JP6466414B2 - 亜鉛クラスター化合物およびアミンと炭酸ジアルキルとの反応における触媒としてのそれらの使用 - Google Patents

亜鉛クラスター化合物およびアミンと炭酸ジアルキルとの反応における触媒としてのそれらの使用 Download PDF

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Publication number
JP6466414B2
JP6466414B2 JP2016514347A JP2016514347A JP6466414B2 JP 6466414 B2 JP6466414 B2 JP 6466414B2 JP 2016514347 A JP2016514347 A JP 2016514347A JP 2016514347 A JP2016514347 A JP 2016514347A JP 6466414 B2 JP6466414 B2 JP 6466414B2
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zinc
catalyst
reaction
tda
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Japanese (ja)
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JP2016520090A (ja
JP2016520090A5 (enExample
Inventor
トルシュテン、ドライアー
シュテファン、ベルショフェン
アントン、ビダル
ローベルト、ハーク
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Covestro Deutschland AG
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Covestro Deutschland AG
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C269/00—Preparation of derivatives of carbamic acid, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
    • C07C269/04—Preparation of derivatives of carbamic acid, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups from amines with formation of carbamate groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/41—Preparation of salts of carboxylic acids
    • C07C51/418—Preparation of metal complexes containing carboxylic acid moieties
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C65/00—Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
    • C07C65/21—Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups containing ether groups, groups, groups, or groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/34—Other additions, e.g. Monsanto-type carbonylations, addition to 1,2-C=X or 1,2-C-X triplebonds, additions to 1,4-C=C-C=X or 1,4-C=-C-X triple bonds with X, e.g. O, S, NH/N
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/20—Complexes comprising metals of Group II (IIA or IIB) as the central metal
    • B01J2531/26—Zinc

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
JP2016514347A 2013-05-22 2014-05-19 亜鉛クラスター化合物およびアミンと炭酸ジアルキルとの反応における触媒としてのそれらの使用 Expired - Fee Related JP6466414B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP13168788 2013-05-22
EP13168788.1 2013-05-22
PCT/EP2014/060174 WO2014187756A1 (en) 2013-05-22 2014-05-19 Zinc cluster compounds and their use as catalysts in the reaction of amines with dialkyl carbonates

Publications (3)

Publication Number Publication Date
JP2016520090A JP2016520090A (ja) 2016-07-11
JP2016520090A5 JP2016520090A5 (enExample) 2017-05-18
JP6466414B2 true JP6466414B2 (ja) 2019-02-06

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JP2016514347A Expired - Fee Related JP6466414B2 (ja) 2013-05-22 2014-05-19 亜鉛クラスター化合物およびアミンと炭酸ジアルキルとの反応における触媒としてのそれらの使用

Country Status (8)

Country Link
US (1) US9988344B2 (enExample)
EP (1) EP2999705B1 (enExample)
JP (1) JP6466414B2 (enExample)
KR (1) KR20160009565A (enExample)
CN (1) CN105229015B (enExample)
HU (1) HUE034953T2 (enExample)
SA (1) SA515370163B1 (enExample)
WO (1) WO2014187756A1 (enExample)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110650944B (zh) 2017-05-15 2022-07-19 科思创德国股份有限公司 基于二氧化硅的锌催化剂、它们的制备以及在胺的烷氧基羰基化中的用途
EP3450424A1 (de) 2017-09-04 2019-03-06 Covestro Deutschland AG Verfahren zur herstellung von isocyanaten
WO2020209578A1 (ko) * 2019-04-11 2020-10-15 덕산네오룩스 주식회사 Ⅲ－ⅴ계 양자점 제조를 위한 활성 나노 클러스터, 이를 포함하는 양자점 및 이들의 제조방법
CN116478205B (zh) * 2023-04-25 2024-10-01 中国科学院福建物质结构研究所 一种亚硒酸根配位的有机锡氧簇合物及其制备方法和应用

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4268683A (en) 1980-02-21 1981-05-19 The Dow Chemical Company Preparation of carbamates from aromatic amines and organic carbonates
EP0065026A1 (en) 1981-05-18 1982-11-24 The Dow Chemical Company Preparation of carbamates from aromatic amines and organic carbonates
DE4113156A1 (de) 1991-04-23 1993-01-14 Bayer Ag Verfahren zur herstellung von poly(o-alkylurethanen) der diphenylmethanreihe
DE4121211A1 (de) 1991-06-27 1993-01-14 Bayer Ag Verfahren zur herstellung von bis(ethoxycarbonylamino)toluolen und deren verwendung zur herstellung von diisocyanatotoluolen
IT1317756B1 (it) 2000-02-03 2003-07-15 Eni Spa Procedimento integrato per la preparazione di isocianati aromatici eprocessi per la realizzazione delle relative fasi intermedie.
IT1318395B1 (it) 2000-03-17 2003-08-25 Enichem Spa Processo in continuo per la sintesi di uretani aromatici.
JP5095415B2 (ja) 2005-12-05 2012-12-12 高砂香料工業株式会社 金属触媒による縮合反応
EP2230228A1 (en) 2009-03-16 2010-09-22 Bayer MaterialScience AG Process for preparing aromatic carbamates

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Publication number Publication date
US20160194277A1 (en) 2016-07-07
CN105229015A (zh) 2016-01-06
SA515370163B1 (ar) 2017-06-14
JP2016520090A (ja) 2016-07-11
KR20160009565A (ko) 2016-01-26
HUE034953T2 (en) 2018-03-28
EP2999705A1 (en) 2016-03-30
CN105229015B (zh) 2020-11-03
US9988344B2 (en) 2018-06-05
WO2014187756A1 (en) 2014-11-27
EP2999705B1 (en) 2017-08-09

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