CN1094959C - 聚碳酸酯树脂和接枝共聚物树脂的耐光组合物 - Google Patents
聚碳酸酯树脂和接枝共聚物树脂的耐光组合物 Download PDFInfo
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- CN1094959C CN1094959C CN97122077A CN97122077A CN1094959C CN 1094959 C CN1094959 C CN 1094959C CN 97122077 A CN97122077 A CN 97122077A CN 97122077 A CN97122077 A CN 97122077A CN 1094959 C CN1094959 C CN 1094959C
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- 239000000460 chlorine Substances 0.000 description 1
- XLJMAIOERFSOGZ-UHFFFAOYSA-M cyanate Chemical compound [O-]C#N XLJMAIOERFSOGZ-UHFFFAOYSA-M 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 125000004956 cyclohexylene group Chemical group 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- XSQNOFMFKVYSNL-UHFFFAOYSA-N ethene;toluene Chemical group C=C.CC1=CC=CC=C1 XSQNOFMFKVYSNL-UHFFFAOYSA-N 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 229920002313 fluoropolymer Polymers 0.000 description 1
- 239000004811 fluoropolymer Substances 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- KETWBQOXTBGBBN-UHFFFAOYSA-N hex-1-enylbenzene Chemical group CCCCC=CC1=CC=CC=C1 KETWBQOXTBGBBN-UHFFFAOYSA-N 0.000 description 1
- AHAREKHAZNPPMI-UHFFFAOYSA-N hexa-1,3-diene Chemical compound CCC=CC=C AHAREKHAZNPPMI-UHFFFAOYSA-N 0.000 description 1
- DPUXQWOMYBMHRN-UHFFFAOYSA-N hexa-2,3-diene Chemical compound CCC=C=CC DPUXQWOMYBMHRN-UHFFFAOYSA-N 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000000654 isopropylidene group Chemical group C(C)(C)=* 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N itaconic acid Chemical compound OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 125000002960 margaryl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- HZVOZRGWRWCICA-UHFFFAOYSA-N methanediyl Chemical compound [CH2] HZVOZRGWRWCICA-UHFFFAOYSA-N 0.000 description 1
- 229920012128 methyl methacrylate acrylonitrile butadiene styrene Polymers 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 125000002950 monocyclic group Chemical group 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- 125000004043 oxo group Chemical group O=* 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- IGEIPFLJVCPEKU-UHFFFAOYSA-N pentan-2-amine Chemical compound CCCC(C)N IGEIPFLJVCPEKU-UHFFFAOYSA-N 0.000 description 1
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical group CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 1
- RFPMGSKVEAUNMZ-UHFFFAOYSA-N pentylidene Chemical group [CH2+]CCC[CH-] RFPMGSKVEAUNMZ-UHFFFAOYSA-N 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 230000000176 photostabilization Effects 0.000 description 1
- 208000007578 phototoxic dermatitis Diseases 0.000 description 1
- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920006149 polyester-amide block copolymer Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- QMRNDFMLWNAFQR-UHFFFAOYSA-N prop-2-enenitrile;prop-2-enoic acid;styrene Chemical compound C=CC#N.OC(=O)C=C.C=CC1=CC=CC=C1 QMRNDFMLWNAFQR-UHFFFAOYSA-N 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000012966 redox initiator Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 description 1
- 125000003375 sulfoxide group Chemical group 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3432—Six-membered rings
- C08K5/3435—Piperidines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3415—Five-membered rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
PC | HRG | SAN | GEL | PHEN | PHOS | PETS |
63.46 | 15.86 | 14.87 | 4.96 | 0.30 | 0.30 | 0.25 |
试样号 | 1 | 2 | 3 | 4 | 5 |
添加剂 | 无 | 0.5%ASHA | 1.0%ASHA | 0.5%HALS | 1.0%HALS |
MVI在260℃ | 19.93 | 21.21 | 22.96 | 25.80 | 29.46 |
Izod切口冲击强度(ft-lbs/英寸) | |||||
标准条件 | 11.17 | 10.93 | 11.30 | 9.42 | 8.26 |
误操作条件 | 9.43 | 9.89 | 8.83 | 3.19 | 2.66 |
镖冲击(ft-lbs) | |||||
标准条件 | 39.97 | 41.97 | 37.77 | 39.90 | 43.16 |
误操作条件 | 34.50 | 33.02 | 29.69 | 26.64 | 12.24 |
抗张强度(psi) | |||||
标准条件 | 6527 | 6674 | 6685 | 6448 | 6446 |
误操作条件 | 6478 | 6503 | 6477 | 6325 | 6258 |
拉伸伸长率(%) | |||||
标准条件 | 45.74 | 67.27 | 74.92 | 41.22 | 40.25 |
误操作条件 | 41.7 | 39.06 | 31.99 | 24.96 | 19.03 |
Claims (11)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/772,228 US5786411A (en) | 1996-12-20 | 1996-12-20 | Light resistant compositions of polycarbonate and graft copolymer resins |
US08/772,228 | 1996-12-20 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1185461A CN1185461A (zh) | 1998-06-24 |
CN1094959C true CN1094959C (zh) | 2002-11-27 |
Family
ID=25094373
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN97122077A Expired - Fee Related CN1094959C (zh) | 1996-12-20 | 1997-12-22 | 聚碳酸酯树脂和接枝共聚物树脂的耐光组合物 |
Country Status (9)
Country | Link |
---|---|
US (1) | US5786411A (zh) |
EP (1) | EP0849327B1 (zh) |
JP (1) | JP3983360B2 (zh) |
KR (1) | KR100598656B1 (zh) |
CN (1) | CN1094959C (zh) |
DE (1) | DE69705197T2 (zh) |
ES (1) | ES2157530T3 (zh) |
SG (1) | SG55441A1 (zh) |
TW (1) | TW442536B (zh) |
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US5990208A (en) * | 1997-12-15 | 1999-11-23 | Ciba Specialty Chemicals Corporation | Stabilization of polycarbonate/ABS blends with mixtures of hindered amines and UV absorbers |
JP3662420B2 (ja) * | 1998-08-13 | 2005-06-22 | 出光興産株式会社 | 熱可塑性樹脂組成物および射出成形品 |
DE19846205A1 (de) * | 1998-10-07 | 2000-04-13 | Basf Ag | Gehäuse für Geräte zur Informationsverarbeitung und -übermittlung |
US6649677B2 (en) * | 1998-11-03 | 2003-11-18 | General Electric Company | Polycarbonate sheet with improved fire retardant performance |
GB2377709B (en) * | 1998-12-14 | 2003-06-18 | Ciba Sc Holding Ag | Sterically hindered amine compounds |
KR100550224B1 (ko) * | 1998-12-14 | 2006-02-08 | 시바 스폐셜티 케미칼스 홀딩 인코포레이티드 | 입체장애 아민 화합물 |
US6437565B1 (en) | 2000-07-11 | 2002-08-20 | General Electric Company | Method and system to determine physical properties |
US8216357B2 (en) * | 2009-09-25 | 2012-07-10 | General Electric Company | Protective coating compositions and devices |
US20150065622A1 (en) * | 2011-09-29 | 2015-03-05 | Styrolution GmbH | Stabilized polycarbonate/acrylonitrile/styrene/acrylic ester moulding compounds |
KR101577006B1 (ko) * | 2013-12-09 | 2015-12-14 | 현대모비스 주식회사 | 열가소성 폴리카보네이트 수지조성물 |
CN108610917A (zh) * | 2017-09-29 | 2018-10-02 | 聊城鲁西聚碳酸酯有限公司 | 一种用于板材涂层的聚碳酸酯组合物及其制备方法 |
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- 1997-11-21 KR KR1019970061773A patent/KR100598656B1/ko not_active IP Right Cessation
- 1997-12-12 EP EP97310037A patent/EP0849327B1/en not_active Expired - Lifetime
- 1997-12-12 DE DE69705197T patent/DE69705197T2/de not_active Expired - Fee Related
- 1997-12-12 JP JP34178497A patent/JP3983360B2/ja not_active Expired - Lifetime
- 1997-12-12 ES ES97310037T patent/ES2157530T3/es not_active Expired - Lifetime
- 1997-12-20 SG SG1997004592A patent/SG55441A1/en unknown
- 1997-12-22 CN CN97122077A patent/CN1094959C/zh not_active Expired - Fee Related
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Also Published As
Publication number | Publication date |
---|---|
CN1185461A (zh) | 1998-06-24 |
EP0849327A3 (en) | 1998-08-12 |
KR19980063597A (ko) | 1998-10-07 |
US5786411A (en) | 1998-07-28 |
SG55441A1 (en) | 1998-12-21 |
TW442536B (en) | 2001-06-23 |
DE69705197T2 (de) | 2002-02-28 |
DE69705197D1 (de) | 2001-07-19 |
JPH10251504A (ja) | 1998-09-22 |
KR100598656B1 (ko) | 2006-12-04 |
ES2157530T3 (es) | 2001-08-16 |
EP0849327A2 (en) | 1998-06-24 |
JP3983360B2 (ja) | 2007-09-26 |
EP0849327B1 (en) | 2001-06-13 |
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