WO2009135150A3 - Metal utilization in supported, metal-containing catalysts - Google Patents
Metal utilization in supported, metal-containing catalysts Download PDFInfo
- Publication number
- WO2009135150A3 WO2009135150A3 PCT/US2009/042562 US2009042562W WO2009135150A3 WO 2009135150 A3 WO2009135150 A3 WO 2009135150A3 US 2009042562 W US2009042562 W US 2009042562W WO 2009135150 A3 WO2009135150 A3 WO 2009135150A3
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- metal
- present
- relates
- regions
- methods
- Prior art date
Links
- 229910052751 metal Inorganic materials 0.000 title abstract 13
- 239000002184 metal Substances 0.000 title abstract 13
- 239000003054 catalyst Substances 0.000 title abstract 5
- 238000000034 method Methods 0.000 abstract 3
- 239000000758 substrate Substances 0.000 abstract 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 abstract 2
- 238000007254 oxidation reaction Methods 0.000 abstract 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 abstract 2
- FDQQNNZKEJIHMS-UHFFFAOYSA-N 3,4,5-trimethylphenol Chemical compound CC1=CC(O)=CC(C)=C1C FDQQNNZKEJIHMS-UHFFFAOYSA-N 0.000 abstract 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 abstract 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 239000012018 catalyst precursor Substances 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- 238000006073 displacement reaction Methods 0.000 abstract 1
- 235000019253 formic acid Nutrition 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 238000001465 metallisation Methods 0.000 abstract 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 abstract 1
- 229910000510 noble metal Inorganic materials 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 229910052697 platinum Inorganic materials 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
Classifications
-
- B01J35/393—
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
- B01J23/622—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead
- B01J23/626—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead with tin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/8906—Iron and noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/8913—Cobalt and noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/8926—Copper and noble metals
-
- B01J35/30—
-
- B01J35/392—
-
- B01J35/397—
-
- B01J35/617—
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
- B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0203—Impregnation the impregnation liquid containing organic compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C227/00—Preparation of compounds containing amino and carboxyl groups bound to the same carbon skeleton
- C07C227/02—Formation of carboxyl groups in compounds containing amino groups, e.g. by oxidation of amino alcohols
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids RP(=O)(OH)2; Thiophosphonic acids, i.e. RP(=X)(XH)2 (X = S, Se)
- C07F9/3804—Phosphonic acids RP(=O)(OH)2; Thiophosphonic acids, i.e. RP(=X)(XH)2 (X = S, Se) not used, see subgroups
- C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
- C07F9/3813—N-Phosphonomethylglycine; Salts or complexes thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/18—Carbon
-
- B01J35/66—
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0205—Impregnation in several steps
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0211—Impregnation using a colloidal suspension
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2009801248482A CN102076409A (en) | 2008-05-01 | 2009-05-01 | Metal utilization in supported, metal-containing catalysts |
MX2010012009A MX304650B (en) | 2008-05-01 | 2009-05-01 | Metal utilization in supported, metal-containing catalysts. |
EP09739952A EP2293874A2 (en) | 2008-05-01 | 2009-05-01 | Metal utilization in supported, metal-containing catalysts |
CA2725434A CA2725434C (en) | 2008-05-01 | 2009-05-01 | Metal utilization in supported, metal-containing catalysts |
BRPI0911514-5A BRPI0911514B1 (en) | 2008-05-01 | 2009-05-01 | "Oxidation Catalyst and Process for Oxidation of a Substrate" |
AU2009242512A AU2009242512B2 (en) | 2008-05-01 | 2009-05-01 | Metal utilization in supported, metal-containing catalysts |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US4946508P | 2008-05-01 | 2008-05-01 | |
US61/049,465 | 2008-05-01 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2009135150A2 WO2009135150A2 (en) | 2009-11-05 |
WO2009135150A3 true WO2009135150A3 (en) | 2010-05-06 |
Family
ID=41130542
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2009/042562 WO2009135150A2 (en) | 2008-05-01 | 2009-05-01 | Metal utilization in supported, metal-containing catalysts |
Country Status (8)
Country | Link |
---|---|
EP (1) | EP2293874A2 (en) |
CN (2) | CN102076409A (en) |
AR (2) | AR071623A1 (en) |
AU (1) | AU2009242512B2 (en) |
BR (1) | BRPI0911514B1 (en) |
CA (1) | CA2725434C (en) |
MX (1) | MX304650B (en) |
WO (1) | WO2009135150A2 (en) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102229621B (en) * | 2011-05-07 | 2013-10-02 | 安徽国星生物化学有限公司 | Method for preparing glyphosate by catalyzing and oxidizing glyphosine in the presence of ultraviolet light source |
WO2013061294A1 (en) * | 2011-10-28 | 2013-05-02 | Basf Se | Process for producing supported silver catalyst |
CN104437449A (en) * | 2014-12-09 | 2015-03-25 | 黑龙江大学 | Preparation method of black titanium dioxide visible light photocatalyst |
EP3183210B1 (en) | 2015-08-14 | 2018-01-17 | SABIC Global Technologies B.V. | Method of metallic clusters fabrication with desired size using scanning tunneling microscopy tip induced reactions |
CN110339860B (en) * | 2019-07-29 | 2022-03-01 | 湖北工程学院 | Crosslinked norbornene copolymer composite carbon black three-dimensional network supported platinum nano-catalyst and preparation method and application thereof |
CN111054329A (en) * | 2019-11-25 | 2020-04-24 | 广东工业大学 | Aluminum-supported noble metal monolithic catalyst and preparation method and application thereof |
CN111430731A (en) * | 2020-04-01 | 2020-07-17 | 安徽师范大学 | Porous carbon platinum-loaded material and preparation method and application thereof |
CN112794508B (en) * | 2021-01-05 | 2022-07-05 | 江山市双氧水有限公司 | Pretreatment method for wastewater generated in production of hydrogen peroxide by anthraquinone process |
CN113337719A (en) * | 2021-06-07 | 2021-09-03 | 林西金易来砷业有限公司 | Comprehensive utilization and harmless treatment process for arsenic-containing smoke dust |
CN114177903A (en) * | 2021-10-21 | 2022-03-15 | 江苏大学 | Method for preparing microporous material loaded monoatomic and diatomic catalyst |
CN114566661A (en) * | 2022-03-09 | 2022-05-31 | 昆明理工大学 | Preparation method of carbon material surface loaded with platinum-cobalt nanoparticles |
CN114540889B (en) * | 2022-03-25 | 2023-03-24 | 江阴纳力新材料科技有限公司 | Copper plating additive, copper plating solution and application thereof |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20020016503A1 (en) * | 1999-12-21 | 2002-02-07 | Leiber Mark A. | Use of a supplemental promoter in conjunction with a carbon-supported, noble-metal containing catalyst in liquid phase oxidation reactions |
US6417133B1 (en) * | 1998-02-25 | 2002-07-09 | Monsanto Technology Llc | Deeply reduced oxidation catalyst and its use for catalyzing liquid phase oxidation reactions |
WO2006031938A2 (en) * | 2004-09-15 | 2006-03-23 | Monsanto Technology Llc | Oxidation catalyst and its use for catalyzing liquid phase oxidation reactions |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1005249B (en) * | 1985-04-01 | 1989-09-27 | 孟山都公司 | Modified oxidizing catalyst |
CA2159828C (en) * | 1993-04-12 | 2004-08-31 | Yukio Kadono | Process to prepare amino-carboxylic acid salts |
US8304362B2 (en) * | 2006-08-30 | 2012-11-06 | Umicore Ag & Co. Kg | Core/shell-type catalyst particles and methods for their preparation |
-
2009
- 2009-05-01 MX MX2010012009A patent/MX304650B/en active IP Right Grant
- 2009-05-01 CA CA2725434A patent/CA2725434C/en active Active
- 2009-05-01 EP EP09739952A patent/EP2293874A2/en not_active Withdrawn
- 2009-05-01 WO PCT/US2009/042562 patent/WO2009135150A2/en active Application Filing
- 2009-05-01 CN CN2009801248482A patent/CN102076409A/en active Pending
- 2009-05-01 CN CN201510845741.4A patent/CN105363475A/en active Pending
- 2009-05-01 BR BRPI0911514-5A patent/BRPI0911514B1/en active IP Right Grant
- 2009-05-01 AU AU2009242512A patent/AU2009242512B2/en active Active
- 2009-05-04 AR ARP090101602A patent/AR071623A1/en active IP Right Grant
-
2014
- 2014-06-19 AR ARP140102333A patent/AR096669A2/en active IP Right Grant
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6417133B1 (en) * | 1998-02-25 | 2002-07-09 | Monsanto Technology Llc | Deeply reduced oxidation catalyst and its use for catalyzing liquid phase oxidation reactions |
US20020016503A1 (en) * | 1999-12-21 | 2002-02-07 | Leiber Mark A. | Use of a supplemental promoter in conjunction with a carbon-supported, noble-metal containing catalyst in liquid phase oxidation reactions |
WO2006031938A2 (en) * | 2004-09-15 | 2006-03-23 | Monsanto Technology Llc | Oxidation catalyst and its use for catalyzing liquid phase oxidation reactions |
Also Published As
Publication number | Publication date |
---|---|
AU2009242512A1 (en) | 2009-11-05 |
CA2725434C (en) | 2017-02-28 |
MX2010012009A (en) | 2010-11-30 |
CN102076409A (en) | 2011-05-25 |
CA2725434A1 (en) | 2009-11-05 |
AU2009242512B2 (en) | 2014-10-23 |
AR096669A2 (en) | 2016-01-27 |
BRPI0911514A2 (en) | 2015-10-06 |
WO2009135150A2 (en) | 2009-11-05 |
BRPI0911514B1 (en) | 2018-03-27 |
CN105363475A (en) | 2016-03-02 |
MX304650B (en) | 2012-10-26 |
AR071623A1 (en) | 2010-06-30 |
EP2293874A2 (en) | 2011-03-16 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
WO2009135150A3 (en) | Metal utilization in supported, metal-containing catalysts | |
WO2006031938A3 (en) | Oxidation catalyst and its use for catalyzing liquid phase oxidation reactions | |
GB201102502D0 (en) | Catalysts for use in reforming processes | |
MY145792A (en) | Hydro-oxidation process using a catalyst prepared from a gold cluster complex | |
SG136044A1 (en) | Catalyst for wastewater treatment and method for wastewater treatment using said catalyst | |
MY155307A (en) | Process for the reduction of aldehyde concentration in a target stream | |
WO2008066947A3 (en) | Formation of carbon and semiconductor nanomaterials using molecular assemblies | |
JP2010519038A5 (en) | ||
WO2008019582A1 (en) | Supported pd/c catalyst and the preparation methodthereof | |
TW200730248A (en) | Palladium complex and catalyst-imparting treatment solution using the same | |
ZA200711249B (en) | Multi-layer catalyst made from niobium for the catalytic conversion of hydrocarbons | |
KR101528334B1 (en) | a micro channel reactor and a fabricating method thereof | |
TR200003534T2 (en) | Vinyl acetate catalyst with metallic palladium, copper and gold. | |
ATE410409T1 (en) | METHOD FOR PRODUCING SATURATED NITRILES | |
US9238218B2 (en) | Metal powderdous catalyst for hydrogenation process | |
WO2010035186A3 (en) | Catalytic method for producing phenolphthalein compounds | |
TW200613058A (en) | Hydrocarbon cracking catalyst using chemical liquid deposition and method for preparing the same | |
WO2010068723A4 (en) | Methods for promoting syngas-to-alcohol catalysis | |
DE602006011360D1 (en) | CATALYSIS METHOD FOR THE PREPARATION OF C-5 SUBSTITUTED HETEROCYCLIC INHIBITORS OF TYPE 1 11BETA HYDROXYSTEROIDDEHYDROGENASE | |
JP2003525723A5 (en) | ||
WO2010075013A3 (en) | Processes for producing organohalohydrosilanes | |
GB2442363A (en) | Catalyst | |
MX2010008663A (en) | Process for preparing substituted biphenylanilides. | |
US20150025267A1 (en) | Metal powderdous catalyst comprising a fe-alloy | |
CA2773617C (en) | Process and catalyst |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
WWE | Wipo information: entry into national phase |
Ref document number: 200980124848.2 Country of ref document: CN |
|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 09739952 Country of ref document: EP Kind code of ref document: A2 |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2009242512 Country of ref document: AU |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2725434 Country of ref document: CA |
|
WWE | Wipo information: entry into national phase |
Ref document number: MX/A/2010/012009 Country of ref document: MX |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
ENP | Entry into the national phase |
Ref document number: 2009242512 Country of ref document: AU Date of ref document: 20090501 Kind code of ref document: A |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2009739952 Country of ref document: EP |
|
ENP | Entry into the national phase |
Ref document number: PI0911514 Country of ref document: BR Kind code of ref document: A2 Effective date: 20101029 |