CN105363475A - 金属在被负载的含金属催化剂中的应用 - Google Patents

金属在被负载的含金属催化剂中的应用 Download PDF

Info

Publication number
CN105363475A
CN105363475A CN201510845741.4A CN201510845741A CN105363475A CN 105363475 A CN105363475 A CN 105363475A CN 201510845741 A CN201510845741 A CN 201510845741A CN 105363475 A CN105363475 A CN 105363475A
Authority
CN
China
Prior art keywords
metal
catalyst
carrier
particle
hole
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510845741.4A
Other languages
English (en)
Chinese (zh)
Inventor
K-T·万
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Monsanto Co
Monsanto Technology LLC
Original Assignee
Monsanto Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Monsanto Co filed Critical Monsanto Co
Publication of CN105363475A publication Critical patent/CN105363475A/zh
Pending legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391—Physical properties of the active metal ingredient
    • B01J35/393—Metal or metal oxide crystallite size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • B01J23/622—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead
    • B01J23/626—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead with tin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8906—Iron and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8913—Cobalt and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8926—Copper and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391—Physical properties of the active metal ingredient
    • B01J35/392—Metal surface area
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/396—Distribution of the active metal ingredient
    • B01J35/397—Egg shell like
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/617—500-1000 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0203—Impregnation the impregnation liquid containing organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C227/00—Preparation of compounds containing amino and carboxyl groups bound to the same carbon skeleton
    • C07C227/02—Formation of carboxyl groups in compounds containing amino groups, e.g. by oxidation of amino alcohols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
    • C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
    • C07F9/3813—N-Phosphonomethylglycine; Salts or complexes thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/18—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0205—Impregnation in several steps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0211—Impregnation using a colloidal suspension
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CN201510845741.4A 2008-05-01 2009-05-01 金属在被负载的含金属催化剂中的应用 Pending CN105363475A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US4946508P 2008-05-01 2008-05-01
US61/049,465 2008-05-01
CN2009801248482A CN102076409A (zh) 2008-05-01 2009-05-01 金属在被负载的含金属催化剂中的应用

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
CN2009801248482A Division CN102076409A (zh) 2008-05-01 2009-05-01 金属在被负载的含金属催化剂中的应用

Publications (1)

Publication Number Publication Date
CN105363475A true CN105363475A (zh) 2016-03-02

Family

ID=41130542

Family Applications (2)

Application Number Title Priority Date Filing Date
CN2009801248482A Pending CN102076409A (zh) 2008-05-01 2009-05-01 金属在被负载的含金属催化剂中的应用
CN201510845741.4A Pending CN105363475A (zh) 2008-05-01 2009-05-01 金属在被负载的含金属催化剂中的应用

Family Applications Before (1)

Application Number Title Priority Date Filing Date
CN2009801248482A Pending CN102076409A (zh) 2008-05-01 2009-05-01 金属在被负载的含金属催化剂中的应用

Country Status (8)

Country Link
EP (1) EP2293874A2 (fr)
CN (2) CN102076409A (fr)
AR (2) AR071623A1 (fr)
AU (1) AU2009242512B2 (fr)
BR (1) BRPI0911514B1 (fr)
CA (1) CA2725434C (fr)
MX (1) MX304650B (fr)
WO (1) WO2009135150A2 (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107073448A (zh) * 2015-08-14 2017-08-18 沙特基础工业全球技术公司 使用扫描隧道显微镜术针尖诱导反应制造具有所期望的尺寸的金属簇的方法
CN111430731A (zh) * 2020-04-01 2020-07-17 安徽师范大学 多孔碳载铂材料及其制备方法和应用
CN114540889A (zh) * 2022-03-25 2022-05-27 江阴纳力新材料科技有限公司 镀铜添加剂、镀铜液及其应用
CN114566661A (zh) * 2022-03-09 2022-05-31 昆明理工大学 一种碳材料表面负载铂钴纳米颗粒的制备方法

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102229621B (zh) * 2011-05-07 2013-10-02 安徽国星生物化学有限公司 一种紫外光源存在下催化氧化双甘膦制备草甘膦的方法
EP2771107A4 (fr) * 2011-10-28 2015-09-02 Basf Se Procédé de préparation d'un catalyseur à l'argent supporté
CN104437449A (zh) * 2014-12-09 2015-03-25 黑龙江大学 黑二氧化钛可见光光催化剂的制备方法
CN110339860B (zh) * 2019-07-29 2022-03-01 湖北工程学院 交联降冰片烯共聚物复合炭黑三维网络固载铂纳米催化剂及其制备方法和应用
JP7175857B2 (ja) 2019-08-02 2022-11-21 日清紡ホールディングス株式会社 金属担持触媒、電池電極及び電池
CN111054329A (zh) * 2019-11-25 2020-04-24 广东工业大学 一种铝负载贵金属的整体催化剂及其制备方法和应用
CN112794508B (zh) * 2021-01-05 2022-07-05 江山市双氧水有限公司 一种蒽醌法生产双氧水废水的预处理方法
CN113337719A (zh) * 2021-06-07 2021-09-03 林西金易来砷业有限公司 一种含砷烟尘综合利用及无害化处理工艺
CN114177903A (zh) * 2021-10-21 2022-03-15 江苏大学 一种制备微孔材料负载单原子和双原子催化剂的方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN85102099A (zh) * 1985-04-01 1987-01-10 孟山都公司 改良氧化催化剂
CN1120835A (zh) * 1993-04-12 1996-04-17 孟山都公司 氨基羧酸盐的制备方法
CN1298322A (zh) * 1998-02-25 2001-06-06 孟山都公司 深度还原的氧化催化剂及其用于催化液相氧化反应的用途
CN1433422A (zh) * 1999-12-21 2003-07-30 孟山都技术有限责任公司 补充促进剂与碳担载的含贵金属的催化剂一起在液相氧化反应中的用途

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8703639B2 (en) * 2004-09-15 2014-04-22 Monsanto Technology Llc Oxidation catalyst and its use for catalyzing liquid phase oxidation reactions
KR101384650B1 (ko) * 2006-08-30 2014-04-14 우미코레 아게 운트 코 카게 코어/쉘형 촉매 입자 및 이의 제조방법

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN85102099A (zh) * 1985-04-01 1987-01-10 孟山都公司 改良氧化催化剂
CN1120835A (zh) * 1993-04-12 1996-04-17 孟山都公司 氨基羧酸盐的制备方法
CN1298322A (zh) * 1998-02-25 2001-06-06 孟山都公司 深度还原的氧化催化剂及其用于催化液相氧化反应的用途
CN1962673A (zh) * 1998-02-25 2007-05-16 孟山都技术有限责任公司 深度还原的氧化催化剂及其用于催化液相氧化反应的用途
CN1433422A (zh) * 1999-12-21 2003-07-30 孟山都技术有限责任公司 补充促进剂与碳担载的含贵金属的催化剂一起在液相氧化反应中的用途

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107073448A (zh) * 2015-08-14 2017-08-18 沙特基础工业全球技术公司 使用扫描隧道显微镜术针尖诱导反应制造具有所期望的尺寸的金属簇的方法
CN111430731A (zh) * 2020-04-01 2020-07-17 安徽师范大学 多孔碳载铂材料及其制备方法和应用
CN114566661A (zh) * 2022-03-09 2022-05-31 昆明理工大学 一种碳材料表面负载铂钴纳米颗粒的制备方法
CN114540889A (zh) * 2022-03-25 2022-05-27 江阴纳力新材料科技有限公司 镀铜添加剂、镀铜液及其应用

Also Published As

Publication number Publication date
MX304650B (es) 2012-10-26
AR071623A1 (es) 2010-06-30
BRPI0911514A2 (pt) 2015-10-06
WO2009135150A2 (fr) 2009-11-05
MX2010012009A (es) 2010-11-30
BRPI0911514B1 (pt) 2018-03-27
AU2009242512A1 (en) 2009-11-05
EP2293874A2 (fr) 2011-03-16
WO2009135150A3 (fr) 2010-05-06
CA2725434A1 (fr) 2009-11-05
AR096669A2 (es) 2016-01-27
CA2725434C (fr) 2017-02-28
AU2009242512B2 (en) 2014-10-23
CN102076409A (zh) 2011-05-25

Similar Documents

Publication Publication Date Title
CN105363475A (zh) 金属在被负载的含金属催化剂中的应用
US9944667B2 (en) Metal utilization in supported, metal-containing catalysts
Rodrigues et al. Nanocatalysis by noble metal nanoparticles: controlled synthesis for the optimization and understanding of activities
CN109305879B (zh) 一种醇类化合物的合成方法
US10258967B2 (en) PT and/or PD egg-shell catalyst and use thereof
US10232354B2 (en) Enhanced dispersion of edge-coated precious metal catalysts
US9440224B2 (en) Catalyst particles comprising hollow multilayered base metal-precious metal core/shell particles and method of their manufacture
JP7397309B2 (ja) 合金触媒の製造方法及び合金触媒
US8951931B2 (en) Noble metal fine particle supported catalyst and method for producing the catalyst, and purifying catalyst
WO2009135189A1 (fr) Utilisation de métal dans des catalyseurs supportés de piles à combustible contenant du métal
Especel et al. Bimetallic Catalysts for Sustainable Chemistry: Surface Redox Reactions For Tuning The Catalytic Surface Composition
CN111470949A (zh) 一种环己醇类化合物的合成方法
Parvulescu Advances in heterogeneous catalysis: concepts of nanocatalysis and single-atom catalysis
KR102521607B1 (ko) 덴드리머-캡슐화 나노입자를 포함하는 수소 생성반응 촉매
CN111470948A (zh) 一种环己醇类化合物的合成方法
CN111470950A (zh) 一种环己醇类化合物的合成方法
SophieáHermans Bimetallic Pd-Bi/C Catalysts Prepared byáGrafting ofáComplexes witháO-Donor Ligands
CN116944509A (zh) 非晶钯基纳米粒子的合成方法及催化应用
CN111470945A (zh) 一种醇类化合物的合成方法
CN111470942A (zh) 一种醇类化合物的合成方法
CN111470975A (zh) 一种苯胺类化合物的合成方法
CN111468123A (zh) 一种苯胺类化合物的合成方法
CN111470943A (zh) 一种醇类化合物的合成方法
Muramatsu et al. Surface Control

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20160302

WD01 Invention patent application deemed withdrawn after publication