CN107829292A - 一种羊毛帽子专用防霉整理液 - Google Patents

一种羊毛帽子专用防霉整理液 Download PDF

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CN107829292A
CN107829292A CN201711235847.8A CN201711235847A CN107829292A CN 107829292 A CN107829292 A CN 107829292A CN 201711235847 A CN201711235847 A CN 201711235847A CN 107829292 A CN107829292 A CN 107829292A
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parts
water
dressing liquid
wool cap
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李佳
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Anhui Zhongfu Wool Cap Co Ltd
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Abstract

本发明公开了一种羊毛帽子专用防霉整理液，其原料按重量份包括：纳米硅溶胶5‑17份、纳米氧化镁2‑13份、植物提取物2‑10份、大蒜油2‑10份、1,2‑戊二醇1‑5份、壳聚糖5‑8份、一氯三嗪‑β‑环糊精1‑8份、有机酸0.3‑2份、次亚磷酸钠0.1‑1份、六羟甲基三聚氰胺1‑5份、改性凹凸棒土10‑25份、二羟甲基脲0.3‑1.5份、水200‑400份。本发明提出的羊毛帽子专用防霉整理液，其稳定性好，处理的羊毛帽子具有优异的抗菌防霉性。

Description

一种羊毛帽子专用防霉整理液
技术领域
本发明涉及羊毛帽子技术领域，尤其涉及一种羊毛帽子专用防霉整理液。
背景技术
羊毛帽子以羊毛为原料制备而成，具有保暖舒适的特点，深受人们喜爱。随着人们生活水平的不断提高，人们对羊毛帽子的要求也越来越高。但是现有的羊毛帽子一般未经过抗菌防霉处理，在佩戴的过程中，易滋生细菌，且收藏时易霉变，从而影响羊毛帽子的使用性能。
发明内容
基于背景技术存在的技术问题，本发明提出了一种羊毛帽子专用防霉整理液，其稳定性好，处理的羊毛帽子具有优异的抗菌防霉性。
本发明提出的一种羊毛帽子专用防霉整理液，其原料按重量份包括：纳米硅溶胶5-17份、纳米氧化镁2-13份、植物提取物2-10份、大蒜油2-10份、1,2-戊二醇1-5份、壳聚糖5-8份、一氯三嗪-β-环糊精1-8份、有机酸0.3-2份、次亚磷酸钠0.1-1份、六羟甲基三聚氰胺1-5份、改性凹凸棒土10-25份、二羟甲基脲0.3-1.5份、水200-400份。
优选地，所述纳米硅溶胶的浓度为0.3-0.8mol/L。
优选地，所述植物提取物按照以下工艺进行制备：将樟树叶和柚子皮分别洗净后破碎，然后加入乙醇水溶液中，其中，乙醇水溶液中，乙醇与水的体积比为1：2-4，乙醇水溶液的体积为樟树叶和柚子皮总体积的15-20倍，加热至回流后搅拌80-100min，然后过滤、干燥、灭菌后得到所述植物提取物。
优选地，所述有机酸为冰醋酸、柠檬酸、酒石酸、苹果酸中的一种或者多种的混合物。
优选地，所述改性凹凸棒土按照以下工艺进行制备：将1，2-苯丙异噻唑啉-3-酮加入水中，调节体系pH值为9-10，然后加入凹凸棒土水溶液，在室温下搅拌5-9h，转移至水热釜中水热反应5-9h，反应结束后离心、洗涤、干燥得到物料A；将物料A、钛酸四丁酯和乙醇混合均匀，加入水后搅拌3-5h，过滤后洗涤、干燥，然后在550-650℃下煅烧120-150min得到物料B；将物料B加入水中搅拌均匀，然后加入二癸基二甲基氯化铵搅拌30-50min，加入硝酸银的氨溶液，搅拌5-8h，然后过滤、洗涤、干燥，在550-650℃下煅烧100-150min得到所述改性凹凸棒土。
优选地，1，2-苯丙异噻唑啉-3-酮、凹凸棒土的重量比为1-5：15-30。
优选地，物料A、钛酸四丁酯的重量比为1：2.5-3。
优选地，物料B、二癸基二甲基氯化铵、硝酸银的重量比为0.5-1.5：2-4：0.1-0.35。
所述硝酸银的氨溶液由硝酸银溶解在浓氨水中搅拌得到。
本发明所述羊毛帽子专用防霉整理液，其原料中，加入纳米硅溶胶，处理后在羊毛帽子的纤维表面形成了多孔膜，覆盖住了羊毛的鳞片结构，一方面赋予羊毛帽子优异的抗起球性，另一方面，与体系中的纳米氧化镁配合，在保持羊毛帽子断裂强度和白度的情况下，赋予羊毛帽子优异的抗菌性和抗静电性，且耐久性好；在改性凹凸棒土的制备过程中，首先以1，2-苯丙异噻唑啉-3-酮和凹凸棒土为原料，通过控制反应的条件，使1，2-苯丙异噻唑啉-3-酮插入到了凹凸棒土的片层间，之后与钛酸四丁酯反应，使二氧化钛负载在了凹凸棒土的表面，与二癸基二甲基氯化铵和硝酸银的氨溶液混合后，又在凹凸棒土的表面负载了氯化银，从而得到了1，2-苯丙异噻唑啉-3-酮、二氧化钛和氯化银改性的凹凸棒土，同时具有1，2-苯丙异噻唑啉-3-酮、二氧化钛和氯化银的性质，将其加入体系中，与植物提取物、大蒜油、1,2-戊二醇、壳聚糖、一氯三嗪-β-环糊精配合，赋予羊毛帽子优异的抗菌性和防霉性，同时能提高壳聚糖的接枝反应效率，赋予羊毛帽子非常好的防缩、抗紫外线、抗日晒等功能，且手感好；同时植物提取液中的柚子皮和樟树叶与改性凹凸棒土中的二癸基二甲基氯化铵具有协同作用，显著提高了整理液的抗菌性和防霉性；一氯三嗪-β-环糊精加入体系中，能与羊毛帽子上的氨基、羟基和硫醇基等发生化学键合，将β-环糊精固定在纤维基体上，提高了与羊毛帽子的结合力，显著提高了羊毛帽子的耐洗耐磨性；加入的1,2-戊二醇与植物提取液配合，增强了整理液的吸收整理能力，在不损伤纤维的条件下，使所述功能附着牢固、持久，赋予羊毛帽子优异的耐紫外线照射和水洗性。
具体实施方式
下面，通过具体实施例对本发明的技术方案进行详细说明。
实施例1
本发明提出的一种羊毛帽子专用防霉整理液，其原料按重量份包括：纳米硅溶胶17份、纳米氧化镁2份、植物提取物10份、大蒜油2份、1,2-戊二醇5份、壳聚糖5份、一氯三嗪-β-环糊精8份、有机酸0.3份、次亚磷酸钠1份、六羟甲基三聚氰胺1份、改性凹凸棒土25份、二羟甲基脲0.3份、水400份。
实施例2
本发明提出的一种羊毛帽子专用防霉整理液，其原料按重量份包括：纳米硅溶胶5份、纳米氧化镁13份、植物提取物2份、大蒜油10份、1,2-戊二醇1份、壳聚糖8份、一氯三嗪-β-环糊精1份、有机酸2份、次亚磷酸钠0.1份、六羟甲基三聚氰胺5份、改性凹凸棒土10份、二羟甲基脲1.5份、水200份。
实施例3
本发明提出的一种羊毛帽子专用防霉整理液，其原料按重量份包括：纳米硅溶胶12份、纳米氧化镁5份、植物提取物8份、大蒜油3.5份、1,2-戊二醇4.6份、壳聚糖6.3份、一氯三嗪-β-环糊精7.6份、有机酸0.6份、次亚磷酸钠0.8份、六羟甲基三聚氰胺2份、改性凹凸棒土21份、二羟甲基脲0.6份、水320份；
其中，所述纳米硅溶胶的浓度为0.3mol/L；
所述植物提取物按照以下工艺进行制备：将樟树叶和柚子皮分别洗净后破碎，然后加入乙醇水溶液中，其中，乙醇水溶液中，乙醇与水的体积比为1：2，乙醇水溶液的体积为樟树叶和柚子皮总体积的20倍，加热至回流后搅拌80min，然后过滤、干燥、灭菌后得到所述植物提取物。
所述有机酸为冰醋酸；
所述改性凹凸棒土按照以下工艺进行制备：将1，2-苯丙异噻唑啉-3-酮加入水中，调节体系pH值为9，然后加入凹凸棒土水溶液，其中，1，2-苯丙异噻唑啉-3-酮、凹凸棒土的重量比为1：30，在室温下搅拌9h，转移至水热釜中水热反应5h，反应结束后离心、洗涤、干燥得到物料A；将物料A、钛酸四丁酯和乙醇混合均匀，其中，物料A、钛酸四丁酯的重量比为1：3，加入水后搅拌3h，过滤后洗涤、干燥，然后在650℃下煅烧120min得到物料B；将物料B加入水中搅拌均匀，然后加入二癸基二甲基氯化铵搅拌50min，加入硝酸银的氨溶液，其中，物料B、二癸基二甲基氯化铵、硝酸银的重量比为0.5：4：0.1，搅拌5h，然后过滤、洗涤、干燥，在650℃下煅烧100min得到所述改性凹凸棒土。
实施例4
本发明提出的一种羊毛帽子专用防霉整理液，其原料按重量份包括：纳米硅溶胶7份、纳米氧化镁10份、植物提取物4份、大蒜油8.6份、1,2-戊二醇2.3份、壳聚糖7.5份、一氯三嗪-β-环糊精2.3份、有机酸1.7份、次亚磷酸钠0.2份、六羟甲基三聚氰胺4份、改性凹凸棒土13份、二羟甲基脲1.2份、水250份；
其中，所述纳米硅溶胶的浓度为0.8mol/L；
所述植物提取物按照以下工艺进行制备：将樟树叶和柚子皮分别洗净后破碎，然后加入乙醇水溶液中，其中，乙醇水溶液中，乙醇与水的体积比为1：4，乙醇水溶液的体积为樟树叶和柚子皮总体积的15倍，加热至回流后搅拌100min，然后过滤、干燥、灭菌后得到所述植物提取物。
所述有机酸为柠檬酸、酒石酸、苹果酸的混合物，且柠檬酸、酒石酸、苹果酸的质量比为3:2:4；
所述改性凹凸棒土按照以下工艺进行制备：将1，2-苯丙异噻唑啉-3-酮加入水中，调节体系pH值为10，然后加入凹凸棒土水溶液，其中，1，2-苯丙异噻唑啉-3-酮、凹凸棒土的重量比为5：15，在室温下搅拌5h，转移至水热釜中水热反应9h，反应结束后离心、洗涤、干燥得到物料A；将物料A、钛酸四丁酯和乙醇混合均匀，其中，物料A、钛酸四丁酯的重量比为1：2.5，加入水后搅拌5h，过滤后洗涤、干燥，然后在550℃下煅烧150min得到物料B；将物料B加入水中搅拌均匀，然后加入二癸基二甲基氯化铵搅拌30min，加入硝酸银的氨溶液，其中，物料B、二癸基二甲基氯化铵、硝酸银的重量比为1.5：2：0.35，搅拌8h，然后过滤、洗涤、干燥，在550℃下煅烧150min得到所述改性凹凸棒土。
实施例5
本发明提出的一种羊毛帽子专用防霉整理液，其原料按重量份包括：纳米硅溶胶11份、纳米氧化镁9份、植物提取物7份、大蒜油6份、1,2-戊二醇3份、壳聚糖7份、一氯三嗪-β-环糊精5份、有机酸1份、次亚磷酸钠0.6份、六羟甲基三聚氰胺3份、改性凹凸棒土17份、二羟甲基脲1份、水300份；
其中，所述纳米硅溶胶的浓度为0.5mol/L；
所述植物提取物按照以下工艺进行制备：将樟树叶和柚子皮分别洗净后破碎，然后加入乙醇水溶液中，其中，乙醇水溶液中，乙醇与水的体积比为1：3，乙醇水溶液的体积为樟树叶和柚子皮总体积的17倍，加热至回流后搅拌90min，然后过滤、干燥、灭菌后得到所述植物提取物；
所述有机酸为冰醋酸、柠檬酸、酒石酸、苹果酸的混合物，且冰醋酸、柠檬酸、酒石酸、苹果酸的质量比为3:4:2:5；
所述改性凹凸棒土按照以下工艺进行制备：将1，2-苯丙异噻唑啉-3-酮加入水中，调节体系pH值为9.5，然后加入凹凸棒土水溶液，其中，1，2-苯丙异噻唑啉-3-酮、凹凸棒土的重量比为3：22，在室温下搅拌7h，转移至水热釜中水热反应8h，反应结束后离心、洗涤、干燥得到物料A；将物料A、钛酸四丁酯和乙醇混合均匀，其中，物料A、钛酸四丁酯的重量比为1：2.7，加入水后搅拌4h，过滤后洗涤、干燥，然后在620℃下煅烧135min得到物料B；将物料B加入水中搅拌均匀，然后加入二癸基二甲基氯化铵搅拌40min，加入硝酸银的氨溶液，其中，物料B、二癸基二甲基氯化铵、硝酸银的重量比为1：3：0.2，搅拌6.5h，然后过滤、洗涤、干燥，在620℃下煅烧130min得到所述改性凹凸棒土。
以上所述，仅为本发明较佳的具体实施方式，但本发明的保护范围并不局限于此，任何熟悉本技术领域的技术人员在本发明揭露的技术范围内，根据本发明的技术方案及其发明构思加以等同替换或改变，都应涵盖在本发明的保护范围之内。

Claims (8)

1.一种羊毛帽子专用防霉整理液，其特征在于，其原料按重量份包括：纳米硅溶胶5-17份、纳米氧化镁2-13份、植物提取物2-10份、大蒜油2-10份、1,2-戊二醇1-5份、壳聚糖5-8份、一氯三嗪-β-环糊精1-8份、有机酸0.3-2份、次亚磷酸钠0.1-1份、六羟甲基三聚氰胺1-5份、改性凹凸棒土10-25份、二羟甲基脲0.3-1.5份、水200-400份。
2.根据权利要求1所述羊毛帽子专用防霉整理液，其特征在于，所述纳米硅溶胶的浓度为0.3-0.8mol/L。
3.根据权利要求1或2所述羊毛帽子专用防霉整理液，其特征在于，所述植物提取物按照以下工艺进行制备：将樟树叶和柚子皮分别洗净后破碎，然后加入乙醇水溶液中，其中，乙醇水溶液中，乙醇与水的体积比为1：2-4，乙醇水溶液的体积为樟树叶和柚子皮总体积的15-20倍，加热至回流后搅拌80-100min，然后过滤、干燥、灭菌后得到所述植物提取物。
4.根据权利要求1-3中任一项所述羊毛帽子专用防霉整理液，其特征在于，所述有机酸为冰醋酸、柠檬酸、酒石酸、苹果酸中的一种或者多种的混合物。
5.根据权利要求1-4中任一项所述羊毛帽子专用防霉整理液，其特征在于，所述改性凹凸棒土按照以下工艺进行制备：将1，2-苯丙异噻唑啉-3-酮加入水中，调节体系pH值为9-10，然后加入凹凸棒土水溶液，在室温下搅拌5-9h，转移至水热釜中水热反应5-9h，反应结束后离心、洗涤、干燥得到物料A；将物料A、钛酸四丁酯和乙醇混合均匀，加入水后搅拌3-5h，过滤后洗涤、干燥，然后在550-650℃下煅烧120-150min得到物料B；将物料B加入水中搅拌均匀，然后加入二癸基二甲基氯化铵搅拌30-50min，加入硝酸银的氨溶液，搅拌5-8h，然后过滤、洗涤、干燥，在550-650℃下煅烧100-150min得到所述改性凹凸棒土。
6.根据权利要求5所述羊毛帽子专用防霉整理液，其特征在于，1，2-苯丙异噻唑啉-3-酮、凹凸棒土的重量比为1-5：15-30。
7.根据权利要求5或6所述羊毛帽子专用防霉整理液，其特征在于，物料A、钛酸四丁酯的重量比为1：2.5-3。
8.根据权利要求5-7中任一项所述羊毛帽子专用防霉整理液，其特征在于，物料B、二癸基二甲基氯化铵、硝酸银的重量比为0.5-1.5：2-4：0.1-0.35。
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