CN106103087A - 具有离型作用的多层塑料薄膜 - Google Patents

具有离型作用的多层塑料薄膜 Download PDF

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Publication number
CN106103087A
CN106103087A CN201580014112.5A CN201580014112A CN106103087A CN 106103087 A CN106103087 A CN 106103087A CN 201580014112 A CN201580014112 A CN 201580014112A CN 106103087 A CN106103087 A CN 106103087A
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CN
China
Prior art keywords
plastic sheeting
film
plastic
embossing
layer
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Granted
Application number
CN201580014112.5A
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English (en)
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CN106103087B (zh
Inventor
I.泽巴尔德
W.施密特
F.格里姆
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Loparex Germany GmbH and Co KG
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Huhtamaki Films Germany GmbH and Co KG
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Priority claimed from DE102014010691.8A external-priority patent/DE102014010691A1/de
Application filed by Huhtamaki Films Germany GmbH and Co KG filed Critical Huhtamaki Films Germany GmbH and Co KG
Publication of CN106103087A publication Critical patent/CN106103087A/zh
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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Laminated Bodies (AREA)
  • Wrappers (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)

Abstract

本发明涉及具有离型作用和≤ 18 µm,优选≤ 12 µm的总厚度且至少单轴拉伸的多层塑料薄膜,其在至少一个表面上具有至少部分的压花。

Description

具有离型作用的多层塑料薄膜
本发明涉及具有离型作用和≤ 18 µm,优选≤ 12 µm的总厚度的多层塑料薄膜,其至少单轴拉伸并在至少一个表面上具有至少部分的压花,和涉及本发明的塑料薄膜作为优选用于独立包装的卫生产品或失禁产品的包装材料的用途。
已知具有离型作用的塑料薄膜用于多种应用中,例如作为用于工业领域中,例如建筑领域、家具工业或包装工业中的粘性产品的保护薄膜和/或离型薄膜。具有离型性能的塑料薄膜还优选地用于包装粘性制品,优选自粘性制品,优选用于一次性使用的那些制品的卫生领域。由于该类卫生制品如卫生护垫或卫生巾以及失禁制品越来越多地独立包装,对于包装材料的需求日益上升。由于不仅该类包装材料,而且另外所用的保护薄膜和离型薄膜几乎不可再循环并因此不能重新使用,越来越多尝试的是,尽可能少地将化石资源用于这些聚合物材料。这意味着,对于相应塑料薄膜的制备,应当尽可能少地使用由化石原料获得的聚合物,但不必丧失对于该类塑料薄膜,特别是对其机械性能、其离型作用、阻隔性能和其它必要的物理性能的不可缺少的品质要求。
为了在所述塑料薄膜的制备中节约聚合物材料,首先显而易见的是减小此类多层塑料薄膜的总层厚度。然而,由于因此通常造成该类塑料薄膜的机械性能例如其拉伸应力、其耐撕裂蔓延性(Weiterreißfestigkeit)和其任选的耐穿刺性的部分强烈降低,这不仅在该塑料薄膜进一步加工成为终产品的过程中不利于其操作,而且也可能对相应包装的耐久性具有负面影响。因此,此类节约材料的可能方式所产生的风险并非微不足道。另外,在甚至对具有≤ 20 µm的总层厚度的塑料薄膜进行离型处理时也可能存在困难。
因此,本发明的目的是提供具有离型性能的塑料薄膜,其尽管将所述塑料薄膜的总厚度减小到低于20 µm,依然具有特别是对于不受干扰的处理和进一步加工来说的优异机械性能,以及优异的离型作用。
此目的通过提供具有离型性能和≤ 18 µm,优选≤ 12 µm,特别是5 µm至≤ 12 µm的总厚度的多层塑料薄膜得以实现,该塑料薄膜至少单轴拉伸并在至少一个表面上具有至少部分的压花。
本发明的多层塑料薄膜的特征在于它在机器方向上具有至少1:2,优选1:3-1:5的至少单轴的拉伸。
任选地,本发明的塑料薄膜也可是双轴拉伸的,这意味着它也可以具有与机器方向横向的1:2-1:3.5拉伸。在双轴拉伸的情况下,即在机器方向上且在与机器方向横向上拉伸的情况下,这两个方向上的拉伸比可以不同,其中在机器方向上的拉伸优选大于在与机器方向横向上的。
本发明的塑料薄膜是多层的,优选地具有至少三层,更优选至少五层的。在其它优选的实施方案中,本发明的塑料薄膜甚至可以具有7-11层。
优选地,本发明的多层塑料薄膜包含由下面的聚合物层构成的层次序:
(a) 作为外层的任选可密封或任选配备有离型处理的层(a),
任选的(b) 增粘剂层(b),
(c) 任选具有阻隔作用的层(c),
任选的(d) 增粘剂层(d),
(e) 作为外层的任选可密封的层(e)。
优选地,本发明的塑料薄膜的各层由选自包含如下的热塑性聚合物制备:聚烯烃、聚酰胺、聚酯、生物可降解的聚合物、所提及的聚合物的至少两种单体的共聚物和所提及的聚合物的至少两种单体的混合物。
优选地,本发明的塑料薄膜由至少50重量%,更优选至少70重量%的聚烯烃、烯烃共聚物或其混合物组成,除了环烯烃或环烯烃共聚物或其混合物之外。
优选地,本发明的多层薄膜的层(a)和(e)以及任选的层(c)各自相同或不同地基于具有2-8个,优选2-3个碳原子的α,β-不饱和烯烃的聚烯烃和烯烃共聚物,其优选选自:聚乙烯(PE)–尤其是0.86-0.93 g/cm3的低密度聚乙烯(LDPE),0.86-0.94 g/cm3的线性低密度聚乙烯(LLDPE),其除了乙烯外还包含一种或多种具有多于2个碳原子的α-烯烃作为共聚单体,0.926-0.94 g/cm3的中密度聚乙烯(MDPE),0.94-0.97 g/cm3 的高密度聚乙烯(HDPE),乙烯与具有4个或更多个碳原子的α-烯烃的共聚物(mPE);聚丙烯(PP),聚异丁烯(PI),聚丁烯(PB)或优选具有1-10摩尔%乙烯的乙烯-丙烯共聚物(EPC)。特别优选地,可以使用至少一种PE与至少一种PP的混合物,优选LDPE、MDPE或LLDPE的混合物或LLDPE和/或MDPE和/或PP的混合物,其中MDPE或PP在混合物中的含量基于所述混合物的总重量计各自为5重量%-80重量%。
所述层(a)和(e)也可以由烯烃/乙烯基羧酸共聚物或烯烃/乙烯基酯,如乙烯-丙烯酸共聚物(EAA),它们的酯如(EMA),乙烯-甲基丙烯酸共聚物(EMAA),它们的酯如(EMMA),优选具有60-99摩尔%乙烯的乙烯-乙酸乙烯酯共聚物(EVA),或前面提及的聚合物种类中各自至少两种的混合物组成。
根据一个另外的实施方案,至少作为外层的层(e)可以基于至少一种聚酯或至少一种共聚酯,其优选选自:聚对苯二甲酸乙二醇酯(PET、c-PET、a-PET)和共聚物如coPET、PBT和coPBT)。“PET”是指通过乙二醇与对苯二甲酸缩聚制备的聚对苯二甲酸乙二醇酯。也可使用无定形的PET (a-PET)和结晶的PET (c-PET)。“coPET”是指除了乙二醇与对苯二甲酸之外还可包含其它单体例如支化或芳族二醇的共聚酯。“coPBT”是指聚对苯二甲酸丁二醇酯。优选地,使用的聚酯或共聚酯具有优选0.1-2.0 dl/g,更优选0.3-1.5 dl/g,特别是0.6-1.0 dl/g的特性粘度,其中用于测定特性粘度的方法是本领域技术人员已知的。合适的PET和PBT的详细描述公开在Kunststoffhandbuch第3/1卷 – technischeThermoplaste:Polycarbonate, Polyacetale, Polyester, Celluloseester;CarlHanser Verlag, 1992,引用其全部内容。
在一个另外的实施方案中,至少层(e)可基于至少一种生物可降解的聚合物。所用的合适的生物可降解的热塑性聚合物可以是至少一种选自如下的生物可降解的聚合物:乳酸均聚物和共聚物,优选聚交酯,更优选DL-丙交酯、L-丙交酯和D-丙交酯聚合物,聚羟基链烷酸酯,纤维素,纤维素衍生物,热塑性淀粉,聚酯,优选聚己内酯,聚醚,至少部分皂化的聚乙酸乙烯酯,乙烯-乙烯醇共聚物和所提及的聚合物的至少两种单体的共聚物。
在一个优选的实施方案中,本发明的多层薄膜具有至少一个具有阻隔作用的层(c)。本领域技术人员已知合适的聚合物,其可用于实现阻隔作用,特别是针对气体或香气损失、针对低分子量组分的迁移和/或针对口味或气味损害物,或针对湿气和/或油和脂肪的阻隔作用。
相应地,针对气体,优选针对O2、H2O蒸汽或香气损失、针对低分子量组分的迁移和/或针对口味或气味损害物具有阻隔作用的层(c)基于至少一种选自如下的热塑性聚合物:乙烯-乙烯醇共聚物、聚乙烯醇、聚偏二氯乙烯、偏二氯乙烯共聚物、聚醚-聚酰胺嵌段共聚物和所述聚合物与乙烯-乙酸乙烯酯共聚物的混合物。优选的偏二氯乙烯共聚物具有80%或更高的偏二氯乙烯含量。乙烯-乙烯醇共聚物是特别优选的。
根据另一个优选的实施方案,针对湿气和/或油与脂肪的阻隔作用通过优选基于热塑性、脂族或(部分)芳族的聚酰胺或共聚酰胺或其混合物的层(c)得以实现。
作为用于制备至少一个层(c)的聚酰胺(PA)或共聚酰胺(coPA),可以使用优选脂族或(部分)芳族的聚酰胺,其优选具有160-240℃,更优选170-220℃的熔点。优选的是脂族聚酰胺,其中使用至少一种选自PA 6、PA 12、PA 6,6、PA 6,12、PA 6/6,6、PA 6,6/6的聚酰胺或共聚酰胺或部分芳族的聚酰胺如PA6T和PA6I。优选地,也可以使用具有异佛尔酮二胺单元的聚酰胺。聚酰胺和共聚酰胺的详细描述可见于Kunststoff-Handbuch第VI卷,Polyamide, Carl Hanser Verlag München, 1966;和Melvin I. Kohan, Nylon Plastics Handbook, Carl Hanser Verlag München, 1995,引用其全部内容。
如已经提及的,特别可用于制备层(c)的是选自如下的均聚酰胺和/或共聚酰胺:热塑性、脂族、部分芳族和芳族且具有异佛尔酮二胺单元的均聚酰胺或共聚酰胺。这些具有异佛尔酮二胺单元的均聚酰胺或共聚酰胺可由具有2-10个碳原子的其它脂族和/或环脂族二胺如六亚甲基二胺和/或具有6-10个碳原子的芳族二胺如对-苯二胺,和由具有6-14个碳原子的脂族或芳族二羧酸例如己二酸、对苯二甲酸或间苯二甲酸形成。另外,具有异佛尔酮二胺单元的均聚酰胺或共聚酰胺可由具有4-10个碳原子的内酰胺例如ɛ-己内酰胺制备。为了制备均聚酰胺和/或共聚酰胺,优选可以使用异佛尔酮二胺作为至少一种二胺组分,以使优选适合于制备层(c)的均聚酰胺和/或共聚酰胺具有异佛尔酮二胺单元。根据本发明,使用的具有异佛尔酮二胺单元的均聚酰胺和/或共聚酰胺是尤其优选由ɛ-己内酰胺、异佛尔酮二胺和芳族二羧酸,优选间苯二甲酸形成的共聚酰胺。
在一个优选的实施方案中,在层(c)的聚酰胺组分中的异佛尔酮二胺单元和间苯二甲酸单元的含量基于所述聚酰胺组分的总重量计为至少1-10重量%,尤其优选2-6重量%。
前面列举的用于制备层(e)的热塑性聚酯也可用于制备层(c)。
通过作为阻隔层的层(c),可以在相应选择合适的聚合物的情况下使本发明的多层塑料薄膜具有根据DIN 53380-3的显著降低的氧气渗透性,其在23℃和50%相对湿度下可为最多10.00 cm3/(m2·d·bar)。本发明的多层塑料薄膜的氧气渗透性可以降低至最多8cm3/(m2·d·bar),优选最多7或6 cm3/(m2·d·bar),更优选最多5、4或3 cm3/(m2·d·bar),还更优选最多2、1或0.5 cm3/(m2·d·bar),最优选最多0.4、0.3或0.2 cm3/(m2·d·bar),和最特别是最多0.1、0.09或0.08 cm3/(m2·d·bar)(在每种情况下在23℃和50%相对湿度下)。
通过作为阻隔层的层(c),可以在相应选择合适的聚合物的情况下将本发明的多层塑料薄膜的水蒸气渗透性降低至最多等于前面提及的氧气渗透性值,其中水蒸气渗透性根据DIN ISO 53 122测定。
如果层(c)用作阻隔层,它优选通过增粘剂层(b)和(d)与相邻的层接合。
可用作增粘剂材料的合适的热塑性聚合物是本领域技术人员已知的。增粘剂层(b)和(d)相同或不同地优选基于优选改性的聚烯烃和/或烯烃共聚物,其优选选自:用羧基或环状酸酐基团改性的聚乙烯、聚丙烯,特别是用马来酸酐基团改性的聚乙烯、聚丙烯和乙烯-乙酸乙烯酯共聚物。优选的是用马来酸酐改性的PE、用COOH基团改性的PE、用羧基改性的乙烯-乙酸乙烯酯共聚物或乙烯-(甲基)丙烯酸酯共聚物、或用酸酐改性的乙烯-乙酸乙烯酯共聚物和包含前面提及的聚合物中的至少两种的聚合物共混物。用马来酸酐改性的共聚物是特别优选的。
在一个另外的特别优选的实施方案中,本发明的多层塑料薄膜包含多于一个层(c)并包含下面的层次序:
(a) 任选可热密封、任选多层的层(a),其优选由至少一种热塑性烯烃均聚物或共聚物或其混合物形成并可对其设计离型涂层作为外层,
(b) 增粘剂层(b),
(c) 层(c),其优选由至少一种均聚酰胺和/或共聚酰胺形成,
(b) 任选的另一个增粘剂层(b),
(c) 另一个层(c),其优选由至少一种均聚酰胺和/或共聚酰胺或乙烯-乙烯醇共聚物形成,
(d) 另一个增粘剂层(d),
(e) 任选可热密封的外层(e),其由至少一种热塑性烯烃均聚物或共聚物或其混合物形成。
所述层(c)相同或不同地基于均聚物、共聚物或如前面描述的聚合物的混合物,更优选基于聚酰胺或乙烯-乙烯醇共聚物。这也适用于其它层。
本发明的多层塑料薄膜的各层可以各自具有相同或不同的选自如下的添加剂:抗氧化剂、防粘剂、防雾剂、抗静电剂、抗微生物活性物质、光保护剂、UV吸收剂、UV过滤剂、染料、着色颜料、稳定剂,优选热稳定剂,加工稳定剂和UV和/或光稳定剂,其优选基于至少一种位阻胺(HALS),加工助剂、阻燃剂、成核剂、结晶剂,优选晶核形成剂(Kristallkeimbildner),润滑剂、光学增亮剂、增塑剂、硅烷、间隔剂、填料如CaCO3、硅酸盐、剥离添加剂、密封添加剂、蜡、润湿剂、表面活性化合物,优选表面活性剂,和分散剂。
本发明的塑料薄膜的各层可含有至少0.01-30重量%,优选至少0.1-20重量%的至少一种前面提及的添加剂,在每种情况下基于所述单个层的总重量计。
本发明的塑料薄膜不仅具有至少单轴的拉伸,而且是经压制的。因此,本发明的塑料薄膜的至少一个表面层,该表面层,优选层(a)的至少一个特定区域,更优选该层,优选层(a)的整个表面具有压花结构。
本发明的离型薄膜的压花结构优选基于重复、规则或不规则排列的图案。所述压花结构可以是连续的压花结构例如连续的凹槽结构,更多个优选重复的单个压花结构,或规则重复但本身随意的压花结构,在每种情况下对应于使用的压花辊。
根据一个实施方案,每个压花结构都可基于多个优选重复的单个压花结构。这些各个单个压花结构可优选基于具有压花凹处(凹槽)的结构,其具有多少程度凸出的压花凸起例如脊(Steg),通过其将所述薄膜的压花高度定义为压花凸起与未压花但拉伸的薄膜的厚度的总和——根据DIN 53370 2006所测量。根据优选重复的单个压花结构的凸起的各自几何形状,俯视图中可显示多个各自不同、优选重复的单个压花结构,例如优选蛇线形、锯齿形、六边形、钻石形、菱形、平行四边形、蜂窝形、环形、点形、星形、绳形(leinenförmig)、网状、多边形,优选三角形、四边形,更优选矩形和正方形、五边形、六边形、七边形和八边形、金属丝形、椭圆形、卵形和晶格形设计的图案,其中也可以使至少两种图案重叠。所述压花凸起可各自优选具有高达1 cm的长度,特别优选0.001 mm-10 mm的长度。所述凸起占具有凹处的压花结构的总长度的比例可以优选为≤ 75%,更优选为5%-60%,和更优选为10%-50%。所述凸起优选以均匀或交替重复的距离排列。单个压花结构的凸起也可优选具有曲率,即:凸面和/或或凹面结构。
在一个另外的优选实施方案中,所述压花结构具有随意排列的压花凹处和压花凸起的重复单元。所述压花结构的压花凸起基于本发明的塑料薄膜的全部压花面积计优选应为≤75%,更优选≤50%。
本发明的塑料薄膜的任选统一的压花凸起的压花凸起优选为≥ 5 µm,如根据DIN53370 2006所测量。
本发明的塑料薄膜的压花结构的压花凸起根据DIN 53370 2006通过表面的机械扫描测定。在此,在样品的带宽度(Bahnbreite)上的直线均匀分布的至少10个位置处测量压花凸起,其中必须注意扫描装置不挤压塑料薄膜的压花结构并形成平均值,由其减去相应的经拉伸但未压花的塑料薄膜的厚度。
在一个另外的优选实施方案中,本发明的多层塑料薄膜具有不对称的压花结构,即:连贯地穿过整个薄膜存在的压花结构,该薄膜的上侧面与下侧面都配备有压花,以致其不再是平面的,其中压花的程度在该薄膜的两面上是不同的。下面,薄膜上侧面表示压花工具作用于或已作用于其上的薄膜侧面。相应地,所述薄膜的薄膜下侧面可以具有较弱的压花(阴模)。
通过本发明的多层塑料薄膜的压花,不仅实现了本发明的塑料薄膜的离型作用,而且令人惊讶地将所述经拉伸和压制的薄膜的收缩相对于相应的经拉伸但未压花的薄膜急剧减小超过50%。本发明的经拉伸和压制的薄膜另外具有优异的抗拉强度、良好至非常好的撕裂蔓延特性和优异的耐穿刺性。
为了改进其离型作用,本发明的多层塑料薄膜也可在其表面层之一上具有离型涂层。该离型涂层优选基于固化的聚硅氧烷涂层,可以甚至在拉伸之前或拉伸之后,或在拉伸和压花之后对本发明的多层塑料薄膜配备这一涂层。产生离型作用的该离型涂层和压花基本上存在于整个表面上,优选除了至少一个在机器方向上延伸的条带;或者存在于部分表面上,优选作为具有精确重复图案(rapportgenau)的横向条带。
术语“聚硅氧烷”在本发明的意义上是指聚合物链由硅原子与氧原子交替形成的化合物。聚硅氧烷基于n个重复硅氧烷单元(-[Si(R2)-O]-)n,其各自相互独立地被两个有机基团R双取代,其中R各自优选为R1或OR1,且R1各自是烷基或芳基。所述固化的聚硅氧烷涂层优选基于重复的二烷基硅氧烷单元或基于重复的烷基芳基硅氧烷单元。取决于单个硅氧烷单元具有多少个Si-O键(各自基于四价硅原子),这些单元可以区分为具有一个Si-O键的末端单官能硅氧烷(M)、具有两个Si-O键的二官能硅氧烷(D)、具有三个Si-O键的三官能硅氧烷(T)和具有四个Si-O键的四官能硅氧烷(Q)。本发明的聚硅氧烷涂层优选具有交联的环状或链状结构,更优选交联的链状结构,其通过(D)、(T)和/或(Q)单元键合成为二维或三维网络。所述聚硅氧烷链中的重复硅氧烷单元[Si(R2)-O]-)n的数目n称为该聚硅氧烷的聚合度。
本发明的塑料薄膜的固化的聚硅氧烷涂层优选基于至少一种选自如下的固化的,即交联的聚硅氧烷:加成交联,优选用金属催化加成交联,缩合交联、自由基交联和/或阳离子交联的聚硅氧烷。
更优选地,所述聚硅氧烷涂层基于至少一种固化的聚硅氧烷,其已通过热固化和/或在UV辐射的作用下固化。所述聚硅氧烷涂层优选基于至少一种选自如下的固化的聚硅氧烷:聚二烷基硅氧烷,优选聚二甲基硅氧烷,和聚烷基芳基硅氧烷,优选聚甲基苯基硅氧烷,其在每种情况下是固化的。所述热固化的聚硅氧烷可以通过具有硅烷官能的聚硅氧烷与具有至少一个碳双键的化合物的热氢化硅烷化得到。UV固化优选在本发明的薄膜拉伸之后发生,然而热固化优选在拉伸之后和在压花之后进行。
本发明的塑料薄膜原则上可以通过任意已知的制造方法,例如通过挤出或通过共挤出制造。
在此,本发明的塑料薄膜的单个层和全部层都可通过挤出,特别通过吹塑薄膜挤出和/或平膜挤出(流延挤出(Cast-Extrusion)),或优选共挤出,特别是吹塑薄膜共挤出和/或平膜共挤出(流延共挤出)形成,其中后者是优选的。这里应当注意的是,在向所述层(a)或其它层掺杂添加剂的情况下,这些添加剂通过任选作为母料与各层的所述(一种或多种)聚合物组分混合用于加工。这一混合可以以丸粒/粉末形式或丸粒/丸粒形式干燥地进行。然而,也可以将所述添加剂加入到各层的所述(一种或多种)熔融的聚合物组分中,优选通过计量加入到用于挤出各层的挤出机中。
根据本身已知的共挤出法,对应于本发明薄膜的各层的熔体同时且共同通过环状模头或扁平模头共挤出,将如此所得的薄膜拉拔(abgezogen)到一个或多个辊上以凝固,并将经拉伸的薄膜热定型。
双轴拉伸(取向)可相继或同时进行。相继拉伸通常接连进行,其中优选的是接连双轴拉伸,其中首先纵向(在机器方向上)和横向(与机器方向垂直)进行拉伸。在通过平膜挤出制备薄膜的情况下,通过随后的单轴或双轴拉伸,各个层的聚合物或聚合物混合物在挤出机中压缩和液化,其中任选加入的添加剂可以已存在于该聚合物或聚合物混合物中。所述熔体接着通过扁平模头(缝隙式模头)同时压制,并在10-100℃,优选10-50℃的温度下将压出的多层薄膜拉拔到一个或多个拉拔辊上,并冷却和凝固。
本发明的多层塑料薄膜接着相对于挤出方向仅仅纵向或纵向且横向地拉伸,这导致分子链的取向。纵向拉伸优选在70-130℃,优选80-110℃的温度下进行,有利地借助两个根据目标拉伸比以不同速度运行的辊,且所述任选的额外的横向拉伸优选在120-180℃的温度下借助相应的伸幅机(Kluppenrahmen)进行。在此,可以设定希望的横向拉伸比。根据本发明优选仅仅在机器方向上的拉伸。
所述薄膜的拉伸之后优选进行其热定型(热处理),其中将所述薄膜在100-160℃的温度下保持大约0.1-10秒。随后,任选在临时存贮之后,可以对所述薄膜配备任选存在的离型涂层并随后进行压制,或者可以在压制之后配备任选存在的离型涂层。另外,所述挤出的多层塑料薄膜可以甚至在拉伸之前就配备有任选存在的离型涂层。
仅具有单面或总体连贯的压花结构的本发明的塑料薄膜的压花可根据压花法借助包含网目施加装置(Rasterauftragswerk)的结构压或花压延机在线或离线地完成。此压延机具有优选在高度方向上彼此以特定距离设置的反向旋转的辊,其中将待配备不对称压花结构的离型薄膜供至所述辊并穿过形成的辊间隙,所述间隙宽度可调节变化。在此,网目辊轧装置优选包含具有相对硬的表面的第一辊,更优选钢辊,和具有相对较不硬的表面且优选由弹性材料形成,更优选由橡胶或硬橡胶形成的第二辊。
所述两个辊中较硬的辊以阴模形式具有待压入塑料薄膜中的图案(压花辊)。与此辊相对的第二辊优选用作反压辊或按压辊(Anpresswalze),并相对于第一压花辊压按压所述塑料薄膜待配备的结构或压花图案。所述塑料薄膜优选在升高的温度下进行压花,因此,在离线压花的情况下,所述塑料薄膜首先穿过热辊装置,之后任选用红外光照射,然后进行上述的实际的压花操作。压花之后,该塑料薄膜穿过任选用于冷却的冷却辊装置。待压花的结构的阴模的建立根据本领域技术人员已知的常规方法进行,其中取决于结构和材料,特定的方法可能是特别有利的。基本上,压花辊上的结构可具有连续结构或设计为间断的结构(单个压花结构的序列),其中也可以是这两种结构的组合。压花辊上的各结构取决于所述塑料薄膜预期的(不对称)结构可具有各种不同的几何形状。
本发明的另一主题是本发明的塑料薄膜作为优选用于各个种类的粘性制品,更优选用于各个种类的自粘性制品的可剥离的离型薄膜或保护薄膜的用途。
本发明的塑料薄膜尤其是在建筑工业中作为用于各个种类的自粘性标签或胶带的可剥离的包装薄膜和/或保护薄膜的用途是本发明的一个另外的主题。
这也适用于本发明的塑料薄膜作为用于卫生制品,优选独立包装、任选折叠、自粘性卫生护垫、卫生巾或失禁制品的可剥离的柔性包装薄膜和/或保护薄膜的用途。
本发明的可剥离的柔性包装材料优选具有的优点在于由其可制造尤其用于独立包装的卫生产品的可低噪音地打开且可清除和包装。在此,产生的作为等效持续声级Leq[db]测量的噪音≤ 60 [db]。
为了测定等效持续声级,将DIN A5大小的薄膜样品在各个长边上借助卡紧装置在中心且水平固定。该卡紧装置之一是固定的,而另一装置可在偏心路径上移动以通过所述薄膜样品的连续压缩和拉伸产生噪音。测量过程中偏心驱动的转数为36 min-1。作为噪音发射参数,等效持续声级Leq[db]借助声音记录仪测定,其从与DIN A5薄膜样品的宽边中心30cm的距离记录薄膜样品连续压缩和拉伸过程中的噪音30秒的时间。该薄膜样品在拉伸和压缩过程中必须不受损。使用的测量仪是Brüel & Kjaer的测量装置2250-L。
本发明的另一主题是由本发明的塑料薄膜制成并用于独立包装、粘性制品,优选用于一次性使用的自粘性制品的柔性包装材料。
本发明的另一主题还是配备有本发明的塑料薄膜作为可剥除的离型薄膜或保护薄膜的卫生或卫生学产品。
另外,本发明的另一个主题是由本发明的塑料薄膜制成并用于独立包装、自粘性卫生制品或失禁制品的柔性包装材料。
测量收缩的方法
根据DIN 5543/4测收缩量。因此,将分别具有标记的在机器方向上或与机器方向横向的运行方向的尺寸为100 mm × 100 mm的各10个样品放入90℃的高沸点油浴中各自3分钟;分别由10个样品测得MD和CD上的长度变化的平均值,各自的变化以%收缩示出。
下面实施例和对比例用于阐述本发明,但不应解释为限制。
I.使用的原料的化学特征
II.制备本发明的塑料薄膜(B1/B2)和根据对比试验的塑料薄膜(V1/V2)
具有表II中所示组成的每一种多层塑料薄膜通过在吹塑薄膜共挤出设备上的共挤出制备,其首先具有40 µm的总层厚度。在该薄膜囊坍塌(Breitlegung)之后,将其供至辊轧拉伸设备并在纵向上以1:4的系数拉伸,以使由其得到的总薄膜厚度为10 µm。本发明的塑料薄膜B1和B2在拉伸之后在压花压延机上具有大约5 µm的微压花(压花凸起),对于本发明的塑料薄膜以及对于对比塑料薄膜,测定并示出下表IV中给出的物理及其收缩特性。
III.塑料薄膜的构造
下面全部的%数据在每种情况下都是重量%。
III.1 实施例B1/对比例V1
(3层,总层厚度10 µm)
III.2 实施例B2/对比例V2
(5层,总层厚度10 µm)

Claims (17)

1.具有离型作用和≤ 18 µm,优选≤ 12 µm的总厚度的多层塑料薄膜,其至少单轴拉伸且由至少50重量%的聚烯烃组成,其在至少一个表面上具有至少部分的压花。
2.如权利要求1所述的塑料薄膜,其特征在于:它在机器方向上具有至少1:2,优选至少1:5的拉伸。
3.如权利要求1或2中任一项所述的塑料薄膜,其特征在于:所述塑料薄膜的离型作用基于至少一个表面上的所述至少部分的压花,其中根据 DIN 53370 2006所测量,所述至少部分的压花的压花凸起为≥ 5 µm。
4.如权利要求1-3中所述的塑料薄膜,其特征在于:所述塑料薄膜在其表面的至少一个上具有离型涂层,所述离型涂层优选由固化的聚硅氧烷制成。
5.如前述权利要求中任一项所述的塑料薄膜,其特征在于:所述塑料薄膜与相应的未压花但经拉伸的塑料薄膜相比具有低至少50%的收缩。
6.如前述权利要求中任一项所述的塑料薄膜,其特征在于:产生所述离型作用的离型涂层和/或压花基本上存在于全部表面上,优选除了至少在机器方向上延伸的条带;或者存在于部分表面上,优选作为所述带状塑料薄膜的具有精确重复图案的横向条带。
7.如前述权利要求中任一项所述的塑料薄膜,其特征在于:所述塑料薄膜由至少70重量%的聚烯烃,优选C2-C8烯烃聚合物,更优选C2-C3烯烃聚合物,它们的混合物或它们的共聚物组成。
8.如前述权利要求中任一项所述的塑料薄膜,其特征在于:存在LDPE、MDPE、LLDPE或所提及的PE中至少两种的混合物作为聚乙烯。
9.如前述权利要求中任一项所述的塑料薄膜,其特征在于:所述塑料薄膜的至少一个层是基于至少一种PE和PP的混合物,优选LLDPE和/或MDPE和/或PP的混合物。
10.如前述权利要求中任一项所述的塑料薄膜,其特征在于:所述薄膜具有阻隔层,优选至少一个针对气体,更优选针对O2、H2O蒸气和/或气体香料、针对低分子量有机化合物的迁移和/或口味或气味损害物和/或针对湿气和/或脂肪和/或油的阻隔层。
11.如前述权利要求中任一项所述的塑料薄膜,其特征在于:所述阻隔层由乙烯/乙烯醇共聚物、聚乙烯醇、聚酰胺、聚酯和/或聚醚-聚酰胺嵌段共聚物形成。
12.如权利要求1-11中任一项所述的塑料薄膜作为离型薄膜或保护薄膜的用途。
13.如权利要求1-11中任一项所述的塑料薄膜作为用于各个种类的优选自粘性制品,优选用于自粘性标签、卫生制品,优选独立包装的自粘性卫生护垫、卫生巾或失禁制品的可剥离的包装薄膜和/或保护薄膜的用途。
14.如权利要求1-11中任一项所述的塑料薄膜作为用于各个种类的胶带,优选卷形式的胶带的载体层的用途。
15.如权利要求1-11中任一项所述的塑料薄膜作为用于独立包装的卫生制品或失禁产品的低噪音且任选可剥离的包装材料的用途。
16.由如权利要求1-11中任一项所述的塑料薄膜制成并优选用于独立包装的粘性制品,优选用于一次性使用的自粘性制品的柔性包装材料。
17.由如权利要求1-11中任一项所述的塑料薄膜制成并用于独立包装的自粘性卫生制品或失禁制品的柔性包装材料。
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