CN105319253B - 一种测量金属熔体中氢含量的传感器及测量方法 - Google Patents

一种测量金属熔体中氢含量的传感器及测量方法 Download PDF

Info

Publication number
CN105319253B
CN105319253B CN201510770945.6A CN201510770945A CN105319253B CN 105319253 B CN105319253 B CN 105319253B CN 201510770945 A CN201510770945 A CN 201510770945A CN 105319253 B CN105319253 B CN 105319253B
Authority
CN
China
Prior art keywords
electrode
sensor
hydrogen content
solid
metal bath
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201510770945.6A
Other languages
English (en)
Chinese (zh)
Other versions
CN105319253A (zh
Inventor
厉英
丁玉石
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Northeastern University China
Original Assignee
Northeastern University China
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Northeastern University China filed Critical Northeastern University China
Priority to CN201510770945.6A priority Critical patent/CN105319253B/zh
Priority to EP15908135.5A priority patent/EP3372998B1/en
Priority to PCT/CN2015/096049 priority patent/WO2017080005A1/zh
Priority to US15/774,205 priority patent/US10598629B2/en
Priority to JP2018517620A priority patent/JP6775012B2/ja
Publication of CN105319253A publication Critical patent/CN105319253A/zh
Application granted granted Critical
Publication of CN105319253B publication Critical patent/CN105319253B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
    • G01N27/26Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
    • G01N27/403Cells and electrode assemblies
    • G01N27/406Cells and probes with solid electrolytes
    • G01N27/411Cells and probes with solid electrolytes for investigating or analysing of liquid metals
    • G01N27/4112Composition or fabrication of the solid electrolyte
    • G01N27/4114Composition or fabrication of the solid electrolyte for detection of gases other than oxygen
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/0004Gaseous mixtures, e.g. polluted air
    • G01N33/0009General constructional details of gas analysers, e.g. portable test equipment
    • G01N33/0027General constructional details of gas analysers, e.g. portable test equipment concerning the detector
    • G01N33/0036General constructional details of gas analysers, e.g. portable test equipment concerning the detector specially adapted to detect a particular component
    • G01N33/005H2
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
    • G01N27/26Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
    • G01N27/28Electrolytic cell components
    • G01N27/30Electrodes, e.g. test electrodes; Half-cells
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
    • G01N27/26Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
    • G01N27/28Electrolytic cell components
    • G01N27/30Electrodes, e.g. test electrodes; Half-cells
    • G01N27/301Reference electrodes
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/20Metals
    • G01N33/202Constituents thereof
    • G01N33/2022Non-metallic constituents
    • G01N33/2025Gaseous constituents

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Pathology (AREA)
  • General Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Immunology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Molecular Biology (AREA)
  • Electrochemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Food Science & Technology (AREA)
  • Medicinal Chemistry (AREA)
  • Measuring Oxygen Concentration In Cells (AREA)
  • Investigating And Analyzing Materials By Characteristic Methods (AREA)
CN201510770945.6A 2015-11-12 2015-11-12 一种测量金属熔体中氢含量的传感器及测量方法 Active CN105319253B (zh)

Priority Applications (5)

Application Number Priority Date Filing Date Title
CN201510770945.6A CN105319253B (zh) 2015-11-12 2015-11-12 一种测量金属熔体中氢含量的传感器及测量方法
EP15908135.5A EP3372998B1 (en) 2015-11-12 2015-11-30 Sensor and method for measuring content of hydrogen in metal melt
PCT/CN2015/096049 WO2017080005A1 (zh) 2015-11-12 2015-11-30 一种测量金属熔体中氢含量的传感器及测量方法
US15/774,205 US10598629B2 (en) 2015-11-12 2015-11-30 Sensor and measurement method for measuring hydrogen content in metal melt
JP2018517620A JP6775012B2 (ja) 2015-11-12 2015-11-30 アルミニウム溶融体中の水素含有量測定用センサー及び測定方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510770945.6A CN105319253B (zh) 2015-11-12 2015-11-12 一种测量金属熔体中氢含量的传感器及测量方法

Publications (2)

Publication Number Publication Date
CN105319253A CN105319253A (zh) 2016-02-10
CN105319253B true CN105319253B (zh) 2019-08-06

Family

ID=55247105

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201510770945.6A Active CN105319253B (zh) 2015-11-12 2015-11-12 一种测量金属熔体中氢含量的传感器及测量方法

Country Status (5)

Country Link
US (1) US10598629B2 (enExample)
EP (1) EP3372998B1 (enExample)
JP (1) JP6775012B2 (enExample)
CN (1) CN105319253B (enExample)
WO (1) WO2017080005A1 (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11549882B2 (en) * 2020-02-21 2023-01-10 The Regents Of The University Of Michigan Reference electrode and electrochemical monitoring system

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105675652A (zh) * 2016-02-19 2016-06-15 鸡西市天合科技有限公司 水稻田稻田水钾含量自动速测仪
CN106770518A (zh) * 2016-12-22 2017-05-31 东北大学 一种用于铝及铝合金熔体中的定氢装置及方法
CN107247080B (zh) * 2017-07-27 2020-01-24 中国原子能科学研究院 一种用于高温熔盐中氧离子的在线检测系统
WO2021002199A1 (ja) * 2019-07-01 2021-01-07 東京窯業株式会社 固体基準物質及び水素ガスセンサ
CN110655399B (zh) * 2019-09-06 2022-01-11 钟祥市中原电子有限责任公司 一种钢水定氢探头用透气陶瓷头及其制备方法
CN111024558B (zh) * 2019-12-24 2021-05-18 东北大学 一种测量铝熔体中氢扩散系数的装置及方法
CN111289405B (zh) * 2020-03-02 2022-07-01 哈尔滨理工大学 铝合金熔体氢分压惰性气体循环在线连续检测装置及其检测方法
CN112129824B (zh) * 2020-09-24 2021-11-30 东北大学 一种无损测量固体钢中氢含量的装置及方法
CN114324535B (zh) * 2022-01-05 2023-03-24 东北大学 一种可拆卸式金属熔体测氢传感器装置
CN114373559B (zh) * 2022-01-10 2024-09-27 中国原子能科学研究院 测定液态碱金属中的碳含量的系统及方法
CN115184238A (zh) * 2022-07-15 2022-10-14 中国人民解放军陆军炮兵防空兵学院 一种测量涂层结构材料氢同位素渗透的装置及方法
CN115856055B (zh) * 2022-12-06 2024-07-16 东北大学 一种测量镁熔体中氢含量的装置及方法
CN115825371B (zh) * 2022-12-06 2024-11-29 东北大学 一种测量金属中氢含量的装置及方法
CN119510529A (zh) * 2025-01-22 2025-02-25 浙江众氢科技有限公司 溶解氢的含量测量方法、测量装置以及计算机程序产品

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0544281A1 (en) * 1991-11-26 1993-06-02 Tokyo Yogyo Kabushiki Kaisha Sensor probe for measuring hydrogen concentration in molten metal and method for measuring hydrogen concentration
CN101071119A (zh) * 2007-06-15 2007-11-14 东北大学 一种测氢传感器及固体电解质的制备方法

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63269053A (ja) * 1987-04-25 1988-11-07 Tottori Univ 溶融金属またはガス中に含有されている水素または水蒸気の濃度の測定装置用基準物質
JP2578542B2 (ja) * 1991-12-27 1997-02-05 東京窯業株式会社 溶融金属中の水素溶解量測定用センサプローブ
US5490965A (en) * 1994-01-24 1996-02-13 Hewlett-Packard Company Method for closing holes in ceramic substrates
JPH0829375A (ja) * 1994-07-12 1996-02-02 Tokyo Yogyo Co Ltd 溶融金属中の水素溶解量測定用センサ
JP3878875B2 (ja) * 2002-03-29 2007-02-07 三井造船株式会社 酸素濃度計
GB0221393D0 (en) * 2002-09-14 2002-10-23 Univ Cambridge Tech Hydrogen sensing apparatus and method
US7396443B2 (en) * 2003-02-17 2008-07-08 Dongsub Park Solid-state electrochemical hydrogen probe for the measurement of hydrogen content in the molten aluminum
JP3095929U (ja) * 2003-02-17 2003-08-29 株式会社エバニユー 運動用ボール空気入れ
DE102004022763B3 (de) * 2004-05-05 2005-09-15 Heraeus Electro-Nite International N.V. Messeinrichtung zur Bestimmung der Sauerstoffaktivität in Metall- oder Schlackeschmelzen
GB0520777D0 (en) * 2005-10-12 2005-11-23 Environmental Monitoring And C Improved apparatus and method for measuring hydrogen concentration
JP4433489B2 (ja) * 2007-08-10 2010-03-17 昭和ホールディングス株式会社 ソフトテニスボール用空気入れポンプ
KR101325508B1 (ko) * 2012-03-14 2013-11-07 한국과학기술원 고체 산소이온 전도체와 고체 수소이온 전도체의 접합구조를 가진 용융금속 내 수소 측정 센서
JP2014160006A (ja) * 2013-02-19 2014-09-04 Tokyo Yogyo Co Ltd センサプローブ
JP2015086093A (ja) * 2013-10-29 2015-05-07 株式会社ノリタケカンパニーリミテド セラミック積層体およびその製造方法

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0544281A1 (en) * 1991-11-26 1993-06-02 Tokyo Yogyo Kabushiki Kaisha Sensor probe for measuring hydrogen concentration in molten metal and method for measuring hydrogen concentration
CN101071119A (zh) * 2007-06-15 2007-11-14 东北大学 一种测氢传感器及固体电解质的制备方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
用质子导体传感法研究钢在脱氢热处理中氢的行为;厉英等;《金属学报》;20110531;第47卷(第5期);第553-558页

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11549882B2 (en) * 2020-02-21 2023-01-10 The Regents Of The University Of Michigan Reference electrode and electrochemical monitoring system

Also Published As

Publication number Publication date
US10598629B2 (en) 2020-03-24
JP6775012B2 (ja) 2020-10-28
WO2017080005A1 (zh) 2017-05-18
JP2018533727A (ja) 2018-11-15
EP3372998A1 (en) 2018-09-12
US20180328881A1 (en) 2018-11-15
EP3372998B1 (en) 2020-11-18
EP3372998A4 (en) 2018-09-19
CN105319253A (zh) 2016-02-10

Similar Documents

Publication Publication Date Title
CN105319253B (zh) 一种测量金属熔体中氢含量的传感器及测量方法
JP2018533727A5 (enExample)
TW305023B (enExample)
CN112129824B (zh) 一种无损测量固体钢中氢含量的装置及方法
JPS60187854A (ja) 酸素濃度測定装置
CN210269703U (zh) 一种用于控制气氛中极低氧含量并测量其氧分压的装置
CN103884752B (zh) 用于研究熔融电解质中电活性氧化物电化学行为的电解池
JP4194452B2 (ja) 高温ガス中の酸素濃度測定装置
CN114072665A (zh) 固体参比物质和氢气传感器
JPH0792449B2 (ja) 溶融金属中の水素溶解量測定用センサプローブ及び水素濃度測定方法
JPH0835947A (ja) 溶融金属中の水素溶解量測定用センサ
CN115856055A (zh) 一种测量镁熔体中氢含量的装置及方法
JPH07225212A (ja) 溶融金属中の水素溶解量測定用センサプローブ
JP2878603B2 (ja) 溶融金属中の水素溶解量測定用センサ
JPH07119730B2 (ja) 溶融金属中の水素溶解量測定用センサプローブ
Ohshima et al. Study of Pd membrane electrode in solid electrolyte hydrogen (Isotopes) sensor for application to liquid blankets
JPH07225209A (ja) 溶融金属中の水素溶解量測定用センサプローブ
JPH0720083A (ja) 溶融金属中の水素溶解量測定用センサプローブ
SANO et al. Electrochemical Measurement of Oxygen Diffusivity in Liquid Silver
NobllO et al. Electrochemical Measurement of Oxygen Diffusivity in Liquid Silver
JPH0720084A (ja) 溶融金属中の水素溶解量測定用センサプローブ
JPH07225210A (ja) 溶融金属中の水素溶解量測定用センサプローブ及びその使用方法
JPS6058549A (ja) 二酸化イオウ用固体電解質ガスセンサ
JPH0835946A (ja) 溶融金属中の水素溶解量測定用センサ
JPH0749330A (ja) 溶融金属中の水素溶解量測定用センサプローブ

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
CB03 Change of inventor or designer information
CB03 Change of inventor or designer information

Inventor after: Li Ying

Inventor after: Ding Yushi

Inventor before: Li Ying

Inventor before: Ding Yushi

Inventor before: Zhou Xudong

GR01 Patent grant
GR01 Patent grant