CN105294922B - 一种锂分离材料的制备方法 - Google Patents
一种锂分离材料的制备方法 Download PDFInfo
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- CN105294922B CN105294922B CN201510846261.XA CN201510846261A CN105294922B CN 105294922 B CN105294922 B CN 105294922B CN 201510846261 A CN201510846261 A CN 201510846261A CN 105294922 B CN105294922 B CN 105294922B
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- lithium
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- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 title claims abstract description 29
- 229910052744 lithium Inorganic materials 0.000 title claims abstract description 29
- 239000000463 material Substances 0.000 title claims abstract description 11
- 238000002360 preparation method Methods 0.000 title claims description 17
- 238000000926 separation method Methods 0.000 title abstract description 8
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000000126 substance Substances 0.000 claims abstract description 4
- 239000012071 phase Substances 0.000 claims description 16
- 239000008346 aqueous phase Substances 0.000 claims description 10
- 239000004088 foaming agent Substances 0.000 claims description 9
- 238000007664 blowing Methods 0.000 claims description 5
- 239000002270 dispersing agent Substances 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 5
- 238000010557 suspension polymerization reaction Methods 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- 108010010803 Gelatin Proteins 0.000 claims description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 229920000159 gelatin Polymers 0.000 claims description 3
- 239000008273 gelatin Substances 0.000 claims description 3
- 235000019322 gelatine Nutrition 0.000 claims description 3
- 235000011852 gelatine desserts Nutrition 0.000 claims description 3
- 229920003063 hydroxymethyl cellulose Polymers 0.000 claims description 3
- 150000002978 peroxides Chemical class 0.000 claims description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 3
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical class COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 229940031574 hydroxymethyl cellulose Drugs 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 150000001336 alkenes Chemical class 0.000 claims 1
- 229910052731 fluorine Inorganic materials 0.000 claims 1
- 239000011737 fluorine Substances 0.000 claims 1
- 230000000977 initiatory effect Effects 0.000 claims 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 1
- 238000001179 sorption measurement Methods 0.000 abstract description 9
- 229910001416 lithium ion Inorganic materials 0.000 abstract description 6
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 abstract description 5
- XSAOIFHNXYIRGG-UHFFFAOYSA-M lithium;prop-2-enoate Chemical compound [Li+].[O-]C(=O)C=C XSAOIFHNXYIRGG-UHFFFAOYSA-M 0.000 abstract description 5
- 238000006116 polymerization reaction Methods 0.000 abstract description 2
- 239000004925 Acrylic resin Substances 0.000 abstract 1
- 229920000178 Acrylic resin Polymers 0.000 abstract 1
- 150000001993 dienes Chemical class 0.000 abstract 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 abstract 1
- 239000011347 resin Substances 0.000 description 10
- 229920005989 resin Polymers 0.000 description 10
- 239000003463 adsorbent Substances 0.000 description 7
- 241001131796 Botaurus stellaris Species 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 238000010521 absorption reaction Methods 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- QNRMTGGDHLBXQZ-UHFFFAOYSA-N buta-1,2-diene Chemical compound CC=C=C QNRMTGGDHLBXQZ-UHFFFAOYSA-N 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- GBDJZMNUWNFRIF-SNAWJCMRSA-N CCO/C=C/C(C(F)(F)F)=C Chemical compound CCO/C=C/C(C(F)(F)F)=C GBDJZMNUWNFRIF-SNAWJCMRSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000012267 brine Substances 0.000 description 1
- 239000013522 chelant Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 1
- 239000002594 sorbent Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Landscapes
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Description
产品编号 | 锂的饱和吸附量mg/ml |
W-1 | 15 |
W-2 | 11 |
W-3 | 17 |
W-4 | 4 |
W-5 | 9 |
Claims (1)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201510846261.XA CN105294922B (zh) | 2015-11-30 | 2015-11-30 | 一种锂分离材料的制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CN201510846261.XA CN105294922B (zh) | 2015-11-30 | 2015-11-30 | 一种锂分离材料的制备方法 |
Publications (2)
Publication Number | Publication Date |
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CN105294922A CN105294922A (zh) | 2016-02-03 |
CN105294922B true CN105294922B (zh) | 2017-11-28 |
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Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106046265A (zh) * | 2016-06-13 | 2016-10-26 | 王金明 | 一种锡吸附材料的制备方法 |
CN105833854A (zh) * | 2016-06-13 | 2016-08-10 | 王金明 | 一种提纯钒吸附材料的制备 |
CN106046264B (zh) * | 2016-06-13 | 2018-09-18 | 王金明 | 一种氢氧化锂吸附剂的制备 |
CN106111092A (zh) * | 2016-07-28 | 2016-11-16 | 王金明 | 一种癸二酸二乙酯纯化用吸附剂的制备方法 |
CN107011447B (zh) * | 2017-04-20 | 2019-07-05 | 江门市长优实业有限公司 | 一种提取废水中锂的吸附剂及其制备方法 |
CN108722341A (zh) * | 2017-04-25 | 2018-11-02 | 比亚迪股份有限公司 | 锂吸附剂复合颗粒及其制备方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4221767A (en) * | 1978-09-05 | 1980-09-09 | The Dow Chemical Company | Recovery of lithium from brines |
CN102631897A (zh) * | 2012-02-14 | 2012-08-15 | 西安蓝晓科技新材料股份有限公司 | 一种制备锂吸附剂树脂的方法 |
CN103772575A (zh) * | 2014-01-22 | 2014-05-07 | 王金明 | 一种用做提取锂分离材料的制备方法 |
CN104014308A (zh) * | 2014-02-25 | 2014-09-03 | 江苏海普功能材料有限公司 | 制备高性能卤水提锂吸附剂的方法及其制备的吸附剂 |
-
2015
- 2015-11-30 CN CN201510846261.XA patent/CN105294922B/zh active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4221767A (en) * | 1978-09-05 | 1980-09-09 | The Dow Chemical Company | Recovery of lithium from brines |
CN102631897A (zh) * | 2012-02-14 | 2012-08-15 | 西安蓝晓科技新材料股份有限公司 | 一种制备锂吸附剂树脂的方法 |
CN103772575A (zh) * | 2014-01-22 | 2014-05-07 | 王金明 | 一种用做提取锂分离材料的制备方法 |
CN104014308A (zh) * | 2014-02-25 | 2014-09-03 | 江苏海普功能材料有限公司 | 制备高性能卤水提锂吸附剂的方法及其制备的吸附剂 |
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CN105294922A (zh) | 2016-02-03 |
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Address after: 432000 Xiaogan province hi tech Zone, the sound of the village of Southern District convenience Road, building No. 5, building 91, No. Applicant after: Wang Jinming Address before: 432000 Hubei city of Xiaogan province high tech Zone Danyang District Community Lisi mall two Room 201 Applicant before: Wang Jinming |
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Address after: 432000 Hubei city of Xiaogan Province Office of the Danyang high tech Zone Lisi District 11 building a commercial street Applicant after: Wang Jinming Address before: 432000 Xiaogan province hi tech Zone, the sound of the village of Southern District convenience Road, building No. 5, building 91, No. Applicant before: Wang Jinming |
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Address after: 322000 Zhejiang province Yiwu City Binwang zipper Street 5 District No. 3 room 602 Applicant after: Wang Jinming Address before: 432000 Hubei city of Xiaogan Province Office of the Danyang high tech Zone Lisi District 11 building a commercial street Applicant before: Wang Jinming |
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Inventor after: Fu Qiang Inventor after: Qi Qing Inventor before: Ma Jun Inventor before: Wang Qiyu |
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Effective date of registration: 20171024 Address after: 324004 Zhejiang province Quzhou Chuncheng Road No. 8 Building 1 layer 1 Applicant after: Zhejiang's west science and Technology Co Ltd Address before: 322000 Zhejiang province Yiwu City Binwang zipper Street 5 District No. 3 room 602 Applicant before: Wang Jinming |
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