CN106586997A - 一种ⅱ型聚磷酸铵的制备方法 - Google Patents
一种ⅱ型聚磷酸铵的制备方法 Download PDFInfo
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- CN106586997A CN106586997A CN201611164228.XA CN201611164228A CN106586997A CN 106586997 A CN106586997 A CN 106586997A CN 201611164228 A CN201611164228 A CN 201611164228A CN 106586997 A CN106586997 A CN 106586997A
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- preparation
- type
- ammonium polyphosphate
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- flame retardant
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- 229920001276 ammonium polyphosphate Polymers 0.000 title claims abstract description 32
- 238000002360 preparation method Methods 0.000 title claims abstract description 18
- 239000004114 Ammonium polyphosphate Substances 0.000 title claims abstract description 14
- 235000019826 ammonium polyphosphate Nutrition 0.000 title claims abstract description 14
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 27
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims abstract description 14
- 238000006243 chemical reaction Methods 0.000 claims abstract description 14
- 239000007788 liquid Substances 0.000 claims abstract description 14
- -1 amide phosphate ester Chemical class 0.000 claims description 18
- 229910021529 ammonia Inorganic materials 0.000 claims description 13
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 12
- 239000003063 flame retardant Substances 0.000 claims description 10
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical class [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims description 8
- 235000019838 diammonium phosphate Nutrition 0.000 claims description 8
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 7
- 229910052698 phosphorus Inorganic materials 0.000 claims description 7
- 239000011574 phosphorus Substances 0.000 claims description 7
- 239000004202 carbamide Substances 0.000 claims description 6
- 235000013877 carbamide Nutrition 0.000 claims description 6
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 5
- 229910019142 PO4 Inorganic materials 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 5
- 239000010452 phosphate Substances 0.000 claims description 5
- 235000021317 phosphate Nutrition 0.000 claims description 5
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 claims description 4
- 238000003786 synthesis reaction Methods 0.000 claims description 3
- 239000005639 Lauric acid Substances 0.000 claims description 2
- NBVXSUQYWXRMNV-UHFFFAOYSA-N monofluoromethane Natural products FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 13
- 238000006116 polymerization reaction Methods 0.000 abstract description 11
- 230000000694 effects Effects 0.000 abstract description 7
- 230000002411 adverse Effects 0.000 abstract description 2
- 230000007423 decrease Effects 0.000 abstract 1
- 150000002500 ions Chemical class 0.000 abstract 1
- 239000013078 crystal Substances 0.000 description 10
- DLYUQMMRRRQYAE-UHFFFAOYSA-N tetraphosphorus decaoxide Chemical compound O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 description 10
- 238000004519 manufacturing process Methods 0.000 description 7
- 239000000463 material Substances 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 3
- 229910000388 diammonium phosphate Inorganic materials 0.000 description 3
- ULOHMAFOISLKBO-UHFFFAOYSA-N methanetrisulfonyl fluoride Chemical compound FS(=O)(=O)C(S(F)(=O)=O)S(F)(=O)=O ULOHMAFOISLKBO-UHFFFAOYSA-N 0.000 description 3
- 229920000137 polyphosphoric acid Polymers 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000005696 Diammonium phosphate Substances 0.000 description 2
- QZXSMBBFBXPQHI-UHFFFAOYSA-N N-(dodecanoyl)ethanolamine Chemical compound CCCCCCCCCCCC(=O)NCCO QZXSMBBFBXPQHI-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- XPDWGBQVDMORPB-UHFFFAOYSA-N trifluoromethane acid Natural products FC(F)F XPDWGBQVDMORPB-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- MKYBYDHXWVHEJW-UHFFFAOYSA-N N-[1-oxo-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propan-2-yl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(C(C)NC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 MKYBYDHXWVHEJW-UHFFFAOYSA-N 0.000 description 1
- 238000007171 acid catalysis Methods 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 235000019628 coolness Nutrition 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000002608 ionic liquid Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/16—Oxyacids of phosphorus; Salts thereof
- C01B25/26—Phosphates
- C01B25/38—Condensed phosphates
- C01B25/40—Polyphosphates
- C01B25/405—Polyphosphates of ammonium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Fireproofing Substances (AREA)
Abstract
Description
编号 | 聚合度 |
M-1 | 1350 |
M-2 | 1322 |
M-3 | 1710 |
M-4 | 1089 |
M-5 | 1066 |
M-6 | 1177 |
M-7 | 541 |
Claims (4)
Priority Applications (1)
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CN106586997A true CN106586997A (zh) | 2017-04-26 |
CN106586997B CN106586997B (zh) | 2018-07-06 |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108059141A (zh) * | 2017-11-26 | 2018-05-22 | 孝感市锐思新材科技有限公司 | 一种ⅱ型聚磷酸铵阻燃材料的制备方法 |
CN108059731A (zh) * | 2017-12-12 | 2018-05-22 | 孝感市锐思新材科技有限公司 | 一种不易水解的聚磷酸铵阻燃剂的制备方法 |
CN109320910A (zh) * | 2018-08-21 | 2019-02-12 | 中国地质大学(武汉) | 金属有机框架结构包裹聚磷酸铵阻燃剂的制备方法及应用 |
CN115159487A (zh) * | 2022-08-05 | 2022-10-11 | 重庆消防安全技术研究服务有限责任公司 | 一种利用废弃干粉灭火剂制备聚磷酸铵的方法 |
CN116040599A (zh) * | 2022-12-08 | 2023-05-02 | 四川大学 | 含氮化合物改性聚磷酸铵及其制备方法与应用 |
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US3514255A (en) * | 1969-04-30 | 1970-05-26 | Chemical Construction Corp | Production of granular diammonium phosphate |
CA2051857A1 (en) * | 1990-10-10 | 1992-04-11 | Thomas Staffel | Process and plant for producing ammonium polyphosphate |
CN101254908A (zh) * | 2008-04-03 | 2008-09-03 | 广州市石磐石阻燃材料有限公司 | 高耐热性结晶ⅱ型聚磷酸铵的制备方法 |
CN101428780A (zh) * | 2008-11-28 | 2009-05-13 | 华东理工大学 | 一种结晶ⅱ型支链聚磷酸铵的制备方法 |
CN101538029A (zh) * | 2009-04-08 | 2009-09-23 | 华东理工大学 | 一种高聚合度结晶ⅱ型聚磷酸铵的制备方法 |
CN101717080A (zh) * | 2009-12-08 | 2010-06-02 | 成都程德化工科技有限责任公司 | 一种结晶ⅱ型聚磷酸铵的制备方法 |
CN101830450A (zh) * | 2010-06-01 | 2010-09-15 | 华东理工大学 | 分段控制制备结晶ⅱ型聚磷酸铵的方法 |
CN102139865A (zh) * | 2011-03-22 | 2011-08-03 | 华东理工大学 | 一种无缩合剂工艺制备结晶ⅱ型聚磷酸铵的方法 |
CN102190291A (zh) * | 2011-03-22 | 2011-09-21 | 华东理工大学 | 一种晶型转化法制备结晶ⅱ型聚磷酸铵的方法 |
CN102259843A (zh) * | 2011-06-16 | 2011-11-30 | 华东理工大学 | 一种低水溶性结晶ⅰ型聚磷酸铵的制备方法 |
CN102976300A (zh) * | 2012-08-23 | 2013-03-20 | 云南天耀化工有限公司 | 采用聚磷酸制备结晶ⅱ型聚磷酸铵的方法 |
CN104724688A (zh) * | 2015-03-17 | 2015-06-24 | 防城港博森化工有限公司 | 一种用磷酸铵盐制取低聚合度水溶性聚磷酸铵的方法 |
CN105800581A (zh) * | 2014-12-29 | 2016-07-27 | 沈阳中化农药化工研发有限公司 | 一种低聚磷酸铵的制备方法 |
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2016
- 2016-12-16 CN CN201611164228.XA patent/CN106586997B/zh active Active
Patent Citations (13)
Publication number | Priority date | Publication date | Assignee | Title |
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US3514255A (en) * | 1969-04-30 | 1970-05-26 | Chemical Construction Corp | Production of granular diammonium phosphate |
CA2051857A1 (en) * | 1990-10-10 | 1992-04-11 | Thomas Staffel | Process and plant for producing ammonium polyphosphate |
CN101254908A (zh) * | 2008-04-03 | 2008-09-03 | 广州市石磐石阻燃材料有限公司 | 高耐热性结晶ⅱ型聚磷酸铵的制备方法 |
CN101428780A (zh) * | 2008-11-28 | 2009-05-13 | 华东理工大学 | 一种结晶ⅱ型支链聚磷酸铵的制备方法 |
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CN101717080A (zh) * | 2009-12-08 | 2010-06-02 | 成都程德化工科技有限责任公司 | 一种结晶ⅱ型聚磷酸铵的制备方法 |
CN101830450A (zh) * | 2010-06-01 | 2010-09-15 | 华东理工大学 | 分段控制制备结晶ⅱ型聚磷酸铵的方法 |
CN102139865A (zh) * | 2011-03-22 | 2011-08-03 | 华东理工大学 | 一种无缩合剂工艺制备结晶ⅱ型聚磷酸铵的方法 |
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CN102259843A (zh) * | 2011-06-16 | 2011-11-30 | 华东理工大学 | 一种低水溶性结晶ⅰ型聚磷酸铵的制备方法 |
CN102976300A (zh) * | 2012-08-23 | 2013-03-20 | 云南天耀化工有限公司 | 采用聚磷酸制备结晶ⅱ型聚磷酸铵的方法 |
CN105800581A (zh) * | 2014-12-29 | 2016-07-27 | 沈阳中化农药化工研发有限公司 | 一种低聚磷酸铵的制备方法 |
CN104724688A (zh) * | 2015-03-17 | 2015-06-24 | 防城港博森化工有限公司 | 一种用磷酸铵盐制取低聚合度水溶性聚磷酸铵的方法 |
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108059141A (zh) * | 2017-11-26 | 2018-05-22 | 孝感市锐思新材科技有限公司 | 一种ⅱ型聚磷酸铵阻燃材料的制备方法 |
CN108059731A (zh) * | 2017-12-12 | 2018-05-22 | 孝感市锐思新材科技有限公司 | 一种不易水解的聚磷酸铵阻燃剂的制备方法 |
CN109320910A (zh) * | 2018-08-21 | 2019-02-12 | 中国地质大学(武汉) | 金属有机框架结构包裹聚磷酸铵阻燃剂的制备方法及应用 |
CN109320910B (zh) * | 2018-08-21 | 2019-10-18 | 中国地质大学(武汉) | 金属有机框架结构包裹的聚磷酸铵阻燃剂的制备方法及应用 |
CN115159487A (zh) * | 2022-08-05 | 2022-10-11 | 重庆消防安全技术研究服务有限责任公司 | 一种利用废弃干粉灭火剂制备聚磷酸铵的方法 |
CN115159487B (zh) * | 2022-08-05 | 2023-08-08 | 重庆消防安全技术研究服务有限责任公司 | 一种利用废弃干粉灭火剂制备聚磷酸铵的方法 |
CN116040599A (zh) * | 2022-12-08 | 2023-05-02 | 四川大学 | 含氮化合物改性聚磷酸铵及其制备方法与应用 |
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Denomination of invention: A preparation method of type II ammonium polyphosphate Granted publication date: 20180706 Pledgee: Zaozhuang rural commercial bank Limited by Share Ltd. Yicheng sub branch Pledgor: Shandong Ruixing Flame Retardant Technology Co.,Ltd. Registration number: Y2024980018120 |
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