CN106232089A - 护肤化妆品 - Google Patents
护肤化妆品 Download PDFInfo
- Publication number
- CN106232089A CN106232089A CN201480078157.4A CN201480078157A CN106232089A CN 106232089 A CN106232089 A CN 106232089A CN 201480078157 A CN201480078157 A CN 201480078157A CN 106232089 A CN106232089 A CN 106232089A
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- CN
- China
- Prior art keywords
- mass
- acid
- cosmetics
- skin
- polyoxyethylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000002537 cosmetic Substances 0.000 title claims abstract description 48
- 230000004224 protection Effects 0.000 title claims abstract description 25
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- 230000006750 UV protection Effects 0.000 claims abstract description 21
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 21
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- -1 methoxyl group Chemical group 0.000 description 82
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- 238000013329 compounding Methods 0.000 description 22
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Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
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- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/26—Aluminium; Compounds thereof
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- Health & Medical Sciences (AREA)
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- Veterinary Medicine (AREA)
- Dermatology (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
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Abstract
目的在于提供能够有效地保护肌肤免受不仅包括大气污染物、酸性液体还包括紫外线的各种外部刺激的护肤化妆品、即抗污染化妆品。本发明提供护肤化妆品,其特征在于,含有(A)0.001~10质量%的偏硅酸铝镁和(B)1~40质量%的紫外线防御剂。本发明的护肤化妆品优选进而含有选自(C)多孔性粉末、(D)柠檬酸(盐)和(E)抗氧化剂的至少一种。
Description
技术领域
本发明涉及能够防止或抑制由大气污染物、紫外线等外部刺激对皮肤造成伤害的护肤化妆品。更详细而言,涉及不仅具有紫外线防御功能还能够有效地吸附大气污染物、并且具有优异的pH缓冲能力的护肤化妆品。
背景技术
皮肤、毛发经常暴露于外部刺激,受到来自外部环境的各种损伤。已知特别是最近被关注的细小颗粒状物质等大气污染物、酸雨等酸性液体附着于皮肤,从而对肌肤带来恶劣影响。另外,还了解到,UVA、UVB等紫外线也对皮肤造成伤害、成为肌肤老化的原因。
为了保护肌肤免受这些外部刺激,可以考虑不使能够成为损伤原因的物质附着于肌肤;和/或缓和由附着的刺激原因物质导致的恶劣影响(酸化防止或中和)等。
作为使化妆品具有如前所述的保护肌肤功能的所谓“抗污染化妆品”,以往提出了配混油性的成膜剂而密密地覆盖肌肤的化妆品等,尽管从不使刺激原因物质附着于肌肤的方面是有效的,但由于以紧密的膜覆盖肌肤,故使用感触较差,是否对所有的刺激原因物质均有效尚未明确。
专利文献1中记载了用于保护皮肤、毛发免受大气污染物所包含的重金属影响的组合物(化妆品),其特征在于,配混有将重金属螯合的螯合剂和神经鞘脂类(sphingolipid)。
专利文献2中记载了配混有兰科紫兰属植物的提取物的皮肤·毛发保护剂,基于该提取物的抗氧化作用缓和了由刺激物质造成的恶劣影响。
这样,还提出了通过捕捉大气污染物等刺激物质、或者抑制氧化作用来保护肌肤的化妆品等,但其效果受到了限制;进一步还具有抑制由紫外线导致的刺激的功能的化妆品也不为人知。
现有技术文献
专利文献
专利文献1:日本特开2004-244423号公报
专利文献2:日本特开2004-262894号公报
发明内容
发明要解决的问题
由此,本发明目的在于提供能够有效地保护肌肤免受不仅包括大气污染物、酸性液体还包括紫外线的各种外部刺激的护肤化妆品、即抗污染化妆品。
用于解决问题的方案
为了解决上述问题,本发明人等进行了深入研究,结果发现,偏硅酸铝镁的大气污染物的吸附性优异,而且还具有中和酸性物质的pH缓冲能力、并且能够与各种紫外线防御剂稳定地组合而配混,至此完成本发明。
即,本发明提供特征在于含有(A)偏硅酸铝镁和(B)紫外线防御剂的护肤化妆品。
发明的效果
本发明的护肤化妆品由于配混有偏硅酸铝镁,因此通过其吸附能力有效地吸附大气污染物而没有到达肌肤,即便附着酸性物质也能够通过pH缓冲能力中和,能够减轻由这些外部刺激导致的肌肤损伤。另外,由于与偏硅酸铝镁组合而配混有紫外线防御剂,因此能够同时抑制由紫外线导致的损伤。
具体实施方式
以下,对于本发明的护肤化妆品详细地进行说明。
本发明的护肤化妆品含有(A)偏硅酸铝镁。
本发明所使用的偏硅酸铝镁优选为不具有晶体形式的非晶形的物质,通常以颗粒状或粉末状使用。由于是无定形结构,所以不能正确地用化学结构式表示,简便地用以下的通式(1)表示。
Al2O3·MgO·1.7SiO2·xH2O (1)
偏硅酸铝镁的颗粒或粉末具有如下特征:比表面积极大(至少100m2/g、通常为250~300m2/g),因此吸水性和吸油性优异,另一方面,具有酸性物质的中和能力。
本发明中,可以使用市售的偏硅酸铝镁,可列举出例如:富士化学工业株式会社制的Neusilin(注册商标)。
本发明中所使用的偏硅酸铝镁可以为颗粒状也可以为粉末状,对于其形状和粒径没有特别的限定,通常优选为具有20、30、40或50μm以上且2000、1000或800μm以下粒径的球状粉末或颗粒。
对于本发明护肤化妆品中的偏硅酸铝镁的配混量没有特别的限定,通常为0.001、0.005、0.008或0.01质量%以上,且优选为10质量%以下、更优选为5质量%以下、进而优选为3质量%以下。可以在例如0.001~10质量%、0.05~5质量%或0.01~3质量%等范围内配混。配混量小于0.001质量%时,难以得到由偏硅酸铝镁的配混带来的效果;大于10质量%配混时,会有损良好的使用感。
本发明的护肤化妆品除了前述(A)偏硅酸铝镁之外还含有(B)紫外线防御剂。本发明中的紫外线防御剂是指由紫外线吸收剂和紫外线散射剂的两者或任一者构成的。
对能够构成紫外线防御剂的紫外线吸收剂,没有特别的限定,可以从化妆品等中选择通常使用的物质。
作为紫外线吸收剂的具体例,可列举出例如:对氨基苯甲酸(PABA)、PABA单甘油酯、N,N-二丙氧基PABA乙酯、N,N-二乙氧基PABA乙酯、N,N-二甲基PABA乙酯、N,N-二甲基PABA丁酯、二乙氨基羟基苯甲酰基苯甲酸己酯等苯甲酸系紫外线吸收剂;N-乙酰基邻氨基苯甲酸均薄荷酯等邻氨基苯甲酸系紫外线吸收剂;水杨酸戊酯、水杨酸薄荷酯、水杨酸均薄荷酯、水杨酸辛酯、水杨酸苯酯、水杨酸苄酯、水杨酸对异丙醇苯酯等水杨酸系紫外线吸收剂;肉桂酸辛酯、乙基-4-异丙基肉桂酸酯、甲基-2,5-二异丙基肉桂酸酯、乙基-2,4-二异丙基肉桂酸酯、甲基-2,4-二异丙基肉桂酸酯、丙基-对甲氧基肉桂酸酯、异丙基-对甲氧基肉桂酸酯、异戊基-对甲氧基肉桂酸酯、辛基-对甲氧基肉桂酸酯〔=2-乙基己基-对甲氧基肉桂酸酯〕、2-乙氧基乙基-对甲氧基肉桂酸酯、环己基-对甲氧基肉桂酸酯、乙基-α-氰基-β-苯基肉桂酸酯、2-乙基己基-α-氰基-β-苯基肉桂酸酯、甘油基单-2-乙基己酰基-二对甲氧基肉桂酸酯、3,4,5-三甲氧基肉桂酸3-甲基-4-[甲基双(三甲基硅烷氧基)甲硅烷基]丁酯等肉桂酸系紫外线吸收剂;2-苯基-5-甲基苯并恶唑、2,2’-羟基-5-甲基苯基苯并三唑、2-(2’-羟基-5’-叔辛基苯基)苯并三唑、2-(2’-羟基-5’-甲基苯基苯并三唑、二苄肼(dibenzalazine)、二茴香酰基甲烷、4-叔丁基-4’-甲氧基二苯甲酰基甲烷、4-(1,1-二甲基乙基)-4’-甲氧基二苯甲酰基甲烷、5-(3,3-二甲基-2-降冰片叉基)-3-戊烷-2-酮、奥克立林〔=2-氰基-3,3-二苯基-2-丙酸-2-乙基己基酯〕、聚硅氧烷-15〔=亚苄基丙二酸盐聚硅氧烷〕、二(2-乙基己基)-4’-甲氧基亚苄基丙二酸酯等。
对能够构成紫外线防御剂的紫外线散射剂,没有特别的限定,可以从化妆品等中通常使用的物质中选择。
优选使用例如:氧化钛、氧化锌等金属氧化物粉末。
通过组合紫外线吸收剂和紫外线散射剂进行配混,能够在广的波长区域提高紫外线防御效果。
本发明的护肤化妆品中的紫外线防御剂的配混量(紫外线吸收剂与紫外线散射剂的总配混量)通常为40质量%以下,优选为35质量%以下,更优选为30质量%以下。对于紫外线防御剂的配混量的下限,没有特别的限定,通常为1、1.5或2质量%以上。可以在例如1~40质量%、1.5~35质量%、或者2~30质量%等范围内配混。配混量小于1质量%时,有得不到充分的紫外线防御功能的情况;超过40质量%配混时,有有损良好的使用感的情况。
本发明的护肤化妆品由于含有(A)偏硅酸铝镁,能够有效地吸附大气污染物等,能够基于其pH缓冲能力中和附着的酸性液体。本发明的护肤化妆品进一步含有(B)紫外线防御剂,所以能够有效地防御皮肤免遭紫外线。兼具有这样的功能的化妆品还不为人知。
本发明的护肤化妆品除了前述必须成分(A)和(B)以外,还优选配混以下的成分。
(C)多孔性粉末
通过在本发明的护肤化妆品中配混具有吸附性的多孔性粉末,能够进一步提高基于(A)偏硅酸铝镁的本发明的化妆品的污染物质吸附功能。
对于本发明中能够配混的多孔性粉末,只要是能够在化妆品等中能够配混的物质则没有特别的限定,可列举出例如:氧化硅、纤维素、沸石、膨润土等粘土矿物作为具体例。
对于前述多孔性粉末的形状和平均粒径,没有特别的限定,从使用性等观点出发,通常优选配混1~100μm左右的球状粉末。
配混多孔性粉末的情况下,其配混量优选为0.01质量%以上,更优选为0.05质量%以上,进而优选为0.1质量%以上,并且优选为10质量%以下,更优选为5质量%以下,进而优选为3质量%以下。可以在例如0.01~10质量%、0.05~5质量%或者0.1~3质量%的范围内配混。
(D)柠檬酸(盐)
通过在本发明的护肤化妆品中配混具有缓冲能力的柠檬酸(盐),能够进一步提高基于(A)偏硅酸铝镁的本发明的pH缓冲能力。
柠檬酸/柠檬酸盐具有形成pH缓冲体系而调节化妆品pH的功能。作为柠檬酸盐,可列举出以钠盐、钾盐等为代表例。
配混柠檬酸(盐)的情况下,其配混量优选为0.01质量%以上,更优选为0.015质量%以上,进一步优选为0.2质量%以上,且优选为5质量%以下,更优选为3质量%以下,进而优选为1质量%以下。可以在例如0.01~5质量%、0.01~3质量%或者0.01~1质量%的范围内配混。
(E)抗氧化剂
本发明的护肤化妆品能够基于(A)偏硅酸铝镁的吸附能力和pH缓冲能力来防止由大气污染物、酸性液体导致的肌肤损伤;进而通过配混抗氧化剂,防止由氧化物质导致的损伤的效果提高。
作为本发明中使用的抗氧化剂,可列举出:硫代牛磺酸、亚牛磺酸、谷胱甘肽、半胱氨酸和胱氨酸等含硫化合物;α-生育酚及其衍生物;红茶提取物、绿茶提取物、百里香提取物、蒲桃提取物等植物提取物。
硫代牛磺酸等含硫化合物和α-生育酚也可以以盐的形式配混,没有特别的限定,可例示出:钠盐、钾盐、锂盐等碱金属盐;镁盐、钙盐等碱土金属盐;铵盐、氨基酸盐等。
配混抗氧化剂的情况下,其配混量优选为0.001质量%以上,更优选为0.0015质量%以上,进而优选为0.02质量%以上,且优选为1质量%以下,更优选为0.5质量%以下,进而优选为0.1质量%以下。可以以例如:0.001~1质量%、0.001~0.5质量%或0.001~0.1质量%的范围内配混。
本发明的护肤化妆品可以以水性化妆品(包括微乳液)、水包油型乳化化妆品、油包水型乳化化妆品和油性化妆品等任意的形式提供。并且,可以在不有损本发明的效果的范围内含有通常在以这些形式提供的化妆品中可以配混的其他的任意成分。
对于能够配混的任意成分没有限定,可列举出:油性成分、表面活性剂、保湿剂、增稠剂、醇类、粉末成分、有机改性粘土矿物、水性成分、各种试剂等。
作为油性成分,可列举出例如:山茶油、澳洲坚果油、橄榄油、蓖麻油、红花油、大豆油、茶籽油、可可脂、椰油、硬化椰油、棕榈油、日本蜡、氢化蓖麻油、蜜蜡、小树烛蜡、巴西棕榈蜡、羊毛脂、液态羊毛脂、霍霍巴蜡、硬质羊毛脂、聚氧乙烯羊毛醇醚、聚氧乙烯胆固醇醚等天然油脂类;液体石蜡、地蜡、角鲨烯、石蜡、白地蜡、凡士林、微晶蜡等烃系油脂类;肉豆蔻酸异丙酯、肉豆蔻酸辛基十二烷基酯、棕榈酸异丙酯、12-羟基硬脂酸胆固醇酯、二-2-乙基己基酸乙二醇酯、二季戊四醇脂肪酸酯、四-2-乙基己基酸季戊四醇、三-2-乙基己基酸甘油酯、三异硬脂酸三羟甲基丙烷、鲸蜡基-2-乙基己酸酯、蓖麻油脂肪酸甲基酯等合成油性成分;二甲基聚硅氧烷、甲基苯基聚硅氧烷、甲基氢聚硅氧烷等链状聚硅氧烷;十甲基聚硅氧烷、十二甲基聚硅氧烷、四甲基四氢聚硅氧烷等环状聚硅氧烷;能够形成三维网络结构的有机硅树脂、有机硅橡胶等有机硅类等。
作为亲油性非离子性表面活性剂,可列举出例如:失水山梨醇单油酸酯、失水山梨醇单异硬脂酸酯、失水山梨醇单月桂酸酯、失水山梨醇单棕榈酸酯、失水山梨醇单硬脂酸酯、失水山梨醇倍半油酸酯、五-2-乙基己基酸失水山梨醇二甘油酯等失水山梨醇的脂肪酸酯类;甘油单硬脂酸酯、焦谷氨酸甘油油酸酯、甘油单硬脂酸酯的苹果酸酯等甘油或聚甘油的脂肪酸酯类、丙二醇单硬脂酸酯等丙二醇的脂肪酸酯类、氢化蓖麻油衍生物、甘油烷基醚等。
作为亲水性非离子性表面活性剂,可列举出例如:聚氧乙烯失水山梨糖醇单油酸酯、聚氧乙烯失水山梨糖醇单硬脂酸酯等聚氧乙烯失水山梨糖醇的脂肪酸酯类;聚氧乙烯山梨醇单月桂酸酯、聚氧乙烯山梨醇单油酸酯、聚氧乙烯山梨醇单硬脂酸酯等聚氧乙烯山梨醇的脂肪酸酯类;聚氧乙烯甘油单硬脂酸酯、聚氧乙烯甘油单异硬脂酸酯、聚氧乙烯甘油三异硬脂酸酯等聚氧乙烯甘油的脂肪酸酯、聚氧乙烯单油酸酯、聚氧乙烯二硬脂酸酯等聚氧乙烯的脂肪酸酯类;聚氧乙烯月桂基醚、聚氧乙烯油基醚、聚氧乙烯硬脂基醚、聚氧乙烯(2-辛基十二烷基)醚、聚氧乙烯胆甾醇醚等聚氧乙烯的烷基醚类;聚氧乙烯辛基苯基醚、聚氧乙烯壬基苯基醚、聚氧乙烯二壬基苯基醚等聚氧乙烯的烷基苯基醚类;Pluronic等Pluronic型表面活性剂、(聚氧乙烯聚氧丙烯)鲸蜡基醚、(聚氧乙烯聚氧丙烯)2-癸基十四烷基醚、(聚氧乙烯聚氧丙烯)丁基醚、氢化羊毛脂、聚氧乙烯聚氧丙烯与甘油的醚等聚氧乙烯聚氧丙烯的烷基醚类;Tetronic等聚氧乙烯或聚氧丙烯与乙二胺的缩合物类;聚氧乙烯蓖麻油、聚氧乙烯氢化蓖麻油、聚氧乙烯氢化蓖麻油单异硬脂酸酯、聚氧乙烯氢化蓖麻油三异硬脂酸酯、聚氧乙烯氢化蓖麻油单焦谷氨酸酯单异硬脂酸酯、聚氧乙烯氢化蓖麻油马来酸酯等聚氧乙烯蓖麻油或者聚氧乙烯氢化蓖麻油的衍生物;椰油脂肪酸二乙醇酰胺、月桂酸单乙醇酰胺、脂肪酸异丙醇酰胺等烷醇酰胺;聚氧乙烯丙二醇的脂肪酸酯类;聚氧乙烯的烷基胺类;聚氧乙烯的脂肪酰胺、蔗糖的脂肪酸酯、聚氧亚乙基壬基酚与甲醛的缩合物、烷基乙氧基二甲基胺氧化物、磷酸三油酯等。
作为阴离子性表面活性剂,可列举出例如:月桂酸钠、棕榈酸钠等脂肪酸皂;月桂硫酸钠、月桂硫酸钾等高级烷基硫酸酯的盐;聚氧乙烯月桂硫酸与三乙醇胺的盐;聚氧乙烯月桂硫酸钠等烷基醚硫酸酯的盐;月桂酰基肌氨酸钠等N-酰基肌氨酸、N-肉豆蔻酰基-N-甲基牛磺酸钠、椰油脂肪酸甲基牛磺酸钠、月桂基甲基牛磺酸钠等高级脂肪酰胺的磺酸盐;聚氧乙烯油基醚磷酸钠、聚氧乙烯硬脂基醚磷酸钠等磷酸酯盐;二-2-乙基己基磺基琥珀酸钠、单月桂酰基单乙醇酰胺聚氧乙烯磺基琥珀酸钠、月桂基聚丙二醇磺基琥珀酸钠等磺基琥珀酸盐;十二烷基苯磺酸钠、十二烷基苯磺酸三乙醇胺等烷基苯磺酸盐;N-月桂酰基谷氨酸单钠、N-硬脂酰基谷氨酸二钠等N-酰基谷氨酸、硬化椰油脂肪酸甘油硫酸钠等高级脂肪酸酯的硫酸酯的盐;聚氧乙烯烷基醚的羧酸盐;α-烯烃磺酸盐;高级脂肪酸酯的磺酸盐;仲醇硫酸酯的盐;高级脂肪酸烷氧基酰胺的硫酸酯的盐;月桂酰基单乙醇酰胺琥珀酸钠、N-棕榈酰基天冬氨酸、二(三乙醇)胺、椰油脂肪酸胶原蛋白水解碱盐等。
作为阳离子性表面活性剂,可列举出例如:硬脂基三甲基氯化铵、月桂基三甲基氯化铵等烷基三甲基铵盐、氯化二硬脂基二甲基铵等二烷基二甲基铵盐、氯化聚(N,N’-二甲基-3,5-亚甲基哌啶鎓盐)、氯化鲸蜡基吡啶鎓等烷基吡啶鎓盐、烷基季铵盐、烷基二甲基苄基铵盐、烷基异喹啉鎓盐、二烷基吗啉鎓盐、聚氧乙烯烷基胺、烷基胺盐、聚胺的脂肪酸衍生物、戊醇的脂肪酸衍生物、苯扎氯铵、苄索氯铵、阳离子聚合物、丙烯酸β-N,N-二甲基-N-乙基氨溶乙基氯化乙烯基吡咯烷酮共聚物等。
作为两性表面活性剂,可列举出例如:2-十一烷基-N,N,N-三(羟基乙基羧基甲基)-2-咪唑啉钠、2-椰油酰基-2-氢氧化咪唑啉鎓-1-羧基乙基氧基二钠等咪唑啉系两性表面活性剂;2-十七烷基-N-羧基甲基-N-羟基乙基咪唑甜菜碱、月桂基二甲基氨基乙酸甜菜碱、烷基甜菜碱、酰胺甜菜碱、磺基甜菜碱等甜菜碱系两性表面活性剂等。
作为保湿剂,可列举出例如:乙二醇、丙二醇、一缩二丙二醇、1,3-丁二醇、甘油、赤藓醇醇、三羟甲基丙烷、季戊四醇、山梨醇、麦芽糖醇、二甘油、聚乙二醇等多元醇;胆固醇-12-羟基硬脂酯、乳酸钠、dl-吡咯烷酮羧酸盐、尿素、二甘油环氧乙烷·环氧丙烷加成物等。
作为增稠剂,可列举出例如:阿拉伯树胶、卡拉胶、黄蓍胶、榅桲籽(marmelo)、酪蛋白、酪蛋白钠、环糊精、明胶、海藻酸钠、甲基纤维素、乙基纤维素、羧基甲基纤维素、羟基乙基纤维素、羟基丙基纤维素、聚乙烯基醇、聚丙烯酸钠、羧基乙烯基聚合物、瓜尔豆胶、黄原胶等。
作为高级醇,可列举出例如:月桂醇、硬脂基醇、山萮醇、肉豆蔻醇、油醇、十八十六醇、单硬脂基甘油醚(鲨肝醇)、羊毛脂醇、胆固醇、植物甾醇、异硬脂基醇、辛基十二醇等。
作为粉末成分,可列举出例如:滑石、高岭土、云母、绢云母(sericite)、金云母、合成云母、碳酸镁、碳酸钙、硅酸铝、氧化硅、沸石、硫酸钡、焙烧硫酸钙(烧石膏)、磷酸钙、氟代磷灰石、羟基磷灰石、陶瓷粉末、金属皂(肉豆蔻酸锌、棕榈酸钙、硬脂酸铝等)、氮化硼等无机粉末;聚酰胺树脂粉末(尼龙粉末)、聚乙烯粉末、聚甲基丙烯酸甲酯粉末、聚苯乙烯粉末、苯乙烯-丙烯酸共聚物粉末、聚甲基倍半硅氧烷粉末、纤维素粉末等有机粉末等。另外,作为合成树脂乳液,可列举出例如:丙烯酸类树脂乳液、聚乙酸乙烯酯树脂乳液等。
作为有机改性粘土矿物,优选膨润土这样的天然或合成的蒙脱石的粘土矿物与季铵盐化合物通过离子交换反应加成而成的物质。有机改性粘土矿物只要是药学上能够允许的物质则没有特别限定,可列举出例如:二甲基铵锂蒙脱石、苄基二甲基硬脂基铵锂蒙脱石、氯化二硬脂基二甲基铵处理偏硅酸铝镁等。作为市售品,优选例示出:由Elementis公司以“Benton38VCG”的名称销售的二甲基二硬脂基铵锂蒙脱石;由Elementis公司以“Benton27VCG”的名称销售的苄基二甲基硬脂基铵锂蒙脱石等。特别是在制成为油包水型乳化化妆品时,通过配混有机改性粘土矿物能够提高乳化物的均匀性。
除了上述之外,还可以适宜含有依地酸二钠、依地酸三钠、柠檬酸钠、多磷酸钠、偏磷酸钠、葡糖酸等金属离子掩蔽剂;咖啡因、单宁、维拉帕米、氨甲环酸及其衍生物、各种生药、乙酸生育酚、甘草酸及其衍生物或其盐等试剂;抗坏血酸、磷酸镁、曲酸等其他的美白剂;葡萄糖、果糖、甘露糖、蔗糖、海藻糖等糖类等。
对于本发明的护肤化妆品,没有特别的限定,优选以霜、软膏、凝胶、化妆水、乳液等形式提供。
实施例
对于本发明以下可以列举实施例进行详细叙述。需要说明的是,对于配混量,只要没有特别的说明,是指质量%。
实施例1:大气污染物吸附效果
以下述表1所示的配方制备试样。
[表1]
向上述各试样中混合5质量%具有下述组成的拟大气污染物(分散物),静置15分钟。
·拟大气污染物:碳黑(1质量%)+辛酸鲸蜡酯(99质量%)
按照以下的基准,对于观察刚加入前述的拟大气污染物之后以及静置15分钟后的试样的外观的结果,进行评价。同时,对各试样的紫外线防御效果进行测定,按照以下的基准进行评价。将这些结果组合示于表2。
·评价基准
吸附效果:
静置15分钟后,碳黑沉降而可见透明层:A
没有看见碳黑的沉降和透明层:B
紫外线防御效果:
波长300nm时的吸光度为1以上:A
波长300nm时的吸光度小于1:B
[表2]
评价项目 | 实施例1 | 比较例1 | 比较例2 | 比较例3 |
吸附效果 | A | A | B | B |
紫外线防御效果 | A | A | A | A |
由表2所示的结果可知,包含等量紫外线防御剂(紫外线吸收剂)的各试样具有充分的紫外线防御功能。但是,作为粉末成分配混了(乙烯基聚二甲基硅氧烷/聚甲基硅氧烷倍半硅氧烷)交联聚合物的比较例2和没有配混粉末成分的比较例3中,没有能吸附作为拟大气污染物的碳黑并使之沈降;与此相对,配混了偏硅酸铝镁或氧化硅的实施例1和比较例1中,碳黑沈降而形成透明层。
实施例2:pH缓冲效果
按照与表1相同的配方制备试样。在各试样中混合与实施例1同样的拟大气污染物,进而加入各试样9倍量(质量)的酸性溶液(1.1质量%的柠檬酸水溶液)之后,测定各试样的pH。加入酸性溶液之后的、各试样的最终组成如以下的表3所示。
[表3]
需要说明的是,将加入了酸性溶液时的pH值变化小于1.0的例子评价为“A”;变化了1.0以上的例子评价为“B”。
如表3所示,只有配混了偏硅酸铝镁的实施例2,即便加入了酸性溶液也能维持接近中性的pH(表现出了缓冲能力);但没有配混粉末的比较例4以及配混了其他的粉末的比较例5和6,没有能防止由酸性溶液导致的酸性化。
即,确认到只有组合偏硅酸铝镁和紫外线防御剂而配混的化妆品起到大气污染物的吸附、pH缓冲和紫外线防御的所有的效果。
实施例3:配方例(防晒霜)
制造方法:
将(1)~(10)混合分散。之后,添加混合溶解了的(11)~(20)的水相进行混合,得到目标的防晒霜。
得到的防晒霜具有大气污染物的吸附能力、pH缓冲能力和紫外线防御功能的全部。
实施例4:配方例(防晒乳液(2层型))
制造方法:
将(1)~(12)混合分散。之后,添加混合溶解了的(13)~(21)的水相进行混合,得到目标的防晒乳液。
得到的防晒乳液具有大气污染物的吸附能力、pH缓冲能力和紫外线防御功能的全部。
Claims (4)
1.一种护肤化妆品,其特征在于,含有(A)0.001~10质量%的偏硅酸铝镁和(B)1~40质量%的紫外线防御剂。
2.根据权利要求1所述的化妆品,其进而含有(C)多孔性粉末。
3.根据权利要求1或2所述的化妆品,其进而含有(D)柠檬酸(盐)。
4.根据权利要求1~3的任一项所述的化妆品,其进而含有(E)抗氧化剂。
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CN111225656A (zh) * | 2017-10-18 | 2020-06-02 | 株式会社Lg生活健康 | 微尘阻隔用化妆料组合物 |
CN111991258A (zh) * | 2020-10-12 | 2020-11-27 | 上海辉文生物技术股份有限公司 | 一种皮肤解毒和抗氧化组合物及其应用 |
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KR102262308B1 (ko) * | 2017-03-31 | 2021-06-09 | (주)아모레퍼시픽 | 구상 파우더를 포함하는 안티-폴루션 화장료 조성물 |
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