CN107056263B - 一种中温长石质骨瓷的制备方法 - Google Patents

一种中温长石质骨瓷的制备方法 Download PDF

Info

Publication number
CN107056263B
CN107056263B CN201710285042.8A CN201710285042A CN107056263B CN 107056263 B CN107056263 B CN 107056263B CN 201710285042 A CN201710285042 A CN 201710285042A CN 107056263 B CN107056263 B CN 107056263B
Authority
CN
China
Prior art keywords
glaze
temperature
tio
sio
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201710285042.8A
Other languages
English (en)
Other versions
CN107056263A (zh
Inventor
肖杨
李木根
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hunan Karpery Industrial Co ltd
Original Assignee
Hunan Karpery Industrial Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hunan Karpery Industrial Co ltd filed Critical Hunan Karpery Industrial Co ltd
Priority to CN201710285042.8A priority Critical patent/CN107056263B/zh
Publication of CN107056263A publication Critical patent/CN107056263A/zh
Application granted granted Critical
Publication of CN107056263B publication Critical patent/CN107056263B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/14—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silica
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/64—Burning or sintering processes
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81—Coating or impregnation
    • C04B41/85—Coating or impregnation with inorganic materials
    • C04B41/86—Glazes; Cold glazes
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3201—Alkali metal oxides or oxide-forming salts thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
    • C04B2235/3206—Magnesium oxides or oxide-forming salts thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
    • C04B2235/3208—Calcium oxide or oxide-forming salts thereof, e.g. lime
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3217—Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3224—Rare earth oxide or oxide forming salts thereof, e.g. scandium oxide
    • C04B2235/3229—Cerium oxides or oxide-forming salts thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3232—Titanium oxides or titanates, e.g. rutile or anatase
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/327—Iron group oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3272—Iron oxides or oxide forming salts thereof, e.g. hematite, magnetite
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
    • C04B2235/656—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
    • C04B2235/6562—Heating rate
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
    • C04B2235/656—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
    • C04B2235/6567—Treatment time
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
    • C04B2235/658—Atmosphere during thermal treatment
    • C04B2235/6581—Total pressure below 1 atmosphere, e.g. vacuum
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
    • C04B2235/66—Specific sintering techniques, e.g. centrifugal sintering
    • C04B2235/661—Multi-step sintering

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Structural Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Cosmetics (AREA)
  • Compositions Of Oxide Ceramics (AREA)

Abstract

本发明涉及一种中温长石质骨瓷的制备方法，采用矿物原料及化工原料,其坯料和釉料配方的重量百分比组成为：坯料：湖南钠长石21%、江西钾长石9%、广东洗泥17%、江西洗泥18%、贺州原矿12%、河北增塑泥4%、龙岩原矿12%、钛白粉2%、骨灰2%、钼酸铵1%、氧化铈1%；釉料：湖南钠长石23%、江西钾长石20%、平江石英18%、烧滑石10%、烧龙岩土7%、烧氧化锌3%、贵州土6%、方解石13%；经过坯料和釉料制备、成型、施釉、干燥、中温烧成获得制品，其烧成时间为6～8h，最高烧成温度为1250～1280℃，获得烧成温度宽、产品光泽度高、热稳定性能好的中温烧结骨瓷，因此具有广阔的应用前景。

Description

一种中温长石质骨瓷的制备方法
技术领域
本发明属于无机非金属材料（陶瓷）领域，具体涉及一种中温长石质骨瓷的制备方法。
背景技术
骨质瓷长期以来一直是各国贵族用瓷，是目前世界上公认的高档瓷种。因其“薄如纸、透如镜、声如磬、白如玉”，瓷质细腻通透，器型美观典雅，彩面润泽光亮，花面多姿多彩的特点，成就了它洁白的质地和华贵的造型，兼有使用和艺术的双重价值，历史上是宫廷专用品和贵族收藏之珍品，是权力和地位的象征，号称“瓷器之王”，被称为“绿色环保健康陶瓷”。骨质瓷以其高质量、高格调、高品位成为各大星级宾馆、百货超市、豪富家庭的必选用瓷，更是馈赠亲友的最佳礼品，骨质瓷已一跃成为国内高档瓷消费的主导。但骨质瓷与传统的高温瓷相比也有他的缺点，一是烧成温度范围窄，产品在烧制过程中容易产生变形、气泡、流釉的缺陷；二是热稳定性相对较差，骤冷骤热使用时，产品容易发生炸裂。因此研究发明一种具有骨质瓷优点，而且瓷体通透、釉面光泽度高、热稳定性好的长石质骨瓷就具有非常大的现实意义。
发明内容
本发明要解决的技术问题是提供一种烧成温度宽、产品光泽度高、热稳定性能好的中温长石质骨瓷的制备方法。
为解决以上技术问题，本发明的技术方案是：一种中温长石质骨瓷的制备方法，采用矿物原料及化工原料 , 其坯料和釉料配方的重量百分比组成为： 坯料：湖南钠长石21%、江西钾长石9%、广东洗泥17%、江西洗泥18%、贺州原矿12%、河北 增塑泥4%、龙岩原矿12%、钛白粉2%、骨灰2%、钼酸铵1%、氧化铈1%； 釉料：湖南钠长石23%、江西钾长石20%、平江石英18%、烧滑石10%、烧龙岩土7%、烧氧化 锌3%、贵州土6%、方解石13%； 经过坯料和釉料制备、成型、施釉、干燥、中温烧成获得制品，其烧成时间为6～8h，最高 烧成温度为1250～1280℃。
所述釉料原料中烧滑石、烧龙岩土、烧氧化锌的煅烧温度为1300℃～1320℃。
所述坯料制备工序为：按坯料配方称量原料混合均匀，然后装入球磨设备内按料：球：水=1:1.5:1的比例球磨15小时，泥浆出磨细度为250目，筛余0 .1%，出磨泥浆分别过120目、180目、200目筛3次除铁，然后陈腐7天以上，再真空练泥3次待用。
所述釉料制备工序为：按釉料配方称量原料混合均匀，然后装入球磨设备内按料：球：水=1:2:0 .5的比例球磨22小时，釉浆出磨细度为250目，万孔筛余0 .01%，出磨釉浆分别 过180目、200目、250目筛3次除铁后备用。
所述施釉工序为：所述釉浆浓度控制为50°Bé-52°Bé，在含水率为2%以下坯体上先施内釉，然后施外釉，所述坯体施外釉前需再次进烘房干燥4小时。
所述获得制品的热稳定性为180～20℃，一次未裂；获得制品的吸水率0.3%以下，釉面光泽度为大于80。
所述中温烧成过程中采用正负压交叉烧制工艺，其烧成制度为：室温至800～950℃，升温速率3～4℃/min，并在800～950℃保温20 min，此过程中窑内处于正压状态；窑内温度从800～950℃至1080～1130℃，升温速率1.5～2℃/min，此过程中窑内处于负压状态；窑内温度从1080～1130℃至1250～1280℃，升温速率3～5℃/min保温40min，此过程中窑内处于正压状态；最后窑炉熄火，自然冷却至室温。
所述坯料和釉料中矿物原料的化学组成为：
Figure 119457DEST_PATH_IMAGE001
本发明通过控制原料的颗粒度，添加钛白粉、骨灰作为分相剂在坯与釉之间产生中间 层以提高坯体的热稳定性，钼酸铵作为结晶剂提高坯体中莫来石的数量，通过添加氧化铈 作为限晶剂用于填补晶粒及缺陷，生成能阻碍坯体游离石英继续生长的膜，从而降低坯体 的膨胀系数；并通过正负压交叉烧成技术很好的提高了瓷体的通透、釉面的光泽度，因此具 有广阔的市场前景。
具体实施方式
实施列一：一种中温长石质骨瓷的制备方法，采用矿物原料及化工原料 , 其坯料和釉料配方的 重量百分比组成为： 坯料：湖南钠长石21%、江西钾长石9%、广东洗泥17%、江西洗泥18%、贺州原矿12%、河北 增塑泥4%、龙岩原矿12%、钛白粉2%、骨灰2%、钼酸铵1%、氧化铈1%； 釉料：湖南钠长石23%、江西钾长石20%、平江石英18%、烧滑石10%、烧龙岩土7%、烧氧化 锌3%、贵州土6%、方解石13%； 经过坯料和釉料制备、成型、施釉、干燥、中温烧成获得制品，其烧成时间为6h，最高烧 成温度为1260℃。
所述釉料原料中烧滑石、烧龙岩土、烧氧化锌的煅烧温度为1310℃。
所述坯料制备工序为：按坯料配方称量原料混合均匀，然后装入球磨设备内按料：球：水=1:1.5:1的比例球磨15小时，泥浆出磨细度为250目，筛余0.1%，出磨泥浆分别过120目、180目、200目筛3次除铁，然后陈腐7天以上，再真空练泥3次待用。
所述釉料制备工序为：按釉料配方称量原料混合均匀，然后装入球磨设备内按料：球：水=1:2:0.5的比例球磨22小时，釉浆出磨细度为250目，万孔筛余0.01%，出磨釉浆分别过180目、200目、250目筛3次除铁后备用。
所述施釉工序为：所述釉浆浓度控制为51°Bé，在含水率为2%以下坯体上先喷内釉，然后浸外釉，所述坯体施外釉前需再次进烘房干燥4小时。
所述获得制品的热稳定性为180～20℃，一次未裂；获得制品的吸水率为0.25%，釉面光泽度为82。
所述中温烧成过程中采用正负压交叉烧制工艺，其烧成制度为：室温至810℃，升温速率3℃/min，并在810℃保温20 min，此过程中窑内处于正压状态；窑内温度从810℃至1100℃，升温速率1.6℃/min，此过程中窑内处于负压状态；窑内温度从1100℃至1260℃，升温速率3℃/min保温40min，此过程中窑内处于正压状态；最后窑炉熄火，自然冷却至室温。
实施列二： 一种中温长石质骨瓷的制备方法，采用矿物原料及化工原料 , 其坯料和釉料配方的 重量百分比组成为： 坯料：湖南钠长石21%、江西钾长石9%、广东洗泥17%、江西洗泥18%、贺州原矿12%、河北 增塑泥4%、龙岩原矿12%、钛白粉2%、骨灰2%、钼酸铵1%、氧化铈1%； 釉料：湖南钠长石23%、江西钾长石20%、平江石英18%、烧滑石10%、烧龙岩土7%、烧氧化 锌3%、贵州土6%、方解石13%； 经过坯料和釉料制备、成型、施釉、干燥、中温烧成获得制品，其烧成时间为7h，最高烧 成温度为1270℃。
所述釉料原料中烧滑石、烧龙岩土、烧氧化锌的煅烧温度为1320℃。
所述坯料制备工序为：按坯料配方称量原料混合均匀，然后装入球磨设备内按料：球：水=1:1.5:1的比例球磨15小时，泥浆出磨细度为250目，筛余0.1%，出磨泥浆分别过120目、180目、200目筛3次除铁，然后陈腐7天以上，再真空练泥3次待用。
所述釉料制备工序为：按釉料配方称量原料混合均匀，然后装入球磨设备内按料：球：水=1:2:0.5的比例球磨22小时，釉浆出磨细度为250目，万孔筛余0.01%，出磨釉浆分别过180目、200目、250目筛3次除铁后备用。
所述施釉工序为：所述釉浆浓度控制为50°Bé，在含水率为2%以下坯体上先喷内釉，然后浸外釉，所述坯体施外釉前需再次进烘房干燥4小时。
所述获得制品的热稳定性为180～20℃，一次未裂；获得制品的吸水率为0.2%，釉面光泽度为85。
所述中温烧成过程中采用正负压交叉烧制工艺，其烧成制度为：室温至910℃，升温速率4℃/min，并在910℃保温20 min，此过程中窑内处于正压状态；窑内温度从910℃至1120℃，升温速率1.8℃/min，此过程中窑内处于负压状态；窑内温度从1120℃至1270℃，升温速率4℃/min保温40min，此过程中窑内处于正压状态；最后窑炉熄火，自然冷却至室温。

Claims (1)

1.一种中温长石质骨瓷的制备方法，采用矿物原料及化工原料, 其坯料和釉料配方的重量百分比组成为：
坯料：湖南钠长石21%、江西钾长石9%、广东洗泥17%、江西洗泥18%、贺州原矿12%、河北增塑泥4%、龙岩原矿12%、钛白粉2%、骨灰2%、钼酸铵1%、氧化铈1%；
釉料：湖南钠长石23%、江西钾长石20%、平江石英18%、烧滑石10%、烧龙岩土7%、烧氧化锌3%、贵州土6%、方解石13%；
经过坯料和釉料制备、成型、施釉、干燥、中温烧成获得制品，其烧成时间为7h，最高烧成温度为1270℃；
所述釉料原料中烧滑石、烧龙岩土、烧氧化锌的煅烧温度为1320℃；
所述坯料制备工序为：按坯料配方称量原料混合均匀，然后装入球磨设备内按料：球：水=1:1.5:1的比例球磨15小时，泥浆出磨细度为250目，筛余0.1%，出磨泥浆分别过120目、180目、200目筛3次除铁，然后陈腐7天以上，再真空练泥3次待用；
所述釉料制备工序为：按釉料配方称量原料混合均匀，然后装入球磨设备内按料：球：水=1:2:0.5的比例球磨22小时，釉浆出磨细度为250目，万孔筛余0.01%，出磨釉浆分别过180目、200目、250目筛3次除铁后备用；
所述施釉工序为：所述釉浆浓度控制为50°Bé，在含水率为2%以下坯体上先喷内釉，然后浸外釉，所述坯体施外釉前需再次进烘房干燥4小时；
所述获得制品的热稳定性为180～20℃，一次未裂；获得制品的吸水率为0.2%，釉面光泽度为85；
所述中温烧成过程中采用正负压交叉烧制工艺，其烧成制度为：室温至910℃，升温速率4℃/min，并在910℃保温20 min，此过程中窑内处于正压状态；窑内温度从910℃至1120℃，升温速率1.8℃/min，此过程中窑内处于负压状态；窑内温度从1120℃至1270℃，升温速率4℃/min保温40min，此过程中窑内处于正压状态；最后窑炉熄火，自然冷却至室温；
广东洗泥的化学组成按重量百分比％为：SiO250.52、Al2O332.95、Fe2O30.02、TiO20、CaO0.16、MgO0.44、K2O3.83、Na2O0.26、IL11.66；
江西洗泥的化学组成按重量百分比％为：SiO251.52、Al2O333.09、Fe2O30.19、TiO20、CaO0.09、MgO0.58、K2O2.67、Na2O0.2、IL11.5；
湖南钠长石的化学组成按重量百分比％为：SiO270.13、Al2O317.73、Fe2O30.02、TiO20、CaO0.29、MgO0.09、K2O0.47、Na2O10.78、IL0.34；
龙岩原矿的化学组成按重量百分比％为：SiO276.35、Al2O314.94、Fe2O30.1、TiO20、CaO0.13、MgO0.07、K2O4.02、Na2O0.89、IL3.43；
江西钾长石的化学组成按重量百分比％为：SiO266.18、Al2O317.2、Fe2O30.21、TiO20、CaO0.84、MgO0.37、K2O10.4、Na2O3.6、IL0.81；
贺州原矿的化学组成按重量百分比％为：SiO283、Al2O311.91、Fe2O30.07、TiO20、CaO0.04、MgO0.14、K2O3、Na2O0、IL1.75；
河北增塑泥的化学组成按重量百分比％为：SiO252、Al2O331.56、Fe2O30.24、TiO20、CaO0.36、MgO0.35、K2O0.35、Na2O0.65、IL14.3；
平江石英的化学组成按重量百分比％为：SiO299、Al2O30.1、Fe2O30、TiO20、CaO0、MgO0、K2O0.1、Na2O0.1、IL0.2；
贵州土的化学组成按重量百分比％为：SiO244.6、Al2O337.1、Fe2O30.4、TiO20、CaO1.1、MgO0.6、K2O0.3、Na2O0.2、IL15.3；
烧龙岩土的化学组成按重量百分比％为：SiO255.7、Al2O337.4、Fe2O30.18、TiO20、CaO1.2、MgO1.1、K2O2.7、Na2O0.9、IL0；
烧滑石的化学组成按重量百分比％为：SiO262.17、Al2O30.61、Fe2O30.02、TiO20、CaO3.42、MgO32.88、K2O0.09、Na2O0.35、IL0。
CN201710285042.8A 2017-04-27 2017-04-27 一种中温长石质骨瓷的制备方法 Active CN107056263B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710285042.8A CN107056263B (zh) 2017-04-27 2017-04-27 一种中温长石质骨瓷的制备方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710285042.8A CN107056263B (zh) 2017-04-27 2017-04-27 一种中温长石质骨瓷的制备方法

Publications (2)

Publication Number Publication Date
CN107056263A CN107056263A (zh) 2017-08-18
CN107056263B true CN107056263B (zh) 2020-07-31

Family

ID=59604331

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710285042.8A Active CN107056263B (zh) 2017-04-27 2017-04-27 一种中温长石质骨瓷的制备方法

Country Status (1)

Country Link
CN (1) CN107056263B (zh)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108083647A (zh) * 2017-12-26 2018-05-29 湖南港鹏实业有限公司 陶瓷透明釉及其制备方法
CN108191389A (zh) * 2018-01-23 2018-06-22 醴陵市湘昊陶瓷科技有限公司 骨质瓷及其制备工艺
CN109053171B (zh) * 2018-08-27 2021-01-26 佛山石湾鹰牌陶瓷有限公司 砖坯及喷墨渗花玉质抛光砖
CN111499194A (zh) * 2020-04-23 2020-08-07 潮州市智信新材料科技有限公司 一种珠光幻彩折射抗菌陶瓷制品的制备方法
CN112159106A (zh) * 2020-09-30 2021-01-01 湖南省醴陵市楚华陶瓷实业有限公司 一种环保陶瓷釉料及其制备方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2746240A1 (en) * 2012-12-24 2014-06-25 King Abdulaziz City for Science & Technology (KACST) A self glazed ceramic/glass composite and method for manufacturing the same

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100337977C (zh) * 2006-03-31 2007-09-19 潮州市波士发陶瓷制作有限公司 一种骨质强化瓷及其生产工艺
CN100360462C (zh) * 2006-08-17 2008-01-09 林伟河 一种釉中彩装饰日用瓷及其生产方法
CN101555129A (zh) * 2009-05-12 2009-10-14 潮州市联源陶瓷制作有限公司 一种含骨质日用强化瓷及其生产工艺
CN101585700B (zh) * 2009-06-22 2012-09-26 潮州升煌陶瓷制作有限公司 一种釉中彩陶瓷及其制备方法
CN103011773A (zh) * 2012-12-25 2013-04-03 青岛科技大学 一种骨质瓷坯体
CN103011765A (zh) * 2012-12-25 2013-04-03 青岛科技大学 一种陶瓷坯体液相烧结用熔剂系统及其制备方法
CN103420667A (zh) * 2013-08-07 2013-12-04 阳城县侨枫瓷业有限公司 强化低骨瓷瓷器及其生产方法
CN103482967B (zh) * 2013-08-13 2014-09-17 应县盛福瓷业有限公司 一种新骨瓷坯料及釉料的加工工艺
CN103896558B (zh) * 2014-03-12 2015-03-25 湖南港鹏实业有限公司 一种红外陶瓷保温杯的制备方法及其制得的产品
CN104058795B (zh) * 2014-04-30 2015-12-09 福建省嘉顺艺品股份有限公司 一种纳米抗菌陶瓷茶具及其制作工艺
CN104529548B (zh) * 2015-01-23 2016-04-06 广东省大埔陶瓷工业研究所 一种红斑结晶釉及采用该釉的陶瓷制备方法
CN105060843B (zh) * 2015-08-17 2017-09-01 景德镇红叶陶瓷股份有限公司 一种强化玉质瓷的制备方法及其制得的产品
CN105272144B (zh) * 2015-11-13 2018-04-10 景德镇市大瓷庄瓷业有限公司 一种中温烧结骨瓷及其制备方法
CN105669161A (zh) * 2016-01-20 2016-06-15 景德镇市中天鑫源陶瓷有限公司 一种中温(1190℃-1260℃)还原烧制陶瓷的方法
CN106116456B (zh) * 2016-06-23 2019-06-04 湖南华联瓷业股份有限公司 一种中温色釉彩色日用细瓷及其制作方法

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2746240A1 (en) * 2012-12-24 2014-06-25 King Abdulaziz City for Science & Technology (KACST) A self glazed ceramic/glass composite and method for manufacturing the same

Also Published As

Publication number Publication date
CN107056263A (zh) 2017-08-18

Similar Documents

Publication Publication Date Title
CN107056263B (zh) 一种中温长石质骨瓷的制备方法
CN102826872B (zh) 一种国旗大红色釉面砖的配方及其制备方法
CN101734948B (zh) 龙泉明代官窑青瓷釉及用该釉制作龙泉明代官窑青瓷产品的方法
CN102060571A (zh) 日用瓷用青釉
CN110963793B (zh) 一种仿玉石陶瓷砖及其制备方法
CN113402305B (zh) 一种砂金釉陶瓷砖及其制备方法
CN111423124B (zh) 耐磨透明釉、耐磨抛釉砖及其制备方法
CN113480298B (zh) 一种高白度高透光度高可塑性陶瓷坯泥的制备及应用方法
CN110092579A (zh) 一种星空釉釉料、星空釉钧瓷及其制备方法
CN107216127A (zh) 德化珍珠白瓷器及其制备工艺
CN110818264A (zh) 一种高温全瓷裂纹釉和制备方法
CN102491641A (zh) 耐磨微晶玻璃板材及其制备方法
CN101913843B (zh) 一种翠玉瓷的制备方法
CN107082624A (zh) 一种长石质强化骨瓷的制备方法
CN106396618B (zh) 一种还原气氛烧制高温亚光紫金釉瓷的制造方法
CN106630934A (zh) 一种使用天目酱金色釉烧制钧瓷的工艺
CN109534802B (zh) 一种高利用沙漠材料的远红外自生釉瓷及其制备工艺
CN107572792A (zh) 一种钧瓷天青釉及其制备方法
CN112408791B (zh) 一种高温烧制骨质日用瓷的烧成方法
CN102875026A (zh) 黑色建筑装饰微晶玻璃及其制备方法
CN115838246B (zh) 一种银色釉以及还原气氛烧制银色釉的制备方法
CN102875025A (zh) 黑色微晶玻璃及其制备方法
CN109942273A (zh) 炻瓷及其制备方法
CN111454051A (zh) 生态石及其制备方法
CN112592208B (zh) 一种丝绸釉瓷砖及其制备方法

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant