CN106637486A - 一种具有抗疲劳功能的胶原蛋白羊绒复合面料及其制作方法 - Google Patents

一种具有抗疲劳功能的胶原蛋白羊绒复合面料及其制作方法 Download PDF

Info

Publication number
CN106637486A
CN106637486A CN201611144213.7A CN201611144213A CN106637486A CN 106637486 A CN106637486 A CN 106637486A CN 201611144213 A CN201611144213 A CN 201611144213A CN 106637486 A CN106637486 A CN 106637486A
Authority
CN
China
Prior art keywords
parts
cashmere
collagen
fiber
adds
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611144213.7A
Other languages
English (en)
Inventor
张永超
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anhui Martial Prowess Cashmere Product Co Ltd
Original Assignee
Anhui Martial Prowess Cashmere Product Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anhui Martial Prowess Cashmere Product Co Ltd filed Critical Anhui Martial Prowess Cashmere Product Co Ltd
Priority to CN201611144213.7A priority Critical patent/CN106637486A/zh
Publication of CN106637486A publication Critical patent/CN106637486A/zh
Pending legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/02—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from cellulose, cellulose derivatives, or proteins
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00—Formation of filaments, threads, or the like
    • D01D5/06—Wet spinning methods
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/10—Other agents for modifying properties
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
    • D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
    • D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
    • D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/02—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements ultrasonic or sonic; Corona discharge
    • D06M10/025—Corona discharge or low temperature plasma
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/11—Compounds containing epoxy groups or precursors thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/15—Proteins or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/10—Animal fibres
    • D06M2101/12—Keratin fibres or silk
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/40—Fibres of carbon
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/35—Abrasion, pilling or fibrillation resistance
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50—Modified hand or grip properties; Softening compositions

Abstract

本发明公开了一种具有抗疲劳功能的胶原蛋白羊绒复合面料，由下列重量份的原料制成：羊绒纤维41‑45、兔毛10‑12、锗纤维15‑17、灰竹炭纤维12‑14、纯胶原蛋白粉8.5‑9.5、乙二醇二缩水甘油醚2.5‑3.5、硬脂酸锌0.5‑0.8、咖啡渣7‑8、预糊化淀粉1.3‑1.5、碳纳米管颗粒1.8‑2.3、磷酸三甲酚酯2‑3、氨丙基三乙氧基硅烷1.1‑1.4、1‑烯丙基‑3‑甲基咪唑氯盐195‑198、适量水，本发明采用氧气低温等离子体进行预处理，接着使用乙二醇二缩水甘油醚作为交联剂将改性后的胶原蛋白嫁接到羊绒复合纤维表面，制得的羊绒复合面料做成床上用品具有抗疲劳功效。

Description

一种具有抗疲劳功能的胶原蛋白羊绒复合面料及其制作方法
技术领域
本发明涉及纺织材料技术领域，尤其涉及一种具有抗疲劳功能的胶原蛋白羊绒复合面料及其制作方法。
背景技术
羊绒纤维是一种天然珍贵纺织材料，近年来，羊绒服饰制品在激烈的服装市场竞争中以其手感舒适、色泽独特、质地轻薄、保暖透气性好等特点越来越受到消费者青睐。但随着生态环境对生活用品绿色友好的要求，健康、舒适、环保、安全已经成为人们的消费主题。因此，利用对环境污染小或无污染的加工技术，开发具有亲肤性和润肤性等特点的、可提升其产品附加值的高档羊绒面料是值得研究的方向。
胶原蛋白具有低抗原性、优越的生物相容性和生物降解性，在生物医学材料、药物输送载体、组织工程、化妆品、食品等许多领域具有很重要地位。尤其是近几年，运用胶原蛋白的生物亲和性在纺织材料改性、复合等方面渐成热点。胶原蛋白可给予皮肤层所必需的养分，使皮肤中的胶原蛋白活性加强，保持角质层水分以及纤维结构的完整性，改善皮肤细胞生存环境和增强皮肤组织的生理循环。一旦胶原蛋白可固定于羊绒纤维，则可能会产生滋润皮肤、延缓衰老和美白等多种保健功效，《应用等离子体-交联剂复合技术在羊绒纤维表面固定胶原蛋白》一文采用氧气低温等离子体预处理羊绒纤维，使用乙二醇二缩水甘油醚作为交联剂将胶原蛋白嫁接到羊绒表面，结果表明胶原改性羊绒纤维的吸放湿性及染色性均优于未处理纤维。另外，胶原蛋白的固定对纤维的断裂强力和断裂伸长均有一定的改善作用。
文中仅仅改善了羊绒的吸放湿性及染色性，然而羊绒产量少价格昂贵，纯羊绒如果储存不当会因环境的湿度而受潮霉变甚至生螨，由于羊绒自身的强度较差，洗涤过多易粉碎、结团、起球，尤其是寒冷的北方干燥，羊绒制品还易产生静电等。因而需要开发出具有多功能的新型胶原蛋白羊绒复合面料。
发明内容
本发明目的就是为了弥补已有技术的缺陷，提供一种具有抗疲劳功能的胶原蛋白羊绒复合面料及其制作方法。
本发明是通过以下技术方案实现的：
一种具有抗疲劳功能的胶原蛋白羊绒复合面料，由下列重量份的原料制成：羊绒纤维41-45、兔毛10-12、锗纤维15-17、灰竹炭纤维12-14、纯胶原蛋白粉8.5-9.5、乙二醇二缩水甘油醚2.5-3.5、硬脂酸锌0.5-0.8、咖啡渣7-8、预糊化淀粉1.3-1.5、碳纳米管颗粒1.8-2.3、磷酸三甲酚酯2-3、氨丙基三乙氧基硅烷1.1-1.4、1-烯丙基-3-甲基咪唑氯盐195-198、适量水。
所述的一种具有抗疲劳功能的胶原蛋白羊绒复合面料的制作方法，包括以下步骤：
（1）将碳纳米管颗粒于450-480℃高温煅烧20-30分钟，冷却至100-120℃恒温加入氨丙基三乙氧基硅烷搅拌10-15分钟，真空干燥得改性碳纳米管颗粒；
（2）将咖啡渣烘干研磨过100目筛，喷洒质量浓度为4-8%的盐酸溶液搅拌混匀，于60-80℃恒温水浴中磁力搅拌2-3小时，洗涤至中性真空干燥，加入磷酸三甲酚酯超声研磨1-3小时，烘干得改性咖啡渣超细粉末；
（3）将1-烯丙基-3-甲基咪唑氯盐投入反应釜中加入羊绒纤维、兔毛、锗纤维、灰竹炭纤维研磨20-40分钟，加热到100-120℃，加入步骤（2）物料、预糊化淀粉搅拌反应50-70分钟，纺丝，烘干放入反应腔，采用氧气低温等离子体，在放电压强150Pa、功率120W处理1分钟，得等离子体预处理羊绒复合纤维；
（4）往纯胶原蛋白粉中加入适量水放入85-95℃恒温水浴中不断搅拌至全部溶解，加入硬脂酸锌、步骤（1）物料超声分散30-40分钟得改性胶原蛋白整理液；
（5）将步骤（3）物料投入步骤（4）整理液中，保持温度加水调节浴比1∶50，加入乙二醇二缩水甘油醚搅拌放置10-15分钟，降温至25℃反应24小时，取出，用蒸馏水冲洗干净，室温晾干，出料。
本发明的优点是：本发明优化配方改进生产工艺，将兔毛、锗纤维、灰竹炭纤维和羊绒纤维复合，以改性咖啡渣超细粉末为粘结剂经湿法纺丝制得羊绒复合纤维，不仅缓解由于环境恶化带来的羊绒纤维逐年减少的问题还克服了纯羊绒制品起球、强度低易霉变生螨等缺陷，最后将制得的羊绒复合纤维采用氧气低温等离子体进行预处理，对纤维内部的损伤较小对环境无污染，等离子体能够刻蚀羊绒表面的鳞片，使鳞片层变薄，减弱表面鳞片的“壁垒”作用，从而增强其吸湿放湿性，改善羊绒在后续染整等过程中的亲水性，接着使用乙二醇二缩水甘油醚作为交联剂将改性后的胶原蛋白嫁接到羊绒表面，因胶原蛋白亦属于保湿性能良好的蛋白质，交联后改善了面料的亲肤性和美容保健性能，制得的羊绒复合面料做成床上用品具有抗疲劳功效，显著提高睡眠质量。
具体实施方式
一种具有抗疲劳功能的胶原蛋白羊绒复合面料，由下列重量份的原料制成：羊绒纤维41、兔毛10、锗纤维15、灰竹炭纤维12、纯胶原蛋白粉8.5、乙二醇二缩水甘油醚2.5、硬脂酸锌0.5、咖啡渣7、预糊化淀粉1.3、碳纳米管颗粒1.8、磷酸三甲酚酯2、氨丙基三乙氧基硅烷1.1、1-烯丙基-3-甲基咪唑氯盐195、适量水。
所述的一种具有抗疲劳功能的胶原蛋白羊绒复合面料的制作方法，包括以下步骤：
（1）将碳纳米管颗粒于450-480℃高温煅烧20-30分钟，冷却至100-120℃恒温加入氨丙基三乙氧基硅烷搅拌10-15分钟，真空干燥得改性碳纳米管颗粒；
（2）将咖啡渣烘干研磨过100目筛，喷洒质量浓度为4-8%的盐酸溶液搅拌混匀，于60-80℃恒温水浴中磁力搅拌2-3小时，洗涤至中性真空干燥，加入磷酸三甲酚酯超声研磨1-3小时，烘干得改性咖啡渣超细粉末；
（3）将1-烯丙基-3-甲基咪唑氯盐投入反应釜中加入羊绒纤维、兔毛、锗纤维、灰竹炭纤维研磨20-40分钟，加热到100-120℃，加入步骤（2）物料、预糊化淀粉搅拌反应50-70分钟，纺丝，烘干放入反应腔，采用氧气低温等离子体，在放电压强150Pa、功率120W处理1分钟，得等离子体预处理羊绒复合纤维；
（4）往纯胶原蛋白粉中加入适量水放入85-95℃恒温水浴中不断搅拌至全部溶解，加入硬脂酸锌、步骤（1）物料超声分散30-40分钟得改性胶原蛋白整理液；
（5）将步骤（3）物料投入步骤（4）整理液中，保持温度加水调节浴比1∶50，加入乙二醇二缩水甘油醚搅拌放置10-15分钟，降温至25℃反应24小时，取出，用蒸馏水冲洗干净，室温晾干，出料。
利用本发明制得的胶原蛋白羊绒复合面料对金黄色葡萄球菌的抑菌率可达到95.781%；平均断裂强力为8.91cN；染色上染百分率可以达到98%。

Claims (2)

1.一种具有抗疲劳功能的胶原蛋白羊绒复合面料，其特征在于，由下列重量份的原料制成：羊绒纤维41-45、兔毛10-12、锗纤维15-17、灰竹炭纤维12-14、纯胶原蛋白粉8.5-9.5、乙二醇二缩水甘油醚2.5-3.5、硬脂酸锌0.5-0.8、咖啡渣7-8、预糊化淀粉1.3-1.5、碳纳米管颗粒1.8-2.3、磷酸三甲酚酯2-3、氨丙基三乙氧基硅烷1.1-1.4、1-烯丙基-3-甲基咪唑氯盐195-198、适量水。
2.根据权利要求1所述的一种具有抗疲劳功能的胶原蛋白羊绒复合面料的制作方法，其特征在于包括以下步骤：
（1）将碳纳米管颗粒于450-480℃高温煅烧20-30分钟，冷却至100-120℃恒温加入氨丙基三乙氧基硅烷搅拌10-15分钟，真空干燥得改性碳纳米管颗粒；
（2）将咖啡渣烘干研磨过100目筛，喷洒质量浓度为4-8%的盐酸溶液搅拌混匀，于60-80℃恒温水浴中磁力搅拌2-3小时，洗涤至中性真空干燥，加入磷酸三甲酚酯超声研磨1-3小时，烘干得改性咖啡渣超细粉末；
（3）将1-烯丙基-3-甲基咪唑氯盐投入反应釜中加入羊绒纤维、兔毛、锗纤维、灰竹炭纤维研磨20-40分钟，加热到100-120℃，加入步骤（2）物料、预糊化淀粉搅拌反应50-70分钟，纺丝，烘干放入反应腔，采用氧气低温等离子体，在放电压强150Pa、功率120W处理1分钟，得等离子体预处理羊绒复合纤维；
（4）往纯胶原蛋白粉中加入适量水放入85-95℃恒温水浴中不断搅拌至全部溶解，加入硬脂酸锌、步骤（1）物料超声分散30-40分钟得改性胶原蛋白整理液；
（5）将步骤（3）物料投入步骤（4）整理液中，保持温度加水调节浴比1∶50，加入乙二醇二缩水甘油醚搅拌放置10-15分钟，降温至25℃反应24小时，取出，用蒸馏水冲洗干净，室温晾干，出料。
CN201611144213.7A 2016-12-13 2016-12-13 一种具有抗疲劳功能的胶原蛋白羊绒复合面料及其制作方法 Pending CN106637486A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611144213.7A CN106637486A (zh) 2016-12-13 2016-12-13 一种具有抗疲劳功能的胶原蛋白羊绒复合面料及其制作方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611144213.7A CN106637486A (zh) 2016-12-13 2016-12-13 一种具有抗疲劳功能的胶原蛋白羊绒复合面料及其制作方法

Publications (1)

Publication Number Publication Date
CN106637486A true CN106637486A (zh) 2017-05-10

Family

ID=58824939

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201611144213.7A Pending CN106637486A (zh) 2016-12-13 2016-12-13 一种具有抗疲劳功能的胶原蛋白羊绒复合面料及其制作方法

Country Status (1)

Country Link
CN (1) CN106637486A (zh)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108505336A (zh) * 2018-04-04 2018-09-07 苏州经贸职业技术学院 群众体育户外服装面料
CN109400700A (zh) * 2018-11-06 2019-03-01 安徽怡发生物科技有限公司 一种易吸收的胶原蛋白低聚肽的制备方法
CN109440258A (zh) * 2018-11-08 2019-03-08 深圳市森诚惠实业有限公司 一种基于咖啡渣锗纤维毛巾及制备工艺
CN117488540A (zh) * 2023-11-10 2024-02-02 潮州市明旦婚纱礼服有限公司 一种透气亲肤面料

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101134852A (zh) * 2007-10-15 2008-03-05 江苏河海纳米科技股份有限公司 一种无机粉体有机表面改性的方法
CN104213415A (zh) * 2014-08-22 2014-12-17 浙江全美实业有限公司 一种抗起球羊绒衫的生产方法
CN104862818A (zh) * 2015-06-09 2015-08-26 江南大学 一种角蛋白复合纤维的制备方法
CN104911737A (zh) * 2015-05-20 2015-09-16 铜陵宏正网络科技有限公司 一种纳米抗菌防虫蛀羊绒复合纤维及其制作方法
CN105239413A (zh) * 2015-11-12 2016-01-13 长兴千尺度纺织品有限公司 一种生态助剂在羊绒衫整理上的应用
CN105839409A (zh) * 2016-03-25 2016-08-10 赤峰昭乌达羊绒制品有限责任公司 一种羊绒针织物的生态型抗起毛起球整理方法

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101134852A (zh) * 2007-10-15 2008-03-05 江苏河海纳米科技股份有限公司 一种无机粉体有机表面改性的方法
CN104213415A (zh) * 2014-08-22 2014-12-17 浙江全美实业有限公司 一种抗起球羊绒衫的生产方法
CN104911737A (zh) * 2015-05-20 2015-09-16 铜陵宏正网络科技有限公司 一种纳米抗菌防虫蛀羊绒复合纤维及其制作方法
CN104862818A (zh) * 2015-06-09 2015-08-26 江南大学 一种角蛋白复合纤维的制备方法
CN105239413A (zh) * 2015-11-12 2016-01-13 长兴千尺度纺织品有限公司 一种生态助剂在羊绒衫整理上的应用
CN105839409A (zh) * 2016-03-25 2016-08-10 赤峰昭乌达羊绒制品有限责任公司 一种羊绒针织物的生态型抗起毛起球整理方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
康红波: "应用等离子体-交联剂复合技术在羊绒纤维表面固定胶原蛋白", 《毛纺科技》 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108505336A (zh) * 2018-04-04 2018-09-07 苏州经贸职业技术学院 群众体育户外服装面料
CN109400700A (zh) * 2018-11-06 2019-03-01 安徽怡发生物科技有限公司 一种易吸收的胶原蛋白低聚肽的制备方法
CN109440258A (zh) * 2018-11-08 2019-03-08 深圳市森诚惠实业有限公司 一种基于咖啡渣锗纤维毛巾及制备工艺
CN117488540A (zh) * 2023-11-10 2024-02-02 潮州市明旦婚纱礼服有限公司 一种透气亲肤面料

Similar Documents

Publication Publication Date Title
CN106637486A (zh) 一种具有抗疲劳功能的胶原蛋白羊绒复合面料及其制作方法
CN107059156B (zh) 一种远红外聚酯纤维
CN107009712A (zh) 一种环保保温面料
CN104695227A (zh) 一种远红外棉纤维的生产工艺
CN104947223A (zh) 一种低损伤绿色生态抑菌羽绒纤维及其制作方法
CN106835703A (zh) 一种新的抗起球天然植物抗菌羊绒复合面料及其制作方法
CN106637909A (zh) 一种热稳定性保暖胶原蛋白羊绒复合面料及其制作方法
CN108018613A (zh) 光杀菌、自清洁、远红外复合纳米粒子及其多功能纤维的制备方法
CN102704142B (zh) 锆纳米复合功能天丝面料及其织造、染整工艺与应用
CN108978191B (zh) 一种抗菌远红外保健腈纶纤维及其制备方法和应用
CN106637970A (zh) 一种防电磁辐射的胶原蛋白羊绒复合面料及其制作方法
CN106757442A (zh) 一种防油污胶原蛋白羊绒复合面料及其制作方法
CN106637974A (zh) 一种悬垂性好的胶原蛋白羊绒复合面料及其制作方法
CN106811971A (zh) 一种具有抗疲劳性的天然植物抗菌羊绒复合面料及其制作方法
CN106637910A (zh) 一种抗静电胶原蛋白羊绒复合面料及其制作方法
CN106811969A (zh) 一种抗静电天然植物抗菌羊绒复合面料及其制作方法
CN106637972A (zh) 一种抗氧化亲肤胶原蛋白羊绒复合面料及其制作方法
CN105167479B (zh) 一种复合毛毯
CN106637971A (zh) 一种阻燃防起球的胶原蛋白羊绒复合面料及其制作方法
CN106637973A (zh) 一种防虫蛀的胶原蛋白羊绒复合面料及其制作方法
CN106521954A (zh) 一种具有抗菌防辐射功能的胶原蛋白羊绒复合面料及其制作方法
CN104928780A (zh) 一种蓄热保暖生态抑菌羽绒纤维及其制作方法
CN104947221A (zh) 一种可纺织性生态抑菌羽绒纤维及其制作方法
CN104947232A (zh) 一种耐水洗防辐射生态抑菌羽绒纤维及其制作方法
CN106948021A (zh) 一种多功能蚕丝纤维的制备方法

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20170510