CN109070065A - 用于制备n-取代马来酰亚胺的脱水催化剂、其制备方法和n-取代马来酰亚胺的制备方法 - Google Patents

用于制备n-取代马来酰亚胺的脱水催化剂、其制备方法和n-取代马来酰亚胺的制备方法 Download PDF

Info

Publication number
CN109070065A
CN109070065A CN201780026293.2A CN201780026293A CN109070065A CN 109070065 A CN109070065 A CN 109070065A CN 201780026293 A CN201780026293 A CN 201780026293A CN 109070065 A CN109070065 A CN 109070065A
Authority
CN
China
Prior art keywords
catalyst
substituted maleimide
preparation
amine
formula
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201780026293.2A
Other languages
English (en)
Chinese (zh)
Inventor
金志娟
崔埈瑄
千周暎
赵旺来
金京秀
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LG Chem Ltd
Original Assignee
LG Chem Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by LG Chem Ltd filed Critical LG Chem Ltd
Priority claimed from PCT/KR2017/008296 external-priority patent/WO2018038415A1/ko
Publication of CN109070065A publication Critical patent/CN109070065A/zh
Pending legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
    • B01J27/18—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr with metals other than Al or Zr
    • B01J27/1802—Salts or mixtures of anhydrides with compounds of other metals than V, Nb, Ta, Cr, Mo, W, Mn, Tc, Re, e.g. phosphates, thiophosphates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
    • B01J27/18—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr with metals other than Al or Zr
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/612—Surface area less than 10 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/04—Mixing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/06—Washing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D207/44—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having three double bonds between ring members or between ring members and non-ring members
    • C07D207/444—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having three double bonds between ring members or between ring members and non-ring members having two doubly-bound oxygen atoms directly attached in positions 2 and 5
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D207/44—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having three double bonds between ring members or between ring members and non-ring members
    • C07D207/444—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having three double bonds between ring members or between ring members and non-ring members having two doubly-bound oxygen atoms directly attached in positions 2 and 5
    • C07D207/448—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having three double bonds between ring members or between ring members and non-ring members having two doubly-bound oxygen atoms directly attached in positions 2 and 5 with only hydrogen atoms or radicals containing only hydrogen and carbon atoms directly attached to other ring carbon atoms, e.g. maleimide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/80—Catalysts, in general, characterised by their form or physical properties characterised by their amorphous structures

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Pyrrole Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201780026293.2A 2016-08-24 2017-08-01 用于制备n-取代马来酰亚胺的脱水催化剂、其制备方法和n-取代马来酰亚胺的制备方法 Pending CN109070065A (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
KR10-2016-0107851 2016-08-24
KR20160107851 2016-08-24
KR10-2017-0097281 2017-07-31
KR1020170097281A KR102146094B1 (ko) 2016-08-24 2017-07-31 N-치환 말레이미드 제조용 탈수 반응 촉매, 이의 제조 방법, 및 n-치환 말레이미드의 제조 방법
PCT/KR2017/008296 WO2018038415A1 (ko) 2016-08-24 2017-08-01 N-치환 말레이미드 제조용 탈수 반응 촉매, 이의 제조 방법, 및 n-치환 말레이미드의 제조 방법

Publications (1)

Publication Number Publication Date
CN109070065A true CN109070065A (zh) 2018-12-21

Family

ID=61727220

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201780026293.2A Pending CN109070065A (zh) 2016-08-24 2017-08-01 用于制备n-取代马来酰亚胺的脱水催化剂、其制备方法和n-取代马来酰亚胺的制备方法

Country Status (5)

Country Link
US (1) US10464050B2 (enExample)
EP (1) EP3417938B1 (enExample)
JP (1) JP6646761B2 (enExample)
KR (1) KR102146094B1 (enExample)
CN (1) CN109070065A (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109071432A (zh) * 2016-12-28 2018-12-21 株式会社Lg化学 使用固体酸催化剂的n-取代马来酰亚胺的合成方法

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102266842B1 (ko) * 2017-12-21 2021-06-21 주식회사 엘지화학 N-치환 말레이미드 제조용 촉매 제조방법
KR102821866B1 (ko) * 2020-01-17 2025-06-16 주식회사 엘지화학 알파 메틸 스티렌의 제조방법

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4851547A (en) * 1986-07-31 1989-07-25 Nippon Shokubai Kagaku Kogyo Co., Ltd. Method for production of maleimides
US4980483A (en) * 1988-03-25 1990-12-25 Nippon Shokubai Kagaku Kogyo Co., Ltd. Method for production of maleimides
CN102317260A (zh) * 2008-08-11 2012-01-11 锦湖石油化学株式会社 制备n-取代的马来酰亚胺的方法

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA906494A (en) 1972-08-01 Fujinami Ashiya-Shi Akira Production of n-aryl-cyclicimide compounds
NL130979C (enExample) 1963-10-25
FR2075356A5 (en) 1970-01-12 1971-10-08 Sumitomo Chemical Co N-aryl cyclic imides preparation
JPS5849338A (ja) 1981-09-17 1983-03-23 Mitsui Toatsu Chem Inc α，β−不飽和カルボン酸エステルの製造方法
JP2899027B2 (ja) * 1988-12-09 1999-06-02 三井化学株式会社 マレイミド類の製造法
CA2018509A1 (en) * 1989-06-16 1990-12-16 Ryuichiro Tsumura Preparation process of n-substituted maleimides
JP2538091B2 (ja) 1990-03-19 1996-09-25 松下電器産業株式会社 客数センサ
US5602205A (en) 1993-01-22 1997-02-11 Cytec Technology Corp. N-(substituted) maleimides and compositions incorporating the same
JP4014683B2 (ja) 1996-06-10 2007-11-28 大八化学工業株式会社 Ｎ−置換マレイミド類の製造方法
TW585855B (en) 2001-12-04 2004-05-01 Ind Tech Res Inst A novel production method for maleimides
JP2004175711A (ja) 2002-11-26 2004-06-24 Koei Chem Co Ltd 多価アルコールエーテル類の製造法
JP5101821B2 (ja) 2006-01-28 2012-12-19 公立大学法人大阪府立大学 不均一系リン酸ジルコニウム触媒、脱水反応方法、５−ヒドロキシメチルフルフラール製造方法、セルロース分解方法、及び不均一系リン酸ジルコニウム触媒の再生方法
JP4724024B2 (ja) 2006-03-22 2011-07-13 アスモ株式会社 モータ制御装置
JP4991471B2 (ja) 2007-05-16 2012-08-01 株式会社日本触媒 グリセリン脱水用触媒、およびアクロレインの製造方法
KR101051543B1 (ko) * 2007-11-27 2011-07-22 주식회사 엘지화학 Ｎ-치환 말레이미드류의 제조방법
KR100923536B1 (ko) 2007-12-24 2009-10-27 금호석유화학 주식회사 Ｎ－치환 말레이미드류의 제조방법
ITNO20130003A1 (it) 2013-05-09 2014-11-10 Novamont Spa Processo di sintesi di 5-idrossimetilfurfurale da saccaridi
KR102175831B1 (ko) 2016-12-28 2020-11-06 주식회사 엘지화학 고체산 촉매를 이용한 n-치환 말레이미드 제조방법

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4851547A (en) * 1986-07-31 1989-07-25 Nippon Shokubai Kagaku Kogyo Co., Ltd. Method for production of maleimides
US4980483A (en) * 1988-03-25 1990-12-25 Nippon Shokubai Kagaku Kogyo Co., Ltd. Method for production of maleimides
CN102317260A (zh) * 2008-08-11 2012-01-11 锦湖石油化学株式会社 制备n-取代的马来酰亚胺的方法

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
HUIMEI GAN等: "Gas phase dehydration of glycerol to acrolein catalyzed by zirconium phosphate", 《CHIN. J. CATAL.》 *
LIYUAN CHENG等: "High performance mesoporous zirconium phosphate for dehydration of xylose to furfural in aqueous-phase", 《RSC ADV.》 *
YUICHI KAMIYA等: "Zirconium phosphate with a high surface area as a water-tolerant solid acid", 《CATALYSIS LETTERS》 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109071432A (zh) * 2016-12-28 2018-12-21 株式会社Lg化学 使用固体酸催化剂的n-取代马来酰亚胺的合成方法

Also Published As

Publication number Publication date
JP6646761B2 (ja) 2020-02-14
EP3417938B1 (en) 2025-05-07
US20190118168A1 (en) 2019-04-25
US10464050B2 (en) 2019-11-05
EP3417938A4 (en) 2019-05-22
KR20180022563A (ko) 2018-03-06
EP3417938A1 (en) 2018-12-26
JP2019512388A (ja) 2019-05-16
KR102146094B1 (ko) 2020-08-19

Similar Documents

Publication Publication Date Title
US9550729B2 (en) Mixed metal oxide catalysts
Ghodke et al. Solvent free synthesis of coumarins using environment friendly solid acid catalysts
CN109070065A (zh) 用于制备n-取代马来酰亚胺的脱水催化剂、其制备方法和n-取代马来酰亚胺的制备方法
Satasia et al. Heteropolyanion-based sulfated ionic liquid catalyzed formamides synthesis by grindstone chemistry
Kong et al. Hierarchically porous AlPO-5-based microspheres as heterogeneous catalysts for the synthesis of 5-substituted 1 H-tetrazoles via [3+ 2] cycloaddition
CN101891651A (zh) 用于制备n-取代的氨基甲酸酯的催化剂及其制备方法和应用
US20190001310A1 (en) Selective ammoxidation catalysts
CN102596858A (zh) 烯烃类的制造方法
JP2015101554A (ja) Ｎ−置換（メタ）アクリルアミドの製造方法
CN109746042B (zh) 用于合成3-甲氧基丙烯酸甲酯的催化剂及固载、使用方法
Xu et al. Preparation and application of zirconium sulfate supported on SAPO-34 molecular sieve as solid acid catalyst for esterification
JP2019512388A5 (enExample)
Jahani et al. An efficient and highly chemoselective N-Boc protection of amines, amino acids, and peptides under heterogeneous conditions
CN103626665B (zh) 一种n,n-二烷基对苯二胺的合成方法
CN103588599A (zh) 一种硝基还原制备羟胺的方法
CN109607560A (zh) 一种薄片状杂原子分子筛及其绿色合成方法
Guan et al. Selective oxidation of isobutane and isobutene over vanadium phosphorus oxides
EA000247B1 (ru) Способ получения модифицированного морденита аммония
Shyamprasad et al. Effective acetylation of alcohols, phenols and amines over mesoporous aluminophosphate solid acids under solvent free conditions
RU2373189C2 (ru) Способ получения n, n, n, n-тетраметилалкадииндиаминов
CN114478300A (zh) 新型酰氯催化剂及其制备方法与应用
CN101053830A (zh) 一种合成水杨酰胺的催化剂及其制备方法和应用
JP2015101553A (ja) Ｎ−置換（メタ）アクリルアミドの製造方法
JPH06179633A (ja) アリールエチレングリコールの製造方法
Rekha et al. Effect of Anion on the Catalytic Activity of Cobalt Aluminophosphate in the Synthesis of N, N‐Biphenyl Urea Derivatives

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination