AR096669A2 - Utilización de metal en catalizadores soportados, que contienen metal - Google Patents

Utilización de metal en catalizadores soportados, que contienen metal

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Publication number
AR096669A2
AR096669A2 ARP140102333A ARP140102333A AR096669A2 AR 096669 A2 AR096669 A2 AR 096669A2 AR P140102333 A ARP140102333 A AR P140102333A AR P140102333 A ARP140102333 A AR P140102333A AR 096669 A2 AR096669 A2 AR 096669A2
Authority
AR
Argentina
Prior art keywords
metal
refers
regions
deposited
methods
Prior art date
Application number
ARP140102333A
Other languages
English (en)
Inventor
Wan Kam
To
Original Assignee
Monsanto Technology Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Monsanto Technology Llc filed Critical Monsanto Technology Llc
Publication of AR096669A2 publication Critical patent/AR096669A2/es

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391Physical properties of the active metal ingredient
    • B01J35/393Metal or metal oxide crystallite size
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56Platinum group metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56Platinum group metals
    • B01J23/62Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • B01J23/622Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead
    • B01J23/626Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead with tin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8906Iron and noble metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8913Cobalt and noble metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8926Copper and noble metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391Physical properties of the active metal ingredient
    • B01J35/392Metal surface area
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/396Distribution of the active metal ingredient
    • B01J35/397Egg shell like
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61Surface area
    • B01J35/617500-1000 m2/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0201Impregnation
    • B01J37/0203Impregnation the impregnation liquid containing organic compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C227/00Preparation of compounds containing amino and carboxyl groups bound to the same carbon skeleton
    • C07C227/02Formation of carboxyl groups in compounds containing amino groups, e.g. by oxidation of amino alcohols
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/28Phosphorus compounds with one or more P—C bonds
    • C07F9/38Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/3804Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
    • C07F9/3808Acyclic saturated acids which can have further substituents on alkyl
    • C07F9/3813N-Phosphonomethylglycine; Salts or complexes thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/18Carbon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66Pore distribution
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0201Impregnation
    • B01J37/0205Impregnation in several steps
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0201Impregnation
    • B01J37/0211Impregnation using a colloidal suspension
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08Heat treatment

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Mejoras en el uso de metal en catalizadores soportados, que contienen metal. Por ejemplo, la presente se refiere a métodos para dirigir y/o controlar la deposición de metal sobre las superficies de sustratos porosos. La presente también se refiere a métodos para preparar catalizadores donde se deposita un primer metal sobre un soporte (por ejemplo, un soporte de carbono poroso) para proveer una o más regiones de un primer metal en la superficie del soporte, y se deposita un segundo metal en la superficie de las una o más regiones del primer metal. En general, el carácter electropositivo del primer metal (por ejemplo, cobre o hierro) es mayor que el carácter electropositivo del segundo metal (por ejemplo, un metal noble tal como platino) y el segundo metal se deposita en la superficie de las una o más regiones del primer metal por desplazamiento del primer metal. La presente también se refiere a sustratos tratados, estructuras precursoras del catalizador y catalizadores preparados por dichos métodos. La presente también se refiere al uso de catalizadores preparados según se detalla aquí en reacciones de oxidación catalítica, como por ejemplo oxidación de un sustrato que se selecciona entre el grupo que consiste en acido N-(fosfonometil)iminodiacético o una sal del mismo, formaldehído, y/o ácido fórmico.
ARP140102333A 2008-05-01 2014-06-19 Utilización de metal en catalizadores soportados, que contienen metal AR096669A2 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US4946508P 2008-05-01 2008-05-01

Publications (1)

Publication Number Publication Date
AR096669A2 true AR096669A2 (es) 2016-01-27

Family

ID=41130542

Family Applications (2)

Application Number Title Priority Date Filing Date
ARP090101602A AR071623A1 (es) 2008-05-01 2009-05-04 Utilizacion de metal en catalizadores soportados, que contienen metal
ARP140102333A AR096669A2 (es) 2008-05-01 2014-06-19 Utilización de metal en catalizadores soportados, que contienen metal

Family Applications Before (1)

Application Number Title Priority Date Filing Date
ARP090101602A AR071623A1 (es) 2008-05-01 2009-05-04 Utilizacion de metal en catalizadores soportados, que contienen metal

Country Status (8)

Country Link
EP (1) EP2293874A2 (es)
CN (2) CN105363475A (es)
AR (2) AR071623A1 (es)
AU (1) AU2009242512B2 (es)
BR (1) BRPI0911514B1 (es)
CA (1) CA2725434C (es)
MX (1) MX304650B (es)
WO (1) WO2009135150A2 (es)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102229621B (zh) * 2011-05-07 2013-10-02 安徽国星生物化学有限公司 一种紫外光源存在下催化氧化双甘膦制备草甘膦的方法
WO2013061294A1 (de) * 2011-10-28 2013-05-02 Basf Se Verfahren zur herstellung eines geträgerten silberkatalysators
CN104437449A (zh) * 2014-12-09 2015-03-25 黑龙江大学 黑二氧化钛可见光光催化剂的制备方法
WO2017029589A1 (en) 2015-08-14 2017-02-23 Sabic Global Technologies B.V. Method of metallic clusters fabrication with desired size using scanning tunneling microscopy tip induced reactions
CN110339860B (zh) * 2019-07-29 2022-03-01 湖北工程学院 交联降冰片烯共聚物复合炭黑三维网络固载铂纳米催化剂及其制备方法和应用
CN111054329A (zh) * 2019-11-25 2020-04-24 广东工业大学 一种铝负载贵金属的整体催化剂及其制备方法和应用
CN111430731A (zh) * 2020-04-01 2020-07-17 安徽师范大学 多孔碳载铂材料及其制备方法和应用
CN112794508B (zh) * 2021-01-05 2022-07-05 江山市双氧水有限公司 一种蒽醌法生产双氧水废水的预处理方法
CN113337719A (zh) * 2021-06-07 2021-09-03 林西金易来砷业有限公司 一种含砷烟尘综合利用及无害化处理工艺
CN114177903A (zh) * 2021-10-21 2022-03-15 江苏大学 一种制备微孔材料负载单原子和双原子催化剂的方法
CN114566661A (zh) * 2022-03-09 2022-05-31 昆明理工大学 一种碳材料表面负载铂钴纳米颗粒的制备方法
CN114540889B (zh) * 2022-03-25 2023-03-24 江阴纳力新材料科技有限公司 镀铜添加剂、镀铜液及其应用

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1005249B (zh) * 1985-04-01 1989-09-27 孟山都公司 应用经热解的活性炭催化剂生产仲胺或伯胺的方法
DK0694030T4 (da) * 1993-04-12 2003-03-03 Monsanto Co Fremgangsmåde til fremstilling af aminocarboxylsyresalte
US6417133B1 (en) * 1998-02-25 2002-07-09 Monsanto Technology Llc Deeply reduced oxidation catalyst and its use for catalyzing liquid phase oxidation reactions
IL150354A0 (en) * 1999-12-21 2002-12-01 Monsanto Technology Llc Use of a supplemental promoter in conjunction with a carbon-supported, noble-metal containing catalyst in liquid phase oxidation reactions
US8703639B2 (en) * 2004-09-15 2014-04-22 Monsanto Technology Llc Oxidation catalyst and its use for catalyzing liquid phase oxidation reactions
CA2661489A1 (en) * 2006-08-30 2008-03-06 Umicore Ag & Co. Kg Core/shell-type catalyst particles comprising metal or ceramic core materials and methods for their preparation

Also Published As

Publication number Publication date
CA2725434A1 (en) 2009-11-05
BRPI0911514B1 (pt) 2018-03-27
AU2009242512A1 (en) 2009-11-05
CN105363475A (zh) 2016-03-02
EP2293874A2 (en) 2011-03-16
BRPI0911514A2 (pt) 2015-10-06
WO2009135150A2 (en) 2009-11-05
MX2010012009A (es) 2010-11-30
WO2009135150A3 (en) 2010-05-06
MX304650B (es) 2012-10-26
AR071623A1 (es) 2010-06-30
AU2009242512B2 (en) 2014-10-23
CA2725434C (en) 2017-02-28
CN102076409A (zh) 2011-05-25

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