CN105696100B - 一种绿色炭源共聚阻燃聚乳酸纤维及其制备方法 - Google Patents
一种绿色炭源共聚阻燃聚乳酸纤维及其制备方法 Download PDFInfo
- Publication number
- CN105696100B CN105696100B CN201610104384.0A CN201610104384A CN105696100B CN 105696100 B CN105696100 B CN 105696100B CN 201610104384 A CN201610104384 A CN 201610104384A CN 105696100 B CN105696100 B CN 105696100B
- Authority
- CN
- China
- Prior art keywords
- green
- charcoal source
- flame
- polylactic acid
- proof polylactic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000003610 charcoal Substances 0.000 title claims abstract description 77
- 229920000747 poly(lactic acid) Polymers 0.000 title claims abstract description 74
- 239000004626 polylactic acid Substances 0.000 title claims abstract description 74
- 238000007334 copolymerization reaction Methods 0.000 title claims abstract description 44
- 239000000835 fiber Substances 0.000 title claims abstract description 32
- 238000002360 preparation method Methods 0.000 title claims abstract description 22
- 239000003063 flame retardant Substances 0.000 claims abstract description 50
- 238000006243 chemical reaction Methods 0.000 claims abstract description 32
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims abstract description 26
- JJTUDXZGHPGLLC-UHFFFAOYSA-N lactide Chemical compound CC1OC(=O)C(C)OC1=O JJTUDXZGHPGLLC-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000000178 monomer Substances 0.000 claims abstract description 22
- 229920001577 copolymer Polymers 0.000 claims abstract description 10
- 238000007142 ring opening reaction Methods 0.000 claims abstract description 10
- 238000007493 shaping process Methods 0.000 claims abstract description 9
- 239000003054 catalyst Substances 0.000 claims abstract description 6
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims description 21
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 15
- 238000010792 warming Methods 0.000 claims description 9
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 8
- XHXFXVLFKHQFAL-UHFFFAOYSA-N phosphoryl trichloride Chemical compound ClP(Cl)(Cl)=O XHXFXVLFKHQFAL-UHFFFAOYSA-N 0.000 claims description 8
- 238000001914 filtration Methods 0.000 claims description 5
- 239000005457 ice water Substances 0.000 claims description 5
- 229920005610 lignin Polymers 0.000 claims description 5
- 238000002844 melting Methods 0.000 claims description 5
- 230000008018 melting Effects 0.000 claims description 5
- 239000007787 solid Substances 0.000 claims description 5
- 229910019213 POCl3 Inorganic materials 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 4
- 238000010907 mechanical stirring Methods 0.000 claims description 4
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 claims description 4
- 229920002472 Starch Polymers 0.000 claims description 3
- 230000003287 optical effect Effects 0.000 claims description 3
- 229920002101 Chitin Polymers 0.000 claims description 2
- 229920002678 cellulose Polymers 0.000 claims description 2
- 239000001913 cellulose Substances 0.000 claims description 2
- 150000008442 polyphenolic compounds Chemical class 0.000 claims description 2
- 235000013824 polyphenols Nutrition 0.000 claims description 2
- 235000019698 starch Nutrition 0.000 claims description 2
- 239000008107 starch Substances 0.000 claims description 2
- 229920001661 Chitosan Polymers 0.000 claims 1
- 239000011159 matrix material Substances 0.000 abstract description 2
- 238000013508 migration Methods 0.000 abstract description 2
- 230000005012 migration Effects 0.000 abstract description 2
- 238000001556 precipitation Methods 0.000 abstract description 2
- 230000001988 toxicity Effects 0.000 abstract description 2
- 231100000419 toxicity Toxicity 0.000 abstract description 2
- 239000000463 material Substances 0.000 description 10
- 238000012360 testing method Methods 0.000 description 9
- 239000004753 textile Substances 0.000 description 5
- 239000003513 alkali Substances 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- 239000011261 inert gas Substances 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 238000011056 performance test Methods 0.000 description 3
- 150000003222 pyridines Chemical class 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 235000019890 Amylum Nutrition 0.000 description 1
- 208000034530 PLAA-associated neurodevelopmental disease Diseases 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 210000000481 breast Anatomy 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000004100 electronic packaging Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 229920000554 ionomer Polymers 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000002464 physical blending Methods 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000007151 ring opening polymerisation reaction Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
- D01F6/62—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/06—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from hydroxycarboxylic acids
- C08G63/08—Lactones or lactides
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Biological Depolymerization Polymers (AREA)
- Polyesters Or Polycarbonates (AREA)
Abstract
Description
Claims (7)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610104384.0A CN105696100B (zh) | 2016-02-25 | 2016-02-25 | 一种绿色炭源共聚阻燃聚乳酸纤维及其制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610104384.0A CN105696100B (zh) | 2016-02-25 | 2016-02-25 | 一种绿色炭源共聚阻燃聚乳酸纤维及其制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN105696100A CN105696100A (zh) | 2016-06-22 |
CN105696100B true CN105696100B (zh) | 2017-10-24 |
Family
ID=56222419
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201610104384.0A Active CN105696100B (zh) | 2016-02-25 | 2016-02-25 | 一种绿色炭源共聚阻燃聚乳酸纤维及其制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN105696100B (zh) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107459637B (zh) * | 2017-08-25 | 2019-10-18 | 华南理工大学 | 低分子量和高熔体黏度的聚丁二酸丁二醇酯离聚物及其制备和基于其的微孔发泡材料及应用 |
CN109825075B (zh) * | 2019-01-28 | 2021-04-27 | 凯尔科美(广州)高新材料科技有限公司 | 无卤阻燃热塑性弹性体新能源汽车用线缆材料 |
CN111411519B (zh) * | 2020-03-27 | 2021-11-26 | 东华大学 | 一种预警型阻燃聚乳酸织物及其制备方法 |
CN111235679A (zh) * | 2020-03-31 | 2020-06-05 | 孙阁 | 一种防污功能纤维及其制备方法 |
CN113121809B (zh) * | 2021-05-12 | 2022-05-20 | 温多利遮阳材料(德州)股份有限公司 | 一种氮磷协效壳聚糖接枝聚乳酸阻燃剂及其制备方法 |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008031296A (ja) * | 2006-07-28 | 2008-02-14 | Teijin Ltd | ポリ乳酸樹脂組成物およびそれよりなる成型体 |
WO2008013316A1 (fr) * | 2006-07-28 | 2008-01-31 | Teijin Limited | Composition de résine, son procédé de fabrication et article moulé |
CN101117405A (zh) * | 2007-09-11 | 2008-02-06 | 天津市联瑞化工有限公司 | 一种无毒性有机磷酸酯阻燃增塑剂的制备方法 |
EP2554595B1 (en) * | 2010-03-30 | 2018-01-03 | Nitto Denko Corporation | Fire-retardant polylactic film or sheet, and method for producing same |
JP5754663B2 (ja) * | 2010-07-14 | 2015-07-29 | 株式会社伏見製薬所 | オリゴ乳酸セグメントを有する環状ホスファゼン化合物およびその製造方法 |
CN102516786B (zh) * | 2011-12-19 | 2014-02-19 | 南京林业大学 | 硅改性木质素膨胀阻燃成炭剂及其制备方法和应用 |
CN102516785B (zh) * | 2011-12-19 | 2014-02-19 | 南京林业大学 | 核-壳型脲醛改性木质素膨胀阻燃成炭剂及其制备方法 |
CN102604346B (zh) * | 2012-02-28 | 2014-01-01 | 中国地质大学(武汉) | 一种生物可降解聚乳酸-淀粉阻燃复合材料及其制备方法 |
CN102924702B (zh) * | 2012-11-06 | 2014-04-16 | 四川大学 | 含磷杂环阻燃共聚酯离聚物及其制备方法 |
CN103122498B (zh) * | 2013-03-19 | 2015-01-07 | 东华大学 | 一种无卤阻燃聚乳酸纤维的制备方法 |
JP2014227452A (ja) * | 2013-05-21 | 2014-12-08 | ユニチカ株式会社 | ポリ乳酸系樹脂 |
CN104163926A (zh) * | 2014-07-31 | 2014-11-26 | 大连工业大学 | 一种磷氮接枝木质素磺酸盐膨胀阻燃剂及其制备方法 |
CN104371031B (zh) * | 2014-10-17 | 2017-01-11 | 中国林业科学研究院林产化学工业研究所 | 纤维素基氮磷系阻燃剂及其制备方法 |
CN104356242B (zh) * | 2014-10-17 | 2017-01-11 | 中国林业科学研究院林产化学工业研究所 | 无卤纤维素基磷系阻燃剂及其制备方法 |
US9187597B1 (en) * | 2014-10-21 | 2015-11-17 | International Business Machines Corporation | Flame-retardant polylactic acid (PLA) by grafting through of phosphorus-containing polymers directly to PLA backbone |
CN104559100B (zh) * | 2015-01-22 | 2017-01-18 | 汪竹青 | 功能化环糊精阻燃聚乳酸复合材料及其制备方法 |
-
2016
- 2016-02-25 CN CN201610104384.0A patent/CN105696100B/zh active Active
Also Published As
Publication number | Publication date |
---|---|
CN105696100A (zh) | 2016-06-22 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN105696100B (zh) | 一种绿色炭源共聚阻燃聚乳酸纤维及其制备方法 | |
CN105603564B (zh) | 一种氮‑磷协效共聚阻燃聚乳酸纤维及其制备方法 | |
CN106752122B (zh) | 一种氮化碳复合物、其制备方法及应用 | |
CN104387571B (zh) | 含磷氮聚对苯二甲酸乙二醇酯阻燃共聚酯及其应用 | |
CN104153035B (zh) | 阻燃凉爽再生聚酯长丝纤维及其生产方法 | |
CA2895255C (en) | Method for preparing flame-retardant melt droplet-resistant polyester | |
CN107177979A (zh) | 一种无熔滴阻燃涤纶纤维/织物及其制备方法 | |
CN106811830A (zh) | 一种阻燃低熔点聚酯纤维及其制备方法 | |
CN105040154A (zh) | 一种阻燃聚酰胺66复合纤维及其制备方法 | |
CN105714401B (zh) | 一种含磷共聚阻燃聚乳酸纤维及其制备方法 | |
CN108018715A (zh) | 一种阻燃整理剂及阻燃再生纤维素纤维的制备方法 | |
CN114990876B (zh) | 一种可用于防护服的阻燃织物及其制备方法 | |
CN110218305B (zh) | 一种磷阻燃防滴型低熔点聚酯材料及其制备方法和应用 | |
CN106400197A (zh) | 一种舒适性涤纶长丝的制造方法 | |
CN105754082A (zh) | 一种含磷离聚物共聚阻燃聚乳酸纤维及其制备方法 | |
CN109824905B (zh) | 耐高温聚碳硅烷先驱体及其制备方法 | |
CN111793851A (zh) | 一种基于纳米材料的防辐射纤维及其制备方法 | |
CN114921870B (zh) | 一种阻燃聚乳酸面料及其制备方法 | |
CN116427173A (zh) | 一种耐洗阻燃抗熔滴涤棉65/35面料及其制备方法 | |
CN114574995B (zh) | 阻燃低熔点聚酯纤维及其制备方法 | |
CN113802212B (zh) | 一种阻燃纤维及其制备方法以及阻燃面料 | |
CN105671672B (zh) | 只含碳、氢、氧三元素的阻燃聚乳酸纤维及其制备方法 | |
CN106835339B (zh) | 阻燃聚酯涤纶长丝 | |
CN105384921B (zh) | 一种膨胀型阻燃亲水聚酯切片及其制备方法 | |
CN111171301B (zh) | 含氮共聚聚乳酸的制备方法及应用 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20220705 Address after: Building 12a, Zilang science and Technology City, No. 60, Chongzhou Avenue, Nantong City, Jiangsu Province, 226000 Patentee after: Jiangsu Jicui advanced fiber material Research Institute Co.,Ltd. Address before: 201620 No. 2999 North Renmin Road, Shanghai, Songjiang District Patentee before: DONGHUA University |
|
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20240129 Address after: 215500 No.19 Jiulong Road, Changkun Industrial Park, Shajiabang Town, Changshu City, Suzhou City, Jiangsu Province Patentee after: Suzhou Guyuan Biotechnology Co.,Ltd. Country or region after: China Address before: Building 12a, Zilang science and Technology City, No. 60, Chongzhou Avenue, Nantong City, Jiangsu Province, 226000 Patentee before: Jiangsu Jicui advanced fiber material Research Institute Co.,Ltd. Country or region before: China |