CN1097558C - 锂锰氧化物尖晶石的制备方法 - Google Patents

锂锰氧化物尖晶石的制备方法 Download PDF

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Publication number
CN1097558C
CN1097558C CN97194637A CN97194637A CN1097558C CN 1097558 C CN1097558 C CN 1097558C CN 97194637 A CN97194637 A CN 97194637A CN 97194637 A CN97194637 A CN 97194637A CN 1097558 C CN1097558 C CN 1097558C
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CN
China
Prior art keywords
lithium
manganese oxide
manganese
manganese dioxide
spinel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN97194637A
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English (en)
Chinese (zh)
Other versions
CN1218443A (zh
Inventor
E·I·王
W·L·鲍登
P·吉尼特
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Gillette Co LLC
Original Assignee
Duracell Inc USA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Duracell Inc USA filed Critical Duracell Inc USA
Publication of CN1218443A publication Critical patent/CN1218443A/zh
Application granted granted Critical
Publication of CN1097558C publication Critical patent/CN1097558C/zh
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G45/00—Compounds of manganese
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G45/00—Compounds of manganese
    • C01G45/12—Complex oxides containing manganese and at least one other metal element
    • C01G45/1221—Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/30—Three-dimensional structures
    • C01P2002/32—Three-dimensional structures spinel-type (AB2O4)
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/40—Electric properties
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Battery Electrode And Active Subsutance (AREA)
CN97194637A 1996-04-08 1997-04-02 锂锰氧化物尖晶石的制备方法 Expired - Fee Related CN1097558C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/629,985 1996-04-08
US08/629,985 US5753202A (en) 1996-04-08 1996-04-08 Method of preparation of lithium manganese oxide spinel

Publications (2)

Publication Number Publication Date
CN1218443A CN1218443A (zh) 1999-06-02
CN1097558C true CN1097558C (zh) 2003-01-01

Family

ID=24525282

Family Applications (1)

Application Number Title Priority Date Filing Date
CN97194637A Expired - Fee Related CN1097558C (zh) 1996-04-08 1997-04-02 锂锰氧化物尖晶石的制备方法

Country Status (14)

Country Link
US (1) US5753202A (enExample)
EP (1) EP0892762B1 (enExample)
JP (1) JP4128627B2 (enExample)
KR (1) KR20000005432A (enExample)
CN (1) CN1097558C (enExample)
AT (1) ATE201662T1 (enExample)
AU (1) AU733425B2 (enExample)
BR (1) BR9708768A (enExample)
DE (1) DE69705039T2 (enExample)
ES (1) ES2157070T3 (enExample)
IL (1) IL126481A0 (enExample)
RU (1) RU2165390C2 (enExample)
TW (1) TW399030B (enExample)
WO (1) WO1997037934A1 (enExample)

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US5759510A (en) * 1996-10-03 1998-06-02 Carus Chemical Company Lithiated manganese oxide
US5783333A (en) 1996-11-27 1998-07-21 Polystor Corporation Lithium nickel cobalt oxides for positive electrodes
US6869547B2 (en) * 1996-12-09 2005-03-22 Valence Technology, Inc. Stabilized electrochemical cell active material
US6183718B1 (en) * 1996-12-09 2001-02-06 Valence Technology, Inc. Method of making stabilized electrochemical cell active material of lithium manganese oxide
US6886207B1 (en) 1999-06-14 2005-05-03 The Procter & Gamble Company Toothbrush
WO1999000860A1 (en) * 1997-06-27 1999-01-07 Maxpower, Inc. Transition manganese oxide cathodes
US6071646A (en) * 1997-08-26 2000-06-06 Kyushu Ceramics Industry Co., Ltd. Spinel compounds as cathodes for lithium materials
US6190800B1 (en) * 1998-05-11 2001-02-20 The Gillette Company Lithiated manganese dioxide
US5955052A (en) * 1998-05-21 1999-09-21 Carus Corporation Method for making lithiated manganese oxide
US5939043A (en) * 1998-06-26 1999-08-17 Ga-Tek Inc. Process for preparing Lix Mn2 O4 intercalation compounds
AU3670500A (en) * 1999-04-08 2000-11-14 Matsushita Electric Industrial Co., Ltd. Method for preparing lithium manganate having spinel structure
US6468695B1 (en) * 1999-08-18 2002-10-22 Valence Technology Inc. Active material having extended cycle life
US6730435B1 (en) * 1999-10-26 2004-05-04 Sumitomo Chemical Company, Limited Active material for non-aqueous secondary battery, and non-aqueous secondary battery using the same
US6403257B1 (en) * 2000-07-10 2002-06-11 The Gillette Company Mechanochemical synthesis of lithiated manganese dioxide
US6964828B2 (en) * 2001-04-27 2005-11-15 3M Innovative Properties Company Cathode compositions for lithium-ion batteries
EP1425810A2 (en) * 2001-08-07 2004-06-09 3M Innovative Properties Company Improved cathode compositions for lithium ion batteries
US20040121234A1 (en) * 2002-12-23 2004-06-24 3M Innovative Properties Company Cathode composition for rechargeable lithium battery
US20040177462A1 (en) 2003-03-14 2004-09-16 The Gillette Company Toothbrush head
US20060272112A9 (en) 2003-03-14 2006-12-07 The Gillette Company Toothbrush
KR100533095B1 (ko) * 2003-04-09 2005-12-01 주식회사 엘지화학 과방전 방지제를 포함하는 양극 활물질 및 이를 이용한리튬 이차 전지
US7941886B2 (en) 2003-09-19 2011-05-17 Braun Gmbh Toothbrushes
US7211237B2 (en) * 2003-11-26 2007-05-01 3M Innovative Properties Company Solid state synthesis of lithium ion battery cathode material
US7476467B2 (en) * 2004-03-29 2009-01-13 Lg Chem, Ltd. Lithium secondary battery with high power
CN1330579C (zh) * 2005-04-12 2007-08-08 武汉理工大学 水热法制备尖晶石型锂锰氧化物锂离子筛分材料
CN100339310C (zh) * 2006-02-27 2007-09-26 新乡市中科科技有限公司 尖晶石结构锂锰氧化物的制备方法
US8734992B2 (en) * 2007-02-14 2014-05-27 Tosoh Corporation Electrolytic manganese dioxide, and method for its production and its application
US8303840B2 (en) * 2010-03-12 2012-11-06 The Gillette Company Acid-treated manganese dioxide and methods of making thereof
CN101880063B (zh) * 2010-07-16 2011-04-27 李运姣 一种锂离子电池正极材料用锰酸锂前驱体的制备方法
JP5741908B2 (ja) * 2011-03-09 2015-07-01 日産自動車株式会社 リチウムイオン二次電池用正極活物質
US8597377B1 (en) 2011-04-07 2013-12-03 The United States Of America, As Represented By The Secretary Of The Army Chlorine modified high voltage LiMn2O4 cathode material for rechargeable lithium/lithium-ion electrochemical systems
US8900756B1 (en) 2011-04-07 2014-12-02 The United States Of America As Represented By The Secretary Of The Army Solid state preparation method for lithium manganese oxide AB2O4 battery cathode
US8900752B2 (en) 2011-10-19 2014-12-02 The United States Of America As Represented By The Secretary Of The Army Lead manganese-based cathode material for lithium electrochemical systems
US9979011B2 (en) 2014-09-26 2018-05-22 The United States Of America As Represented By The Secretary Of The Army LixMn2O4-y(C1z) spinal cathode material, method of preparing the same, and rechargeable lithium and li-ion electrochemical systems containing the same
US10505188B2 (en) 2015-03-03 2019-12-10 The Government Of The United States As Represented By The Secretary Of The Army “B” and “O” site doped AB2O4 spinel cathode material, method of preparing the same, and rechargeable lithium and Li-ion electrochemical systems containing the same
CN105152220B (zh) * 2015-08-05 2017-11-07 柳州豪祥特科技有限公司 球磨法制备尖晶石锰酸锂的方法
CN105152217B (zh) * 2015-08-05 2017-06-20 柳州豪祥特科技有限公司 一种尖晶石锰酸锂的制备方法
CN105304895B (zh) * 2015-10-23 2017-11-14 南京邮电大学 含锂金属氧化物锂电纳米电极材料及其制备方法
PL3414787T3 (pl) * 2016-02-09 2023-04-11 Camx Power Llc Wstępnie litowane materiały elektrod i ogniwa wykorzystujące te materiały
JP6944641B2 (ja) * 2017-04-24 2021-10-06 トヨタ自動車株式会社 リチウムイオン二次電池およびその製造方法
US11024850B2 (en) 2017-09-27 2021-06-01 Xilectric, Inc. Li-ion batteries with improved abuse tolerance and performance
JP7365565B2 (ja) * 2020-03-18 2023-10-20 トヨタ自動車株式会社 正極活物質および該正極活物質を備える二次電池
CN115636430B (zh) * 2021-07-20 2024-04-09 深圳市研一新材料有限责任公司 一种锂离子电池用复合锂盐及其制备方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01234331A (ja) * 1988-03-16 1989-09-19 Mitsui Mining & Smelting Co Ltd 三・二酸化マンガンおよびその製造法
JPH01234330A (ja) * 1988-03-16 1989-09-19 Mitsui Mining & Smelting Co Ltd 二酸化マンガンおよびその製造法
JPH01234329A (ja) * 1988-03-16 1989-09-19 Mitsui Mining & Smelting Co Ltd 二酸化マンガンおよびその製造法

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0746607B2 (ja) * 1987-01-29 1995-05-17 三洋電機株式会社 非水系二次電池
US4959282A (en) * 1988-07-11 1990-09-25 Moli Energy Limited Cathode active materials, methods of making same and electrochemical cells incorporating the same
CA1331506C (en) * 1988-07-12 1994-08-23 Michael Makepeace Thackeray Method of synthesizing a lithium manganese oxide
JPH02270269A (ja) * 1989-04-11 1990-11-05 Matsushita Electric Ind Co Ltd 非水電解質二次電池
JPH02270268A (ja) * 1989-04-11 1990-11-05 Matsushita Electric Ind Co Ltd 非水電解質二次電池
GB2234233B (en) * 1989-07-28 1993-02-17 Csir Lithium manganese oxide
JPH03122968A (ja) * 1989-10-05 1991-05-24 Mitsui Mining & Smelting Co Ltd リチウム一次電池用二酸化マンガンの製造方法
US5135732A (en) * 1991-04-23 1992-08-04 Bell Communications Research, Inc. Method for preparation of LiMn2 O4 intercalation compounds and use thereof in secondary lithium batteries
GB9305457D0 (en) * 1993-03-17 1993-05-05 Dowty Electronic Components Lithiated manganese oxide
GB9305440D0 (en) * 1993-03-17 1993-05-05 Dowty Electronic Components Lithiated manganese oxide

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01234331A (ja) * 1988-03-16 1989-09-19 Mitsui Mining & Smelting Co Ltd 三・二酸化マンガンおよびその製造法
JPH01234330A (ja) * 1988-03-16 1989-09-19 Mitsui Mining & Smelting Co Ltd 二酸化マンガンおよびその製造法
JPH01234329A (ja) * 1988-03-16 1989-09-19 Mitsui Mining & Smelting Co Ltd 二酸化マンガンおよびその製造法

Also Published As

Publication number Publication date
TW399030B (en) 2000-07-21
DE69705039T2 (de) 2001-11-15
ATE201662T1 (de) 2001-06-15
AU2434197A (en) 1997-10-29
US5753202A (en) 1998-05-19
DE69705039D1 (de) 2001-07-05
WO1997037934A1 (en) 1997-10-16
HK1015757A1 (en) 1999-10-22
BR9708768A (pt) 1999-08-03
RU2165390C2 (ru) 2001-04-20
CN1218443A (zh) 1999-06-02
EP0892762B1 (en) 2001-05-30
EP0892762A1 (en) 1999-01-27
IL126481A0 (en) 1999-08-17
JP2000508289A (ja) 2000-07-04
JP4128627B2 (ja) 2008-07-30
AU733425B2 (en) 2001-05-17
ES2157070T3 (es) 2001-08-01
KR20000005432A (ko) 2000-01-25

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C06 Publication
PB01 Publication
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C56 Change in the name or address of the patentee

Owner name: THE GILLETTE COMPANY

Free format text: FORMER NAME OR ADDRESS: DURACELL CO., LTD.

CP01 Change in the name or title of a patent holder

Address after: Connecticut, USA

Patentee after: THE GILLETTE Co.

Address before: Connecticut, USA

Patentee before: Duracell Inc.

C56 Change in the name or address of the patentee
CP02 Change in the address of a patent holder

Address after: Massachusetts, USA

Patentee after: THE GILLETTE Co.

Address before: Connecticut, USA

Patentee before: THE GILLETTE Co.

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CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20030101

Termination date: 20100402