CN105312081B - 用于NOx还原的新型含金属的沸石β - Google Patents

用于NOx还原的新型含金属的沸石β Download PDF

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Publication number
CN105312081B
CN105312081B CN201510593813.0A CN201510593813A CN105312081B CN 105312081 B CN105312081 B CN 105312081B CN 201510593813 A CN201510593813 A CN 201510593813A CN 105312081 B CN105312081 B CN 105312081B
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zeolite beta
silica
beta
iron
zeolite
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CN105312081A (zh
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黎鸿昕
W·E·克米尔
B·穆登
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Ekovist Catalyst Technology Co ltd
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PQ Corp
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404—Removing only nitrogen compounds
    • B01D53/9409—Nitrogen oxides
    • B01D53/9413—Processes characterised by a specific catalyst
    • B01D53/9418—Processes characterised by a specific catalyst for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/76—Iron group metals or copper
    • B01J29/7615—Zeolite Beta
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/20—Reductants
    • B01D2251/206—Ammonium compounds
    • B01D2251/2062—Ammonia
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20738—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20761—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/50—Zeolites
    • B01D2255/502—Beta zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Geology (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Exhaust Gas After Treatment (AREA)
CN201510593813.0A 2010-05-21 2011-05-18 用于NOx还原的新型含金属的沸石β Active CN105312081B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US34721010P 2010-05-21 2010-05-21
US61/347,210 2010-05-21
CN201180032195.2A CN102971065B (zh) 2010-05-21 2011-05-18 用于NOx还原的新型含金属的沸石β

Related Parent Applications (1)

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CN105312081A CN105312081A (zh) 2016-02-10
CN105312081B true CN105312081B (zh) 2020-09-15

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CN201180032195.2A Active CN102971065B (zh) 2010-05-21 2011-05-18 用于NOx还原的新型含金属的沸石β

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US (2) US20110286914A1 (https=)
EP (2) EP2571604B1 (https=)
JP (3) JP5797749B2 (https=)
KR (1) KR101852143B1 (https=)
CN (2) CN105312081B (https=)
BR (1) BR112012029648B1 (https=)
CA (1) CA2800393C (https=)
DK (1) DK2571604T3 (https=)
ES (1) ES2465617T3 (https=)
MX (1) MX343465B (https=)
PL (1) PL2571604T3 (https=)
RU (1) RU2641771C1 (https=)
WO (1) WO2011146615A2 (https=)
ZA (2) ZA201209485B (https=)

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JP5351216B2 (ja) 2010-07-01 2013-11-27 日本化学工業株式会社 ゼオライトの製造方法
JP5116880B2 (ja) * 2011-01-18 2013-01-09 日本化学工業株式会社 Ｆｅ（ＩＩ）置換ベータ型ゼオライト、それを含むガス吸着剤及びその製造方法、並びに一酸化窒素及びハイドロカーボンの除去方法
WO2013082550A1 (en) 2011-12-02 2013-06-06 Pq Corporation Stabilized microporous crystalline material, the method of making the same, and the use for selective catalytic reduction of nox
EP3744427B1 (en) * 2012-02-06 2026-01-28 Basf Se Process and apparatus for the treatment of gas streams containing nitrogen oxides
CN107362824B (zh) * 2012-02-06 2021-03-23 巴斯夫欧洲公司 获自无有机模板合成法的含铁和铜的沸石β
US20130202524A1 (en) 2012-02-06 2013-08-08 Basf Se Iron- And Copper-Containing Zeolite Beta From Organotemplate-Free Synthesis And Use Thereof In The Selective Catalytic Reduction Of NOx
JP6034224B2 (ja) * 2012-04-10 2016-11-30 ユニゼオ株式会社 ベータ型ゼオライト及びその製造方法
JP5988743B2 (ja) * 2012-07-18 2016-09-07 ユニゼオ株式会社 Ｆｅ（ＩＩ）置換ベータ型ゼオライト、それを含むガス吸着剤及びその製造方法、並びに一酸化窒素及びハイドロカーボンの除去方法
JP6058433B2 (ja) 2013-03-12 2017-01-11 ユニゼオ株式会社 ハイドロカーボンリフォーマトラップ材及びハイドロカーボンの除去方法
JP6153196B2 (ja) * 2013-06-14 2017-06-28 ユニゼオ株式会社 Ｍｎ＋置換ベータ型ゼオライト、それを含むガス吸着剤及びその製造方法、並びに一酸化窒素の除去方法
WO2015001095A1 (en) 2013-07-05 2015-01-08 Friedrich-Alexander-Universität Erlangen-Nürnberg Process for the preparation of organo-template free supported zeolite layers
CN103691481B (zh) * 2013-12-23 2016-04-13 中国科学院上海硅酸盐研究所 一种负载型多级孔Beta分子筛催化剂及其制备方法和应用
US10596518B2 (en) * 2014-01-03 2020-03-24 Basf Se Bimetal-exchanged zeolite beta from organotemplate-free synthesis and use thereof in the selective catalytic reduction of NOx
US20150231620A1 (en) * 2014-02-19 2015-08-20 Ford Global Technologies, Llc IRON-ZEOLITE CHABAZITE CATALYST FOR USE IN NOx REDUCTION AND METHOD OF MAKING
US20150290632A1 (en) * 2014-04-09 2015-10-15 Ford Global Technologies, Llc IRON AND COPPER-CONTAINING CHABAZITE ZEOLITE CATALYST FOR USE IN NOx REDUCTION
CZ2014448A3 (cs) * 2014-06-27 2016-04-13 Ústav fyzikální chemie J. Heyrovského AV ČR, v. v. i. Katalyzátor pro selektivní katalytickou redukci oxidů dusíku, způsob jeho výroby a použití
TWI657860B (zh) 2014-07-07 2019-05-01 荷蘭商蜆殼國際研究公司 異構化催化劑
WO2017062323A1 (en) 2015-10-06 2017-04-13 Shell Oil Company A process for making cumene by alkylation of benzene using an organotemplate-free zeolite beta
CN107029781B (zh) * 2016-02-04 2019-08-09 中触媒新材料股份有限公司 铁和铈改性β分子筛选择性还原催化剂及制备方法与应用
GB201608643D0 (en) * 2016-05-17 2016-06-29 Thermo Fisher Scient Bremen Elemental analysis system and method
AU2018299887B2 (en) 2017-07-11 2021-07-29 Shell Internationale Research Maatschappij B.V. A catalyst and method of use thereof
EP3651899B1 (en) * 2017-07-11 2026-05-06 Shell Internationale Research Maatschappij B.V. Catalyst and method of use thereof in the conversion of nox and n2o
CN111263733A (zh) * 2017-10-25 2020-06-09 三井金属矿业株式会社 金属取代的β型沸石及其制造方法
US20230173455A1 (en) * 2017-12-29 2023-06-08 Korea University Research And Business Foundation Hydrocarbon adsorbent
KR102085652B1 (ko) * 2017-12-29 2020-03-06 현대자동차 주식회사 규칙적인 메조 기공을 가진 제오라이트 입자에 금속이 함침된 탄화수소 흡착제 및 그 제조방법
JP2018108927A (ja) * 2018-01-29 2018-07-12 出光興産株式会社 金属担持ゼオライト成型体、金属担持ゼオライト成型体の製造方法、硫黄化合物除去用吸着剤、水素の製造方法、及び燃料電池システム
US10669908B1 (en) 2018-12-03 2020-06-02 Wellhead Power Solutions, Llc Power generating systems and methods for reducing startup NOx emissions in fossile fueled power generation system
WO2022158588A1 (ja) * 2021-01-25 2022-07-28 国立大学法人東京大学 ベータ型ゼオライト及びその製造方法
US20250205641A1 (en) 2022-03-29 2025-06-26 Mitsubishi Heavy Industries, Ltd. N2o decomposition catalyst
DE102023002844A1 (de) 2023-07-13 2025-01-16 Hans-Jürgen Eberle Katalysator zur Reduktion und/oder Zersetzung von Lachgas

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EP0393917A2 (en) * 1989-04-20 1990-10-24 Engelhard Corporation Method for reduction of nitrogen oxides with ammonia using promoted zeolite catalysts
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JP2017109924A (ja) 2017-06-22
JP6231525B2 (ja) 2017-11-15
US20110286914A1 (en) 2011-11-24
CN105312081A (zh) 2016-02-10
CN102971065A (zh) 2013-03-13
BR112012029648B1 (pt) 2020-12-22
WO2011146615A3 (en) 2012-04-26
CN102971065B (zh) 2015-11-25
KR101852143B1 (ko) 2018-04-25
ZA201209485B (en) 2014-02-26
DK2571604T3 (da) 2014-05-12
KR20130109980A (ko) 2013-10-08
MX343465B (es) 2016-11-07
EP2571604A2 (en) 2013-03-27
JP2015205277A (ja) 2015-11-19
ZA201309393B (en) 2014-08-27
US11786864B2 (en) 2023-10-17
JP5797749B2 (ja) 2015-10-21
RU2641771C1 (ru) 2018-01-22
EP2571604B1 (en) 2014-04-16
MX2012013535A (es) 2013-04-03
JP2013526406A (ja) 2013-06-24
JP6397064B2 (ja) 2018-09-26
WO2011146615A2 (en) 2011-11-24
ES2465617T3 (es) 2014-06-06
EP2742991A1 (en) 2014-06-18
PL2571604T3 (pl) 2014-09-30
US20190054420A1 (en) 2019-02-21
BR112012029648A2 (pt) 2016-08-02
RU2012155698A (ru) 2014-06-27
CA2800393A1 (en) 2011-11-24
CA2800393C (en) 2016-08-02

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