CN1100602C - 使用亚氨基噁二嗪二酮多异氰酸酯的微胶囊 - Google Patents
使用亚氨基噁二嗪二酮多异氰酸酯的微胶囊 Download PDFInfo
- Publication number
- CN1100602C CN1100602C CN97122266A CN97122266A CN1100602C CN 1100602 C CN1100602 C CN 1100602C CN 97122266 A CN97122266 A CN 97122266A CN 97122266 A CN97122266 A CN 97122266A CN 1100602 C CN1100602 C CN 1100602C
- Authority
- CN
- China
- Prior art keywords
- isocyanates
- formula
- microcapsules
- crosslinking agent
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000003094 microcapsule Substances 0.000 title claims abstract description 62
- 239000005056 polyisocyanate Substances 0.000 title description 25
- 229920001228 polyisocyanate Polymers 0.000 title description 25
- PJMDLNIAGSYXLA-UHFFFAOYSA-N 6-iminooxadiazine-4,5-dione Chemical compound N=C1ON=NC(=O)C1=O PJMDLNIAGSYXLA-UHFFFAOYSA-N 0.000 title 1
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 33
- -1 iminooxadiazinedione isocyanates Chemical class 0.000 claims abstract description 24
- 238000004519 manufacturing process Methods 0.000 claims abstract description 24
- 238000000034 method Methods 0.000 claims abstract description 17
- 239000012948 isocyanate Substances 0.000 claims description 69
- 150000002513 isocyanates Chemical class 0.000 claims description 66
- 239000002775 capsule Substances 0.000 claims description 42
- 239000000203 mixture Substances 0.000 claims description 31
- 239000003921 oil Substances 0.000 claims description 26
- 239000000839 emulsion Substances 0.000 claims description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 22
- 239000000126 substance Substances 0.000 claims description 13
- QMEQBOSUJUOXMX-UHFFFAOYSA-N 2h-oxadiazine Chemical compound N1OC=CC=N1 QMEQBOSUJUOXMX-UHFFFAOYSA-N 0.000 claims description 12
- 239000003995 emulsifying agent Substances 0.000 claims description 12
- STIAPHVBRDNOAJ-UHFFFAOYSA-N carbamimidoylazanium;carbonate Chemical group NC(N)=N.NC(N)=N.OC(O)=O STIAPHVBRDNOAJ-UHFFFAOYSA-N 0.000 claims description 10
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Natural products OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 claims description 10
- QSJXEFYPDANLFS-UHFFFAOYSA-N Diacetyl Chemical group CC(=O)C(C)=O QSJXEFYPDANLFS-UHFFFAOYSA-N 0.000 claims description 9
- OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical compound NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 claims description 9
- 125000005594 diketone group Chemical group 0.000 claims description 8
- AVWRKZWQTYIKIY-UHFFFAOYSA-N urea-1-carboxylic acid Chemical compound NC(=O)NC(O)=O AVWRKZWQTYIKIY-UHFFFAOYSA-N 0.000 claims description 8
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 7
- 239000004202 carbamide Substances 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 7
- 210000002700 urine Anatomy 0.000 claims description 7
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 5
- 239000003960 organic solvent Substances 0.000 claims description 5
- 239000000654 additive Substances 0.000 claims description 4
- 230000000996 additive effect Effects 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 239000003381 stabilizer Substances 0.000 claims description 3
- 235000010290 biphenyl Nutrition 0.000 claims description 2
- 238000004945 emulsification Methods 0.000 claims description 2
- 230000002401 inhibitory effect Effects 0.000 claims description 2
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims description 2
- 238000002844 melting Methods 0.000 claims description 2
- 230000008018 melting Effects 0.000 claims description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N o-dicarboxybenzene Natural products OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims description 2
- 239000012188 paraffin wax Substances 0.000 claims description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical class C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims 2
- 239000004305 biphenyl Substances 0.000 claims 1
- 230000008569 process Effects 0.000 abstract description 4
- 239000007795 chemical reaction product Substances 0.000 abstract 2
- 239000000243 solution Substances 0.000 description 33
- 235000019198 oils Nutrition 0.000 description 24
- 150000001875 compounds Chemical class 0.000 description 17
- 239000012071 phase Substances 0.000 description 17
- 239000006185 dispersion Substances 0.000 description 16
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 14
- 238000006243 chemical reaction Methods 0.000 description 12
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 12
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 10
- 239000003054 catalyst Substances 0.000 description 10
- 229920002451 polyvinyl alcohol Polymers 0.000 description 10
- 238000003756 stirring Methods 0.000 description 10
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 9
- 229910000040 hydrogen fluoride Inorganic materials 0.000 description 9
- 239000004372 Polyvinyl alcohol Substances 0.000 description 7
- 238000012644 addition polymerization Methods 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 7
- 229940068984 polyvinyl alcohol Drugs 0.000 description 7
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 7
- 125000001931 aliphatic group Chemical group 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 239000002253 acid Substances 0.000 description 5
- 239000008367 deionised water Substances 0.000 description 5
- 229910021641 deionized water Inorganic materials 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 description 4
- OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 4
- 238000005054 agglomeration Methods 0.000 description 4
- 230000002776 aggregation Effects 0.000 description 4
- 238000004364 calculation method Methods 0.000 description 4
- 239000012141 concentrate Substances 0.000 description 4
- 150000004985 diamines Chemical class 0.000 description 4
- 229920000768 polyamine Polymers 0.000 description 4
- IAUKWGFWINVWKS-UHFFFAOYSA-N 1,2-di(propan-2-yl)naphthalene Chemical compound C1=CC=CC2=C(C(C)C)C(C(C)C)=CC=C21 IAUKWGFWINVWKS-UHFFFAOYSA-N 0.000 description 3
- 239000004606 Fillers/Extenders Substances 0.000 description 3
- 239000005058 Isophorone diisocyanate Substances 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 150000001414 amino alcohols Chemical class 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 230000001804 emulsifying effect Effects 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 230000002209 hydrophobic effect Effects 0.000 description 3
- 125000002462 isocyano group Chemical group *[N+]#[C-] 0.000 description 3
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 3
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 239000007764 o/w emulsion Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 238000005829 trimerization reaction Methods 0.000 description 3
- LIZLYZVAYZQVPG-UHFFFAOYSA-N (3-bromo-2-fluorophenyl)methanol Chemical compound OCC1=CC=CC(Br)=C1F LIZLYZVAYZQVPG-UHFFFAOYSA-N 0.000 description 2
- BANXPJUEBPWEOT-UHFFFAOYSA-N 2-methyl-Pentadecane Chemical compound CCCCCCCCCCCCCC(C)C BANXPJUEBPWEOT-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 2
- ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical compound NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 description 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 125000003277 amino group Chemical group 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 235000019864 coconut oil Nutrition 0.000 description 2
- 239000003240 coconut oil Substances 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 2
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- IIEWJVIFRVWJOD-UHFFFAOYSA-N ethylcyclohexane Chemical compound CCC1CCCCC1 IIEWJVIFRVWJOD-UHFFFAOYSA-N 0.000 description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- KRTSDMXIXPKRQR-AATRIKPKSA-N monocrotophos Chemical compound CNC(=O)\C=C(/C)OP(=O)(OC)OC KRTSDMXIXPKRQR-AATRIKPKSA-N 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- BKIMMITUMNQMOS-UHFFFAOYSA-N nonane Chemical compound CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 description 2
- 230000035479 physiological effects, processes and functions Effects 0.000 description 2
- DEDZSLCZHWTGOR-UHFFFAOYSA-N propylcyclohexane Chemical compound CCCC1CCCCC1 DEDZSLCZHWTGOR-UHFFFAOYSA-N 0.000 description 2
- 238000010008 shearing Methods 0.000 description 2
- DVQHRBFGRZHMSR-UHFFFAOYSA-N sodium methyl 2,2-dimethyl-4,6-dioxo-5-(N-prop-2-enoxy-C-propylcarbonimidoyl)cyclohexane-1-carboxylate Chemical compound [Na+].C=CCON=C(CCC)[C-]1C(=O)CC(C)(C)C(C(=O)OC)C1=O DVQHRBFGRZHMSR-UHFFFAOYSA-N 0.000 description 2
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 2
- 238000004448 titration Methods 0.000 description 2
- RSJKGSCJYJTIGS-UHFFFAOYSA-N undecane Chemical compound CCCCCCCCCCC RSJKGSCJYJTIGS-UHFFFAOYSA-N 0.000 description 2
- HUZSVEPTSDMQDN-UHFFFAOYSA-N 1,1-diethyl-2-methylcyclohexane Chemical compound CCC1(CC)CCCCC1C HUZSVEPTSDMQDN-UHFFFAOYSA-N 0.000 description 1
- PKHWFZURRIHTGW-UHFFFAOYSA-N 1,2-dimethyl-3-phenylbenzene ethane Chemical compound CC.C1(=CC=CC=C1)C=1C(=C(C=CC1)C)C PKHWFZURRIHTGW-UHFFFAOYSA-N 0.000 description 1
- WFOQXUOOXMEVQB-UHFFFAOYSA-N 1-butan-2-yl-2-phenylbenzene Chemical group CCC(C)C1=CC=CC=C1C1=CC=CC=C1 WFOQXUOOXMEVQB-UHFFFAOYSA-N 0.000 description 1
- 229940043268 2,2,4,4,6,8,8-heptamethylnonane Drugs 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- ONIKNECPXCLUHT-UHFFFAOYSA-N 2-chlorobenzoyl chloride Chemical compound ClC(=O)C1=CC=CC=C1Cl ONIKNECPXCLUHT-UHFFFAOYSA-N 0.000 description 1
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- UMXQYXDUVDWFAM-UHFFFAOYSA-N CC1(CCCCC1)N=C=O.N=C=O Chemical class CC1(CCCCC1)N=C=O.N=C=O UMXQYXDUVDWFAM-UHFFFAOYSA-N 0.000 description 1
- CKDWPUIZGOQOOM-UHFFFAOYSA-N Carbamyl chloride Chemical compound NC(Cl)=O CKDWPUIZGOQOOM-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- 208000035126 Facies Diseases 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 description 1
- 238000012695 Interfacial polymerization Methods 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- HDONYZHVZVCMLR-UHFFFAOYSA-N N=C=O.N=C=O.CC1CCCCC1 Chemical compound N=C=O.N=C=O.CC1CCCCC1 HDONYZHVZVCMLR-UHFFFAOYSA-N 0.000 description 1
- KYIMHWNKQXQBDG-UHFFFAOYSA-N N=C=O.N=C=O.CCCCCC Chemical compound N=C=O.N=C=O.CCCCCC KYIMHWNKQXQBDG-UHFFFAOYSA-N 0.000 description 1
- 229920002396 Polyurea Polymers 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 239000010692 aromatic oil Substances 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229940049706 benzodiazepine Drugs 0.000 description 1
- YOUGRGFIHBUKRS-UHFFFAOYSA-N benzyl(trimethyl)azanium Chemical compound C[N+](C)(C)CC1=CC=CC=C1 YOUGRGFIHBUKRS-UHFFFAOYSA-N 0.000 description 1
- 150000004074 biphenyls Chemical class 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- PVXRCPDNJSFYBV-UHFFFAOYSA-N carbamoyl fluoride Chemical compound NC(F)=O PVXRCPDNJSFYBV-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 150000001924 cycloalkanes Chemical class 0.000 description 1
- DIOQZVSQGTUSAI-NJFSPNSNSA-N decane Chemical compound CCCCCCCCC[14CH3] DIOQZVSQGTUSAI-NJFSPNSNSA-N 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 229940043237 diethanolamine Drugs 0.000 description 1
- 125000005442 diisocyanate group Chemical group 0.000 description 1
- 238000006471 dimerization reaction Methods 0.000 description 1
- CZZYITDELCSZES-UHFFFAOYSA-N diphenylmethane Chemical class C=1C=CC=CC=1CC1=CC=CC=C1 CZZYITDELCSZES-UHFFFAOYSA-N 0.000 description 1
- KWKXNDCHNDYVRT-UHFFFAOYSA-N dodecylbenzene Chemical compound CCCCCCCCCCCCC1=CC=CC=C1 KWKXNDCHNDYVRT-UHFFFAOYSA-N 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 239000004009 herbicide Substances 0.000 description 1
- 239000002638 heterogeneous catalyst Substances 0.000 description 1
- 239000002815 homogeneous catalyst Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 125000001841 imino group Chemical group [H]N=* 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000002779 inactivation Effects 0.000 description 1
- 239000000077 insect repellent Substances 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- KUVMKLCGXIYSNH-UHFFFAOYSA-N isopentadecane Natural products CCCCCCCCCCCCC(C)C KUVMKLCGXIYSNH-UHFFFAOYSA-N 0.000 description 1
- 125000000468 ketone group Chemical group 0.000 description 1
- QDLAGTHXVHQKRE-UHFFFAOYSA-N lichenxanthone Natural products COC1=CC(O)=C2C(=O)C3=C(C)C=C(OC)C=C3OC2=C1 QDLAGTHXVHQKRE-UHFFFAOYSA-N 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical class C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 239000012184 mineral wax Substances 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- DIOQZVSQGTUSAI-UHFFFAOYSA-N n-butylhexane Natural products CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 1
- HKKDKUMUWRTAIA-UHFFFAOYSA-N nitridooxidocarbon(.) Chemical compound [O]C#N HKKDKUMUWRTAIA-UHFFFAOYSA-N 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 239000004476 plant protection product Substances 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical group [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 238000007348 radical reaction Methods 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 238000005057 refrigeration Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000010517 secondary reaction Methods 0.000 description 1
- 238000002444 silanisation Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 230000001131 transforming effect Effects 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
- B01J13/06—Making microcapsules or microballoons by phase separation
- B01J13/14—Polymerisation; cross-linking
- B01J13/16—Interfacial polymerisation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/914—Transfer or decalcomania
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2984—Microcapsule with fluid core [includes liposome]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2984—Microcapsule with fluid core [includes liposome]
- Y10T428/2985—Solid-walled microcapsule from synthetic polymer
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Manufacturing Of Micro-Capsules (AREA)
- Polyurethanes Or Polyureas (AREA)
- Color Printing (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
Abstract
Description
交联剂 | ||||||||||
实施例序号 | 异氰酸酯(混合物)1) | 异氰酸酯的NCO含量%(重量)2) | 壁含量%(重量)3) | 类型 | 量%(重量)4) | 成色物质溶液序号 | 乳化能(rpm) | 平均胶囊大小(μm) | 防漏性 | 胶囊分散体的浓度%(重量) |
3 | A | 23.6 | 7 | GUCA | 100 | 1 | 7500 | 7.5 | 防漏 | 52.0 |
4 | A | 23.6 | 5 | GUCA | 100 | 1 | 6800 | 7.3 | 防漏 | 51.2 |
5 | A | 23.6 | 10 | GUCA | 100 | 1 | 7800 | 7.6 | 防漏 | 52.2 |
6 | A | 23.6 | 7 | GUCA | 100 | 2 | 6300 | 6.4 | 防漏 | 49.9 |
7 | A | 23.6 | 7 | GUCA+DETA | 50 | 3 | 7600 | 6.8 | 防漏 | 51.0 |
8 | A | 23.6 | 7 | GUCA+DETA | 100 | 3 | 7600 | 6.9 | 防漏 | 50.5 |
9 | A+UD,1∶1 | 22.7 | 10 | GUCA | 100 | 1 | 7800 | 7.2 | 防漏 | 50.9 |
10 | A+BU,1∶4 | 23.1 | 10 | GUCA | 100 | 1 | 8500 | 7.7 | 防漏 | 51.6 |
11 | A+IC,1∶9 | 22.0 | 10 | GUCA | 50 | 1 | 9000 | 7.6 | 浅蓝 | 50.2 |
12 | ON(比较) | 20.3 | 10 | GUCA | 100 | 1 | 10500 | 6) | 蓝色 | 6) |
Claims (8)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19646110.3 | 1996-11-08 | ||
DE19646110A DE19646110A1 (de) | 1996-11-08 | 1996-11-08 | Mikrokapseln unter Verwendung von Iminooxadiazindion-Polyisocyanaten |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1189393A CN1189393A (zh) | 1998-08-05 |
CN1100602C true CN1100602C (zh) | 2003-02-05 |
Family
ID=7811048
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN97122266A Expired - Fee Related CN1100602C (zh) | 1996-11-08 | 1997-11-07 | 使用亚氨基噁二嗪二酮多异氰酸酯的微胶囊 |
Country Status (13)
Country | Link |
---|---|
US (1) | US6020066A (zh) |
EP (1) | EP0841088B1 (zh) |
JP (1) | JPH10137578A (zh) |
CN (1) | CN1100602C (zh) |
AR (1) | AR010555A1 (zh) |
BR (1) | BR9705447A (zh) |
DE (2) | DE19646110A1 (zh) |
ES (1) | ES2157509T3 (zh) |
ID (1) | ID18090A (zh) |
IN (1) | IN186809B (zh) |
PT (1) | PT841088E (zh) |
TW (1) | TW341526B (zh) |
ZA (1) | ZA9710042B (zh) |
Families Citing this family (48)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE59902995D1 (de) * | 1998-06-02 | 2002-11-14 | Bayer Ag | Verfahren zur Herstellung Iminooxadiazindiongruppen enhaltender Polyisocyanate |
DE19840583A1 (de) | 1998-09-05 | 2000-03-09 | Bayer Ag | Mikrokapsel-Formulierungen |
DE19840582A1 (de) * | 1998-09-05 | 2000-03-09 | Bayer Ag | Mikrokapsel-Formulierungen |
US6653256B1 (en) | 1999-08-24 | 2003-11-25 | Bayer Aktiengesellschaft | Microcapsule formulations |
MXPA02011951A (es) | 2000-06-05 | 2003-07-14 | Syngenta Ltd | Microcapsulas novedosas. |
DE10051194A1 (de) * | 2000-10-16 | 2002-04-25 | Bayer Ag | Mikrokapseln mit Wänden aus Polyharnstoff |
DE10051190A1 (de) * | 2000-10-16 | 2002-04-25 | Bayer Ag | Mikrokapseln mit Wänden aus Polyharnstoff |
DE10117671A1 (de) * | 2001-04-09 | 2002-10-10 | Bayer Ag | Mit duftstoffhaltigen Mikrokapseln ausgerüstetes Leder |
US8828902B2 (en) * | 2001-07-12 | 2014-09-09 | Reaxa Limited | Microencapsulated catalyst methods of preparation and method of use thereof |
DE10241000A1 (de) * | 2001-09-10 | 2003-03-27 | Bayer Ag | Mikrokapsel-haltige Vliese |
GB0128839D0 (en) * | 2001-12-01 | 2002-01-23 | Univ Cambridge Tech | Encapsulated transition metal reagents for reactions in supercritical carbon dioxide |
AU2003297683A1 (en) * | 2002-12-13 | 2004-07-09 | Monsanto Technology Llc | Microcapsules with amine adjusted release rates |
CA2562107C (en) | 2004-04-09 | 2012-10-16 | Unilever Plc | Granulate for use in a cleaning product and process for its manufacture |
BRPI0512102A (pt) * | 2004-06-14 | 2008-02-06 | Monsanto Technology Llc | microcápsulas tendo liberação ativada de material de núcleo dentro delas |
ATE432975T1 (de) * | 2004-12-23 | 2009-06-15 | Unilever Nv | Flüssigwaschmittel und ihre verwendung |
GB0524659D0 (en) * | 2005-12-02 | 2006-01-11 | Unilever Plc | Improvements relating to fabric treatment compositions |
JP4739995B2 (ja) * | 2006-03-10 | 2011-08-03 | Jx日鉱日石エネルギー株式会社 | 感圧記録材料用マイクロカプセルとその製造方法及びそれを用いた感圧記録材料 |
DE102008002145A1 (de) | 2008-06-02 | 2009-12-03 | Symrise Gmbh & Co. Kg | Kapsel mit organisch-anorganischer Hybridwand |
ATE554158T1 (de) | 2008-09-30 | 2012-05-15 | Procter & Gamble | Zusammensetzung mit mikrokapseln |
MX2011004847A (es) | 2008-11-07 | 2011-05-30 | Procter & Gamble | Agente benefico que contiene particulas de suministro. |
CN102395277B (zh) * | 2009-02-13 | 2018-08-03 | 孟山都技术公司 | 减少作物损伤的胶囊化除草剂 |
GB0902634D0 (en) | 2009-02-18 | 2009-04-01 | Reaxa Ltd | Microencapsulated catalyst |
PL2336285T3 (pl) * | 2009-12-18 | 2014-01-31 | Procter & Gamble | Kompozycja zawierająca mikrokapsułki |
EP2336286A1 (en) | 2009-12-18 | 2011-06-22 | The Procter & Gamble Company | Composition comprising microcapsules |
ES2457495T3 (es) | 2010-03-31 | 2014-04-28 | Unilever N.V. | Incorporación de microcápsulas a detergentes líquidos estructurados |
EP2553072B1 (en) | 2010-04-01 | 2015-05-06 | Unilever PLC | Structuring detergent liquids with hydrogenated castor oil |
AU2011291580B2 (en) | 2010-08-18 | 2015-08-20 | Monsanto Technology Llc | Early applications of encapsulated acetamides for reduced injury in crops |
FR2965190B1 (fr) * | 2010-09-24 | 2013-12-27 | Univ Tours Francois Rabelais | Procede de fabrication de microcapsules polysiloxane fonctionnalisees et peu poreuses. |
CN102146219B (zh) * | 2011-01-19 | 2013-04-24 | 山西大学 | 活性染料微胶囊的制备方法 |
US8936030B2 (en) | 2011-03-25 | 2015-01-20 | Katherine Rose Kovarik | Nail polish remover method and device |
EP2495300A1 (en) | 2011-03-04 | 2012-09-05 | Unilever Plc, A Company Registered In England And Wales under company no. 41424 of Unilever House | Structuring detergent liquids with hydrogenated castor oil |
EP2841550B1 (en) | 2012-04-23 | 2016-01-20 | Unilever Plc. | Externally structured aqueous isotropic liquid detergent compositions |
IN2014MN02040A (zh) | 2012-04-23 | 2015-09-11 | Unilever Plc | |
EP2841551B1 (en) | 2012-04-23 | 2015-12-09 | Unilever Plc. | Externally structured aqueous isotropic liquid detergent compositions |
US9221989B2 (en) * | 2013-08-28 | 2015-12-29 | P.H. Glatfelter Company | Tamper evident documents and inks |
US20150037565A1 (en) * | 2013-07-31 | 2015-02-05 | P.H. Glatfelter Company | Tamper evident documents and inks |
EP2839877A1 (de) | 2013-08-21 | 2015-02-25 | Kwizda Agro GmbH | Verfahren zur Herstellung von Konzentraten von vorzugsweise wasserlöslichen Wirkstoffen |
CA2937505C (en) | 2014-01-27 | 2023-02-14 | Monsanto Technology Llc | Aqueous herbicidal concentrates comprising an acetanilide herbicide, a protoporphyrinogen oxidase inhibitor, and a pseudoplastic thickener |
CN106400589B (zh) * | 2016-08-30 | 2018-09-28 | 苏州丰倍生物科技有限公司 | 一种环保型无碳复写纸压敏油的制备方法 |
WO2018210522A1 (en) | 2017-05-15 | 2018-11-22 | Unilever Plc | Composition |
WO2018210523A1 (en) | 2017-05-15 | 2018-11-22 | Unilever Plc | Composition |
EP3625320A1 (en) | 2017-05-15 | 2020-03-25 | Unilever PLC | Composition |
WO2018210524A1 (en) | 2017-05-15 | 2018-11-22 | Unilever Plc | Composition |
US10464948B2 (en) * | 2017-05-30 | 2019-11-05 | Covestro Deutschland Ag | Polycyclic diiminooxadiazinones |
US11129381B2 (en) | 2017-06-13 | 2021-09-28 | Monsanto Technology Llc | Microencapsulated herbicides |
SG10201806031VA (en) * | 2018-07-13 | 2020-02-27 | Mitsui Chemicals Inc | Re-dispersible polyurea microcapsules and method of preparing re-dispersible polyurea microcapsules |
UY38564A (es) | 2019-01-30 | 2020-08-31 | Monsanto Technology Llc | Herbicidas de acetamida microencapsulada |
EP4339121A1 (en) | 2022-09-14 | 2024-03-20 | The Procter & Gamble Company | Consumer product |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4299723A (en) * | 1979-03-14 | 1981-11-10 | Bayer Aktiengesellschaft | Microcapsules and their preparation |
CN1165711A (zh) * | 1996-02-29 | 1997-11-26 | 拜尔公司 | 胶囊壁为缩二脲多异氰酸酯与胍类化合物的反应产物的微胶囊 |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2909906A1 (de) * | 1979-03-14 | 1980-10-02 | Bayer Ag | Verfahren zur kontinuierlichen herstellung von mikrokapseln |
DE3421865A1 (de) * | 1984-06-13 | 1985-12-19 | Bayer Ag, 5090 Leverkusen | Kontinuierliche herstellung von mikrokapseldispersionen |
FR2591124B1 (fr) * | 1985-12-10 | 1988-02-12 | Rhone Poulenc Spec Chim | Procede de microencapsulation par polyaddition-interfaciale. |
DE3902078A1 (de) * | 1989-01-25 | 1990-07-26 | Bayer Ag | Verfahren zur herstellung von modifizierten, isocyanuratgruppen aufweisenden polyisocyanaten und ihre verwendung |
US5164126A (en) * | 1991-03-05 | 1992-11-17 | Appleton Papers Inc. | Process for microencapsulation |
DE19532060A1 (de) * | 1995-08-31 | 1997-03-06 | Bayer Ag | Polycyclische Iminooxadiazindione, deren Herstellung und Verwendung |
-
1996
- 1996-11-08 DE DE19646110A patent/DE19646110A1/de not_active Withdrawn
-
1997
- 1997-09-25 TW TW086113943A patent/TW341526B/zh active
- 1997-10-09 IN IN2903DE1997 patent/IN186809B/en unknown
- 1997-10-23 US US08/956,821 patent/US6020066A/en not_active Expired - Fee Related
- 1997-10-27 DE DE59703664T patent/DE59703664D1/de not_active Expired - Lifetime
- 1997-10-27 ES ES97118626T patent/ES2157509T3/es not_active Expired - Lifetime
- 1997-10-27 PT PT97118626T patent/PT841088E/pt unknown
- 1997-10-27 EP EP97118626A patent/EP0841088B1/de not_active Expired - Lifetime
- 1997-10-31 JP JP9315901A patent/JPH10137578A/ja active Pending
- 1997-11-07 AR ARP970105196A patent/AR010555A1/es unknown
- 1997-11-07 BR BR9705447-0A patent/BR9705447A/pt not_active Application Discontinuation
- 1997-11-07 ZA ZA9710042A patent/ZA9710042B/xx unknown
- 1997-11-07 CN CN97122266A patent/CN1100602C/zh not_active Expired - Fee Related
- 1997-11-07 ID IDP973626A patent/ID18090A/id unknown
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4299723A (en) * | 1979-03-14 | 1981-11-10 | Bayer Aktiengesellschaft | Microcapsules and their preparation |
CN1165711A (zh) * | 1996-02-29 | 1997-11-26 | 拜尔公司 | 胶囊壁为缩二脲多异氰酸酯与胍类化合物的反应产物的微胶囊 |
Also Published As
Publication number | Publication date |
---|---|
EP0841088A3 (de) | 1998-07-22 |
AR010555A1 (es) | 2000-06-28 |
ES2157509T3 (es) | 2001-08-16 |
EP0841088B1 (de) | 2001-05-30 |
BR9705447A (pt) | 2000-02-29 |
DE59703664D1 (de) | 2001-07-05 |
TW341526B (en) | 1998-10-01 |
US6020066A (en) | 2000-02-01 |
EP0841088A2 (de) | 1998-05-13 |
CN1189393A (zh) | 1998-08-05 |
PT841088E (pt) | 2001-11-30 |
MX9708588A (es) | 1998-09-30 |
ID18090A (id) | 1998-02-26 |
IN186809B (zh) | 2001-11-10 |
ZA9710042B (en) | 1998-05-25 |
DE19646110A1 (de) | 1998-05-14 |
JPH10137578A (ja) | 1998-05-26 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN1100602C (zh) | 使用亚氨基噁二嗪二酮多异氰酸酯的微胶囊 | |
JP6888759B2 (ja) | ダブルエマルジョンによってマイクロカプセルを作製するための方法 | |
JP4557965B2 (ja) | 電気泳動ディスプレー用高性能カプセル | |
KR930002240B1 (ko) | 계면 중부가 반응을 이용한 마이크로 캡슐화 방법 | |
CN1239248C (zh) | 具有聚脲壁的微胶囊 | |
FI83334C (fi) | Kontinuerlig framstaellning av mikrokapseldispersioner. | |
CN1541138A (zh) | 微胶囊分散体 | |
EP0535384B1 (en) | Method of continuous production of microcapsules | |
US4766037A (en) | Photodegradable microcapsules | |
CN1348832A (zh) | 具有聚脲壁的微胶囊 | |
KR101202736B1 (ko) | 포화알코올 분산매를 포함하는 폴리우레아 마이크로 캡슐의제조 방법 및 이에 의해 제조된 마이크로캡슐 | |
CN101056701A (zh) | 低粘度的微胶囊分散体 | |
JPH02293041A (ja) | 水溶性物質内包マイクロカプセルの製法 | |
CN1318467C (zh) | 聚氨酯-丙烯酸酯复合乳液的细乳液聚合法 | |
JP2020500708A (ja) | サイズ制御されたマイクロカプセル及びマイクロ粒子の製造方法 | |
CN1165711A (zh) | 胶囊壁为缩二脲多异氰酸酯与胍类化合物的反应产物的微胶囊 | |
KR20040059997A (ko) | 자기수복 특성을 갖는 마이크로캡슐 함유 강판 코팅제조성물 | |
EP1151789A1 (de) | Mikrokapseln erhältlich unter Verwendung von Eiweisshydrolysaten als Emulgator | |
JP4098863B2 (ja) | マイクロカプセルの製造法 | |
JPH10139818A (ja) | 微小カプセルの製造方法 | |
JP3354615B2 (ja) | 複合壁マイクロカプセルの製造方法 | |
JP2006051476A (ja) | マイクロカプセル | |
JPH04277027A (ja) | マイクロカプセルの製造方法 | |
AU592900B2 (en) | Microcapsules with improved walls | |
JPH026519A (ja) | 高分子ゲルの製造方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
ASS | Succession or assignment of patent right |
Owner name: LANXESS DEUTSCHLAND GMBH Free format text: FORMER OWNER: BAYER AG Effective date: 20070601 |
|
C41 | Transfer of patent application or patent right or utility model | ||
TR01 | Transfer of patent right |
Effective date of registration: 20070601 Address after: Germany Leverkusen Patentee after: Lanxess Deutschland GmbH Address before: The Federal Republic of Germany Leverkusen Patentee before: Bayer Aktiengesellschaft |
|
C17 | Cessation of patent right | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20030205 Termination date: 20111107 |