CN1054384C - 烯烃聚合物的制备方法 - Google Patents

烯烃聚合物的制备方法 Download PDF

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Publication number
CN1054384C
CN1054384C CN93120452A CN93120452A CN1054384C CN 1054384 C CN1054384 C CN 1054384C CN 93120452 A CN93120452 A CN 93120452A CN 93120452 A CN93120452 A CN 93120452A CN 1054384 C CN1054384 C CN 1054384C
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catalyst component
carbon atom
polymerization
electron donor
alkyl
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Expired - Lifetime
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CN93120452A
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Chinese (zh)
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CN1090854A (zh
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扇泽雅明
木冈护
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Mitsui Chemicals Inc
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Mitsui Chemicals Inc
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/645—Component covered by group C08F4/64 with a metal or compound covered by group C08F4/44, not provided for in a single group of groups C08F4/642 - C08F4/643
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/658—Pretreating with metals or metal-containing compounds with metals or metal-containing compounds, not provided for in a single group of groups C08F4/653 - C08F4/657
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
CN93120452A 1992-12-04 1993-12-04 烯烃聚合物的制备方法 Expired - Lifetime CN1054384C (zh)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
JP32569892 1992-12-04
JP325697/1992 1992-12-04
JP325698/92 1992-12-04
JP325698/1992 1992-12-04
JP32569792 1992-12-04
JP325697/92 1992-12-04

Publications (2)

Publication Number Publication Date
CN1090854A CN1090854A (zh) 1994-08-17
CN1054384C true CN1054384C (zh) 2000-07-12

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ID=26571918

Family Applications (1)

Application Number Title Priority Date Filing Date
CN93120452A Expired - Lifetime CN1054384C (zh) 1992-12-04 1993-12-04 烯烃聚合物的制备方法

Country Status (7)

Country Link
US (1) US5844046A (enExample)
EP (1) EP0601496B2 (enExample)
KR (1) KR0137119B1 (enExample)
CN (1) CN1054384C (enExample)
CA (1) CA2110606C (enExample)
DE (1) DE69309864T3 (enExample)
TW (1) TW300235B (enExample)

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* Cited by examiner, † Cited by third party
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JP3304462B2 (ja) † 1993-01-04 2002-07-22 住友化学工業株式会社 エチレン−プロピレンブロック共重合体の製造方法
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DE69502480T2 (de) * 1994-02-04 1998-12-10 Exxon Chemical Patents, Inc., Baytown, Tex. Zweidonokatalysatorsystem zur olefinpolymerisation
US6635734B2 (en) 1994-04-26 2003-10-21 Fina Technology, Inc. Catalyst system to produce highly crystalline polypropylene
FR2728181B1 (fr) 1994-12-16 1997-01-31 Appryl Snc Composante catalytique pour la polymerisation des olefines, son procede de fabrication, et procede de polymerisation des olefines en presence de ladite composante catalytique
CN1089106C (zh) * 1995-01-09 2002-08-14 黄庆源 合成树脂粘合剂的连续化生产方法及其设施
USH1722H (en) * 1995-05-05 1998-04-07 Goode; Mark Gregory Process for producing polypropylene impact block copolymers
KR960041206A (ko) * 1995-05-26 1996-12-19 이현태 폴리프로필렌의 제조방법
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KR100334165B1 (ko) 1998-04-17 2002-11-27 삼성종합화학주식회사 에틸렌 중합 및 에틸렌/α-올레핀 공중합용 담지촉매의 제조방법
JP2002514666A (ja) * 1998-05-14 2002-05-21 エクソンモービル・ケミカル・パテンツ・インク 電子供与体のブレンドを使用して形成されたポリマー性物質
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KR100705475B1 (ko) 1998-12-30 2007-12-20 삼성토탈 주식회사 올레핀 중합 및 공중합용 촉매
KR100546499B1 (ko) 1999-05-27 2006-01-26 삼성토탈 주식회사 에틸렌 중합 및 공중합용 촉매
KR100524293B1 (ko) 1999-05-27 2005-10-26 삼성토탈 주식회사 에틸렌 중합 및 공중합용 촉매
CN1167715C (zh) 1999-10-23 2004-09-22 三星阿托菲纳株式会社 用于烯烃均聚和共聚反应的改进的催化剂
KR100361224B1 (ko) 1999-12-01 2002-11-29 삼성종합화학주식회사 에틸렌 중합 및 공중합용 촉매의 제조방법
KR100351386B1 (ko) 2000-04-24 2002-09-05 삼성종합화학주식회사 초고분자량 폴리에틸렌 제조용 촉매 및 이를 이용한초고분자량 폴리에틸렌 제조방법
WO2001081434A1 (en) * 2000-04-24 2001-11-01 Toho Titanium Co., Ltd. Solid catalyst component and catalyst for olefin polymerization
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KR100359932B1 (ko) 2000-06-15 2002-11-07 삼성종합화학주식회사 에틸렌 중합 및 공중합용 촉매
KR100387734B1 (ko) 2000-06-17 2003-06-18 삼성종합화학주식회사 올레핀 중합용 촉매 및 중합방법
KR100389476B1 (ko) 2000-11-09 2003-06-27 삼성종합화학주식회사 에틸렌 중합체 및 공중합체 제조방법
KR100389477B1 (ko) 2000-11-09 2003-06-27 삼성종합화학주식회사 에틸렌 중합체 및 공중합체 제조방법
KR100389475B1 (ko) 2000-11-09 2003-06-27 삼성종합화학주식회사 에틸렌 중합 또는 공중합용 촉매의 제조 방법
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CN100491458C (zh) 2006-04-20 2009-05-27 中国石油化工股份有限公司 高性能聚丙烯组合物的制备方法
CN103467630B (zh) 2007-08-24 2016-08-10 格雷斯公司 具有受控的铝和选择性控制剂之比的自限制催化剂体系和方法
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CN102186889B (zh) 2008-08-21 2013-11-06 陶氏环球技术有限责任公司 具有混合的选择性控制剂的催化剂组合物和使用它的聚合反应方法
RU2567391C2 (ru) 2009-08-21 2015-11-10 Чайна Петролеум Энд Кемикал Корпорейшн Компонент катализатора для полимеризации этилена, приготовление такового и катализатор, включающий компонент катализатора
WO2011088754A1 (zh) * 2010-01-22 2011-07-28 中国石油化工股份有限公司 一种具有高熔体强度的丙烯均聚物及其制备方法
CN102134291B (zh) * 2010-01-22 2013-12-04 中国石油化工股份有限公司 一种高熔体强度聚丙烯的制备方法
JP5984173B2 (ja) 2012-09-24 2016-09-06 インディアン オイル コーポレーション リミテッド オレフィン重合用の触媒を調製するプロセス
CN104610475B (zh) * 2013-11-05 2017-07-28 中国石油化工股份有限公司 一种用于烯烃聚合反应的催化剂
CN108174605B (zh) * 2015-08-07 2021-03-26 Sabic环球技术有限责任公司 用于烯烃聚合的方法
US10696756B2 (en) 2015-08-07 2020-06-30 Sabic Global Technologies B.V. Process for the polymerization of olefins
EP3331924B1 (en) 2015-08-07 2019-08-21 SABIC Global Technologies B.V. Process for the polymerization of olefins
CN106565870B (zh) * 2015-10-12 2019-07-05 中国科学院化学研究所 烯烃聚合催化剂及其制备方法和烯烃聚合催化剂体系及其应用以及聚烯烃树脂的制备方法
US11427660B2 (en) 2016-08-17 2022-08-30 Formosa Plastics Corporation, Usa Organosilicon compounds as electron donors for olefin polymerization catalysts and methods of making and using same
CN112004836B (zh) * 2018-04-20 2025-01-10 东邦钛株式会社 烯烃类聚合物和烯烃类聚合物的制造方法
US20250109218A1 (en) 2023-09-29 2025-04-03 Formosa Plastics Corporation, U.S.A. Method for preparing catalyst component for polymerization of polyolefin without the use of internal electron donors

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Patent Citations (1)

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Publication number Publication date
EP0601496A1 (en) 1994-06-15
CA2110606C (en) 1999-06-01
CA2110606A1 (en) 1994-06-05
US5844046A (en) 1998-12-01
DE69309864D1 (de) 1997-05-22
EP0601496B2 (en) 2001-06-27
EP0601496B1 (en) 1997-04-16
CN1090854A (zh) 1994-08-17
DE69309864T3 (de) 2001-11-22
KR940014456A (ko) 1994-07-18
TW300235B (enExample) 1997-03-11
DE69309864T2 (de) 1997-09-11
KR0137119B1 (ko) 1998-04-27

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