CN107059383B - 一种全棉织物的涂料染色生产工艺 - Google Patents
一种全棉织物的涂料染色生产工艺 Download PDFInfo
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Abstract
本发明公开了一种全棉织物的涂料染色生产工艺,包括如下步骤:S1、预处理,将全棉织物依次进行煮漂、酶洗处理;S2、改性处理,将全棉织物浸轧整理液中,所述整理液包括:阳离子改性剂5‑25g/L、固体碱2‑6g/L;S3、染色,将全棉织物浸轧染液中,所述染液包括:涂料色浆10‑60g/L、pH调节剂1‑10g/L、表面活性剂3‑5g/L、黏合剂10‑40g/L;S4、后整理,将全棉织物先水洗,再进行柔软、阻燃整理。本发明所述全棉织物的涂料染色生产工艺,其不仅显著改善了织物的手感、弹性等性能,而且上染率高、色牢度强、染色均匀且色泽丰满。
Description
技术领域
本发明涉及染色加工技术领域,尤其涉及一种全棉织物的涂料染色生产工艺。
背景技术
采用涂料对织物染色具有环境污染小、工艺简单、节能省水等优点,在印染行业中得到广应用。随着印染加工技术的进步,对全棉织物的涂料轧染加工虽然有了较大的发展,但是经过一般轧染处理的全棉织物的手感往往还是较硬,弹性和延展性较差,样式单调,人们在穿着这种织物制作的服装过程中,会有紧巴、伸缩不自由的感觉,而且对一般的全棉织物的印染性能较差,上染率低且得色浅。
发明内容
基于背景技术中存在的问题,本发明提出了一种全棉织物的涂料染色生产工艺,其不仅显著改善了织物的手感、弹性等性能,而且上染率高、色牢度强、染色均匀且色泽丰满。
本发明提出了一种全棉织物的涂料染色生产工艺,包括如下步骤:
S1、预处理,将全棉织物常温下浸轧工作液中,二浸二轧,轧余率为60-90%,所述工作液包括:烧碱5-10g/L、双氧水3-5g/L、渗透剂0.3-0.5g/L、精炼剂0.5-1g/L、螯合分散剂1-5g/L,60-80℃热水洗涤后浸入酶处理液中,在30-60℃下处理10-30min,所述酶处理液包括:淀粉酶2-5g/L、果胶酶0-2g/L、纤维素酶0.01-1g/L,80-100℃热水洗涤后烘干;
S2、改性处理,将经S1预处理后的全棉织物浸轧整理液中,二浸二轧,浸轧温度为70-80℃,轧余率为90-100%,在80-100℃下烘焙1-5min,40-50℃水洗后烘干,所述整理液包括:阳离子改性剂5-25g/L、固体碱2-6g/L;
S3、染色,将经S2改性处理后的全棉织物浸轧染液中,二浸二轧,轧余率为60-80%,所述染液包括:涂料色浆10-60g/L、pH调节剂1-10g/L、表面活性剂3-5g/L、黏合剂10-40g/L,再将浸轧后的织物烘干,烘干温度为80-100℃,时间为5-15min,接着汽蒸固色,汽蒸温度为100-105℃,时间为1-10min;
S4、后整理,将经S3染色后的全棉织物先水洗,再进行柔软、阻燃整理。
优选地,S2中,所述阳离子改性剂选自环氧丙基三甲基氯化铵、环氧丙基三乙基氯化铵、聚酰胺多胺环氧氯丙烷、甲基丙烯酸环氧丙酯-季铵盐单体共聚物、氯代三嗪型季铵盐化合物中的一种或者多种的组合。
优选地,S3中,制备所述黏合剂的方法包括:将单体聚氨酯丙烯酸酯PUA、丙烯酸乙酯、丙烯酸丁酯、1,3-丁二醇二甲基丙烯酸酯和引发剂AIBN混匀后,加入乳化剂苯乙烯-马来酸酐共聚物钠盐SMA和平平加O,在4000-6000r/min的速率下高速搅拌10-20min,升温至80-90℃后搅拌反应2-4h,过滤,洗涤,得到所述黏合剂;
优选地,聚氨酯丙烯酸酯PUA、丙烯酸乙酯、丙烯酸丁酯、1,3-丁二醇二甲基丙烯酸酯、苯乙烯-马来酸酐共聚物钠盐SMA、平平加O的重量比为10:1-2:1-3:1-3:0.1-1:0.01-0.3。
优选地,所述pH调节剂选自氢氧化钾、氢氧化钠、碳酸钠、碳酸氢钠、三乙醇胺的水溶液或者氨水中的一种或者多种的组合;更优选地,pH调节剂调节染液的pH值为7-11。
优选地,S4中,柔软整理采用的柔软处理液包括:聚醚氨基改性硅油50-70g/L、抗滑移剂5-15g/L、抗静电剂5-10g/L,柔软整理中,调节pH值为5.5-6,工作温度为100-120℃,车速为40-60m/min。
优选地,S4中,阻燃整理采用的整理液按重量份包括:聚丙烯基二甲基磷酸酯100份、KH-570 1-3份、蒙脱土3-8份、异丙醇5-20份、水4-8份,阻燃整理中,将阻燃整理液喷涂在全棉织物的表面,阻燃剂整理液的用量为全棉织物重量的5-10%,在60-80℃下预烘0.5-1h后,再在110-130℃焙烘1-2h,水洗,晾干。
优选地,所述聚丙烯基二甲基磷酸酯的制备方法包括:按重量份将10份三氯氧磷加入50-70份乙醚中搅拌均匀,降温至0-5℃后加入4-5份丙烯醇和8-10份三乙胺搅拌反应5-8h,再加入5-7份甲醇和4-12份三乙胺搅拌反应2-4h,抽滤,减压蒸馏,得到丙烯基二甲基磷酸酯;将丙烯基二甲基磷酸酯加入20-30份水中搅拌均匀,升温至85-105℃后加入1-3份过硫酸钾和1-3份司班-60搅拌聚合,反应1-2h后冷却至室温,抽滤,洗涤,干燥,得到所述聚丙烯基二甲基磷酸酯。
优选地,S4中,还包括将后整理后的全棉织物进行预缩;预缩时,将所述织物置于预缩整理机内进行预缩处理,预缩整理机的车速为30-70m/min,预缩率为5-10%。
本发明中提出的一种全棉织物的涂料染色生产工艺,首先在对织物进行预处理中采用碱/氧煮漂液进行处理,对全棉织物的色素、麻皮的去除效果较为明显,使得布面的光洁度、白度明显提高,并且织物整体手感较碱处理更柔软,同时考虑到全棉织物的特性和需要的效果,在退浆操作中,选用酶退浆代替碱退浆进行处理,由于选用的酶处理液只对淀粉浆进行分解,经热洗后可以对面料进行了充分润湿,有利于提高织物的吸水性能和后续处理过程,使最终得到的面料清晰飘逸,且手感柔软,穿着舒服;然后,在对织物进行改性处理中,通过采用含有反应性基团的阳离子改性剂对纤维进行预处理,通过在棉纤维表面引入阳离子基团,可有效提高棉纤维对涂料的吸附能力,达到提高颜色深度的目的;接着,在对织物进行涂料染色过程中,通过在涂料染液中加入表面活性剂、pH调节剂和黏合剂,混合均匀后,直接对织物进行浸轧,然后进行烘干和固色处理,得到涂料染色产品,其中为了解决现有水性聚丙烯酸酯类黏合剂存在的热黏冷脆、湿摩擦牢度和手感较差等缺点,通过采用聚氨酯丙烯酸酯等单体原料进行丙烯酸基共聚物的制备得到黏合剂,由于聚氨酯基团的引入,相比于传统的水性聚丙烯酸酯类黏合剂,加入该黏合剂的染色产品各项牢度均有较明显的提高,干、湿摩擦牢度可达4-5级,刷洗牢度、皂洗牢度均可达4级,用于涂料染色时,织物手感柔软、光洁滑爽、弹性好;与此同时,通过以苯乙烯-马来酸酐共聚物钠盐SMA等作为乳化剂,由此制备的黏合剂可以与经过阳离子改性的纤维进行良好粘附,进一步提高了染色产品的各项牢度;最后,在对织物进行后整理中,先对面料进行柔软整理,赋予面料良好的弹性效果以及丰满度和持久性,再进行阻燃整理,通过选用聚丙烯基二甲基磷酸酯、蒙脱土作为阻燃剂,使得织物阻燃效果更好,且无环境污染。
综合上述,本发明所述的全棉织物的涂料染色生产工艺,无论是预处理还是后续染色,都避免了对织物纤维造成损伤,因此,不仅显著改善了织物的手感、弹性等性能,而且上染率高、色牢度强、染色均匀且色泽丰满。
具体实施方式
实施例1
本实施例中,一种全棉织物的涂料染色生产工艺,包括如下步骤:
S1、预处理,将全棉织物常温下浸轧工作液中,二浸二轧,轧余率为75%,所述工作液包括:烧碱7g/L、双氧水4g/L、渗透剂0.4g/L、精炼剂0.7g/L、螯合分散剂3g/L,70℃热水洗涤后浸入酶处理液中,在45℃下处理20min,所述酶处理液包括:淀粉酶3g/L、果胶酶1g/L、纤维素酶0.5g/L,90℃热水洗涤后烘干;
S2、改性处理,将经S1预处理后的全棉织物浸轧整理液中,二浸二轧,浸轧温度为75℃,轧余率为95%,在90℃下烘焙3min,45℃水洗后烘干,所述整理液包括:阳离子改性剂15g/L、固体碱4g/L;
S3、染色,将经S2改性处理后的全棉织物浸轧染液中,二浸二轧,轧余率为70%,所述染液包括:涂料色浆35g/L、pH调节剂5g/L、表面活性剂4g/L、黏合剂25g/L,再将浸轧后的织物烘干,烘干温度为90℃,时间为10min,接着汽蒸固色,汽蒸温度为102℃,时间为5min;
S4、后整理,将经S3染色后的全棉织物先水洗,再进行柔软、阻燃整理。
实施例2
本实施例中,一种全棉织物的涂料染色生产工艺,包括如下步骤:
S1、预处理,将全棉织物常温下浸轧工作液中,二浸二轧,轧余率为60%,所述工作液包括:烧碱10g/L、双氧水3g/L、渗透剂0.5g/L、精炼剂0.5g/L、螯合分散剂5g/L,60℃热水洗涤后浸入酶处理液中,在60℃下处理10min,所述酶处理液包括:淀粉酶5g/L、纤维素酶1g/L,80℃热水洗涤后烘干;
S2、改性处理,将经S1预处理后的全棉织物浸轧整理液中,二浸二轧,浸轧温度为70℃,轧余率为100%,在80℃下烘焙5min,40℃水洗后烘干,所述整理液包括:环氧丙基三甲基氯化铵25g/L、固体碱2g/L;
S3、染色,将经S2改性处理后的全棉织物浸轧染液中,二浸二轧,轧余率为60%,所述染液包括:涂料色浆60g/L、pH调节剂1g/L、表面活性剂5g/L、黏合剂10g/L,再将浸轧后的织物烘干,烘干温度为100℃,时间为5min,接着汽蒸固色,汽蒸温度为105℃,时间为1min;其中制备所述黏合剂的方法包括:将单体聚氨酯丙烯酸酯PUA、丙烯酸乙酯、丙烯酸丁酯、1,3-丁二醇二甲基丙烯酸酯和引发剂AIBN混匀后,加入乳化剂苯乙烯-马来酸酐共聚物钠盐SMA和平平加O,在4000r/min的速率下高速搅拌20min,升温至80℃后搅拌反应4h,过滤,洗涤,得到所述黏合剂,聚氨酯丙烯酸酯PUA、丙烯酸乙酯、丙烯酸丁酯、1,3-丁二醇二甲基丙烯酸酯、苯乙烯-马来酸酐共聚物钠盐SMA、平平加O的重量比为10:1:3:1:1:0.01;所述pH调节剂为氢氧化钾和氢氧化钠的水溶液,pH调节剂调节染液的pH值为11;
S4、后整理,将经S3染色后的全棉织物先40℃水洗20min,再进行柔软,柔软整理采用的柔软处理液包括:聚醚氨基改性硅油50g/L、抗滑移剂15g/L、抗静电剂5g/L,柔软整理中,调节pH值为6,工作温度为100℃,车速为60m/min;接着进行阻燃整理,阻燃整理采用的整理液按重量份包括:聚丙烯基二甲基磷酸酯100份、KH-570 1份、蒙脱土8份、异丙醇5份、水8份,阻燃整理中,将阻燃整理液喷涂在全棉织物的表面,阻燃剂整理液的用量为全棉织物重量的5%,在80℃下预烘0.5h后,再在130℃焙烘1h,水洗,晾干;其中所述聚丙烯基二甲基磷酸酯的制备方法包括:按重量份将10份三氯氧磷加入50份乙醚中搅拌均匀,降温至5℃后加入4份丙烯醇和10份三乙胺搅拌反应5h,再加入7份甲醇和4份三乙胺搅拌反应4h,抽滤,减压蒸馏,得到丙烯基二甲基磷酸酯;将丙烯基二甲基磷酸酯加入20份水中搅拌均匀,升温至105℃后加入1份过硫酸钾和3份司班-60搅拌聚合,反应1h后冷却至室温,抽滤,洗涤,干燥,得到所述聚丙烯基二甲基磷酸酯;再进行预缩,预缩时,将所述织物置于预缩整理机内进行预缩处理,预缩整理机的车速为70m/min,预缩率为5%。
实施例3
本实施例中,一种全棉织物的涂料染色生产工艺,包括如下步骤:
S1、预处理,将全棉织物常温下浸轧工作液中,二浸二轧,轧余率为90%,所述工作液包括:烧碱5g/L、双氧水5g/L、渗透剂0.3g/L、精炼剂1g/L、螯合分散剂1g/L,80℃热水洗涤后浸入酶处理液中,在30℃下处理30min,所述酶处理液包括:淀粉酶2g/L、果胶酶2g/L、纤维素酶0.01g/L,100℃热水洗涤后烘干;
S2、改性处理,将经S1预处理后的全棉织物浸轧整理液中,二浸二轧,浸轧温度为80℃,轧余率为90%,在100℃下烘焙1min,50℃水洗后烘干,所述整理液包括:环氧丙基三乙基氯化铵5g/L、固体碱6g/L;
S3、染色,将经S2改性处理后的全棉织物浸轧染液中,二浸二轧,轧余率为80%,所述染液包括:涂料色浆10g/L、pH调节剂10g/L、表面活性剂3g/L、黏合剂40g/L,再将浸轧后的织物烘干,烘干温度为80℃,时间为15min,接着汽蒸固色,汽蒸温度为100℃,时间为10min;其中制备所述黏合剂的方法包括:将单体聚氨酯丙烯酸酯PUA、丙烯酸乙酯、丙烯酸丁酯、1,3-丁二醇二甲基丙烯酸酯和引发剂AIBN混匀后,加入乳化剂苯乙烯-马来酸酐共聚物钠盐SMA和平平加O,在6000r/min的速率下高速搅拌10min,升温至90℃后搅拌反应2h,过滤,洗涤,得到所述黏合剂,聚氨酯丙烯酸酯PUA、丙烯酸乙酯、丙烯酸丁酯、1,3-丁二醇二甲基丙烯酸酯、苯乙烯-马来酸酐共聚物钠盐SMA、平平加O的重量比为10:2:1:3:0.1:0.3;所述pH调节剂为碳酸钠、碳酸氢钠和三乙醇胺的水溶液,pH调节剂调节染液的pH值为7;
S4、后整理,将经S3染色后的全棉织物先50℃水洗5min,再进行柔软,柔软整理采用的柔软处理液包括:聚醚氨基改性硅油70g/L、抗滑移剂5g/L、抗静电剂10g/L,柔软整理中,调节pH值为5.5,工作温度为120℃,车速为40m/min;接着进行阻燃整理,阻燃整理采用的整理液按重量份包括:聚丙烯基二甲基磷酸酯100份、KH-570 3份、蒙脱土3份、异丙醇20份、水4份,阻燃整理中,将阻燃整理液喷涂在全棉织物的表面,阻燃剂整理液的用量为全棉织物重量的10%,在60℃下预烘1h后,再在110℃焙烘2h,水洗,晾干;其中所述聚丙烯基二甲基磷酸酯的制备方法包括:按重量份将10份三氯氧磷加入70份乙醚中搅拌均匀,降温至0℃后加入5份丙烯醇和8份三乙胺搅拌反应8h,再加入5份甲醇和12份三乙胺搅拌反应2h,抽滤,减压蒸馏,得到丙烯基二甲基磷酸酯;将丙烯基二甲基磷酸酯加入30份水中搅拌均匀,升温至85℃后加入3份过硫酸钾和1份司班-60搅拌聚合,反应2h后冷却至室温,抽滤,洗涤,干燥,得到所述聚丙烯基二甲基磷酸酯;再进行预缩,预缩时,将所述织物置于预缩整理机内进行预缩处理,预缩整理机的车速为30m/min,预缩率为10%。
实施例4
本实施例中,一种全棉织物的涂料染色生产工艺,包括如下步骤:
S1、预处理,将全棉织物常温下浸轧工作液中,二浸二轧,轧余率为80%,所述工作液包括:烧碱8g/L、双氧水3.5g/L、渗透剂0.4g/L、精炼剂0.8g/L、螯合分散剂4g/L,75℃热水洗涤后浸入酶处理液中,在50℃下处理15min,所述酶处理液包括:淀粉酶4g/L、果胶酶1.5g/L、纤维素酶0.05g/L,95℃热水洗涤后烘干;
S2、改性处理,将经S1预处理后的全棉织物浸轧整理液中,二浸二轧,浸轧温度为78℃,轧余率为92%,在85℃下烘焙4min,48℃水洗后烘干,所述整理液包括:阳离子改性剂10g/L、固体碱3g/L;其中所述阳离子改性剂为聚酰胺多胺环氧氯丙烷、甲基丙烯酸环氧丙酯-季铵盐单体共聚物和氯代三嗪型季铵盐化合物;
S3、染色,将经S2改性处理后的全棉织物浸轧染液中,二浸二轧,轧余率为65%,所述染液包括:涂料色浆40g/L、pH调节剂6g/L、表面活性剂4g/L、黏合剂30g/L,再将浸轧后的织物烘干,烘干温度为85℃,时间为12min,接着汽蒸固色,汽蒸温度为103℃,时间为6min;其中制备所述黏合剂的方法包括:将单体聚氨酯丙烯酸酯PUA、丙烯酸乙酯、丙烯酸丁酯、1,3-丁二醇二甲基丙烯酸酯和引发剂AIBN混匀后,加入乳化剂苯乙烯-马来酸酐共聚物钠盐SMA和平平加O,在5000r/min的速率下高速搅拌15min,升温至85℃后搅拌反应3h,过滤,洗涤,得到所述黏合剂,聚氨酯丙烯酸酯PUA、丙烯酸乙酯、丙烯酸丁酯、1,3-丁二醇二甲基丙烯酸酯、苯乙烯-马来酸酐共聚物钠盐SMA、平平加O的重量比为10:1.5:2:2:0.5:0.1;所述pH调节剂为氨水,pH调节剂调节染液的pH值为8;
S4、后整理,将经S3染色后的全棉织物先45℃水洗15min,再进行柔软,柔软整理采用的柔软处理液包括:聚醚氨基改性硅油60g/L、抗滑移剂10g/L、抗静电剂7g/L,柔软整理中,调节pH值为5.8,工作温度为110℃,车速为50m/min;接着进行阻燃整理,阻燃整理采用的整理液按重量份包括:聚丙烯基二甲基磷酸酯100份、KH-570 2份、蒙脱土5份、异丙醇10份、水6份,阻燃整理中,将阻燃整理液喷涂在全棉织物的表面,阻燃剂整理液的用量为全棉织物重量的7%,在70℃下预烘0.8h后,再在120℃焙烘1.5h,水洗,晾干;其中所述聚丙烯基二甲基磷酸酯的制备方法包括:按重量份将10份三氯氧磷加入60份乙醚中搅拌均匀,降温至2℃后加入4.5份丙烯醇和9份三乙胺搅拌反应6h,再加入6份甲醇和8份三乙胺搅拌反应3h,抽滤,减压蒸馏,得到丙烯基二甲基磷酸酯;将丙烯基二甲基磷酸酯加入25份水中搅拌均匀,升温至95℃后加入2份过硫酸钾和2份司班-60搅拌聚合,反应1.5h后冷却至室温,抽滤,洗涤,干燥,得到所述聚丙烯基二甲基磷酸酯;再进行预缩,预缩时,将所述织物置于预缩整理机内进行预缩处理,预缩整理机的车速为50m/min,预缩率为7%。
本发明中提出的一种全棉织物的涂料染色生产工艺,首先在对织物进行预处理中采用碱/氧煮漂液进行处理,对全棉织物的色素、麻皮的去除效果较为明显,使得布面的光洁度、白度明显提高,并且织物整体手感较碱处理更柔软,同时考虑到全棉织物的特性和需要的效果,在退浆操作中,选用酶退浆代替碱退浆进行处理,由于选用的酶处理液只对淀粉浆进行分解,经热洗后可以对面料进行了充分润湿,有利于提高织物的吸水性能和后续处理过程,使最终得到的面料清晰飘逸,且手感柔软,穿着舒服;然后,在对织物进行改性处理中,通过采用含有反应性基团的阳离子改性剂对纤维进行预处理,通过在棉纤维表面引入阳离子基团,可有效提高棉纤维对涂料的吸附能力,达到提高颜色深度的目的;接着,在对织物进行涂料染色过程中,通过在涂料染液中加入表面活性剂、pH调节剂和黏合剂,混合均匀后,直接对织物进行浸轧,然后进行烘干和固色处理,得到涂料染色产品,其中为了解决现有水性聚丙烯酸酯类黏合剂存在的热黏冷脆、湿摩擦牢度和手感较差等缺点,通过采用聚氨酯丙烯酸酯等单体原料进行丙烯酸基共聚物的制备得到黏合剂,由于聚氨酯基团的引入,相比于传统的水性聚丙烯酸酯类黏合剂,加入该黏合剂的染色产品各项牢度均有较明显的提高,干、湿摩擦牢度可达4-5级,刷洗牢度、皂洗牢度均可达4级,用于涂料染色时,织物手感柔软、光洁滑爽、弹性好;与此同时,通过以苯乙烯-马来酸酐共聚物钠盐SMA等作为乳化剂,由此制备的黏合剂可以与经过阳离子改性的纤维进行良好粘附,进一步提高了染色产品的各项牢度;最后,在对织物进行后整理中,先对面料进行柔软整理,赋予面料良好的弹性效果以及丰满度和持久性,再进行阻燃整理,通过选用聚丙烯基二甲基磷酸酯、蒙脱土作为阻燃剂,使得织物阻燃效果更好,且无环境污染。
综合上述,本发明所述的全棉织物的涂料染色生产工艺,无论是预处理还是后续染色,都避免了对织物纤维造成损伤,因此,不仅显著改善了织物的手感、弹性等性能,而且上染率高、色牢度强、染色均匀且色泽丰满。
以上所述,仅为本发明较佳的具体实施方式,但本发明的保护范围并不局限于此,任何熟悉本技术领域的技术人员在本发明揭露的技术范围内,根据本发明的技术方案及其发明构思加以等同替换或改变,都应涵盖在本发明的保护范围之内。
Claims (9)
1.一种全棉织物的涂料染色生产工艺,其特征在于,包括如下步骤:
S1、预处理,将全棉织物常温下浸轧工作液中,二浸二轧,轧余率为60-90%,所述工作液包括:烧碱5-10g/L、双氧水3-5g/L、渗透剂0.3-0.5g/L、精炼剂0.5-1g/L、螯合分散剂1-5g/L,60-80℃热水洗涤后浸入酶处理液中,在30-60℃下处理10-30min,所述酶处理液包括:淀粉酶2-5g/L、果胶酶0-2g/L、纤维素酶0.01-1g/L,80-100℃热水洗涤后烘干;
S2、改性处理,将经S1预处理后的全棉织物浸轧整理液中,二浸二轧,浸轧温度为70-80℃,轧余率为90-100%,在80-100℃下烘焙1-5min,40-50℃水洗后烘干,所述整理液包括:阳离子改性剂5-25g/L、固体碱2-6g/L;
S3、染色,将经S2改性处理后的全棉织物浸轧染液中,二浸二轧,轧余率为60-80%,所述染液包括:涂料色浆10-60g/L、pH调节剂1-10g/L、表面活性剂3-5g/L、黏合剂10-40g/L,再将浸轧后的织物烘干,烘干温度为80-100℃,时间为5-15min,接着汽蒸固色,汽蒸温度为100-105℃,时间为1-10min;
S4、后整理,将经S3染色后的全棉织物先水洗,再进行柔软、阻燃整理;
S3中,制备所述黏合剂的方法包括:将单体聚氨酯丙烯酸酯PUA、丙烯酸乙酯、丙烯酸丁酯、1,3-丁二醇二甲基丙烯酸酯和引发剂AIBN混匀后,加入乳化剂苯乙烯-马来酸酐共聚物钠盐SMA和平平加O,在4000-6000r/min的速率下高速搅拌10-20min,升温至80-90℃后搅拌反应2-4h,过滤,洗涤,得到所述黏合剂;聚氨酯丙烯酸酯PUA、丙烯酸乙酯、丙烯酸丁酯、1,3-丁二醇二甲基丙烯酸酯、苯乙烯-马来酸酐共聚物钠盐SMA、平平加O的重量比为10:1-2:1-3:1-3:0.1-1:0.01-0.3。
2.根据权利要求1所述的全棉织物的涂料染色生产工艺,其特征在于,S2中,所述阳离子改性剂选自环氧丙基三甲基氯化铵、环氧丙基三乙基氯化铵、聚酰胺多胺环氧氯丙烷、甲基丙烯酸环氧丙酯-季铵盐单体共聚物、氯代三嗪型季铵盐化合物中的一种或者多种的组合。
3.根据权利要求1-2任一项所述的全棉织物的涂料染色生产工艺,其特征在于,S3中,所述pH调节剂选自氢氧化钾、氢氧化钠、碳酸钠、碳酸氢钠、三乙醇胺的水溶液、氨水中的一种或者多种的组合。
4.根据权利要求1-2任一项所述的全棉织物的涂料染色生产工艺,其特征在于,pH调节剂调节染液的pH值为7-11。
5.根据权利要求1-2任一项所述的全棉织物的涂料染色生产工艺,其特征在于,S4中,水洗温度为40-50℃,水洗时间为5-20min。
6.根据权利要求1-2任一项所述的全棉织物的涂料染色生产工艺,其特征在于,S4中,柔软整理采用的柔软处理液包括:聚醚氨基改性硅油50-70g/L、抗滑移剂5-15g/L、抗静电剂5-10g/L,柔软整理中,调节pH值为5.5-6,工作温度为100-120℃,车速为40-60m/min。
7.根据权利要求1-2任一项所述的全棉织物的涂料染色生产工艺,其特征在于,S4中,阻燃整理采用的整理液按重量份包括:聚丙烯基二甲基磷酸酯100份、KH-570 1-3份、蒙脱土3-8份、异丙醇5-20份、水4-8份,阻燃整理中,将阻燃整理液喷涂在全棉织物的表面,阻燃剂整理液的用量为全棉织物重量的5-10%,在60-80℃下预烘0.5-1h后,再在110-130℃焙烘1-2h,水洗,晾干。
8.根据权利要求7所述的全棉织物的涂料染色生产工艺,其特征在于,所述聚丙烯基二甲基磷酸酯的制备方法包括:按重量份将10份三氯氧磷加入50-70份乙醚中搅拌均匀,降温至0-5℃后加入4-5份丙烯醇和8-10份三乙胺搅拌反应5-8h,再加入5-7份甲醇和4-12份三乙胺搅拌反应2-4h,抽滤,减压蒸馏,得到丙烯基二甲基磷酸酯;将丙烯基二甲基磷酸酯加入20-30份水中搅拌均匀,升温至85-105℃后加入1-3份过硫酸钾和1-3份司班-60搅拌聚合,反应1-2h后冷却至室温,抽滤,洗涤,干燥,得到所述聚丙烯基二甲基磷酸酯。
9.根据权利要求1-2任一项所述的全棉织物的涂料染色生产工艺,其特征在于,S4中,还包括将后整理后的全棉织物进行预缩;预缩时,将所述织物置于预缩整理机内进行预缩处理,预缩整理机的车速为30-70m/min,预缩率为5-10%。
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