FR2075356A5 - N-aryl cyclic imides preparation - Google Patents

N-aryl cyclic imides preparation

Info

Publication number
FR2075356A5
FR2075356A5 FR7100536A FR7100536A FR2075356A5 FR 2075356 A5 FR2075356 A5 FR 2075356A5 FR 7100536 A FR7100536 A FR 7100536A FR 7100536 A FR7100536 A FR 7100536A FR 2075356 A5 FR2075356 A5 FR 2075356A5
Authority
FR
France
Prior art keywords
aryl
degrees
preparation
residue
subst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
FR7100536A
Other languages
French (fr)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sumitomo Chemical Co Ltd
Original Assignee
Sumitomo Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Chemical Co Ltd filed Critical Sumitomo Chemical Co Ltd
Application granted granted Critical
Publication of FR2075356A5 publication Critical patent/FR2075356A5/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D207/30—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members
    • C07D207/34—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D207/36—Oxygen or sulfur atoms
    • C07D207/40—2,5-Pyrrolidine-diones
    • C07D207/404—2,5-Pyrrolidine-diones with only hydrogen atoms or radicals containing only hydrogen and carbon atoms directly attached to other ring carbon atoms, e.g. succinimide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D207/30—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members
    • C07D207/34—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D207/36—Oxygen or sulfur atoms
    • C07D207/40—2,5-Pyrrolidine-diones
    • C07D207/404—2,5-Pyrrolidine-diones with only hydrogen atoms or radicals containing only hydrogen and carbon atoms directly attached to other ring carbon atoms, e.g. succinimide
    • C07D207/408—Radicals containing only hydrogen and carbon atoms attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D207/30—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members
    • C07D207/34—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D207/36—Oxygen or sulfur atoms
    • C07D207/40—2,5-Pyrrolidine-diones
    • C07D207/404—2,5-Pyrrolidine-diones with only hydrogen atoms or radicals containing only hydrogen and carbon atoms directly attached to other ring carbon atoms, e.g. succinimide
    • C07D207/408—Radicals containing only hydrogen and carbon atoms attached to ring carbon atoms
    • C07D207/412—Acyclic radicals containing more than six carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D207/44—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having three double bonds between ring members or between ring members and non-ring members
    • C07D207/444—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having three double bonds between ring members or between ring members and non-ring members having two doubly-bound oxygen atoms directly attached in positions 2 and 5
    • C07D207/448—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having three double bonds between ring members or between ring members and non-ring members having two doubly-bound oxygen atoms directly attached in positions 2 and 5 with only hydrogen atoms or radicals containing only hydrogen and carbon atoms directly attached to other ring carbon atoms, e.g. maleimide
    • C07D207/452—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having three double bonds between ring members or between ring members and non-ring members having two doubly-bound oxygen atoms directly attached in positions 2 and 5 with only hydrogen atoms or radicals containing only hydrogen and carbon atoms directly attached to other ring carbon atoms, e.g. maleimide with hydrocarbon radicals, substituted by hetero atoms, directly attached to the ring nitrogen atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D209/02—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom condensed with one carbocyclic ring
    • C07D209/44—Iso-indoles; Hydrogenated iso-indoles
    • C07D209/48—Iso-indoles; Hydrogenated iso-indoles with oxygen atoms in positions 1 and 3, e.g. phthalimide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D209/02—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom condensed with one carbocyclic ring
    • C07D209/52—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom condensed with one carbocyclic ring condensed with a ring other than six-membered
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/04—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D211/80—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members
    • C07D211/84—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen directly attached to ring carbon atoms
    • C07D211/86—Oxygen atoms
    • C07D211/88—Oxygen atoms attached in positions 2 and 6, e.g. glutarimide

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Indole Compounds (AREA)

Abstract

N-aryl imides of the formula CO-N(Aryl)-CO-A (where A is an opt. subst. divalent hydrocarbon residue, residue with 2 or 3 C-atoms between the two carbonyl gps. and Aryl is an opt. subst. carbocyclic or heterocyclic aromatic residue), which are useful as intermediates (e.g. for dyes, pesticides and medicines) are prepd. in excellent yield by either (a) reacting a dicarboxylic acid HOOC-A-COOH or its anhydride CO-A-CO-O with an amide Aryl-NH2 or (b) intramolecularly acylating a dicarboxylic acid monoamide HOOC-A-CO-NH Aryl, the reaction in either case being carried out in the presence of a basic catalyst (pref. NEt3) at not >150 degrees C, pref. 110-150 degrees C (esp. ca 140 degrees C).
FR7100536A 1970-01-12 1971-01-08 N-aryl cyclic imides preparation Expired FR2075356A5 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP365670 1970-01-12

Publications (1)

Publication Number Publication Date
FR2075356A5 true FR2075356A5 (en) 1971-10-08

Family

ID=11563498

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7100536A Expired FR2075356A5 (en) 1970-01-12 1971-01-08 N-aryl cyclic imides preparation

Country Status (4)

Country Link
BE (1) BE761427A (en)
DE (1) DE2100800A1 (en)
FR (1) FR2075356A5 (en)
NL (1) NL7100377A (en)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2740848A1 (en) * 1977-09-10 1979-03-29 Bayer Ag SUBSTITUTED N-PHENYL AMBER ACID IMIDES, METHOD FOR THE PRODUCTION THEREOF AND THEIR USE AS FUNGICIDES
JPS615066A (en) * 1984-06-18 1986-01-10 Nippon Shokubai Kagaku Kogyo Co Ltd Production of maleimide
DE19504623A1 (en) * 1995-02-13 1996-08-14 Bayer Ag Process for the preparation of N-substituted cyclic imides
DE19504626A1 (en) * 1995-02-13 1996-08-14 Bayer Ag Process for the preparation of N- (ortho-alkylphenyl) imides
US6355664B1 (en) 1997-03-03 2002-03-12 Boehringer Ingelheim Pharmaceuticals, Inc. Phenylpyrrolidines, phenylimidazolidines, 3-phenyl-1,3-oxizolidines and 3-phenyl-1,3-thiazolidines and their use in the treatment of inflammatory disease
USRE38132E1 (en) 1997-03-03 2003-06-03 Boehringer Ingelheim Pharmaceuticals, Inc. Phenylpyrrolidines, phenylimidazolidines,3-phenyl-1,3-oxizolidines and 3-phenyl-1,3-thiazolidines and their use in the treatment of inflammatory disease
US6492408B1 (en) 1999-07-21 2002-12-10 Boehringer Ingelheim Pharmaceuticals, Inc. Small molecules useful in the treatment of inflammatory disease
WO2001007044A1 (en) 1999-07-21 2001-02-01 Boehringer Ingelheim Pharmaceuticals, Inc. Small molecules useful in the treatment of inflammatory disease
US6365615B1 (en) 1999-07-21 2002-04-02 Boehringer Ingelheim Pharmaceuticals, Inc. Small molecules useful in the treatment of inflammatory disease
CA2378369C (en) 1999-07-21 2007-10-02 Terence Alfred Kelly Small molecules useful in the treatment of inflammatory disease
AU2015273578B2 (en) * 2014-06-12 2019-10-03 Allocyte Pharmaceuticals Ag Small molecule LFA-1 inhibitors
KR102146094B1 (en) 2016-08-24 2020-08-19 주식회사 엘지화학 Catalyst for dehydration of preparing n-substituted maleimides, method of preparing the same, and preparing method of n-substituted maleimides
WO2018038415A1 (en) 2016-08-24 2018-03-01 주식회사 엘지화학 Dehydration reaction catalyst for preparing n-substituted maleimide, method for preparing same, and method for preparing n-substituted maleimide

Also Published As

Publication number Publication date
NL7100377A (en) 1971-07-14
BE761427A (en) 1971-07-12
DE2100800A1 (en) 1971-07-15

Similar Documents

Publication Publication Date Title
FR2075356A5 (en) N-aryl cyclic imides preparation
GB1276446A (en) Process for the preparation of bis-maleimides
GB1353962A (en) Method of making dianhydride terminated cyclic monomers
GB1133013A (en) Process of preparing amides
GB768821A (en) Novel products of the amino-piperidine-2, 6-dione series
CA988527A (en) Benzophenone-3,4,3',4'-tetracarboxylic acid diimides of 3,5-dialkyl-4-hydroxyphenylsubstituted amines
GB1410516A (en) Phenoxy-carboxylic acid amides
GB1348077A (en) Oligomers possessing 8mide groups
GB1132019A (en) Urethane coating compositions
KR830007553A (en) Method for preparing N- (cyclohexylthio) -phthalimide
GB1355917A (en) Process for the catalytic production of linear mono-unsaturated dicarboxylic acid derivatives
GB1343942A (en) Procedure for obtaining 6-amino-penicillan-acid
GB1069337A (en) Basically substituted bis-naphthalimides and their production
GB1393106A (en) Pyromellitic diimides of 3,5-dialkyl-4-hydroxyphenyl substituted amines
FR2224477A1 (en) 9-Methyl-7-substd.-trans-decalin-3-chloromercurate - obtd under mild conditions from trans-5-methyl-1,5,9-decatriene
GB1319165A (en) Polyurea-carboxylate salts and greases thickened therewith
GB1361555A (en) Catalytic production of aromatic and heterocyclic amines
BE776188A (en) Pyrrolidine-2-carboxylic acid -2-methyl-6-ethyl-anilides - useful as local anaesthetics
UST971003I4 (en) Synthesis of dimaleimides
SE7713439L (en) ALKANOYLANILIDE DERIVATIVES
GB1393835A (en) Aryloxy dianhydrides
GB1147232A (en) Naphthalene-1:4:5:8-tetracarboxylic acid diimide derivatives
FR2152344A1 (en) N-(3,5-diamino-2,4,6-triazin-1-yl)amines - as pre-and post- emergence herbicides
BE779164A (en) UNDOUBING OF AN ORGANIC ACID, INTERMEDIATE OF SYNTHESIS
GB1374690A (en) Isothiazolopyrimidine derivatives

Legal Events

Date Code Title Description
ST Notification of lapse