CN105229015B - 锌簇合物及其在胺与碳酸二烷基酯的反应中作为催化剂的用途 - Google Patents

锌簇合物及其在胺与碳酸二烷基酯的反应中作为催化剂的用途 Download PDF

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CN105229015B
CN105229015B CN201480029298.7A CN201480029298A CN105229015B CN 105229015 B CN105229015 B CN 105229015B CN 201480029298 A CN201480029298 A CN 201480029298A CN 105229015 B CN105229015 B CN 105229015B
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phenylenediamine
zinc
equal
less
methyl
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CN105229015A (zh
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T.德里尔
S.韦肖芬
A.维达尔
R.哈克
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Covestro Deutschland AG
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Bayer MaterialScience AG
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C269/00—Preparation of derivatives of carbamic acid, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
    • C07C269/04—Preparation of derivatives of carbamic acid, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups from amines with formation of carbamate groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/41—Preparation of salts of carboxylic acids
    • C07C51/418—Preparation of metal complexes containing carboxylic acid moieties
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C65/00—Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
    • C07C65/21—Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups containing ether groups, groups, groups, or groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/34—Other additions, e.g. Monsanto-type carbonylations, addition to 1,2-C=X or 1,2-C-X triplebonds, additions to 1,4-C=C-C=X or 1,4-C=-C-X triple bonds with X, e.g. O, S, NH/N
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/20—Complexes comprising metals of Group II (IIA or IIB) as the central metal
    • B01J2531/26—Zinc

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201480029298.7A 2013-05-22 2014-05-19 锌簇合物及其在胺与碳酸二烷基酯的反应中作为催化剂的用途 Active CN105229015B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP13168788.1 2013-05-22
EP13168788 2013-05-22
PCT/EP2014/060174 WO2014187756A1 (en) 2013-05-22 2014-05-19 Zinc cluster compounds and their use as catalysts in the reaction of amines with dialkyl carbonates

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CN105229015A CN105229015A (zh) 2016-01-06
CN105229015B true CN105229015B (zh) 2020-11-03

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US (1) US9988344B2 (enExample)
EP (1) EP2999705B1 (enExample)
JP (1) JP6466414B2 (enExample)
KR (1) KR20160009565A (enExample)
CN (1) CN105229015B (enExample)
HU (1) HUE034953T2 (enExample)
SA (1) SA515370163B1 (enExample)
WO (1) WO2014187756A1 (enExample)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3625210B1 (en) 2017-05-15 2021-06-23 Covestro Intellectual Property GmbH & Co. KG Silica-based zinc catalysts. their preparation and use in the alkoxycarbonylation of amines
EP3450424A1 (de) 2017-09-04 2019-03-06 Covestro Deutschland AG Verfahren zur herstellung von isocyanaten
WO2020209578A1 (ko) * 2019-04-11 2020-10-15 덕산네오룩스 주식회사 Ⅲ－ⅴ계 양자점 제조를 위한 활성 나노 클러스터, 이를 포함하는 양자점 및 이들의 제조방법
CN116478205B (zh) * 2023-04-25 2024-10-01 中国科学院福建物质结构研究所 一种亚硒酸根配位的有机锡氧簇合物及其制备方法和应用

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102356062A (zh) * 2009-03-16 2012-02-15 拜尔材料科学股份公司 制备芳族氨基甲酸酯的方法

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US4268683A (en) 1980-02-21 1981-05-19 The Dow Chemical Company Preparation of carbamates from aromatic amines and organic carbonates
EP0065026A1 (en) 1981-05-18 1982-11-24 The Dow Chemical Company Preparation of carbamates from aromatic amines and organic carbonates
DE4113156A1 (de) 1991-04-23 1993-01-14 Bayer Ag Verfahren zur herstellung von poly(o-alkylurethanen) der diphenylmethanreihe
DE4121211A1 (de) 1991-06-27 1993-01-14 Bayer Ag Verfahren zur herstellung von bis(ethoxycarbonylamino)toluolen und deren verwendung zur herstellung von diisocyanatotoluolen
IT1317756B1 (it) 2000-02-03 2003-07-15 Eni Spa Procedimento integrato per la preparazione di isocianati aromatici eprocessi per la realizzazione delle relative fasi intermedie.
IT1318395B1 (it) 2000-03-17 2003-08-25 Enichem Spa Processo in continuo per la sintesi di uretani aromatici.
US7888513B2 (en) 2005-12-05 2011-02-15 Takasago International Corporation Condensation reaction by metal catalyst

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102356062A (zh) * 2009-03-16 2012-02-15 拜尔材料科学股份公司 制备芳族氨基甲酸酯的方法

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
Evidence for unimolecular CO2elimination in C–N bond metathesis reactions of basic carbamatozinc complexes Zn4O(O2CAm)6(Am=N-diethylamino,N-piperidyl,N-pyrrolidyl);M. Tyler Caudle et al.;《Dalton Trans.》;20051231;第238-246页 *
Improved Synthesis of Basic Zinc Acetate, Hexakis(u-acetate)-u-oxatetrazinc;Algirdas C. Poshkus;《Ind. Eng. Chem. Prod. Res. Dev.》;19831231;第22卷;第380-381页 *
Janusz Lewiński et al..Oxozinc Carboxylate Complexes: A New Synthetic Approach and the Carboxylate Ligand Effect on the Noncovalent-Interactions-Driven Self-Assembly.《Inorg. Chem.》.2012,第51卷第7410-7414页. *
Organometallic Route to Surface-Modified ZnO Nanoparticles Suitable for In Situ Nanocomposite Synthesis: Bound Carboxylate Stoichiometry Controls Particle Size or Surface Coverage;Charlotte K. Williams et al.;《Chem. Mater.》;20120620;第24卷;第2443-2448页 *

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Publication number Publication date
CN105229015A (zh) 2016-01-06
JP6466414B2 (ja) 2019-02-06
WO2014187756A1 (en) 2014-11-27
KR20160009565A (ko) 2016-01-26
JP2016520090A (ja) 2016-07-11
SA515370163B1 (ar) 2017-06-14
EP2999705B1 (en) 2017-08-09
US20160194277A1 (en) 2016-07-07
HUE034953T2 (en) 2018-03-28
US9988344B2 (en) 2018-06-05
EP2999705A1 (en) 2016-03-30

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