CN106882799A - 剑麻纤维基氮、硫共掺杂类石墨烯碳材料及制备方法 - Google Patents
剑麻纤维基氮、硫共掺杂类石墨烯碳材料及制备方法 Download PDFInfo
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- CN106882799A CN106882799A CN201710125304.4A CN201710125304A CN106882799A CN 106882799 A CN106882799 A CN 106882799A CN 201710125304 A CN201710125304 A CN 201710125304A CN 106882799 A CN106882799 A CN 106882799A
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- sisal fiber
- carbon material
- fiber base
- sulphur
- graphene carbon
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 title claims abstract description 88
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 57
- 239000000835 fiber Substances 0.000 title claims abstract description 57
- 244000198134 Agave sisalana Species 0.000 title claims abstract description 56
- 239000003575 carbonaceous material Substances 0.000 title claims abstract description 52
- 229910021389 graphene Inorganic materials 0.000 title claims abstract description 47
- 229910052757 nitrogen Inorganic materials 0.000 title claims abstract description 44
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title claims abstract description 34
- 239000005864 Sulphur Substances 0.000 title claims abstract description 34
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- 238000001035 drying Methods 0.000 claims abstract description 28
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000007787 solid Substances 0.000 claims abstract description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- 238000010438 heat treatment Methods 0.000 claims abstract description 18
- 244000144992 flock Species 0.000 claims abstract description 17
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 15
- 238000001816 cooling Methods 0.000 claims abstract description 13
- 239000008367 deionised water Substances 0.000 claims abstract description 13
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 13
- 239000000463 material Substances 0.000 claims abstract description 8
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000002135 nanosheet Substances 0.000 claims abstract description 3
- 239000000843 powder Substances 0.000 claims abstract description 3
- 239000002585 base Substances 0.000 claims description 44
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 22
- 238000010792 warming Methods 0.000 claims description 12
- 238000001704 evaporation Methods 0.000 claims description 8
- 230000008020 evaporation Effects 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 5
- 239000000243 solution Substances 0.000 claims description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- 229910000831 Steel Inorganic materials 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 4
- 239000003513 alkali Substances 0.000 claims description 4
- 238000006253 efflorescence Methods 0.000 claims description 4
- 238000010828 elution Methods 0.000 claims description 4
- 238000000227 grinding Methods 0.000 claims description 4
- 239000012535 impurity Substances 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- 238000003760 magnetic stirring Methods 0.000 claims description 4
- 239000004570 mortar (masonry) Substances 0.000 claims description 4
- 206010037844 rash Diseases 0.000 claims description 4
- 150000003839 salts Chemical class 0.000 claims description 4
- 239000010959 steel Substances 0.000 claims description 4
- 239000003643 water by type Substances 0.000 claims description 4
- 238000009413 insulation Methods 0.000 claims description 3
- 239000007864 aqueous solution Substances 0.000 claims description 2
- RQPZNWPYLFFXCP-UHFFFAOYSA-L barium dihydroxide Chemical compound [OH-].[OH-].[Ba+2] RQPZNWPYLFFXCP-UHFFFAOYSA-L 0.000 claims description 2
- 229910001863 barium hydroxide Inorganic materials 0.000 claims description 2
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 2
- 239000000920 calcium hydroxide Substances 0.000 claims description 2
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims description 2
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 2
- 239000000347 magnesium hydroxide Substances 0.000 claims description 2
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 2
- 240000007594 Oryza sativa Species 0.000 claims 1
- 235000007164 Oryza sativa Nutrition 0.000 claims 1
- 229910052571 earthenware Inorganic materials 0.000 claims 1
- 235000009566 rice Nutrition 0.000 claims 1
- 238000005303 weighing Methods 0.000 claims 1
- 238000001994 activation Methods 0.000 abstract description 7
- 238000004146 energy storage Methods 0.000 abstract description 3
- 238000003837 high-temperature calcination Methods 0.000 abstract description 2
- 238000011031 large-scale manufacturing process Methods 0.000 abstract description 2
- 238000004377 microelectronic Methods 0.000 abstract description 2
- 230000007935 neutral effect Effects 0.000 abstract description 2
- 239000002904 solvent Substances 0.000 abstract description 2
- 230000006641 stabilisation Effects 0.000 abstract description 2
- 238000011105 stabilization Methods 0.000 abstract description 2
- 238000005554 pickling Methods 0.000 abstract 1
- 235000011118 potassium hydroxide Nutrition 0.000 description 7
- 238000001228 spectrum Methods 0.000 description 6
- 241000446313 Lamella Species 0.000 description 4
- 238000001069 Raman spectroscopy Methods 0.000 description 4
- 230000005540 biological transmission Effects 0.000 description 4
- 230000005611 electricity Effects 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 238000012512 characterization method Methods 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 description 2
- 229910001950 potassium oxide Inorganic materials 0.000 description 2
- 239000002028 Biomass Substances 0.000 description 1
- 240000003826 Eichhornia crassipes Species 0.000 description 1
- 241001494479 Pecora Species 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 210000003608 fece Anatomy 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 238000005087 graphitization Methods 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- 239000010871 livestock manure Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 238000011017 operating method Methods 0.000 description 1
- 238000000643 oven drying Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000009656 pre-carbonization Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
- C01P2002/82—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by IR- or Raman-data
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/04—Particle morphology depicted by an image obtained by TEM, STEM, STM or AFM
Landscapes
- Carbon And Carbon Compounds (AREA)
- Inorganic Fibers (AREA)
Abstract
Description
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CN201710125304.4A CN106882799B (zh) | 2017-03-04 | 2017-03-04 | 剑麻纤维基氮、硫共掺杂类石墨烯碳材料及制备方法 |
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CN201710125304.4A CN106882799B (zh) | 2017-03-04 | 2017-03-04 | 剑麻纤维基氮、硫共掺杂类石墨烯碳材料及制备方法 |
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CN106882799A true CN106882799A (zh) | 2017-06-23 |
CN106882799B CN106882799B (zh) | 2020-07-31 |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107746055A (zh) * | 2017-10-19 | 2018-03-02 | 天津工业大学 | 一种氮硫共掺杂的多级孔碳纳米片的制备的新方法 |
CN108288702A (zh) * | 2018-01-28 | 2018-07-17 | 桂林理工大学 | 剑麻纤维基三维碳纳米片/二硫化钼/聚苯胺多级结构材料的制备及应用 |
CN110270358A (zh) * | 2018-03-14 | 2019-09-24 | 河北工程大学 | 一种N、S共掺杂石墨烯负载CuO催化剂的制备方法 |
CN112979334A (zh) * | 2021-02-25 | 2021-06-18 | 攀枝花容则钒钛有限公司 | 一种基于3d打印的碳纤维增强受电弓碳滑板的制备方法 |
CN115231568A (zh) * | 2022-05-27 | 2022-10-25 | 塔里木大学 | 类石墨烯碳纳米片大孔交联棉秆生物质碳电极材料及其制备方法 |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103172057A (zh) * | 2013-03-07 | 2013-06-26 | 华南理工大学 | 一种氮硫共掺杂石墨烯的制备方法 |
CN103449399A (zh) * | 2013-07-09 | 2013-12-18 | 新疆师范大学 | 以生物质为原料制备类石墨烯结构碳材料 |
CN104495833A (zh) * | 2015-01-14 | 2015-04-08 | 北京化工大学 | 一种三维结构硫氮共掺杂多级孔石墨烯及其制备方法 |
CN104852016A (zh) * | 2015-05-17 | 2015-08-19 | 桂林理工大学 | 一种亚微米级硫化铜/剑麻纤维炭锂离子电池负极材料及其制备方法 |
CN104891479A (zh) * | 2015-05-26 | 2015-09-09 | 中国林业科学研究院林产化学工业研究所 | 植物基类石墨烯及其制备方法 |
CN106348274A (zh) * | 2016-11-07 | 2017-01-25 | 华南农业大学 | 一种以农林废弃生物质为碳源制备石墨烯的方法 |
CN106365163A (zh) * | 2016-08-23 | 2017-02-01 | 中南大学 | 一种剑麻纤维活性炭的制备方法及该剑麻纤维活性炭在锂离子电容器中的应用 |
CN107665777A (zh) * | 2016-07-30 | 2018-02-06 | 北京化工大学 | 一种生物质基活性炭电极材料的制备方法 |
-
2017
- 2017-03-04 CN CN201710125304.4A patent/CN106882799B/zh active Active
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
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CN103172057A (zh) * | 2013-03-07 | 2013-06-26 | 华南理工大学 | 一种氮硫共掺杂石墨烯的制备方法 |
CN103449399A (zh) * | 2013-07-09 | 2013-12-18 | 新疆师范大学 | 以生物质为原料制备类石墨烯结构碳材料 |
CN104495833A (zh) * | 2015-01-14 | 2015-04-08 | 北京化工大学 | 一种三维结构硫氮共掺杂多级孔石墨烯及其制备方法 |
CN104852016A (zh) * | 2015-05-17 | 2015-08-19 | 桂林理工大学 | 一种亚微米级硫化铜/剑麻纤维炭锂离子电池负极材料及其制备方法 |
CN104891479A (zh) * | 2015-05-26 | 2015-09-09 | 中国林业科学研究院林产化学工业研究所 | 植物基类石墨烯及其制备方法 |
CN107665777A (zh) * | 2016-07-30 | 2018-02-06 | 北京化工大学 | 一种生物质基活性炭电极材料的制备方法 |
CN106365163A (zh) * | 2016-08-23 | 2017-02-01 | 中南大学 | 一种剑麻纤维活性炭的制备方法及该剑麻纤维活性炭在锂离子电容器中的应用 |
CN106348274A (zh) * | 2016-11-07 | 2017-01-25 | 华南农业大学 | 一种以农林废弃生物质为碳源制备石墨烯的方法 |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107746055A (zh) * | 2017-10-19 | 2018-03-02 | 天津工业大学 | 一种氮硫共掺杂的多级孔碳纳米片的制备的新方法 |
CN108288702A (zh) * | 2018-01-28 | 2018-07-17 | 桂林理工大学 | 剑麻纤维基三维碳纳米片/二硫化钼/聚苯胺多级结构材料的制备及应用 |
CN108288702B (zh) * | 2018-01-28 | 2020-07-31 | 桂林理工大学 | 剑麻纤维基三维碳纳米片/二硫化钼/聚苯胺多级结构材料的制备及应用 |
CN110270358A (zh) * | 2018-03-14 | 2019-09-24 | 河北工程大学 | 一种N、S共掺杂石墨烯负载CuO催化剂的制备方法 |
CN112979334A (zh) * | 2021-02-25 | 2021-06-18 | 攀枝花容则钒钛有限公司 | 一种基于3d打印的碳纤维增强受电弓碳滑板的制备方法 |
CN115231568A (zh) * | 2022-05-27 | 2022-10-25 | 塔里木大学 | 类石墨烯碳纳米片大孔交联棉秆生物质碳电极材料及其制备方法 |
CN115231568B (zh) * | 2022-05-27 | 2024-04-02 | 塔里木大学 | 类石墨烯碳纳米片大孔交联棉秆生物质碳电极材料及其制备方法 |
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