CN105073804B - 具有抗冲击性并具有改进的光学性质的pmma - Google Patents
具有抗冲击性并具有改进的光学性质的pmma Download PDFInfo
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- C—CHEMISTRY; METALLURGY
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1802—C2-(meth)acrylate, e.g. ethyl (meth)acrylate
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
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- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
- C08F265/06—Polymerisation of acrylate or methacrylate esters on to polymers thereof
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- C08F285/00—Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers
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- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/10—Homopolymers or copolymers of methacrylic acid esters
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/10—Homopolymers or copolymers of methacrylic acid esters
- C08L33/12—Homopolymers or copolymers of methyl methacrylate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/12—Copolymers of styrene with unsaturated nitriles
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/08—Homopolymers or copolymers of acrylic acid esters
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/53—Core-shell polymer
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- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Graft Or Block Polymers (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacturing & Machinery (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
Description
IE1 | IE2 | IE3 | IE4 | IE5 | CE1 | |
种子胶乳 | 93.00 | 58.00 | 28.00 | 20.00 | 16.00 | 5.00 |
乳液(i) | ||||||
水 | 878.70 | 878.70 | 878.70 | 878.70 | 878.70 | 732.69 |
过硫酸钠 | 0.70 | 0.70 | 0.70 | 0.70 | 0.70 | 0.51 |
Aerosol OT75 | 5.60 | 5.60 | 5.60 | 5.60 | 5.60 | 4.67 |
甲基丙烯酸甲酯 | 1071.62 | 1071.62 | 1071.62 | 1071.62 | 1071.62 | 703.47 |
丙烯酸乙酯 | 44.74 | 44.74 | 44.74 | 44.74 | 44.74 | 29.40 |
甲基丙烯酸烯丙酯 | 2.24 | 2.24 | 2.24 | 2.24 | 2.24 | 2.21 |
乳液(ii) | ||||||
水 | 606.90 | 606.90 | 606.90 | 606.90 | 606.90 | 628.65 |
过硫酸钠 | 1.58 | 1.58 | 1.58 | 1.58 | 1.58 | 1.44 |
Aerosol OT75 | 7.20 | 7.20 | 7.20 | 7.20 | 7.20 | 7.46 |
丙烯酸丁酯 | 1160.63 | 1160.63 | 1160.63 | 1160.63 | 1160.63 | 1219.72 |
苯乙烯 | 256.00 | 256.00 | 256.00 | 256.00 | 256.00 | 262.87 |
甲基丙烯酸烯丙酯 | 21.57 | 21.57 | 21.57 | 21.57 | 21.57 | 19.53 |
乳液(iii) | ||||||
水 | 404.30 | 404.30 | 404.30 | 404.30 | 404.30 | 381.56 |
过硫酸钠 | 0.70 | 0.70 | 0.70 | 0.70 | 0.70 | 0.44 |
Aerosol OT75 | 1.08 | 1.08 | 1.08 | 1.08 | 1.08 | 1.34 |
甲基丙烯酸甲酯 | 614.27 | 614.27 | 614.27 | 614.27 | 614.27 | 920.45 |
丙烯酸乙酯 | 24.93 | 24.93 | 24.93 | 24.93 | 24.93 | 38.35 |
Claims (31)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP13160867 | 2013-03-25 | ||
EP13160867.1 | 2013-03-25 | ||
PCT/EP2014/055489 WO2014154543A1 (de) | 2013-03-25 | 2014-03-19 | Schlagzäh ausgerüstetes pmma mit verbesserten optischen eigenschaften |
Publications (2)
Publication Number | Publication Date |
---|---|
CN105073804A CN105073804A (zh) | 2015-11-18 |
CN105073804B true CN105073804B (zh) | 2018-01-19 |
Family
ID=47915582
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201480017789.XA Active CN105073804B (zh) | 2013-03-25 | 2014-03-19 | 具有抗冲击性并具有改进的光学性质的pmma |
Country Status (18)
Country | Link |
---|---|
US (1) | US9988548B2 (zh) |
EP (1) | EP2978785B1 (zh) |
JP (1) | JP6359080B2 (zh) |
KR (1) | KR101796850B1 (zh) |
CN (1) | CN105073804B (zh) |
CA (1) | CA2907995C (zh) |
ES (1) | ES2625434T3 (zh) |
HK (1) | HK1213275A1 (zh) |
HU (1) | HUE034249T2 (zh) |
MX (1) | MX348358B (zh) |
MY (1) | MY172180A (zh) |
PL (1) | PL2978785T3 (zh) |
RU (1) | RU2648238C2 (zh) |
SA (1) | SA515361228B1 (zh) |
SG (1) | SG11201507941RA (zh) |
SI (1) | SI2978785T1 (zh) |
TW (1) | TWI603987B (zh) |
WO (1) | WO2014154543A1 (zh) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR3031106B1 (fr) * | 2014-12-24 | 2017-02-03 | Arkema France | Composition de polymeres a phases multiples, son procede de preparation, son utilisation et composition la comprenant |
FR3046605B1 (fr) * | 2016-01-11 | 2019-09-06 | Arkema France | Composition liquide comprenant un polymere a phases multiples, son procede de preparation et son utilisation |
KR102580151B1 (ko) * | 2016-02-05 | 2023-09-19 | 미쯔비시 가스 케미칼 컴파니, 인코포레이티드 | 광확산제, 광확산성 수지 조성물 및 성형체 |
CN106565914A (zh) * | 2016-11-09 | 2017-04-19 | 安徽新胜塑料科技有限公司 | 一种用于灯罩板的浇筑亚克力板制备方法 |
KR102034597B1 (ko) * | 2017-11-10 | 2019-10-21 | 엘지엠엠에이 주식회사 | 자동차 글레이징용 수지 조성물 |
FR3075212B1 (fr) | 2017-12-18 | 2020-11-20 | Arkema France | Composition de polymere (meth)acrylique, son procede de preparation et utilisation |
CN112334503A (zh) * | 2018-06-26 | 2021-02-05 | 阿科玛法国公司 | 基于多级聚合物的可固化组合物 |
CN109971086A (zh) * | 2019-02-14 | 2019-07-05 | 山东东临新材料股份有限公司 | 一种pvc易加工不透明高抗冲mbs及其制备方法 |
CN114174417A (zh) * | 2019-03-25 | 2022-03-11 | 盛禧奥欧洲有限责任公司 | 高效的抗冲改性剂和聚合物组合物 |
Citations (4)
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US3793402A (en) * | 1971-11-05 | 1974-02-19 | F Owens | Low haze impact resistant compositions containing a multi-stage,sequentially produced polymer |
EP0542036A1 (de) * | 1991-11-11 | 1993-05-19 | BASF Aktiengesellschaft | Transparente, schlagzähmodifizierte PMMA-Formmassen mit verbesserter Tieftemperatur-Schlagzähigkeit und hoher Bewitterungsstabilität |
CN1185165A (zh) * | 1995-05-24 | 1998-06-17 | 帝国化学工业公司 | 抗冲击改性的(甲基)丙烯酸酯类聚合物 |
CN1729219A (zh) * | 2002-12-19 | 2006-02-01 | 罗姆两合公司 | 水分散体的制备方法 |
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KR100274658B1 (ko) | 1997-12-30 | 2000-12-15 | 하영준, 마르코스 고메즈 | 폴리메틸메타크릴레이트의 충격보강제용 코어-쉘 복합입자의 제조방법 및 이를 함유하는 조성물 |
KR100309581B1 (ko) | 1998-05-19 | 2001-09-26 | 구광시 | 충격보강제가 캡슐화된 아크릴 수지 및 그의 제조방법. |
DE10043868A1 (de) * | 2000-09-04 | 2002-04-04 | Roehm Gmbh | PMMA Formmassen mit verbesserter Schlagzähigkeit |
JP3835275B2 (ja) | 2001-12-14 | 2006-10-18 | 住友化学株式会社 | アクリル系樹脂フィルム及びそれを積層した射出成形品 |
JP3956712B2 (ja) | 2002-02-13 | 2007-08-08 | 住友化学株式会社 | 耐白化性アクリル系樹脂フィルムとそれを用いた積層成形品 |
US7294399B2 (en) | 2002-04-02 | 2007-11-13 | Arkema France | Weather-resistant, high-impact strength acrylic compositions |
DE10260065A1 (de) * | 2002-12-19 | 2004-07-01 | Röhm GmbH & Co. KG | Kern-Schale-Teilchen zur Schlagzähmodifizierung von Poly(meth)acrylat-Formmassen |
JP4242207B2 (ja) * | 2003-05-28 | 2009-03-25 | 株式会社クラレ | アクリル系樹脂組成物からなるフィルムの製造方法 |
DE10336130A1 (de) * | 2003-08-04 | 2005-02-24 | Röhm GmbH & Co. KG | Streuscheibe für LCD-Anwendungen, Verfahren zu deren Herstellung und Verwendung |
DE10354379A1 (de) * | 2003-11-20 | 2005-06-23 | Röhm GmbH & Co. KG | Formmasse, enthaltend ein Mattierungsmittel |
DE102004045296A1 (de) * | 2004-09-16 | 2006-03-23 | Röhm GmbH & Co. KG | Verwendung von Polyalkyl (meth) acrylat-Perlpolymerisaten und Formmasse zur Herstellung von extrudierten Formteilen mit mattierter Oberfläche |
JP2008239739A (ja) * | 2007-03-27 | 2008-10-09 | Toray Ind Inc | 熱可塑性樹脂フィルムおよびその製造方法 |
FR2934861B1 (fr) | 2008-08-05 | 2012-12-28 | Arkema France | Nouveaux modifiants chocs du type coeur-ecorce pour matrices polymeres transparentes. |
JP2012136644A (ja) * | 2010-12-27 | 2012-07-19 | Toray Ind Inc | ゴム強化熱可塑性樹脂組成物 |
WO2012107435A1 (en) | 2011-02-07 | 2012-08-16 | Evonik Röhm Gmbh | Method for manufacturing antimicrobial acrylic materials |
KR20140012110A (ko) | 2011-03-28 | 2014-01-29 | 에보니크 룀 게엠베하 | 자동차 또는 유틸리티 차량용 윈도우로서 사용하기 위한 플라스틱 성형물 |
-
2014
- 2014-03-19 MY MYPI2015002155A patent/MY172180A/en unknown
- 2014-03-19 CA CA2907995A patent/CA2907995C/en active Active
- 2014-03-19 HU HUE14711249A patent/HUE034249T2/en unknown
- 2014-03-19 JP JP2016504576A patent/JP6359080B2/ja active Active
- 2014-03-19 ES ES14711249.4T patent/ES2625434T3/es active Active
- 2014-03-19 KR KR1020157026434A patent/KR101796850B1/ko active IP Right Grant
- 2014-03-19 CN CN201480017789.XA patent/CN105073804B/zh active Active
- 2014-03-19 US US14/772,618 patent/US9988548B2/en active Active
- 2014-03-19 RU RU2015145608A patent/RU2648238C2/ru active
- 2014-03-19 SI SI201430216A patent/SI2978785T1/sl unknown
- 2014-03-19 WO PCT/EP2014/055489 patent/WO2014154543A1/de active Application Filing
- 2014-03-19 PL PL14711249T patent/PL2978785T3/pl unknown
- 2014-03-19 MX MX2015013598A patent/MX348358B/es active IP Right Grant
- 2014-03-19 SG SG11201507941RA patent/SG11201507941RA/en unknown
- 2014-03-19 EP EP14711249.4A patent/EP2978785B1/de active Active
- 2014-03-20 TW TW103110490A patent/TWI603987B/zh active
-
2015
- 2015-09-22 SA SA515361228A patent/SA515361228B1/ar unknown
-
2016
- 2016-02-04 HK HK16101317.6A patent/HK1213275A1/zh unknown
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3793402A (en) * | 1971-11-05 | 1974-02-19 | F Owens | Low haze impact resistant compositions containing a multi-stage,sequentially produced polymer |
EP0542036A1 (de) * | 1991-11-11 | 1993-05-19 | BASF Aktiengesellschaft | Transparente, schlagzähmodifizierte PMMA-Formmassen mit verbesserter Tieftemperatur-Schlagzähigkeit und hoher Bewitterungsstabilität |
CN1185165A (zh) * | 1995-05-24 | 1998-06-17 | 帝国化学工业公司 | 抗冲击改性的(甲基)丙烯酸酯类聚合物 |
EP0828772B2 (en) * | 1995-05-24 | 2003-08-20 | Ineos Acrylics UK Limited | Impact modified (meth)acrylic polymers |
CN1729219A (zh) * | 2002-12-19 | 2006-02-01 | 罗姆两合公司 | 水分散体的制备方法 |
Also Published As
Publication number | Publication date |
---|---|
CA2907995C (en) | 2018-02-13 |
WO2014154543A1 (de) | 2014-10-02 |
SA515361228B1 (ar) | 2017-02-06 |
KR20150133735A (ko) | 2015-11-30 |
MX2015013598A (es) | 2016-02-05 |
ES2625434T3 (es) | 2017-07-19 |
TWI603987B (zh) | 2017-11-01 |
HUE034249T2 (en) | 2018-02-28 |
EP2978785B1 (de) | 2017-03-08 |
CN105073804A (zh) | 2015-11-18 |
MY172180A (en) | 2019-11-15 |
SI2978785T1 (sl) | 2017-06-30 |
US9988548B2 (en) | 2018-06-05 |
US20150376437A1 (en) | 2015-12-31 |
RU2648238C2 (ru) | 2018-03-23 |
KR101796850B1 (ko) | 2017-11-10 |
JP2016514743A (ja) | 2016-05-23 |
TW201500386A (zh) | 2015-01-01 |
CA2907995A1 (en) | 2014-10-02 |
RU2015145608A (ru) | 2017-05-02 |
HK1213275A1 (zh) | 2016-06-30 |
PL2978785T3 (pl) | 2017-08-31 |
JP6359080B2 (ja) | 2018-07-18 |
EP2978785A1 (de) | 2016-02-03 |
MX348358B (es) | 2017-06-07 |
SG11201507941RA (en) | 2015-10-29 |
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