CN105504370B - 包含偶氮‑硅烷偶联剂的橡胶轮胎组合物 - Google Patents
包含偶氮‑硅烷偶联剂的橡胶轮胎组合物 Download PDFInfo
- Publication number
- CN105504370B CN105504370B CN201510934981.1A CN201510934981A CN105504370B CN 105504370 B CN105504370 B CN 105504370B CN 201510934981 A CN201510934981 A CN 201510934981A CN 105504370 B CN105504370 B CN 105504370B
- Authority
- CN
- China
- Prior art keywords
- composition
- coupling agent
- formula
- inorganic filler
- elastomer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 162
- 229920001971 elastomer Polymers 0.000 title claims abstract description 74
- -1 azo silane Chemical compound 0.000 title claims abstract description 51
- 229910000077 silane Inorganic materials 0.000 title claims abstract description 48
- 239000005060 rubber Substances 0.000 title claims abstract description 43
- 239000007822 coupling agent Substances 0.000 claims abstract description 78
- 229920003244 diene elastomer Polymers 0.000 claims abstract description 50
- 239000011256 inorganic filler Substances 0.000 claims abstract description 50
- 229910003475 inorganic filler Inorganic materials 0.000 claims abstract description 49
- 239000003795 chemical substances by application Substances 0.000 claims description 10
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 8
- 229910052710 silicon Inorganic materials 0.000 abstract description 12
- 229910052799 carbon Inorganic materials 0.000 abstract description 11
- 125000004432 carbon atom Chemical group C* 0.000 abstract description 10
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract description 10
- 125000003118 aryl group Chemical group 0.000 abstract description 7
- 229910052760 oxygen Inorganic materials 0.000 abstract description 7
- 229910052717 sulfur Inorganic materials 0.000 abstract description 6
- 125000000217 alkyl group Chemical group 0.000 abstract description 5
- 229910052757 nitrogen Inorganic materials 0.000 abstract description 5
- 239000012763 reinforcing filler Substances 0.000 abstract description 5
- 239000004215 Carbon black (E152) Substances 0.000 abstract description 4
- 229930195733 hydrocarbon Natural products 0.000 abstract description 4
- 150000002430 hydrocarbons Chemical class 0.000 abstract description 4
- 125000005346 substituted cycloalkyl group Chemical group 0.000 abstract description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 63
- KAKZBPTYRLMSJV-UHFFFAOYSA-N vinyl-ethylene Natural products C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 36
- 230000002708 enhancing effect Effects 0.000 description 34
- 239000000806 elastomer Substances 0.000 description 31
- 239000000377 silicon dioxide Substances 0.000 description 29
- 229920001577 copolymer Polymers 0.000 description 27
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 25
- 150000001875 compounds Chemical class 0.000 description 24
- 244000043261 Hevea brasiliensis Species 0.000 description 22
- 229920003052 natural elastomer Polymers 0.000 description 22
- 229920001194 natural rubber Polymers 0.000 description 22
- 239000006229 carbon black Substances 0.000 description 21
- 235000019241 carbon black Nutrition 0.000 description 21
- 239000000945 filler Substances 0.000 description 19
- 150000001993 dienes Chemical class 0.000 description 16
- 239000005062 Polybutadiene Substances 0.000 description 14
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 14
- 125000000524 functional group Chemical group 0.000 description 13
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 12
- 238000012360 testing method Methods 0.000 description 12
- 239000005864 Sulphur Substances 0.000 description 11
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 10
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 10
- 238000004073 vulcanization Methods 0.000 description 10
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 9
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 9
- 230000015572 biosynthetic process Effects 0.000 description 9
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 9
- 238000007711 solidification Methods 0.000 description 9
- 230000008023 solidification Effects 0.000 description 9
- 238000003786 synthesis reaction Methods 0.000 description 9
- PCLIMKBDDGJMGD-UHFFFAOYSA-N N-bromosuccinimide Chemical compound BrN1C(=O)CCC1=O PCLIMKBDDGJMGD-UHFFFAOYSA-N 0.000 description 8
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 150000001721 carbon Chemical group 0.000 description 7
- 239000006185 dispersion Substances 0.000 description 7
- 239000000178 monomer Substances 0.000 description 7
- 239000002243 precursor Substances 0.000 description 7
- 238000002360 preparation method Methods 0.000 description 7
- 238000003756 stirring Methods 0.000 description 7
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 6
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 6
- 235000021355 Stearic acid Nutrition 0.000 description 6
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 6
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 6
- 239000003921 oil Substances 0.000 description 6
- 239000010703 silicon Substances 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- 239000008117 stearic acid Substances 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 229910052782 aluminium Inorganic materials 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
- 150000002148 esters Chemical group 0.000 description 5
- 229920003049 isoprene rubber Polymers 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 229920003051 synthetic elastomer Polymers 0.000 description 5
- 229920002554 vinyl polymer Polymers 0.000 description 5
- 239000011787 zinc oxide Substances 0.000 description 5
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 239000003963 antioxidant agent Substances 0.000 description 4
- 230000003078 antioxidant effect Effects 0.000 description 4
- 229920005549 butyl rubber Polymers 0.000 description 4
- 230000008878 coupling Effects 0.000 description 4
- 238000010168 coupling process Methods 0.000 description 4
- 238000005859 coupling reaction Methods 0.000 description 4
- 238000004132 cross linking Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 239000000376 reactant Substances 0.000 description 4
- 239000012429 reaction media Substances 0.000 description 4
- 238000006467 substitution reaction Methods 0.000 description 4
- QAZLUNIWYYOJPC-UHFFFAOYSA-M sulfenamide Chemical compound [Cl-].COC1=C(C)C=[N+]2C3=NC4=CC=C(OC)C=C4N3SCC2=C1C QAZLUNIWYYOJPC-UHFFFAOYSA-M 0.000 description 4
- 125000004066 1-hydroxyethyl group Chemical group [H]OC([H])([*])C([H])([H])[H] 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 150000001336 alkenes Chemical class 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 229910052786 argon Inorganic materials 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 239000003153 chemical reaction reagent Substances 0.000 description 3
- 230000006866 deterioration Effects 0.000 description 3
- 125000002897 diene group Chemical group 0.000 description 3
- 229920001519 homopolymer Polymers 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 239000012766 organic filler Substances 0.000 description 3
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 3
- 239000012188 paraffin wax Substances 0.000 description 3
- 229920002857 polybutadiene Polymers 0.000 description 3
- 229920001195 polyisoprene Polymers 0.000 description 3
- VVWRJUBEIPHGQF-MDZDMXLPSA-N propan-2-yl (ne)-n-propan-2-yloxycarbonyliminocarbamate Chemical compound CC(C)OC(=O)\N=N\C(=O)OC(C)C VVWRJUBEIPHGQF-MDZDMXLPSA-N 0.000 description 3
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 3
- 238000005096 rolling process Methods 0.000 description 3
- 229920006395 saturated elastomer Polymers 0.000 description 3
- 239000011265 semifinished product Substances 0.000 description 3
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical class [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 description 3
- SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 229920003048 styrene butadiene rubber Polymers 0.000 description 3
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 3
- VTHOKNTVYKTUPI-UHFFFAOYSA-N triethoxy-[3-(3-triethoxysilylpropyltetrasulfanyl)propyl]silane Chemical class CCO[Si](OCC)(OCC)CCCSSSSCCC[Si](OCC)(OCC)OCC VTHOKNTVYKTUPI-UHFFFAOYSA-N 0.000 description 3
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 description 2
- SDJHPPZKZZWAKF-UHFFFAOYSA-N 2,3-dimethylbuta-1,3-diene Chemical compound CC(=C)C(C)=C SDJHPPZKZZWAKF-UHFFFAOYSA-N 0.000 description 2
- OVSKIKFHRZPJSS-UHFFFAOYSA-N 2,4-D Chemical compound OC(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-N 0.000 description 2
- ZAFNJMIOTHYJRJ-UHFFFAOYSA-N Diisopropyl ether Chemical compound CC(C)OC(C)C ZAFNJMIOTHYJRJ-UHFFFAOYSA-N 0.000 description 2
- 229920002943 EPDM rubber Polymers 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 2
- KFFQABQEJATQAT-UHFFFAOYSA-N N,N'-dibutylthiourea Chemical compound CCCCNC(=S)NCCCC KFFQABQEJATQAT-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- 239000006057 Non-nutritive feed additive Substances 0.000 description 2
- 229920006978 SSBR Polymers 0.000 description 2
- 229910003978 SiClx Inorganic materials 0.000 description 2
- 239000012190 activator Substances 0.000 description 2
- 238000005917 acylation reaction Methods 0.000 description 2
- 150000001335 aliphatic alkanes Chemical group 0.000 description 2
- 239000004411 aluminium Substances 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- 125000005604 azodicarboxylate group Chemical group 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- 239000003610 charcoal Substances 0.000 description 2
- 238000005660 chlorination reaction Methods 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- VYSYZMNJHYOXGN-UHFFFAOYSA-N ethyl n-aminocarbamate Chemical compound CCOC(=O)NN VYSYZMNJHYOXGN-UHFFFAOYSA-N 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 239000012065 filter cake Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 125000000717 hydrazino group Chemical group [H]N([*])N([H])[H] 0.000 description 2
- 230000000640 hydroxylating effect Effects 0.000 description 2
- 238000004898 kneading Methods 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 125000005647 linker group Chemical group 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- DEQZTKGFXNUBJL-UHFFFAOYSA-N n-(1,3-benzothiazol-2-ylsulfanyl)cyclohexanamine Chemical compound C1CCCCC1NSC1=NC2=CC=CC=C2S1 DEQZTKGFXNUBJL-UHFFFAOYSA-N 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 229920000570 polyether Polymers 0.000 description 2
- 239000005077 polysulfide Substances 0.000 description 2
- 229920001021 polysulfide Polymers 0.000 description 2
- 150000008117 polysulfides Polymers 0.000 description 2
- 238000005728 strengthening Methods 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 239000013589 supplement Substances 0.000 description 2
- 230000000930 thermomechanical effect Effects 0.000 description 2
- 229960002447 thiram Drugs 0.000 description 2
- QQQSFSZALRVCSZ-UHFFFAOYSA-N triethoxysilane Chemical compound CCO[SiH](OCC)OCC QQQSFSZALRVCSZ-UHFFFAOYSA-N 0.000 description 2
- WMYJOZQKDZZHAC-UHFFFAOYSA-H trizinc;dioxido-sulfanylidene-sulfido-$l^{5}-phosphane Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([S-])=S.[O-]P([O-])([S-])=S WMYJOZQKDZZHAC-UHFFFAOYSA-H 0.000 description 2
- SZNCKQHFYDCMLZ-UHFFFAOYSA-L zinc;propan-2-yloxymethanedithioate Chemical compound [Zn+2].CC(C)OC([S-])=S.CC(C)OC([S-])=S SZNCKQHFYDCMLZ-UHFFFAOYSA-L 0.000 description 2
- 239000004711 α-olefin Substances 0.000 description 2
- OJOWICOBYCXEKR-KRXBUXKQSA-N (5e)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C/C)/CC1C=C2 OJOWICOBYCXEKR-KRXBUXKQSA-N 0.000 description 1
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical compound C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 1
- KKDHWGOHWGLLPR-UHFFFAOYSA-N 1,1-bis(sulfanylidene)-3h-1,3-benzothiazole-2-thione Chemical compound C1=CC=C2S(=S)(=S)C(S)=NC2=C1 KKDHWGOHWGLLPR-UHFFFAOYSA-N 0.000 description 1
- XFRVVPUIAFSTFO-UHFFFAOYSA-N 1-Tridecanol Chemical compound CCCCCCCCCCCCCO XFRVVPUIAFSTFO-UHFFFAOYSA-N 0.000 description 1
- NVZWEEGUWXZOKI-UHFFFAOYSA-N 1-ethenyl-2-methylbenzene Chemical compound CC1=CC=CC=C1C=C NVZWEEGUWXZOKI-UHFFFAOYSA-N 0.000 description 1
- JZHGRUMIRATHIU-UHFFFAOYSA-N 1-ethenyl-3-methylbenzene Chemical compound CC1=CC=CC(C=C)=C1 JZHGRUMIRATHIU-UHFFFAOYSA-N 0.000 description 1
- CBXRMKZFYQISIV-UHFFFAOYSA-N 1-n,1-n,1-n',1-n',2-n,2-n,2-n',2-n'-octamethylethene-1,1,2,2-tetramine Chemical compound CN(C)C(N(C)C)=C(N(C)C)N(C)C CBXRMKZFYQISIV-UHFFFAOYSA-N 0.000 description 1
- IGGDKDTUCAWDAN-UHFFFAOYSA-N 1-vinylnaphthalene Chemical compound C1=CC=C2C(C=C)=CC=CC2=C1 IGGDKDTUCAWDAN-UHFFFAOYSA-N 0.000 description 1
- ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 2,3-dimethylbutane Chemical group CC(C)C(C)C ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 0.000 description 1
- HMWCQCYUKQZPRA-UHFFFAOYSA-N 2,4-dimethyl-3-methylidenepent-1-ene Chemical compound CC(C)C(=C)C(C)=C HMWCQCYUKQZPRA-UHFFFAOYSA-N 0.000 description 1
- SBYMUDUGTIKLCR-UHFFFAOYSA-N 2-chloroethenylbenzene Chemical compound ClC=CC1=CC=CC=C1 SBYMUDUGTIKLCR-UHFFFAOYSA-N 0.000 description 1
- PDELBHCVXBSVPJ-UHFFFAOYSA-N 2-ethenyl-1,3,5-trimethylbenzene Chemical group CC1=CC(C)=C(C=C)C(C)=C1 PDELBHCVXBSVPJ-UHFFFAOYSA-N 0.000 description 1
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- CTHJQRHPNQEPAB-UHFFFAOYSA-N 2-methoxyethenylbenzene Chemical compound COC=CC1=CC=CC=C1 CTHJQRHPNQEPAB-UHFFFAOYSA-N 0.000 description 1
- AIDLAEPHWROGFI-UHFFFAOYSA-N 2-methylbenzene-1,3-dicarboxylic acid Chemical class CC1=C(C(O)=O)C=CC=C1C(O)=O AIDLAEPHWROGFI-UHFFFAOYSA-N 0.000 description 1
- OAOZZYBUAWEDRA-UHFFFAOYSA-N 3,4-dimethylidenehexane Chemical compound CCC(=C)C(=C)CC OAOZZYBUAWEDRA-UHFFFAOYSA-N 0.000 description 1
- JNRLEMMIVRBKJE-UHFFFAOYSA-N 4,4'-Methylenebis(N,N-dimethylaniline) Chemical compound C1=CC(N(C)C)=CC=C1CC1=CC=C(N(C)C)C=C1 JNRLEMMIVRBKJE-UHFFFAOYSA-N 0.000 description 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- ZZMVLMVFYMGSMY-UHFFFAOYSA-N 4-n-(4-methylpentan-2-yl)-1-n-phenylbenzene-1,4-diamine Chemical compound C1=CC(NC(C)CC(C)C)=CC=C1NC1=CC=CC=C1 ZZMVLMVFYMGSMY-UHFFFAOYSA-N 0.000 description 1
- 241000208340 Araliaceae Species 0.000 description 1
- 241000640882 Condea Species 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- HECLRDQVFMWTQS-UHFFFAOYSA-N Dicyclopentadiene Chemical compound C1C2C3CC=CC3C1C=C2 HECLRDQVFMWTQS-UHFFFAOYSA-N 0.000 description 1
- 241000790917 Dioxys <bee> Species 0.000 description 1
- 239000013032 Hydrocarbon resin Substances 0.000 description 1
- 239000006237 Intermediate SAF Substances 0.000 description 1
- 239000007987 MES buffer Substances 0.000 description 1
- 239000004594 Masterbatch (MB) Substances 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 235000005035 Panax pseudoginseng ssp. pseudoginseng Nutrition 0.000 description 1
- 235000003140 Panax quinquefolius Nutrition 0.000 description 1
- 239000005662 Paraffin oil Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 229910052581 Si3N4 Inorganic materials 0.000 description 1
- FZWLAAWBMGSTSO-UHFFFAOYSA-N Thiazole Chemical compound C1=CSC=N1 FZWLAAWBMGSTSO-UHFFFAOYSA-N 0.000 description 1
- 239000005843 Thiram Substances 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- RLAHNGKRJJEIJL-RFZPGFLSSA-N [(2r,4r)-4-(2,6-diaminopurin-9-yl)-1,3-dioxolan-2-yl]methanol Chemical compound C12=NC(N)=NC(N)=C2N=CN1[C@H]1CO[C@@H](CO)O1 RLAHNGKRJJEIJL-RFZPGFLSSA-N 0.000 description 1
- BQODPTQLXVVEJG-UHFFFAOYSA-N [O].C=C Chemical compound [O].C=C BQODPTQLXVVEJG-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000005083 alkoxyalkoxy group Chemical group 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 229920002892 amber Polymers 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 230000002929 anti-fatigue Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- LMAVPIIJOYURAF-UHFFFAOYSA-N benzene guanidine Chemical compound NC(=N)N.C1=CC=CC=C1.C1=CC=CC=C1 LMAVPIIJOYURAF-UHFFFAOYSA-N 0.000 description 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 230000001588 bifunctional effect Effects 0.000 description 1
- 239000007767 bonding agent Substances 0.000 description 1
- 230000031709 bromination Effects 0.000 description 1
- 238000005893 bromination reaction Methods 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- PBAYDYUZOSNJGU-UHFFFAOYSA-N chelidonic acid Natural products OC(=O)C1=CC(=O)C=C(C(O)=O)O1 PBAYDYUZOSNJGU-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 229920003211 cis-1,4-polyisoprene Polymers 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 150000001868 cobalt Chemical class 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 125000000000 cycloalkoxy group Chemical group 0.000 description 1
- IOJUPLGTWVMSFF-UHFFFAOYSA-N cyclobenzothiazole Natural products C1=CC=C2SC=NC2=C1 IOJUPLGTWVMSFF-UHFFFAOYSA-N 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- AFZSMODLJJCVPP-UHFFFAOYSA-N dibenzothiazol-2-yl disulfide Chemical compound C1=CC=C2SC(SSC=3SC4=CC=CC=C4N=3)=NC2=C1 AFZSMODLJJCVPP-UHFFFAOYSA-N 0.000 description 1
- KZNICNPSHKQLFF-UHFFFAOYSA-N dihydromaleimide Natural products O=C1CCC(=O)N1 KZNICNPSHKQLFF-UHFFFAOYSA-N 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- NAGJZTKCGNOGPW-UHFFFAOYSA-N dithiophosphoric acid Chemical compound OP(O)(S)=S NAGJZTKCGNOGPW-UHFFFAOYSA-N 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000006735 epoxidation reaction Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 235000008434 ginseng Nutrition 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 125000005456 glyceride group Chemical group 0.000 description 1
- 150000002357 guanidines Chemical class 0.000 description 1
- 229940083094 guanine derivative acting on arteriolar smooth muscle Drugs 0.000 description 1
- 230000026030 halogenation Effects 0.000 description 1
- 238000005658 halogenation reaction Methods 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229920006270 hydrocarbon resin Polymers 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 150000003949 imides Chemical class 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000001404 mediated effect Effects 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 150000004692 metal hydroxides Chemical class 0.000 description 1
- 239000012764 mineral filler Substances 0.000 description 1
- 239000012452 mother liquor Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 238000010068 moulding (rubber) Methods 0.000 description 1
- VILGDADBAQFRJE-UHFFFAOYSA-N n,n-bis(1,3-benzothiazol-2-ylsulfanyl)-2-methylpropan-2-amine Chemical compound C1=CC=C2SC(SN(SC=3SC4=CC=CC=C4N=3)C(C)(C)C)=NC2=C1 VILGDADBAQFRJE-UHFFFAOYSA-N 0.000 description 1
- IUJLOAKJZQBENM-UHFFFAOYSA-N n-(1,3-benzothiazol-2-ylsulfanyl)-2-methylpropan-2-amine Chemical compound C1=CC=C2SC(SNC(C)(C)C)=NC2=C1 IUJLOAKJZQBENM-UHFFFAOYSA-N 0.000 description 1
- CMAUJSNXENPPOF-UHFFFAOYSA-N n-(1,3-benzothiazol-2-ylsulfanyl)-n-cyclohexylcyclohexanamine Chemical compound C1CCCCC1N(C1CCCCC1)SC1=NC2=CC=CC=C2S1 CMAUJSNXENPPOF-UHFFFAOYSA-N 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- PMJHHCWVYXUKFD-UHFFFAOYSA-N penta-1,3-diene Chemical class CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 125000001863 phosphorothioyl group Chemical group *P(*)(*)=S 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- VVWRJUBEIPHGQF-UHFFFAOYSA-N propan-2-yl n-propan-2-yloxycarbonyliminocarbamate Chemical compound CC(C)OC(=O)N=NC(=O)OC(C)C VVWRJUBEIPHGQF-UHFFFAOYSA-N 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- OSFBJERFMQCEQY-UHFFFAOYSA-N propylidene Chemical group [CH]CC OSFBJERFMQCEQY-UHFFFAOYSA-N 0.000 description 1
- 239000003223 protective agent Substances 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- LVTJOONKWUXEFR-FZRMHRINSA-N protoneodioscin Natural products O(C[C@@H](CC[C@]1(O)[C@H](C)[C@@H]2[C@]3(C)[C@H]([C@H]4[C@@H]([C@]5(C)C(=CC4)C[C@@H](O[C@@H]4[C@H](O[C@H]6[C@@H](O)[C@@H](O)[C@@H](O)[C@H](C)O6)[C@@H](O)[C@H](O[C@H]6[C@@H](O)[C@@H](O)[C@@H](O)[C@H](C)O6)[C@H](CO)O4)CC5)CC3)C[C@@H]2O1)C)[C@H]1[C@H](O)[C@H](O)[C@H](O)[C@@H](CO)O1 LVTJOONKWUXEFR-FZRMHRINSA-N 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 229960002317 succinimide Drugs 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 125000000446 sulfanediyl group Chemical group *S* 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
- ZNCAMSISVWKWHL-UHFFFAOYSA-L zinc;butoxy-butylsulfanyl-oxido-sulfanylidene-$l^{5}-phosphane Chemical compound [Zn+2].CCCCOP([O-])(=S)SCCCC.CCCCOP([O-])(=S)SCCCC ZNCAMSISVWKWHL-UHFFFAOYSA-L 0.000 description 1
- MBBWTVUFIXOUBE-UHFFFAOYSA-L zinc;dicarbamodithioate Chemical compound [Zn+2].NC([S-])=S.NC([S-])=S MBBWTVUFIXOUBE-UHFFFAOYSA-L 0.000 description 1
- AUMBZPPBWALQRO-UHFFFAOYSA-L zinc;n,n-dibenzylcarbamodithioate Chemical compound [Zn+2].C=1C=CC=CC=1CN(C(=S)[S-])CC1=CC=CC=C1.C=1C=CC=CC=1CN(C(=S)[S-])CC1=CC=CC=C1 AUMBZPPBWALQRO-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/544—Silicon-containing compounds containing nitrogen
- C08K5/5455—Silicon-containing compounds containing nitrogen containing at least one group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F136/08—Isoprene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L21/00—Compositions of unspecified rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1152831 | 2011-04-01 | ||
| FR1152831A FR2973385B1 (fr) | 2011-04-01 | 2011-04-01 | Composition de caoutchouc pour pneumatique comportant un agent de couplage azosilane. |
| CN201280015708.3A CN103476848B (zh) | 2011-04-01 | 2012-03-28 | 包含偶氮-硅烷偶联剂的橡胶轮胎组合物 |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201280015708.3A Division CN103476848B (zh) | 2011-04-01 | 2012-03-28 | 包含偶氮-硅烷偶联剂的橡胶轮胎组合物 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105504370A CN105504370A (zh) | 2016-04-20 |
| CN105504370B true CN105504370B (zh) | 2018-01-26 |
Family
ID=45928887
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510934981.1A Active CN105504370B (zh) | 2011-04-01 | 2012-03-28 | 包含偶氮‑硅烷偶联剂的橡胶轮胎组合物 |
| CN201280015708.3A Active CN103476848B (zh) | 2011-04-01 | 2012-03-28 | 包含偶氮-硅烷偶联剂的橡胶轮胎组合物 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201280015708.3A Active CN103476848B (zh) | 2011-04-01 | 2012-03-28 | 包含偶氮-硅烷偶联剂的橡胶轮胎组合物 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US9624358B2 (enExample) |
| EP (2) | EP2694582B1 (enExample) |
| JP (1) | JP5974076B2 (enExample) |
| CN (2) | CN105504370B (enExample) |
| FR (1) | FR2973385B1 (enExample) |
| WO (1) | WO2012130885A1 (enExample) |
Families Citing this family (152)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9155262B2 (en) * | 2011-03-22 | 2015-10-13 | Pioneer Hi-Bred International, Inc. | Maize variety hybrid X05B916 |
| FR2973384B1 (fr) * | 2011-04-01 | 2014-08-22 | Michelin Soc Tech | Composition de caoutchouc pour pneumatique comportant un agent de couplage azosilane. |
| PT2508559E (pt) * | 2011-04-01 | 2014-02-12 | Evonik Degussa Gmbh | Misturas de borrachas |
| US9351455B1 (en) * | 2012-06-27 | 2016-05-31 | Agrigenetics, Inc. | Hybrid corn variety 3468680 |
| US9351459B1 (en) * | 2012-06-27 | 2016-05-31 | Agrigenetics, Inc. | Hybrid corn variety 1374689 |
| US9351454B1 (en) * | 2012-06-27 | 2016-05-31 | Agrigenetics, Inc. | Hybrid corn variety 19253331 |
| US9351457B1 (en) * | 2012-06-28 | 2016-05-31 | Agrigenetics, Inc. | Hybrid corn variety 2643350 |
| US9351456B1 (en) * | 2012-06-28 | 2016-05-31 | Agrigenetics, Inc. | Hybrid corn variety 232220 |
| US9351458B1 (en) * | 2012-06-28 | 2016-05-31 | Agrigenetics, Inc. | Hybrid corn variety 2643391 |
| US9179637B2 (en) * | 2012-07-27 | 2015-11-10 | Nunhems B.V. | Leek variety NUN 08412 |
| US9040779B2 (en) * | 2012-12-18 | 2015-05-26 | Monsanto Technology Llc | Soybean variety A1035446 |
| US9024116B2 (en) * | 2012-12-18 | 2015-05-05 | Monsanto Technology Llc | Soybean variety A1035957 |
| US9024117B2 (en) * | 2012-12-18 | 2015-05-05 | Monsanto Technology Llc | Soybean variety A1037394 |
| US9029644B2 (en) * | 2012-12-18 | 2015-05-12 | Monsanto Technology Llc | Soybean variety A1037403 |
| US9635818B1 (en) * | 2013-02-13 | 2017-05-02 | Pioneer Hi-Bred International, Inc. | Maize hybrid X18D810 |
| JP6141077B2 (ja) * | 2013-04-08 | 2017-06-07 | 東洋ゴム工業株式会社 | 物性改良剤、その製造方法及びゴム組成物 |
| US9210860B2 (en) * | 2013-05-09 | 2015-12-15 | Monsanto Technology Llc | Plants and seeds of hybrid corn variety CH856863 |
| US9210861B2 (en) * | 2013-05-09 | 2015-12-15 | Monsanto Technology Llc | Plants and seeds of hybrid corn variety CH030486 |
| US9210864B2 (en) * | 2013-05-13 | 2015-12-15 | Monsanto Technology Llc | Plants and seeds of hybrid corn variety CH558899 |
| US9210863B2 (en) * | 2013-05-13 | 2015-12-15 | Monsanto Technology Llc | Plants and seeds of hybrid corn variety CH338635 |
| US9210862B2 (en) * | 2013-05-13 | 2015-12-15 | Monsanto Technology Llc | Plants and seeds of hybrid corn variety CH768004 |
| US9210867B2 (en) * | 2013-05-14 | 2015-12-15 | Monsanto Technology Llc | Plants and seeds of hybrid corn variety CH369747 |
| US9210866B2 (en) * | 2013-05-14 | 2015-12-15 | Monsanto Technology Llc | Plants and seeds of hybrid corn variety CH225896 |
| US9210865B2 (en) * | 2013-05-14 | 2015-12-15 | Monsanto Technology Llc | Plants and seeds of hybrid corn variety CH813276 |
| US9210872B2 (en) * | 2013-05-30 | 2015-12-15 | Monsanto Technology Llc | Plants and seeds of hybrid corn variety CH236451 |
| US9210871B2 (en) * | 2013-05-30 | 2015-12-15 | Monsanto Technology Llc | Plants and seeds of hybrid corn variety CH071511 |
| US9210875B2 (en) * | 2013-05-31 | 2015-12-15 | Monsanto Technology Llc | Plants and seeds of hybrid corn variety CH183171 |
| US9210874B2 (en) * | 2013-05-31 | 2015-12-15 | Monsanto Technology Llc | Plants and seeds of hybrid corn variety CH790911 |
| US9210878B2 (en) * | 2013-05-31 | 2015-12-15 | Monsanto Technology Llc | Plants and seeds of hybrid corn variety CH921588 |
| US9210877B2 (en) * | 2013-05-31 | 2015-12-15 | Monsanto Technology Llc | Plants and seeds of hybrid corn variety CH325995 |
| US9210876B2 (en) * | 2013-05-31 | 2015-12-15 | Monsanto Technology Llc | Plants and seeds of hybrid corn variety CH651815 |
| FR3017392B1 (fr) * | 2014-02-07 | 2016-02-12 | Michelin & Cie | Composition de caoutchouc a base de polyisoprene epoxyde |
| US9699994B1 (en) * | 2014-02-27 | 2017-07-11 | Pioneer Hi-Bred International, Inc. | Maize hybrid X13F360 |
| US9699991B1 (en) * | 2014-02-27 | 2017-07-11 | Pioneer Hi-Bred International, Inc. | Maize hybrid X13F334 |
| US9699992B1 (en) * | 2014-02-27 | 2017-07-11 | Pioneer Hi-Bred International, Inc. | Maize hybrid X13F335 |
| US9699993B1 (en) * | 2014-02-27 | 2017-07-11 | Pioneer Hi-Bred International, Inc. | Maize hybrid X13F338 |
| US9699990B1 (en) * | 2014-03-06 | 2017-07-11 | Pioneer Hi-Bred International, Inc. | Maize hybrid X95F553 |
| US9699987B2 (en) * | 2014-03-06 | 2017-07-11 | Pioneer Hi-Bred International, Inc. | Maize hybrid X85F784 |
| US9699989B1 (en) * | 2014-03-06 | 2017-07-11 | Pioneer Hi-Bred International, Inc. | Maize hybrid X90F449 |
| US9699985B1 (en) * | 2014-03-06 | 2017-07-11 | Pioneer Hi-Bred International, Inc. | Maize hybrid X08F022 |
| US9699995B1 (en) * | 2014-03-06 | 2017-07-11 | Pioneer Hi-Bred International, Inc. | Maize hybrid X08F037 |
| US9693513B2 (en) * | 2014-03-06 | 2017-07-04 | Pioneer Hi-Bred International, Inc. | Maize hybrid X08F032XR |
| US9699988B2 (en) * | 2014-03-06 | 2017-07-11 | Pioneer Hi-Bred International, Inc. | Maize hybrid X90F448 |
| FR3020066B1 (fr) * | 2014-04-22 | 2016-04-01 | Michelin & Cie | Composition de caoutchouc pour pneumatique comportant un agent de couplage azosilane |
| PT2937351T (pt) * | 2014-04-22 | 2018-01-08 | Evonik Degussa Gmbh | Silanos funcionalizados de azocarbonilo |
| US9060491B1 (en) * | 2014-05-08 | 2015-06-23 | Monsanto Technology Llc | Soybean cultivar 39242052 |
| FR3024154B1 (fr) * | 2014-07-22 | 2016-07-22 | Michelin & Cie | Pneumatique pour avion |
| US9578828B2 (en) * | 2014-12-22 | 2017-02-28 | Syngenta Participations Ag | Soybean cultivar AR1100280 |
| US9532527B2 (en) * | 2015-03-07 | 2017-01-03 | Syngenta Participations Ag | Soybean cultivar AR1215506 |
| US9642321B2 (en) * | 2015-03-07 | 2017-05-09 | Syngenta Participations Ag | Soybean cultivar AR1210856 |
| US9723799B2 (en) * | 2015-03-07 | 2017-08-08 | Syngenta Participations Ag | Soybean cultivar AR1210886 |
| US20160255796A1 (en) * | 2015-03-07 | 2016-09-08 | Syngenta Participations Ag | Soybean Cultivar AR1215506 |
| US9642320B2 (en) * | 2015-03-07 | 2017-05-09 | Syngenta Participations Ag | Soybean cultivar AR1210100 |
| US9532534B2 (en) * | 2015-03-16 | 2017-01-03 | Syngenta Participations Ag | Soybean cultivar SJ1210512 |
| US9532532B2 (en) * | 2015-03-16 | 2017-01-03 | Syngenta Participations Ag | Soybean cultivar CE1211377 |
| US9532533B2 (en) * | 2015-03-16 | 2017-01-03 | Syngenta Participations Ag | Soybean cultivar SJ1210678 |
| US9532535B2 (en) * | 2015-03-16 | 2017-01-03 | Syngenta Participations Ag | Soybean cultivar BY1213080 |
| FR3045624A1 (fr) * | 2015-12-17 | 2017-06-23 | Michelin & Cie | Composition de caoutchouc pour pneumatique comportant un agent de couplage azosilane |
| EP3181571B1 (en) * | 2015-12-17 | 2019-07-24 | Evonik Degussa GmbH | Silicon-containing azodicarboxamides, their preparation and use |
| US9750213B1 (en) * | 2016-03-03 | 2017-09-05 | Pioneer Hi-Bred International, Inc. | Soybean variety XB55L15R |
| US9750214B1 (en) * | 2016-03-03 | 2017-09-05 | Pioneer Hi-Bred International, Inc. | Soybean variety XBP35012R |
| US9763409B1 (en) * | 2016-03-03 | 2017-09-19 | Pioneer Hi-Bred International, Inc. | Soybean variety XB55M15R |
| US9743606B1 (en) * | 2016-03-03 | 2017-08-29 | Pioneer Hi-Bred International, Inc. | Soybean variety XB57G15R |
| US9743609B1 (en) * | 2016-03-03 | 2017-08-29 | Pioneer Hi-Bred International, Inc. | Soybean variety XBP38014R |
| US9743608B1 (en) * | 2016-03-03 | 2017-08-29 | Pioneer Hi-Bred International, Inc. | Soybean variety XBP27011R |
| US9814202B2 (en) * | 2016-03-31 | 2017-11-14 | Pioneer Hi-Bred International, Inc. | Maize hybrid X05H214 |
| US9820454B1 (en) * | 2016-03-31 | 2017-11-21 | Pioneer Hi-Bred International, Inc. | Maize hybrid X13H829W |
| US9861059B1 (en) * | 2016-03-31 | 2018-01-09 | Pioneer Hi-Bred International, Inc. | Maize hybrid X08H842 |
| US9861061B1 (en) * | 2016-03-31 | 2018-01-09 | Pioneer Hi-Bred International, Inc. | Maize hybrid X13H943 |
| US9861065B1 (en) * | 2016-03-31 | 2018-01-09 | Pioneer Hi-Bred International, Inc. | Maize hybrid X05H223 |
| US9861064B1 (en) * | 2016-03-31 | 2018-01-09 | Pioneer Hi-Bred International, Inc. | Maize hybrid X13H845 |
| US9814203B1 (en) * | 2016-03-31 | 2017-11-14 | Pioneer Hi-Bred International, Inc. | Maize hybrid X08H806 |
| US9826695B1 (en) * | 2016-03-31 | 2017-11-28 | Pioneer Hi-Bred International, Inc. | Maize hybrid X05H211 |
| US9814200B1 (en) * | 2016-03-31 | 2017-11-14 | Pioneer Hi-Bred International, Inc. | Maize hybrid X08H824 |
| US9820455B1 (en) * | 2016-03-31 | 2017-11-21 | Pioneer Hi-Bred International, Inc. | Maize hybrid X08H716 |
| US9848553B1 (en) * | 2016-03-31 | 2017-12-26 | Pioneer Hi-Bred International, Inc. | Maize hybrid X80H130 |
| US9861058B1 (en) * | 2016-03-31 | 2018-01-09 | Pioneer Hi-Bred International, Inc. | Maize hybrid X08H734 |
| US9826694B1 (en) * | 2016-03-31 | 2017-11-28 | Pioneer Hi-Bred International, Inc. | Maize hybrid X08H838 |
| US9814198B1 (en) * | 2016-03-31 | 2017-11-14 | Pioneer Hi-Bred International, Inc. | Maize hybrid X05H205 |
| US9861057B1 (en) * | 2016-03-31 | 2018-01-09 | Pioneer Hi-Bred International, Inc. | Maize hybrid X05H206 |
| US9872461B1 (en) * | 2016-03-31 | 2018-01-23 | Pioneer Hi-Bred International, Inc. | Maize hybrid X95H691 |
| US9814199B1 (en) * | 2016-03-31 | 2017-11-14 | Pioneer Hi-Bred International, Inc. | Maize hybrid X13H830W |
| US9814197B1 (en) * | 2016-03-31 | 2017-11-14 | Pioneer Hi-Bred International, Inc. | Maize hybrid X13H974 |
| US9832947B1 (en) * | 2016-03-31 | 2017-12-05 | Pioneer Hi-Bred International, Inc. | Maize hybrid X13H930 |
| US9861060B1 (en) * | 2016-03-31 | 2018-01-09 | Pioneer Hi-Bred International, Inc. | Maize hybrid X08H823 |
| US9795109B1 (en) * | 2017-02-27 | 2017-10-24 | Syngenta Participations Ag | Lettuce variety holbrook |
| US10085405B1 (en) * | 2017-03-02 | 2018-10-02 | Pioneer Hi-Bred International, Inc. | Maize hybrid X08K219 |
| US10051813B1 (en) * | 2017-03-02 | 2018-08-21 | Pioneer Hi-Bred International, Inc. | Maize hybrid X00K390 |
| US10028465B1 (en) * | 2017-03-02 | 2018-07-24 | Pioneer Hi-Bred International, Inc. | Maize hybrid X13K545 |
| US10051828B1 (en) * | 2017-03-02 | 2018-08-21 | Pioneer Hi-Bred International, Inc. | Maize hybrid X13K495 |
| US10085407B1 (en) * | 2017-03-02 | 2018-10-02 | Pioneer Hi-Bred International, Inc. | Maize hybrid X05K690 |
| US10051812B1 (en) * | 2017-03-02 | 2018-08-21 | Pioneer Hi-Bred International, Inc. | Maize hybrid X08K237 |
| US10051811B1 (en) * | 2017-03-02 | 2018-08-21 | Pioneer Hi-Bred International, Inc. | Maize hybrid X03K064 |
| US10182538B1 (en) * | 2017-03-02 | 2019-01-22 | Pioneer Hi-Bred International, Inc. | Maize hybrid X13K488 |
| US10028464B1 (en) * | 2017-03-02 | 2018-07-24 | Pioneer Hi-Bred International, Inc. | Maize hybrid X15K728 |
| US10085406B1 (en) * | 2017-03-02 | 2018-10-02 | Pioneer Hi-Bred International, Inc. | Maize hybrid X08K187 |
| US10085408B1 (en) * | 2017-03-02 | 2018-10-02 | Pioneer Hi-Bred International, Inc. | Maize hybrid X13H147 |
| US10085404B1 (en) * | 2017-03-02 | 2018-10-02 | Pioneer Hi-Bred International, Inc. | Maize hybrid X13K502 |
| US10051810B1 (en) * | 2017-03-02 | 2018-08-21 | Pioneer Hi-Bred International, Inc. | Maize hybrid X08K266 |
| US9907283B1 (en) * | 2017-03-29 | 2018-03-06 | Monsanto Technology Llc | Soybean cultivar 62103227 |
| US10258007B1 (en) * | 2017-05-08 | 2019-04-16 | Pioneer Hi-Bred International, Inc. | Soybean variety 5PLQE62 |
| US10433510B2 (en) * | 2017-05-08 | 2019-10-08 | Syngenta Participations Ag | Lettuce variety Red Crispita |
| US10244700B1 (en) * | 2017-05-08 | 2019-04-02 | Pioneer Hi-Bred International, Inc. | Soybean variety 5PBDN11 |
| US10244699B1 (en) * | 2017-05-08 | 2019-04-02 | Pioneer Hi-Bred International, Inc. | Soybean variety 5PNJE71 |
| CA2987216C (en) * | 2017-11-20 | 2020-01-14 | Agrigenetics, Inc. | Soybean variety cl21924007 |
| DE102017221234A1 (de) * | 2017-11-28 | 2019-05-29 | Continental Reifen Deutschland Gmbh | Schwefelvernetzbare Kautschukmischung, Vulkanisat der Kautschukmischung und Fahrzeugreifen |
| US10681891B1 (en) * | 2017-12-01 | 2020-06-16 | Agrigenetics, Inc. | Soybean variety BR33576499 |
| US10548279B1 (en) * | 2018-05-15 | 2020-02-04 | Pioneer Hi-Bred International, Inc. | Soybean variety 5PKPE88 |
| US10750699B2 (en) * | 2018-10-25 | 2020-08-25 | Syngenta Crop Protection Ag | Lettuce variety Annita |
| FR3088333A3 (fr) * | 2018-11-08 | 2020-05-15 | Michelin & Cie | Composition de caoutchouc a base d'un elastomere dienique modifie |
| US10398109B1 (en) * | 2018-11-30 | 2019-09-03 | Syngenta Crop Protection Ag | Lettuce variety Glenrio |
| KR102778122B1 (ko) * | 2019-01-09 | 2025-03-10 | 주식회사 엘지화학 | 변성 공액디엔계 중합체, 이의 제조방법 및 이를 포함하는 고무 조성물 |
| US10420304B1 (en) * | 2019-01-24 | 2019-09-24 | Salinas Valley Seeds, Inc. | Lettuce variety Armstrong |
| US10631492B1 (en) * | 2019-05-23 | 2020-04-28 | Syngenta Crop Protection Ag | Lettuce variety Boronda |
| US10945395B2 (en) * | 2019-07-31 | 2021-03-16 | Syngenta Crop Protection Ag | Lettuce variety Takita |
| US11178836B2 (en) * | 2019-10-17 | 2021-11-23 | Benson Hill Seeds, Inc. | Soybean cultivar 2562880 |
| CA3169404C (en) * | 2020-02-19 | 2023-02-07 | Charlotte's Web, Inc. | Hemp plant named 'lindorea' |
| US10888060B1 (en) | 2020-02-19 | 2021-01-12 | Charlotte's Web, Inc. | Hemp plant named ‘KIRSCHE’ |
| US11234386B2 (en) * | 2020-03-05 | 2022-02-01 | A. Duda & Sons, Inc. | Celery cultivar TBG 40 |
| US11234388B2 (en) * | 2020-03-13 | 2022-02-01 | A. Duda & Sons, Inc. | Celery cultivar TBG 41 |
| US11234387B2 (en) * | 2020-03-13 | 2022-02-01 | A. Duda & Sons, Inc. | Celery cultivar TBG 39 |
| US11266088B2 (en) * | 2020-03-16 | 2022-03-08 | Syngenta Crop Protection Ag | Lettuce variety growler |
| US11382294B2 (en) * | 2020-11-18 | 2022-07-12 | Syngenta Crop Protection Ag | Variety corn line BFJD5618 |
| US11730134B2 (en) * | 2020-12-08 | 2023-08-22 | Sakata Seed America, Inc. | Serrano pepper hybrid SHP16817 |
| US11503791B2 (en) * | 2021-02-08 | 2022-11-22 | Hm.Clause, Inc. | Bean plant named HMC016335 |
| US11510385B2 (en) * | 2021-02-08 | 2022-11-29 | Hm.Clause, Inc. | Bean plant named bass |
| US11503790B2 (en) * | 2021-02-08 | 2022-11-22 | Hm.Clause, Inc. | Bean plant named WILLS |
| US11503789B2 (en) * | 2021-02-08 | 2022-11-22 | Hm.Clause, Inc. | Bean plant named peary |
| US11510386B2 (en) * | 2021-02-08 | 2022-11-29 | Hm.Clause, Inc. | Bean plant named JOLIET |
| US11700808B2 (en) * | 2021-02-16 | 2023-07-18 | H.M.CLAUSE, Inc. | Hybrid squash plant named yellow queen |
| US12089558B2 (en) * | 2021-02-23 | 2024-09-17 | Syngenta Crop Protection Ag | Soybean variety CL1922650 |
| US11805747B2 (en) * | 2021-09-02 | 2023-11-07 | Syngenta Crop Protection Ag | Garden bean variety MaCallan |
| US20230089210A1 (en) * | 2021-09-22 | 2023-03-23 | M.S. Technologies, L.L.C. | Soybean cultivar 00540608 |
| US12108729B2 (en) * | 2022-01-28 | 2024-10-08 | Hm.Clause, Inc. | Bean plant named HMX0175722 |
| WO2023152766A1 (en) * | 2022-02-09 | 2023-08-17 | Tvs Srichakra Limited | Tyre tread rubber composition using coconut shell powder and method thereof |
| US12317854B2 (en) * | 2022-03-11 | 2025-06-03 | Syngenta Crop Protection Ag | Garden bean variety redemption |
| US12317855B2 (en) * | 2022-03-14 | 2025-06-03 | Syngenta Crop Protection Ag | Garden bean variety rogue |
| US12329113B2 (en) * | 2022-03-15 | 2025-06-17 | M.S. Technologies, L.L.C. | Soybean cultivar 12040102 |
| US12396425B2 (en) * | 2022-03-15 | 2025-08-26 | M.S. Technologies, L.L.C. | Soybean cultivar 19090504 |
| US12336484B2 (en) * | 2022-03-15 | 2025-06-24 | M.S. Technologies, L.L.C. | Soybean cultivar 12270248 |
| US12329082B2 (en) * | 2022-04-08 | 2025-06-17 | A. Duda & Sons, Inc. | Celery cultivar TBG 43 |
| US12317797B2 (en) * | 2022-04-25 | 2025-06-03 | A. Duda & Sons, Inc. | Celery cultivar TBG 37 |
| US12324398B2 (en) * | 2022-06-03 | 2025-06-10 | Seminis Vegetable Seeds, Inc. | Bean variety SVGF2123 |
| US12336486B2 (en) * | 2022-09-07 | 2025-06-24 | M.S. Technologies, L.L.C. | Soybean cultivar 16440906 |
| US12336488B2 (en) * | 2022-09-09 | 2025-06-24 | M.S. Technologies, L.L.C. | Soybean cultivar 12210857 |
| US12336487B2 (en) * | 2022-09-09 | 2025-06-24 | M.S. Technologies, L.L.C. | Soybean cultivar 16220101 |
| US12317845B2 (en) * | 2022-09-09 | 2025-06-03 | M.S. Technologies, L.L.C. | Soybean cultivar 15240808 |
| US12336491B2 (en) * | 2022-09-23 | 2025-06-24 | Mertec, Llc | Soybean cultivar 12140843 |
| US12324396B2 (en) * | 2022-09-29 | 2025-06-10 | M.S. Technologies, L.L.C. | Soybean cultivar 10320519 |
| FR3143035B1 (fr) * | 2022-12-08 | 2024-11-29 | Michelin & Cie | Composition de caoutchouc |
| US20250072352A1 (en) * | 2023-08-31 | 2025-03-06 | M.S. Technologies, L.L.C. | Soybean cultivar 26130812 |
| US20250072370A1 (en) * | 2023-08-31 | 2025-03-06 | M.S. Technologies, L.L.C. | Soybean cultivar 24220205 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4118367A (en) * | 1976-02-06 | 1978-10-03 | The Malaysian Rubber Producers Research Association | Reinforced rubber |
| CN101228224A (zh) * | 2005-05-26 | 2008-07-23 | 米其林技术公司 | 用于轮胎的包含有机硅偶合体系的橡胶组合物 |
| CN101228223A (zh) * | 2005-05-26 | 2008-07-23 | 米其林技术公司 | 用于轮胎的包含有机硅偶合剂和无机填料遮盖剂的橡胶组合物 |
Family Cites Families (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2673187B1 (fr) | 1991-02-25 | 1994-07-01 | Michelin & Cie | Composition de caoutchouc et enveloppes de pneumatiques a base de ladite composition. |
| FR2732351B1 (fr) | 1995-03-29 | 1998-08-21 | Michelin & Cie | Composition de caoutchouc pour enveloppe de pneumatique renfermant de la silice dopee aluminium a titre de charge renforcante |
| FR2740778A1 (fr) | 1995-11-07 | 1997-05-09 | Michelin & Cie | Composition de caoutchouc a base de silice et de polymere dienique fonctionalise ayant une fonction silanol terminale |
| ATE411891T1 (de) | 1996-04-01 | 2008-11-15 | Cabot Corp | Neue elastomere verbundwerkstoffe, verfahren und vorrichtung zur herstellung derselben |
| FR2749313A1 (fr) | 1996-05-28 | 1997-12-05 | Michelin & Cie | Composition de caoutchouc dienique a base d'alumine en tant que charge renforcante et son utilisation pour la fabrication d'enveloppes de pneumatiques |
| FR2763593B1 (fr) | 1997-05-26 | 1999-07-09 | Michelin & Cie | Composition de caoutchouc a base de silice destinee a la fabrication d'enveloppes de pneumatiques routiers ayant une resistance au roulement amelioree |
| EP0996666B1 (fr) | 1997-07-07 | 2003-10-29 | Compagnie Générale des Etablissements MICHELIN-MICHELIN & CIE | Composition de caoutchouc de pneumatique couleur |
| FR2765882B1 (fr) | 1997-07-11 | 1999-09-03 | Michelin & Cie | Composition de caoutchouc a base de noir de carbone ayant de la silice fixee a sa surface et de polymere dienique fonctionnalise alcoxysilane |
| WO1999006480A1 (fr) | 1997-08-01 | 1999-02-11 | Compagnie Generale Des Etablissements Michelin-Michelin & Cie. | Composition de caoutchouc pour pneumatique couleur |
| ES2383959T3 (es) | 1997-09-30 | 2012-06-27 | Cabot Corporation | Mezclas de composiciones de elastómeros y métodos para su producción |
| KR100758143B1 (ko) | 1997-11-28 | 2007-09-14 | 꽁빠니 제네랄 드 에따블리세망 미쉘린-미쉘린 에 씨 | 입자 응집체 형태의 충전제의 초음파 붕해 속도 측정장치및 측정방법 |
| JP4596646B2 (ja) | 1998-07-22 | 2010-12-08 | ソシエテ ド テクノロジー ミシュラン | ポリ硫化アルコキシシラン、ジチオリン酸亜鉛及びグアニジン誘導体に基づくカップリング系（白色充填剤／ジエンエラストマー） |
| KR20010072010A (ko) | 1998-07-22 | 2001-07-31 | 미첼 롤리에르 | 폴리설파이드 알콕시실란, 엔아민 및 구아니딘 유도체를기본으로 하는 커플링 시스템(백색 충전제/디엔엘라스토머) |
| EP1114093B1 (fr) | 1999-05-28 | 2004-10-13 | Société de Technologie Michelin | Composition de caoutchouc pour pneumatique, a base d'elastomere dienique et d'un oxyde de titane renfor ant |
| EP1127909B1 (fr) | 2000-02-24 | 2005-03-09 | Société de Technologie Michelin | Composition de caoutchouc vulcanisable, utilisable pour fabriquer un pneumatique, et pneumatique comprenant cette composition |
| WO2001092402A1 (fr) | 2000-05-26 | 2001-12-06 | Societe De Technologie Michelin | Composition de caoutchouc utilisable comme bande de roulement de pneumatique |
| EP1311600A2 (fr) | 2000-07-31 | 2003-05-21 | Société de Technologie Michelin | Bande de roulement pour pneumatique |
| ATE362958T1 (de) | 2001-01-02 | 2007-06-15 | Michelin Soc Tech | Kautschukmischung auf der basis eines dienelastomers und eines verstärkenden siliciumcarbids |
| JP4536375B2 (ja) | 2001-06-28 | 2010-09-01 | ソシエテ ド テクノロジー ミシュラン | 極めて低い比表面積のシリカで強化されたタイヤトレッド |
| WO2003002648A1 (fr) | 2001-06-28 | 2003-01-09 | Societe De Technologie Michelin | Bande de roulement pour pneumatique renforcee d'une silice a basse surface specifique |
| DE50205120D1 (de) | 2001-08-06 | 2006-01-05 | Degussa | Organosiliciumverbindungen |
| FR2841560B1 (fr) | 2002-07-01 | 2006-02-03 | Michelin Soc Tech | Composition de caoutchouc a base d'elastomere dienique et d'un nitrure de silicium renforcant |
| JP4633471B2 (ja) | 2002-12-19 | 2011-02-16 | ソシエテ ド テクノロジー ミシュラン | 補強アルミノシリケートに基づくタイヤゴム組成物 |
| FR2854404B1 (fr) | 2003-04-29 | 2005-07-01 | Michelin Soc Tech | Procede d'obtention d'un elastomere greffe a groupes fonctionnels le long de la chaine et compositions de caoutchouc |
| FR2880349B1 (fr) | 2004-12-31 | 2009-03-06 | Michelin Soc Tech | Nanoparticules de polyvinylaromatique fonctionnalise |
| FR2880354B1 (fr) | 2004-12-31 | 2007-03-02 | Michelin Soc Tech | Composition elastomerique renforcee d'une charge de polyvinylaromatique fonctionnalise |
| FR2918062B1 (fr) * | 2007-06-29 | 2010-04-23 | Rhodia Recherches & Tech | Procede de preparation de composes hydrazo-silanes mettant en oeuvre un precurseur hydrazocarboxylate alcoxyle |
| PT2508559E (pt) * | 2011-04-01 | 2014-02-12 | Evonik Degussa Gmbh | Misturas de borrachas |
| FR2973384B1 (fr) * | 2011-04-01 | 2014-08-22 | Michelin Soc Tech | Composition de caoutchouc pour pneumatique comportant un agent de couplage azosilane. |
-
2011
- 2011-04-01 FR FR1152831A patent/FR2973385B1/fr not_active Expired - Fee Related
-
2012
- 2012-03-28 EP EP12711862.8A patent/EP2694582B1/fr active Active
- 2012-03-28 JP JP2014501596A patent/JP5974076B2/ja active Active
- 2012-03-28 US US14/008,620 patent/US9624358B2/en not_active Expired - Fee Related
- 2012-03-28 WO PCT/EP2012/055519 patent/WO2012130885A1/fr not_active Ceased
- 2012-03-28 CN CN201510934981.1A patent/CN105504370B/zh active Active
- 2012-03-28 EP EP18168270.9A patent/EP3395877B1/fr active Active
- 2012-03-28 CN CN201280015708.3A patent/CN103476848B/zh active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4118367A (en) * | 1976-02-06 | 1978-10-03 | The Malaysian Rubber Producers Research Association | Reinforced rubber |
| CN101228224A (zh) * | 2005-05-26 | 2008-07-23 | 米其林技术公司 | 用于轮胎的包含有机硅偶合体系的橡胶组合物 |
| CN101228223A (zh) * | 2005-05-26 | 2008-07-23 | 米其林技术公司 | 用于轮胎的包含有机硅偶合剂和无机填料遮盖剂的橡胶组合物 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103476848A (zh) | 2013-12-25 |
| US20140228479A1 (en) | 2014-08-14 |
| CN103476848B (zh) | 2016-06-15 |
| EP2694582A1 (fr) | 2014-02-12 |
| EP3395877A1 (fr) | 2018-10-31 |
| EP2694582B1 (fr) | 2018-05-16 |
| EP3395877B1 (fr) | 2020-05-13 |
| CN105504370A (zh) | 2016-04-20 |
| JP2014515050A (ja) | 2014-06-26 |
| WO2012130885A1 (fr) | 2012-10-04 |
| FR2973385A1 (fr) | 2012-10-05 |
| US9624358B2 (en) | 2017-04-18 |
| JP5974076B2 (ja) | 2016-08-23 |
| FR2973385B1 (fr) | 2014-08-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105504370B (zh) | 包含偶氮‑硅烷偶联剂的橡胶轮胎组合物 | |
| US7834074B2 (en) | Plasticizing system for rubber composition | |
| CN101855287B (zh) | 用于轮胎的包括羟基硅烷遮盖剂的橡胶组合物 | |
| JP5501563B2 (ja) | 亜鉛を含まない又は実質的に含まないゴム組成物 | |
| CN102300917B (zh) | 含有封端的巯基硅烷偶联剂的橡胶化合物 | |
| CN104870207B (zh) | 含有包含与多元羧酸交联的环氧弹性体的橡胶组合物的轮胎 | |
| CN102918089B (zh) | 制备包括热塑性填料的橡胶组合物的方法 | |
| US9040613B2 (en) | Plasticizing system and rubber composition for tire containing said system | |
| US20070082991A1 (en) | Tread for pneumatic tires | |
| EP1880870A1 (en) | Tire with silica-rich rubber tread for winter performance | |
| CN103459485A (zh) | 包含偶氮-硅烷偶联剂的橡胶轮胎组合物 | |
| CN104327331A (zh) | 含有封端的巯基硅烷偶联剂的橡胶组合物 | |
| JP2000103907A (ja) | シリカ強化トレッドおよび／またはサイドウォ―ル成分を有するタイヤ | |
| CN102428133B (zh) | 包含有机硅烷偶联剂的橡胶组合物 | |
| CN107001714A (zh) | 具有包含橡胶组合物的胎面的雪地轮胎 | |
| CN104024317A (zh) | 包含封端的巯基硅烷偶联剂的橡胶组合物 | |
| CN105992798B (zh) | 包含聚苯醚树脂作为增塑剂的橡胶组合物 | |
| CN102575056B (zh) | 包含噻唑的橡胶组合物 | |
| CN110099801B (zh) | 包括含有由亲二烯体交联的带有共轭二烯基团的聚合物的橡胶组合物的轮胎 | |
| CN105829434A (zh) | 包含作为塑化剂的聚苯醚树脂的橡胶组合物 | |
| CN1993416B (zh) | 不含或基本上不含锌的橡胶组合物 | |
| CN110023097A (zh) | 轮胎的胎面 | |
| US20210230401A1 (en) | Rubber composition comprising a polyphenylene ether resin as a plasticizer | |
| CN117615918A (zh) | 橡胶组合物 | |
| CN109415390A (zh) | 包含单羟基硅烷多硫化物偶联剂的橡胶组合物 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20170814 Address after: French Clermont Ferrand Applicant after: Compagnie General Des Etablissements Michelin Address before: French Clermont Ferrand Applicant before: Compagnie General Des Etablissements Michelin Applicant before: Michelin Research & Technology Co., Ltd. |
|
| TA01 | Transfer of patent application right | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |