒径，
b.游离香料，其具有1nm至30μm的乳液粒径。
2.根据权利要求1所述的组合物，其中所述组合物包含0.0001-10重量％的游离香料。
3.根据前述权利要求中任一项所述的组合物，其中所述组合物进一步包含异味成分。
4.根据前述权利要求中任一项所述的组合物，其中所述游离香料组合物包含至少10重量％的释香香料成分。
5.根据前述权利要求中任一项所述的组合物，其中所述硅酮具1,000至500,000的分子量。
6.根据前述权利要求中任一项所述的组合物，其中所述硅酮包含官能化硅酮。
7.根据权利要求7所述的组合物，其中所述官能化硅酮上的官能团位于硅酮链上的悬垂位置。
8.根据前述权利要求中任一项所述的组合物，其中所述硅酮包含非官能化硅酮。
9.根据权利要求9所述的组合物，其中所述非官能化硅酮是根据下式：
R1-Si(R3)2-O-[-Si(R3)2-O-]x-Si(R3)2-R2
R1＝氢、甲基、甲氧基、乙氧基、羟基、丙氧基和芳氧基基团，
R2＝氢、甲基、甲氧基、乙氧基、羟基、丙氧基和芳氧基基团，
R3＝烷基、芳基、羟基或羟基烷基基团，及其混合物。
10.根据前述权利要求中任一项所述的组合物，其中所述硅酮选自：羧基官能化硅酮；阴离子官能化硅酮；非官能化硅酮；及其混合物。
11.根据前述权利要求中任一项所述的组合物，其中所述硅酮组合物包含0.001至3meq/g的胺含量。
12.根据前述权利要求中任一项所述的组合物，其中所述硅酮组合物包含聚二甲基硅氧烷聚合物。
13.一种使织物复原或使衣服回到“刚洗”状态的方法，其包括将根据前述权利要求中任一项所述的组合物喷雾到所述织物或衣服上的步骤。
14.根据权利要求1至11所述的组合物用于使衣服复原或使衣服回到“刚洗状态”的用途。
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP17196289 | 2017-10-13 | ||
| EP17196289.7 | 2017-10-13 | ||
| PCT/EP2018/076838 WO2019072645A1 (en) | 2017-10-13 | 2018-10-02 | AQUEOUS AEROSOL COMPOSITION |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN111212894A true CN111212894A (zh) | 2020-05-29 |
Family
ID=60083842
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201880066497.3A Pending CN111212894A (zh) | 2017-10-13 | 2018-10-02 | 水性喷雾组合物 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US11807834B2 (zh) |
| EP (1) | EP3694964A1 (zh) |
| CN (1) | CN111212894A (zh) |
| AR (1) | AR113326A1 (zh) |
| BR (1) | BR112020007275A2 (zh) |
| WO (1) | WO2019072645A1 (zh) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PL3894529T3 (pl) * | 2018-12-11 | 2023-05-29 | Unilever Ip Holdings B.V. | Kompozycje do kondycjonowania tkanin |
| BR112023003398A2 (pt) * | 2020-09-09 | 2023-04-11 | Unilever Ip Holdings B V | Composição aquosa em spray para tecido, método para prover perfume ao tecido e uso da composição |
Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999055953A1 (en) * | 1998-04-27 | 1999-11-04 | The Procter & Gamble Company | Fabric wrinkle control composition and method |
| CN1278033A (zh) * | 1999-05-24 | 2000-12-27 | 陶氏康宁东丽硅氧烷株式会社 | 水基纤维处理剂和用来处理纤维的方法 |
| WO2001016266A2 (en) * | 1999-09-02 | 2001-03-08 | The Procter & Gamble Company | Method of deodorizing and/or cleaning carpet using a composition comprising odor control agent |
| CN1384895A (zh) * | 1999-10-27 | 2002-12-11 | 宝洁公司 | 防皱组合物 |
| CN101802293A (zh) * | 2007-09-14 | 2010-08-11 | 宝洁公司 | 用于处理织物的组合物 |
| CN102260604A (zh) * | 2002-08-16 | 2011-11-30 | 莫门蒂夫性能材料股份有限公司 | 含有硅氧烷添加剂的液体洗衣组合物 |
| WO2014003180A1 (ja) * | 2012-06-29 | 2014-01-03 | ライオン株式会社 | 液体柔軟剤組成物 |
| CN103748204A (zh) * | 2011-08-26 | 2014-04-23 | 高露洁-棕榄公司 | 织物皱折降低组合物 |
| CN106574214A (zh) * | 2014-07-28 | 2017-04-19 | 宝洁公司 | 包含氨基硅氧烷聚合物纳米乳液的织物处理组合物 |
| BR102015027601A2 (pt) * | 2015-10-30 | 2017-05-02 | De Aguiar Pereira Tiago | aperfeiçoamentos introduzidos em formulação de solução química para impregnação de artigo de limpeza e produto resultante |
| CN106661514A (zh) * | 2014-07-28 | 2017-05-10 | 宝洁公司 | 包含氨基硅氧烷聚合物纳米乳液的织物处理组合物 |
Family Cites Families (111)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4009253A (en) | 1973-11-05 | 1977-02-22 | Monsanto Company | 4-cyclohexyl-4-methyl-2-pentanone useful as a malodor counteractant |
| US4719105A (en) | 1975-11-05 | 1988-01-12 | Bush Boake Allen, Inc. | Method, compositions and compounds useful in room fresheners employing cyclohexyl alcohol and ester derivatives |
| US4187251A (en) | 1976-12-16 | 1980-02-05 | Schleppnik Alfred A | Malodor counteractants |
| JPS63212318A (ja) | 1987-02-28 | 1988-09-05 | キヤノン株式会社 | 眼測定装置 |
| US6033679A (en) | 1998-04-27 | 2000-03-07 | The Procter & Gamble Company | Uncomplexed cyclodextrin compositions for odor control |
| US5942217A (en) | 1997-06-09 | 1999-08-24 | The Procter & Gamble Company | Uncomplexed cyclodextrin compositions for odor control |
| US4917303A (en) | 1988-09-26 | 1990-04-17 | Afa Products, Inc. | Snap-in trigger |
| NZ228775A (en) | 1989-04-17 | 1990-10-26 | Afa Products Inc | Trigger sprayer nozzle with spray and foam output options |
| JPH02284997A (ja) | 1989-04-26 | 1990-11-22 | Osaka Yakuhin Kenkyusho:Kk | 消臭洗剤 |
| ES2016450A6 (es) | 1989-05-19 | 1990-11-01 | Afa Products Inc | Conjunto de tobera. |
| US5111971A (en) | 1989-05-26 | 1992-05-12 | Robert Winer | Self-pressurized container having a convoluted liner and an elastomeric sleeve |
| US5441727A (en) | 1989-06-21 | 1995-08-15 | The Procter & Gamble Company | Diketone deodorant composition and method of deodorization |
| US4991778A (en) | 1989-11-16 | 1991-02-12 | Afa Products, Inc. | Adjustable nozzle assembly |
| US5234166A (en) | 1990-10-25 | 1993-08-10 | Contico International, Inc. | Spinner assembly for a sprayer |
| US5344053A (en) | 1992-03-09 | 1994-09-06 | Contico International, Inc. | Trigger sprayer having a two-piece housing construction |
| CA2106173A1 (en) | 1992-09-23 | 1994-03-24 | Kalliopi S. Haley | Fabric finish stiffening composition |
| EP0731717B1 (en) | 1993-11-30 | 2002-07-31 | Quest International B.V. | Anti-smoke perfumes and compositions |
| US5397060A (en) | 1994-01-21 | 1995-03-14 | Afa Products, Inc. | Foam-spray-off trigger sprayer |
| US5534165A (en) | 1994-08-12 | 1996-07-09 | The Procter & Gamble Company | Fabric treating composition containing beta-cyclodextrin and essentially free of perfume |
| ES2158885T3 (es) | 1994-09-12 | 2001-09-16 | Procter & Gamble | Un detergente envasado unitario. |
| US5783541A (en) | 1994-09-12 | 1998-07-21 | Procter & Gamble Company | Unit packaged detergent |
| DE4439570A1 (de) | 1994-11-05 | 1996-05-09 | Henkel Kgaa | Wäschenachbehandlungsmittel |
| US6550694B1 (en) | 1994-12-05 | 2003-04-22 | Continental Sprayers International, Inc. | Dual component trigger sprayer which mixes components in discharge passage |
| US5730006A (en) | 1994-12-12 | 1998-03-24 | Conley; Christopher T. | Garment de-wrinkler |
| US5626259A (en) | 1995-11-16 | 1997-05-06 | Afa Products, Inc. | Two liquid sprayer assembly |
| US5789368A (en) | 1996-01-26 | 1998-08-04 | The Procter & Gamble Company | Fabric care bag |
| JP3651714B2 (ja) | 1996-04-19 | 2005-05-25 | 株式会社丸一 | トリガー型エアゾルキャップ |
| JP3132391B2 (ja) | 1996-07-15 | 2001-02-05 | 三菱自動車工業株式会社 | ４輪駆動車のトランスファ装置 |
| US6491840B1 (en) | 2000-02-14 | 2002-12-10 | The Procter & Gamble Company | Polymer compositions having specified PH for improved dispensing and improved stability of wrinkle reducing compositions and methods of use |
| US5955093A (en) | 1997-06-09 | 1999-09-21 | The Procter & Gamble Company | Uncomplexed cyclodextrin compositions for odor control |
| ES2242999T3 (es) | 1997-06-09 | 2005-11-16 | THE PROCTER & GAMBLE COMPANY | Composiciones de ciclodextrina no acomplejada para controlar olores. |
| ATE302835T1 (de) | 1997-06-09 | 2005-09-15 | Procter & Gamble | Zusammensetzung mit unkomplexiertem cyclodextrin zur geruchs- und knitterkontrolle |
| US5997759A (en) | 1997-06-09 | 1999-12-07 | The Procter & Gamble Company | Uncomplexed cyclodextrin compositions for odor control |
| US6001343A (en) | 1997-06-09 | 1999-12-14 | The Procter & Gamble Company | Uncomplexed cyclodextrin compositions for odor and wrinkle control |
| AU4356997A (en) | 1997-06-09 | 1998-12-30 | Procter & Gamble Company, The | Malodor reducing composition containing amber and musk materials |
| US6987099B2 (en) | 1997-06-09 | 2006-01-17 | The Procter & Gamble Company | Uncomplexed cyclodextrin compositions for odor control |
| AU3866699A (en) | 1998-04-27 | 1999-11-16 | Procter & Gamble Company, The | Fabric wrinkle control composition and method |
| WO1999055814A1 (en) | 1998-04-27 | 1999-11-04 | The Procter & Gamble Company | Improved uncomplexed cyclodextrin compositions for odor and wrinkle control |
| TR200003129T2 (tr) | 1998-04-27 | 2001-03-21 | The Procter & Gamble Company | Koku kontrolü için geliştirilmiş, kompleks oluşturmamış siklodekstrin bileşimleri. |
| AR017716A1 (es) | 1998-04-27 | 2001-09-12 | Procter & Gamble | Articulo de manufactura en la forma de un expendedor atomizador operado no-manualmente |
| GB9814366D0 (en) | 1998-07-02 | 1998-09-02 | Reckitt & Colmann Prod Ltd | Malodour treatment |
| JP2000063204A (ja) | 1998-08-19 | 2000-02-29 | Nitomuzu:Kk | 衣類用薬剤包装体 |
| WO2000024856A1 (en) | 1998-10-23 | 2000-05-04 | The Procter & Gamble Company | Fabric care composition and method |
| US7341674B1 (en) | 1998-12-09 | 2008-03-11 | The Procter & Gamble Company | Fabric wrinkle control composition and method |
| GB2346900A (en) | 1999-02-18 | 2000-08-23 | Reckitt & Colman Inc | Deodorizing compositions for fibrous substrates |
| GB2352179A (en) | 1999-07-21 | 2001-01-24 | Unilever Plc | Deodorising perfume compositions |
| GB9917623D0 (en) | 1999-07-27 | 1999-09-29 | Unilever Plc | Process for treating fabrics |
| US6194470B1 (en) | 1999-08-06 | 2001-02-27 | Bath & Body Works, Inc. | Sparkle linen spray |
| US7012053B1 (en) | 1999-10-22 | 2006-03-14 | The Procter & Gamble Company | Fabric care composition and method comprising a fabric care polysaccharide and wrinkle control agent |
| US6495058B1 (en) | 2000-02-14 | 2002-12-17 | The Procter & Gamble Company | Aqueous wrinkle control compositions dispensed using optimal spray patterns |
| CA2417740A1 (en) | 2000-08-18 | 2002-02-28 | The Procter & Gamble Company | Compositions and methods for odor and fungal control of protective garments |
| JP2004506820A (ja) | 2000-08-18 | 2004-03-04 | ザ、プロクター、エンド、ギャンブル、カンパニー | 衣服を回復し、脱臭し、及び仕上げるための方法及び製造物品 |
| GB0023713D0 (en) | 2000-09-27 | 2000-11-08 | Unilever Plc | A water soluble package |
| EP1203809A1 (en) | 2000-11-06 | 2002-05-08 | The Procter & Gamble Company | Polymer containing granules and compositions thereof |
| AU2002241483A1 (en) | 2000-11-20 | 2002-06-11 | The Procter And Gamble Company | Predictive method for polymers |
| US6446882B1 (en) | 2001-02-02 | 2002-09-10 | Owens-Illinois Closure Inc. | Trigger sprayer having sprayer/foamer selector nozzle cap |
| US6524494B2 (en) | 2001-02-02 | 2003-02-25 | Givaudan Sa | Compositions to enhance fabric freshness and appearance |
| RU2184619C1 (ru) | 2001-03-22 | 2002-07-10 | Душкин Андрей Леонидович | Распылитель жидкости (варианты) |
| US20030071075A1 (en) | 2001-04-23 | 2003-04-17 | Frankenbach Gayle Marie | Aqueous fabric care compositions for effective use away from the home and accessories for use therewith |
| US20030068375A1 (en) | 2001-08-06 | 2003-04-10 | Curtis Wright | Pharmaceutical formulation containing gelling agent |
| US6746617B2 (en) | 2001-09-10 | 2004-06-08 | Procter & Gamble Company | Fabric treatment composition and method |
| US6557783B1 (en) | 2001-11-23 | 2003-05-06 | Continental Sprayers International, Inc. | Telescoping foamer nozzle |
| ES2231428T3 (es) | 2001-11-23 | 2005-05-16 | THE PROCTER & GAMBLE COMPANY | Bolsa hidrosoluble. |
| DE60117752T2 (de) | 2001-11-23 | 2006-11-09 | The Procter & Gamble Company, Cincinnati | Wasserlöslicher Beutel |
| GB0200607D0 (en) | 2002-01-11 | 2002-02-27 | Unilever Plc | Improvements relating to garment care |
| US20030215417A1 (en) | 2002-04-18 | 2003-11-20 | The Procter & Gamble Company | Malodor-controlling compositions comprising odor control agents and microcapsules containing an active material |
| US20030216488A1 (en) | 2002-04-18 | 2003-11-20 | The Procter & Gamble Company | Compositions comprising a dispersant and microcapsules containing an active material |
| US7017833B2 (en) | 2003-02-04 | 2006-03-28 | Continental Afa Dispensing Company | Trigger sprayer spray, off, stream, off indexing nozzle assembly |
| US7655613B2 (en) | 2004-10-20 | 2010-02-02 | Firmenich Sa | Solubilizing systems for flavors and fragrances |
| US7226607B2 (en) | 2003-09-11 | 2007-06-05 | The Procter & Gamble Company | Compositions comprising a dispersant and microcapsules containing an active material and a stabilizer |
| US20050113282A1 (en) | 2003-11-20 | 2005-05-26 | Parekh Prabodh P. | Melamine-formaldehyde microcapsule slurries for fabric article freshening |
| US20060003913A1 (en) | 2004-06-30 | 2006-01-05 | The Procter & Gamble Company | Perfumed liquid laundry detergent compositions with functionalized silicone fabric care agents |
| CN1631549A (zh) | 2005-01-13 | 2005-06-29 | 浙江大学 | 雾化喷头 |
| GB0504708D0 (en) | 2005-03-08 | 2005-04-13 | Incro Ltd | Flow control apparatus |
| GB0505618D0 (en) | 2005-03-18 | 2005-04-27 | Unilever Plc | Fabric care compositions |
| FR2903328B1 (fr) | 2006-07-10 | 2008-12-05 | Rexam Dispensing Systems Sas | Buse de pulverisation, dispositif de pulverisation et utilisation de ce dispositif. |
| EP1903099A1 (en) | 2006-09-22 | 2008-03-26 | Dalli-Werke GmbH & Co. KG | Coated detergent compositions and manufacture process |
| CN101568634A (zh) | 2006-12-11 | 2009-10-28 | 宝洁公司 | 印花膜上图像的改善的视觉感受性 |
| US20090178212A1 (en) | 2008-01-11 | 2009-07-16 | Errol Hoffman Wahl | Fabric color restoration composition, article, and method |
| US20090178211A1 (en) | 2008-01-11 | 2009-07-16 | Errol Hoffman Wahl | Fabric color restoration composition, article, and method |
| PL2196531T3 (pl) | 2008-12-05 | 2015-02-27 | Dalli Werke Gmbh & Co Kg | Pokryta polimerem tabletka detergentu |
| EP2216394A1 (en) | 2009-01-30 | 2010-08-11 | The Procter & Gamble Company | Method for perfuming fabrics |
| US20120181305A1 (en) | 2009-07-17 | 2012-07-19 | Ellery West | Fibrous Container With Pump |
| US20110305659A1 (en) | 2009-09-18 | 2011-12-15 | Ricky Ah-Man Woo | Freshening compositions comprising malodor binding polymers and malodor control components |
| US20120183605A1 (en) | 2009-12-18 | 2012-07-19 | Kristin Arnold | Quinine formulations, method of making, and method of use thereof |
| FR2955040B1 (fr) | 2010-01-12 | 2017-02-10 | Arnaud Becker | Pre-broyeur ou pre-dechiqueteur |
| RU2546651C2 (ru) | 2010-01-29 | 2015-04-10 | МОНОСОЛ, ЭлЭлСи | Водорастворимая пленка с улучшенной растворимостью и улучшенными механическими свойствами, а также пакеты, изготовленные из нее |
| EP2385099A1 (en) * | 2010-05-06 | 2011-11-09 | The Procter & Gamble Company | Process of making liquid fabric softening compositions |
| US8322631B2 (en) | 2010-05-10 | 2012-12-04 | The Procter & Gamble Company | Trigger pump sprayer having favorable particle size distribution with specified liquids |
| US20130139327A1 (en) | 2010-08-03 | 2013-06-06 | Henkel Ag & Co. Kgaa | Textile treatment composition for removal of deodorant stains |
| FR2971768B1 (fr) | 2011-02-18 | 2013-03-22 | Valois Sas | Tete de distribution de produit fluide. |
| US9394092B2 (en) | 2012-04-16 | 2016-07-19 | Monosol, Llc | Powdered pouch and method of making same |
| DE102012212849A1 (de) | 2012-07-23 | 2014-05-22 | Henkel Ag & Co. Kgaa | Gefärbte, wasserlösliche Verpackung |
| DE102012214608A1 (de) | 2012-08-16 | 2014-02-20 | Henkel Ag & Co. Kgaa | Wasserlösliche Verpackung mit Bittermittel II |
| DE102012214607A1 (de) | 2012-08-16 | 2014-02-20 | Henkel Ag & Co. Kgaa | Wasserlösliche Verpackung mit Bittermittel I |
| EP2906194B1 (en) | 2012-10-11 | 2018-06-06 | Dow Corning Corporation | Aqueous silicone polyether microemulsions |
| WO2014156855A1 (ja) | 2013-03-25 | 2014-10-02 | 株式会社マンダム | エアゾール製品及びエアゾール製品の使用 |
| DE202014001084U1 (de) | 2014-02-10 | 2015-05-12 | Aptar Dortmund Gmbh | Abgabevorrichtung |
| US20150252305A1 (en) | 2014-03-07 | 2015-09-10 | The Procter & Gamble Company | Compositions comprising a bittering agent |
| CN106062164A (zh) | 2014-03-07 | 2016-10-26 | 宝洁公司 | 包含刺激剂的组合物 |
| US20150292141A1 (en) | 2014-04-11 | 2015-10-15 | Jerome P. Behr | Method and system for garment de-wrinkling |
| EP2933101A1 (en) | 2014-04-14 | 2015-10-21 | The Procter and Gamble Company | An apparatus to print on water-soluble film |
| US9714396B2 (en) | 2014-10-16 | 2017-07-25 | Encapsys Llc | Controlled release dual walled microcapsules |
| US9506019B2 (en) | 2015-01-28 | 2016-11-29 | The Procter & Gamble Company | Silicone nanoemulsion comprising alkylene glycol alkyl ether |
| WO2017025426A1 (en) | 2015-08-11 | 2017-02-16 | Unilever Plc | Water-soluble package |
| EP3138896A1 (en) | 2015-09-04 | 2017-03-08 | The Procter and Gamble Company | Water soluble unit dose article comprising an aversive agent |
| EP3138901A1 (en) | 2015-09-04 | 2017-03-08 | The Procter & Gamble Company | Water soluble unit dose detergent article comprising an aversive or bittering agent |
| US20200181833A1 (en) | 2016-08-05 | 2020-06-11 | Conopco, Inc. D/B/A Unilever | Improvements in and relating to garment refreshment |
| EP3493916A1 (en) | 2016-08-05 | 2019-06-12 | Unilever PLC | Improvements in and relating to garment refreshment |
| WO2019072646A1 (en) | 2017-10-13 | 2019-04-18 | Unilever Plc | IMPROVEMENTS IN AND RELATING TO REFRESHMENT OF CLOTHES |
| BR112020007281A2 (pt) | 2017-10-13 | 2020-11-03 | Unilever N.V. | composição spray aquosa para tecido, método de rejuvenescimento de tecido e uso da composição |
-
2018
- 2018-10-02 WO PCT/EP2018/076838 patent/WO2019072645A1/en active Search and Examination
- 2018-10-02 EP EP18782060.0A patent/EP3694964A1/en active Pending
- 2018-10-02 BR BR112020007275-3A patent/BR112020007275A2/pt active IP Right Grant
- 2018-10-02 CN CN201880066497.3A patent/CN111212894A/zh active Pending
- 2018-10-02 US US16/754,864 patent/US11807834B2/en active Active
- 2018-10-12 AR ARP180102972A patent/AR113326A1/es active IP Right Grant
Patent Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999055953A1 (en) * | 1998-04-27 | 1999-11-04 | The Procter & Gamble Company | Fabric wrinkle control composition and method |
| CN1278033A (zh) * | 1999-05-24 | 2000-12-27 | 陶氏康宁东丽硅氧烷株式会社 | 水基纤维处理剂和用来处理纤维的方法 |
| WO2001016266A2 (en) * | 1999-09-02 | 2001-03-08 | The Procter & Gamble Company | Method of deodorizing and/or cleaning carpet using a composition comprising odor control agent |
| CN1384895A (zh) * | 1999-10-27 | 2002-12-11 | 宝洁公司 | 防皱组合物 |
| CN102260604A (zh) * | 2002-08-16 | 2011-11-30 | 莫门蒂夫性能材料股份有限公司 | 含有硅氧烷添加剂的液体洗衣组合物 |
| CN101802293A (zh) * | 2007-09-14 | 2010-08-11 | 宝洁公司 | 用于处理织物的组合物 |
| CN103748204A (zh) * | 2011-08-26 | 2014-04-23 | 高露洁-棕榄公司 | 织物皱折降低组合物 |
| WO2014003180A1 (ja) * | 2012-06-29 | 2014-01-03 | ライオン株式会社 | 液体柔軟剤組成物 |
| CN106574214A (zh) * | 2014-07-28 | 2017-04-19 | 宝洁公司 | 包含氨基硅氧烷聚合物纳米乳液的织物处理组合物 |
| CN106661514A (zh) * | 2014-07-28 | 2017-05-10 | 宝洁公司 | 包含氨基硅氧烷聚合物纳米乳液的织物处理组合物 |
| BR102015027601A2 (pt) * | 2015-10-30 | 2017-05-02 | De Aguiar Pereira Tiago | aperfeiçoamentos introduzidos em formulação de solução química para impregnação de artigo de limpeza e produto resultante |
Also Published As
| Publication number | Publication date |
|---|---|
| US20210198597A1 (en) | 2021-07-01 |
| EP3694964A1 (en) | 2020-08-19 |
| WO2019072645A1 (en) | 2019-04-18 |
| BR112020007275A2 (pt) | 2020-10-27 |
| AR113326A1 (es) | 2020-04-08 |
| US11807834B2 (en) | 2023-11-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP4641307B2 (ja) | 分散剤と、活性物質及び安定剤を含有するマイクロカプセルとを含む組成物 | |
| CN111971375A (zh) | 织物喷雾组合物 | |
| JP2005523078A (ja) | 臭気抑制剤と活性物質を含有するマイクロカプセルとを含む悪臭抑制組成物 | |
| CN111201308A (zh) | 水性喷雾组合物 | |
| JP2008517051A (ja) | フレーバーおよびフレグランスの可溶化系 | |
| CN111212895A (zh) | 水性喷雾组合物 | |
| CN111212894A (zh) | 水性喷雾组合物 | |
| US20210198843A1 (en) | Improvements in and relating to garment revival | |
| CN111225971A (zh) | 衣物复新中的改善和与衣物复新相关的改善 | |
| CN116685735A (zh) | 洗衣喷雾组合物 | |
| EP4211213B1 (en) | Laundry spray composition | |
| CN115836149A (zh) | 织物喷剂 | |
| CN114174584A (zh) | 织物喷涂组合物 | |
| CN114901901A (zh) | 织物喷剂 | |
| WO2019072644A1 (en) | AQUEOUS SPRAY COMPOSITION | |
| CN116568786A (zh) | 协同加香组合物 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20210804 Address after: Rotterdam Applicant after: Unilever Intellectual Property Holdings Ltd. Address before: Rotterdam Applicant before: Netherlands Unilever Co.,Ltd. |
|
| TA01 | Transfer of patent application right |