CN1098281C - 烯烃聚合催化剂体系、其生产方法和用途 - Google Patents

烯烃聚合催化剂体系、其生产方法和用途 Download PDF

Info

Publication number
CN1098281C
CN1098281C CN97192604A CN97192604A CN1098281C CN 1098281 C CN1098281 C CN 1098281C CN 97192604 A CN97192604 A CN 97192604A CN 97192604 A CN97192604 A CN 97192604A CN 1098281 C CN1098281 C CN 1098281C
Authority
CN
China
Prior art keywords
compound
catalyst system
organic solvent
metal compound
olefin polymerization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN97192604A
Other languages
English (en)
Chinese (zh)
Other versions
CN1211995A (zh
Inventor
O·S·安德尔
H·霍卡南
M·穆斯托南
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Borealis AS
Original Assignee
Borealis AS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=8545089&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=CN1098281(C) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Borealis AS filed Critical Borealis AS
Publication of CN1211995A publication Critical patent/CN1211995A/zh
Application granted granted Critical
Publication of CN1098281C publication Critical patent/CN1098281C/zh
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61908—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61916—Component covered by group C08F4/60 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
CN97192604A 1996-01-26 1997-01-24 烯烃聚合催化剂体系、其生产方法和用途 Expired - Fee Related CN1098281C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FI960363 1996-01-26
FI960363A FI104825B (fi) 1996-01-26 1996-01-26 Olefiinien polymerointikatalysaattorisysteemi, sen valmistus ja käyttö

Publications (2)

Publication Number Publication Date
CN1211995A CN1211995A (zh) 1999-03-24
CN1098281C true CN1098281C (zh) 2003-01-08

Family

ID=8545089

Family Applications (1)

Application Number Title Priority Date Filing Date
CN97192604A Expired - Fee Related CN1098281C (zh) 1996-01-26 1997-01-24 烯烃聚合催化剂体系、其生产方法和用途

Country Status (9)

Country Link
US (1) US6225423B1 (fr)
EP (1) EP0876405B2 (fr)
JP (1) JP2000504045A (fr)
CN (1) CN1098281C (fr)
AT (1) ATE190631T1 (fr)
AU (1) AU1547497A (fr)
DE (1) DE69701447T3 (fr)
FI (1) FI104825B (fr)
WO (1) WO1997027224A1 (fr)

Families Citing this family (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6136742A (en) 1996-09-24 2000-10-24 Exxon Chemical Patents, Inc. Metallocene catalyst systems
US6977283B1 (en) 1998-04-07 2005-12-20 Exxonmobil Chemical Patents Inc. Polymerization process
US6245868B1 (en) 1998-05-29 2001-06-12 Univation Technologies Catalyst delivery method, a catalyst feeder and their use in a polymerization process
EP1860127B1 (fr) * 1998-10-27 2011-01-12 Westlake Longview Corporation Procédé pour la polymérisation d'oléfines, polyéthylènes et films et articles fabriqués à partir de ceux-ci
US6841634B1 (en) 1999-10-02 2005-01-11 Borealis Technology Oy Modified supported catalysts for the polymerization of olefins
US7041617B2 (en) 2004-01-09 2006-05-09 Chevron Phillips Chemical Company, L.P. Catalyst compositions and polyolefins for extrusion coating applications
US6593267B2 (en) 2000-12-18 2003-07-15 Univation Technologies, Llc Method for preparing a supported catalyst system and its use in a polymerization process
US6933258B2 (en) 2000-12-19 2005-08-23 Univation Technologies, L.L.C. Catalyst composition and methods for its preparation and use in a polymerization process
JP2002338617A (ja) * 2001-05-22 2002-11-27 Sumitomo Chem Co Ltd ビニル化合物重合用触媒成分、ビニル化合物重合用触媒、ビニル化合物重合体の製造方法および遷移金属化合物の使用方法
GB0118010D0 (en) 2001-07-24 2001-09-19 Borealis Tech Oy Catalysts
US6689852B2 (en) 2002-01-15 2004-02-10 Exxonmobil Research And Engineering Company Modifiers for improved olefin polymerization with activated neutral aluminum compounds
TWI300782B (en) * 2002-08-29 2008-09-11 Ineos Europe Ltd Supported polymerisation catalysts
DE602004027473D1 (de) 2003-03-21 2010-07-15 Dow Global Technologies Inc Verfahren zur herstellung von polyolefinen mit kontrollierter morphologie
GB0319773D0 (en) * 2003-08-22 2003-09-24 Bp Chem Int Ltd Supported polymerisation catalysts
KR101164043B1 (ko) * 2003-08-22 2012-07-18 이네오스 유럽 리미티드 지지 중합 촉매
GB0402959D0 (en) * 2004-02-11 2004-03-17 Bp Chem Int Ltd Supported polymerisation catalysts
US7294599B2 (en) * 2004-06-25 2007-11-13 Chevron Phillips Chemical Co. Acidic activator-supports and catalysts for olefin polymerization
EP1731536A1 (fr) * 2005-06-09 2006-12-13 Innovene Manufacturing France SAS Catalyseurs de polymérisation supportés
JP5156197B2 (ja) * 2006-04-20 2013-03-06 日本ポリプロ株式会社 オレフィン重合体の製造方法
US20070255022A1 (en) * 2006-04-28 2007-11-01 Fina Technology, Inc. Fluorinated transition metal catalysts and formation thereof
US8420733B2 (en) 2007-08-16 2013-04-16 Univation Technologies, Llc Continuity additives and their use in polymerization processes
WO2010080871A1 (fr) 2009-01-08 2010-07-15 Univation Technologies, Llc Additif pour procédés de polymérisation en phase gazeuse
RU2527945C2 (ru) 2009-01-08 2014-09-10 Юнивейшн Текнолоджиз, Ллк Добавка для процессов полимеризации полиолефинов
WO2011017092A1 (fr) 2009-07-28 2011-02-10 Univation Technologies, Llc Procédés de polymérisation utilisant un catalyseur supporté à géométrie contrainte
US8858525B2 (en) * 2009-11-20 2014-10-14 Cryovac, Inc. Noise dampening film
WO2012087560A1 (fr) 2010-12-22 2012-06-28 Univation Technologies, Llc Additif pour procédés de polymérisation de polyoléfines
EP2610269A1 (fr) 2011-12-28 2013-07-03 Saudi Basic Industries Corporation Composition de catalyseur et son procédé de préparation
WO2015088624A1 (fr) 2013-12-09 2015-06-18 Univation Technologies, Llc Alimentation d'additifs de polymérisation à des procédés de polymérisation
EP4105246A4 (fr) 2020-03-25 2023-09-06 Japan Polypropylene Corporation Catalyseur pour la polymérisation d'oléfines, procédé de production de catalyseur pour la polymérisation d'oléfines, et procédé de production de polymère d'oléfine utilisant ledit catalyseur pour la polymérisation d'oléfines
KR102513518B1 (ko) 2020-12-23 2023-03-22 디엘케미칼 주식회사 메탈로센 올레핀 중합 공정용 대전방지제를 이용한 올레핀 중합 방법

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0354893A2 (fr) * 1988-08-05 1990-02-14 Fina Technology, Inc. Procédé de production de grandes particules symétriques de polymères
US5416179A (en) * 1994-03-16 1995-05-16 Phillips Petroleum Company Catalyst compositions and olefin polymerization

Family Cites Families (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2154242A (en) 1984-02-03 1985-09-04 Bp Chem Int Ltd Continuous slurry process for producing olefin (co)polymers
US4701432A (en) 1985-11-15 1987-10-20 Exxon Chemical Patents Inc. Supported polymerization catalyst
EP0588277B1 (fr) 1987-02-02 2001-05-16 Fina Technology, Inc. Procédé d'amélioration de l'efficacité d'un catalyseur prépolymérisé
JPH06501047A (ja) 1990-09-14 1994-01-27 エクソン・ケミカル・パテンツ・インク 制御されたタクチシティーのポリ−α−オレフィンを製造するためのイオン触媒
DE4120006A1 (de) 1991-06-18 1992-12-24 Basf Ag Durch vorpolymerisation getraegerte katalysatorsysteme zur herstellung von polyalk-1-enen
DE4121368A1 (de) 1991-06-28 1993-01-07 Hoechst Ag Katalysator und verfahren zur herstellung von hochmolekularen polyolefinen
DE4139262A1 (de) 1991-11-29 1993-06-03 Basf Ag Getraegerte katalysatorsysteme zur polymerisation von c(pfeil abwaerts)2(pfeil abwaerts)- bis c(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)-alkenen
EP0567952B1 (fr) 1992-04-29 1997-12-03 Hoechst Aktiengesellschaft Catalyseur de polymérisation d'olefins, procédé pour sa préparation et son utilisation
US5240894A (en) 1992-05-18 1993-08-31 Exxon Chemical Patents Inc. Method for making and using a supported metallocene catalyst system
WO1994003506A1 (fr) 1992-08-05 1994-02-17 Exxon Chemical Patents Inc. Catalyseurs ioniques a support a base de metal transitoire pour la polymerisation des olefines
PT586167E (pt) 1992-09-04 2000-12-29 Bp Chem Int Ltd Composicoes de catalisadores e processo para a preparacao de poliolefinas
DE4242486A1 (de) 1992-12-16 1994-06-23 Basf Ag Propylen-Homopolymere
US5347024A (en) 1993-03-19 1994-09-13 The Dow Chemical Company Preparation of addition polymerization catalysts via Lewis acid mitigated metal center oxidation
CA2163789C (fr) * 1993-05-25 2006-10-24 Terry John Burkhardt Systemes catalytiques de type metallocene sur support pour la polymerisation d'olefines; preparation et utilisation
WO1995000562A1 (fr) 1993-06-24 1995-01-05 Exxon Chemical Patents Inc. Procede de production de poly-alpha-olefines amorphes au moyen d'un catalyseur a metal de transition de monocyclopentadienyle
ES2141833T3 (es) 1993-08-06 2000-04-01 Exxon Chemical Patents Inc Catalizadores de polimerizacion, su produccion y uso.
US5466649A (en) 1993-10-15 1995-11-14 Exxon Chemical Patents Inc. Polymerization catalyst systems, their production and use
DE4337232A1 (de) 1993-10-30 1995-05-04 Basf Ag Racemische Metallocenkomplexe und Verfahren zu ihrer Herstellung
DE69421411T2 (de) 1993-11-19 2000-06-08 Exxon Chemical Patents, Inc. Polymerisationskatalysatorsysteme, ihre herstellung und verwendung
DE4344688A1 (de) 1993-12-27 1995-06-29 Hoechst Ag Metallocenverbindung
IT1273615B (it) † 1995-05-05 1997-07-08 Enichem Spa Catalizzatore a migliorata attivita' per la (co)polimerizzazione dell'etilene

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0354893A2 (fr) * 1988-08-05 1990-02-14 Fina Technology, Inc. Procédé de production de grandes particules symétriques de polymères
US5416179A (en) * 1994-03-16 1995-05-16 Phillips Petroleum Company Catalyst compositions and olefin polymerization

Also Published As

Publication number Publication date
DE69701447D1 (de) 2000-04-20
JP2000504045A (ja) 2000-04-04
DE69701447T2 (de) 2000-09-14
AU1547497A (en) 1997-08-20
EP0876405A1 (fr) 1998-11-11
DE69701447T3 (de) 2007-07-12
CN1211995A (zh) 1999-03-24
EP0876405B2 (fr) 2007-01-03
ATE190631T1 (de) 2000-04-15
FI960363A (fi) 1997-07-27
FI960363A0 (fi) 1996-01-26
WO1997027224A1 (fr) 1997-07-31
FI104825B (fi) 2000-04-14
US6225423B1 (en) 2001-05-01
EP0876405B1 (fr) 2000-03-15

Similar Documents

Publication Publication Date Title
CN1098281C (zh) 烯烃聚合催化剂体系、其生产方法和用途
CN1044372C (zh) 烯烃聚合催化剂的固体组份及其制备和该催化剂及其应用
CN1222546C (zh) 用单一的金属茂催化剂和单一的单体制备e－p共聚物
JP3219277B2 (ja) オレフィン系重合体の製造方法及びエチレン系重合
US7759271B2 (en) Activating supports for metallocene catalysis
RU2238281C2 (ru) Способ полимеризации
CN1173186A (zh) 氮杂金属茂聚合催化剂
KR20110042056A (ko) 하프-메탈로센 촉매조성물 및 이들의 중합체 생성물
EP0768319A1 (fr) Méthode pour la préparation de polyoléfines
CN1069646C (zh) 过渡金属化合物
EP0553491B1 (fr) Catalyseur pour polymérisation d'oléfines et procédé de production de polymères d'oléfines
CN1487956A (zh) 催化剂组合物及其制备方法和在聚合方法中的用途
JP3292649B2 (ja) α−オレフィンの単独重合体又は共重合体の製造方法
CN1157291A (zh) 制备烯烃聚合物用的催化剂
CN1227271C (zh) 用于烯烃聚合的固体催化组合物
US20020099154A1 (en) Supported metallocene catalyst system for olefin polymerization
CN1529719A (zh) 聚合方法
JP2006500459A (ja) オレフィンの重合方法
CN1249762A (zh) 聚合方法
JP2022512099A (ja) オレフィン重合用触媒の調製方法
CN87105242A (zh) 含铬双金属络合催化剂
JP2001064329A (ja) プロピレン系共重合体およびその製造方法
JPH08208733A (ja) オレフィン重合用触媒
JP3858372B2 (ja) オレフィン重合用触媒およびそれを用いたポリオレフィンの製造方法
EP1042377A1 (fr) Procede de polymerisation de boues avec des metallocenes de bis-cyclopentadienyle a substitution alkyle

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20030108

Termination date: 20160124

EXPY Termination of patent right or utility model