CN107004881A - 用于氧化还原液流电池的聚合物电解质膜 - Google Patents

用于氧化还原液流电池的聚合物电解质膜 Download PDF

Info

Publication number
CN107004881A
CN107004881A CN201580065523.7A CN201580065523A CN107004881A CN 107004881 A CN107004881 A CN 107004881A CN 201580065523 A CN201580065523 A CN 201580065523A CN 107004881 A CN107004881 A CN 107004881A
Authority
CN
China
Prior art keywords
polymer
sulfonamide
dielectric film
redox flow
sulfonic acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201580065523.7A
Other languages
English (en)
Chinese (zh)
Inventor
M·S·沙伯格
G·M·豪根
S·J·哈姆罗克
P·N·熊
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Innovative Properties Co
Original Assignee
3M Innovative Properties Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 3M Innovative Properties Co filed Critical 3M Innovative Properties Co
Publication of CN107004881A publication Critical patent/CN107004881A/zh
Pending legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/1016Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018Polymeric electrolyte materials
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/1016Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018Polymeric electrolyte materials
    • H01M8/102Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1023Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon, e.g. polyarylenes, polystyrenes or polybutadiene-styrenes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/1016Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018Polymeric electrolyte materials
    • H01M8/102Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1032Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having sulfur, e.g. sulfonated-polyethersulfones [S-PES]
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/1016Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018Polymeric electrolyte materials
    • H01M8/1039Polymeric electrolyte materials halogenated, e.g. sulfonated polyvinylidene fluorides
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/1016Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018Polymeric electrolyte materials
    • H01M8/1041Polymer electrolyte composites, mixtures or blends
    • H01M8/1044Mixtures of polymers, of which at least one is ionically conductive
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/18Regenerative fuel cells, e.g. redox flow batteries or secondary fuel cells
    • H01M8/184Regeneration by electrochemical means
    • H01M8/188Regeneration by electrochemical means by recharging of redox couples containing fluids; Redox flow type batteries
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/20Indirect fuel cells, e.g. fuel cells with redox couple being irreversible
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M2008/1095Fuel cells with polymeric electrolytes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00Electrolytes
    • H01M2300/0017Non-aqueous electrolytes
    • H01M2300/0065Solid electrolytes
    • H01M2300/0082Organic polymers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00Electrolytes
    • H01M2300/0088Composites
    • H01M2300/0091Composites in the form of mixtures
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Composite Materials (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Conductive Materials (AREA)
  • Fuel Cell (AREA)
CN201580065523.7A 2014-12-03 2015-11-24 用于氧化还原液流电池的聚合物电解质膜 Pending CN107004881A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201462086956P 2014-12-03 2014-12-03
US62/086,956 2014-12-03
PCT/US2015/062246 WO2016089658A1 (en) 2014-12-03 2015-11-24 Polymeric electrolyte membrane for a redox flow battery

Publications (1)

Publication Number Publication Date
CN107004881A true CN107004881A (zh) 2017-08-01

Family

ID=56092259

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201580065523.7A Pending CN107004881A (zh) 2014-12-03 2015-11-24 用于氧化还原液流电池的聚合物电解质膜

Country Status (7)

Country Link
US (1) US20170365870A1 (enExample)
EP (1) EP3227949A4 (enExample)
JP (1) JP2018503219A (enExample)
KR (1) KR20170086117A (enExample)
CN (1) CN107004881A (enExample)
CA (1) CA2969424A1 (enExample)
WO (1) WO2016089658A1 (enExample)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2016122631A (ja) * 2014-12-25 2016-07-07 トヨタ自動車株式会社 リチウムイオン二次電池用電極の製造方法
US11499006B2 (en) 2018-06-14 2022-11-15 Massachusetts Institute Of Technology Polymer compound, solid electrolyte film including the same, and lithium-air battery including the solid electrolyte film
EP3821490A4 (en) 2018-08-10 2022-01-26 ESS Tech, Inc. METHODS AND SYSTEM FOR FABRICATING A REDOX FLOW BATTERY SYSTEM BY ROLLER TO ROLLER PROCESSING
US12199290B2 (en) 2018-12-21 2025-01-14 3M Innovative Properties Company Fluoropolymer ionomers with reduced catalyst poisoning and articles therefrom
EP4127002A1 (en) 2020-03-30 2023-02-08 3M Innovative Properties Company Fluoropolymer comprising pendent groups with ionic bis(sulfonyl)imide moiety and perfluoroether terminal group
US11970589B2 (en) * 2021-01-29 2024-04-30 Uop Llc Composite proton conductive membranes
CN116065171A (zh) * 2022-11-30 2023-05-05 华电重工股份有限公司 一种电解水制氢用增强型长寿命质子交换膜及其制备方法

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4170537A (en) * 1978-10-20 1979-10-09 Ppg Industries, Inc. Method of preparing a diaphragm having a gel of a hydrous oxide of zirconium in a porous matrix
US6733914B1 (en) * 2000-02-18 2004-05-11 Ion Power, Inc. Fuel cell membranes
CN101383403A (zh) * 2007-09-05 2009-03-11 中国科学院大连化学物理研究所 一种复合离子交换膜及其制备
CN101383404A (zh) * 2007-09-05 2009-03-11 中国科学院大连化学物理研究所 一种氟/烃复合离子交换膜及其制备方法
CN101460554A (zh) * 2006-06-01 2009-06-17 纳幕尔杜邦公司 含氟聚合物分散体和膜
CN101685865A (zh) * 2008-07-29 2010-03-31 山东东岳神舟新材料有限公司 一种多层含氟交联离子膜及其制备方法
WO2012174463A1 (en) * 2011-06-17 2012-12-20 E. I. Du Pont De Nemours And Company Improved composite polymer electrolyte membrane
JP2013048080A (ja) * 2011-07-28 2013-03-07 Panasonic Corp 高分子電解質型燃料電池およびその製造方法

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL160013C (nl) * 1968-11-26 1979-09-17 Du Pont Werkwijze ter bereiding van oplossingen van een sulfonyl- groepen bevattend fluorkoolstofpolymeer.
US3784399A (en) * 1971-09-08 1974-01-08 Du Pont Films of fluorinated polymer containing sulfonyl groups with one surface in the sulfonamide or sulfonamide salt form and a process for preparing such
JPS6053059B2 (ja) * 1978-07-11 1985-11-22 旭化成株式会社 改良された陽イオン交換膜の製法
JPS5641392A (en) * 1979-09-11 1981-04-18 Toyo Soda Mfg Co Ltd Electrolytic method of alkali chloride aqueous solution
US4402806A (en) * 1982-03-04 1983-09-06 General Electric Company Multi layer ion exchanging membrane with protected interior hydroxyl ion rejection layer
SG73410A1 (en) * 1992-06-13 2000-06-20 Hoechst Ag Polymer electrolyte membrane and process for the production thereof
JP2004087288A (ja) * 2002-08-27 2004-03-18 Teijin Ltd 固体高分子電解質、それを用いた膜、触媒電極層及び燃料電池
WO2010143634A1 (ja) * 2009-06-09 2010-12-16 シャープ株式会社 レドックスフロー電池
CN102834374B (zh) * 2010-04-16 2016-08-03 3M创新有限公司 质子传导材料
JP2011253753A (ja) * 2010-06-03 2011-12-15 Toyobo Co Ltd 高分子固体電解質膜積層体
JP2014507520A (ja) * 2011-01-11 2014-03-27 ユーティーシー パワー コーポレイション プロトン交換材料及びその製造方法
US20130218868A1 (en) * 2012-02-21 2013-08-22 James B. Pitts Smart linking a file to a product
JP2013218868A (ja) * 2012-04-09 2013-10-24 Toyobo Co Ltd イオン交換膜およびその製造方法、レドックスフロー電池、燃料電池
US9923223B2 (en) * 2012-12-21 2018-03-20 Audi Ag Electrolyte membrane, dispersion and method therefor

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4170537A (en) * 1978-10-20 1979-10-09 Ppg Industries, Inc. Method of preparing a diaphragm having a gel of a hydrous oxide of zirconium in a porous matrix
US6733914B1 (en) * 2000-02-18 2004-05-11 Ion Power, Inc. Fuel cell membranes
CN101460554A (zh) * 2006-06-01 2009-06-17 纳幕尔杜邦公司 含氟聚合物分散体和膜
CN101383403A (zh) * 2007-09-05 2009-03-11 中国科学院大连化学物理研究所 一种复合离子交换膜及其制备
CN101383404A (zh) * 2007-09-05 2009-03-11 中国科学院大连化学物理研究所 一种氟/烃复合离子交换膜及其制备方法
CN101685865A (zh) * 2008-07-29 2010-03-31 山东东岳神舟新材料有限公司 一种多层含氟交联离子膜及其制备方法
WO2012174463A1 (en) * 2011-06-17 2012-12-20 E. I. Du Pont De Nemours And Company Improved composite polymer electrolyte membrane
JP2013048080A (ja) * 2011-07-28 2013-03-07 Panasonic Corp 高分子電解質型燃料電池およびその製造方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
QINGTAO LUO: "Preparation and characterization of Nafion/SPEEK layered composite membrane and its application in vanadium redox flow battery", 《JOURNAL OF MEMBRANE SCIENCE》 *

Also Published As

Publication number Publication date
US20170365870A1 (en) 2017-12-21
EP3227949A4 (en) 2018-05-16
WO2016089658A1 (en) 2016-06-09
CA2969424A1 (en) 2016-06-09
EP3227949A1 (en) 2017-10-11
KR20170086117A (ko) 2017-07-25
JP2018503219A (ja) 2018-02-01

Similar Documents

Publication Publication Date Title
US9975995B2 (en) Ion conducting polymer comprising partially branched block copolymer and use thereof
CN107004881A (zh) 用于氧化还原液流电池的聚合物电解质膜
US10256493B2 (en) Redox flow secondary battery and electrolyte membrane for redox flow secondary battery
KR101684036B1 (ko) 레독스 플로우 2차 전지 및 레독스 플로우 2차 전지용 전해질막
CN101589496B (zh) 聚合物电解质膜及其制造方法以及膜电极组件及聚合物电解质燃料电池
CN104813529B (zh) 氧化还原液流二次电池用隔膜及使用其的氧化还原液流二次电池
JP7359139B2 (ja) 積層電解質膜、膜電極複合体、および、水電解式水素発生装置、ならびに、積層電解質膜の製造方法
CN110573559B (zh) 离子交换膜、其制造方法及包括其的能量存储装置
WO2014034415A1 (ja) バナジウム系レドックス電池用イオン交換膜、複合体、及びバナジウム系レドックス電池
US10211474B2 (en) Redox flow secondary battery and electrolyte membrane for redox flow secondary battery
CN107004882A (zh) 聚合物电解质膜
US20120301767A1 (en) Redox flow battery
CN107004880B (zh) 聚合物电解质膜
Williams et al. Leveraging sulfonated poly (ether ether ketone) for superior performance in zinc iodine redox flow batteries
KR20240064714A (ko) 전기화학 반응을 위한 양성자 교환 막
WO2005001971A1 (ja) 高分子電解質複合膜、その製造方法及びその用途
JP2016192294A (ja) バナジウム系レドックス電池用イオン交換膜、複合体、及びバナジウム系レドックス電池
JP6338896B2 (ja) 樹脂付電極層、樹脂付電極複合体及びレドックスフロー二次電池
KR100956652B1 (ko) 가교 고분자 전해질막, 가교 고분자 전해질막의 제조방법및 그 전해질막을 포함하는 연료전지
CN115474444B (zh) 氧化还原液流电池用隔膜、氧化还原液流电池用隔膜的制造方法、氧化还原液流电池用隔膜电极接合体、氧化还原液流电池用单元、及氧化还原液流电池
CN107001254B (zh) 卤代化合物、包含该卤代化合物的聚合物和包含该聚合物的聚合物电解质膜
CN108028407B (zh) 离子导电体及其制造方法、以及包含该导电体的离子交换膜、膜电极组件及燃料电池
KR101750412B1 (ko) 폴리페닐렌계 친수성 주쇄 구조를 갖는 음이온 전도성 블록공중합체를 포함하는 음이온 이온전도체, 이의 제조방법 및 이의 용도
KR20200070813A (ko) 화합물, 이로부터 유래되는 단위를 포함하는 중합체, 이를 포함하는 고분자 분리막, 이를 포함하는 막 전극 집합체, 연료전지 및 레독스 플로우 전지
JPWO2011125735A1 (ja) 固体高分子電解質複合膜およびその製造方法

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20170801