CN104903367B - (甲基)丙烯酸五溴苄基酯的聚合方法、获得的聚合物及其用途 - Google Patents

(甲基)丙烯酸五溴苄基酯的聚合方法、获得的聚合物及其用途 Download PDF

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CN104903367B
CN104903367B CN201380063405.3A CN201380063405A CN104903367B CN 104903367 B CN104903367 B CN 104903367B CN 201380063405 A CN201380063405 A CN 201380063405A CN 104903367 B CN104903367 B CN 104903367B
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poly
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pentabromobenzyl acrylate
pbbpa
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CN104903367A (zh
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B.克罗伊托卢
D.贝鲁本
M.皮莱德
Y.拉克米莱威奇
Y.赫希森
Y.埃普施泰恩阿索尔
E.拉帕波特
D.科佩尔
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Bromine Compounds Ltd
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Bromine Compounds Ltd
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/04Polymerisation in solution
    • C08F2/10Aqueous solvent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/22Esters containing halogen
    • C08F220/24Esters containing halogen containing perhaloalkyl radicals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/14Copolymers of propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02Homopolymers or copolymers of hydrocarbons
    • C08L25/04Homopolymers or copolymers of styrene
    • C08L25/06Polystyrene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04Homopolymers or copolymers of esters
    • C08L33/14Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur, or oxygen atoms in addition to the carboxy oxygen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04Homopolymers or copolymers of esters
    • C08L33/14Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur, or oxygen atoms in addition to the carboxy oxygen
    • C08L33/16Homopolymers or copolymers of esters containing halogen atoms
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02Monomers containing only one unsaturated aliphatic radical
    • C08F212/04Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06Hydrocarbons
    • C08F212/08Styrene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/12Applications used for fibers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02Natural fibres, other than mineral fibres
    • D06M2101/04Vegetal fibres
    • D06M2101/06Vegetal fibres cellulosic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16Synthetic fibres, other than mineral fibres
    • D06M2101/30Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32Polyesters
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/30Flame or heat resistance, fire retardancy properties

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Polymerisation Methods In General (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
CN201380063405.3A 2012-10-17 2013-10-17 (甲基)丙烯酸五溴苄基酯的聚合方法、获得的聚合物及其用途 Active CN104903367B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201261714767P 2012-10-17 2012-10-17
US61/714,767 2012-10-17
PCT/IL2013/000078 WO2014061010A1 (en) 2012-10-17 2013-10-17 Process for the polymerization of pentabromobenzyl (meth) acrylate, the polymer obtained and uses thereof

Publications (2)

Publication Number Publication Date
CN104903367A CN104903367A (zh) 2015-09-09
CN104903367B true CN104903367B (zh) 2018-11-27

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Country Link
US (1) US9493584B2 (https=)
EP (1) EP2909245A1 (https=)
JP (2) JP6472751B2 (https=)
KR (1) KR20150083837A (https=)
CN (1) CN104903367B (https=)
WO (1) WO2014061010A1 (https=)

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WO2014106841A1 (en) 2013-01-06 2014-07-10 Bromine Compounds Ltd. Preparation of bromine-containing aromatic compounds and their application as flame retardants
US10336858B2 (en) 2014-07-08 2019-07-02 Bromine Compounds Ltd. Preparation of bromine-containing polymers useful as flame retardants
JP6609614B2 (ja) * 2014-07-08 2019-11-20 ブローミン コンパウンズ リミテッド 臭素含有重合体の調製およびその難燃剤としての応用
JP6326102B2 (ja) * 2015-09-11 2018-05-16 三菱エンジニアリングプラスチックス株式会社 ポリエステル系樹脂組成物及びその製造方法
CN108026361B (zh) * 2015-09-11 2020-05-22 三菱工程塑料株式会社 聚酯系树脂组合物和其制造方法
JP6792376B2 (ja) * 2016-03-31 2020-11-25 三菱エンジニアリングプラスチックス株式会社 ポリエステル系樹脂組成物及び成形品
JP6663292B2 (ja) * 2016-04-28 2020-03-11 三菱エンジニアリングプラスチックス株式会社 ポリエステル系樹脂組成物及び成形品
JP7144924B2 (ja) 2017-08-22 2022-09-30 ポリプラスチックス株式会社 難燃性ポリブチレンテレフタレート樹脂組成物
WO2019182006A1 (ja) 2018-03-22 2019-09-26 ポリプラスチックス株式会社 難燃性ポリブチレンテレフタレート樹脂組成物
EP4556625A1 (en) * 2018-04-09 2025-05-21 Albemarle Corporation Flame retardants for textile applications
JP7071236B2 (ja) * 2018-07-03 2022-05-18 ポリプラスチックス株式会社 電気絶縁部品用難燃性ポリブチレンテレフタレート樹脂組成物
JP7665278B2 (ja) * 2018-08-03 2025-04-21 ポリプラスチックス株式会社 難燃性ポリブチレンテレフタレート樹脂組成物
JP7182396B2 (ja) * 2018-08-10 2022-12-02 ポリプラスチックス株式会社 難燃性ポリブチレンテレフタレート樹脂組成物
JP7195315B2 (ja) * 2018-11-09 2022-12-23 ポリプラスチックス株式会社 難燃性ポリブチレンテレフタレート樹脂組成物
CN117024635B (zh) * 2023-07-28 2024-04-02 潍坊裕凯化工有限公司 一种制备聚丙烯酸五溴苄酯的方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4128709A (en) * 1975-06-21 1978-12-05 Dynamit Nobel Aktiengesellschaft Acrylate-based polymers and their use as flameproofing agents
DE2920085A1 (de) * 1979-05-18 1980-11-27 Kalk Chemische Fabrik Gmbh Verfahren zur herstellung polymerer pentabrombenzylacrylate
US6028156A (en) * 1996-01-16 2000-02-22 Bromine Compounds, Ltd. Process for the preparation of poly-(halobenzyl acrylate)

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IL86605A (en) * 1988-06-02 1992-02-16 Bromine Compounds Ltd Process for the polymerization of pentabromobenzylester monoacrylate
US5387636A (en) 1991-08-14 1995-02-07 Albemarle Corporation Flame-retarded hips formulations with enhanced impact strength
IL103573A (en) * 1992-10-28 1996-10-31 Bromine Compounds Ltd Method of improving the surface compatibility of polypropylene and its compositions and articles obtained thereby
JPH08218003A (ja) * 1995-02-17 1996-08-27 Hitachi Chem Co Ltd ワニス組成物及び防汚塗料組成物
US6503988B1 (en) 1995-11-09 2003-01-07 Daikin Industries, Ltd. Polytetrafluoroethylene fine powders and their use
CA2205099A1 (en) * 1996-05-24 1997-11-24 Patricia Marie Lesko Fluorescent polymers and coating compositions
KR100490444B1 (ko) 1997-12-31 2005-09-02 삼성전자주식회사 광통신용 폴리아미드이미드
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US4128709A (en) * 1975-06-21 1978-12-05 Dynamit Nobel Aktiengesellschaft Acrylate-based polymers and their use as flameproofing agents
DE2920085A1 (de) * 1979-05-18 1980-11-27 Kalk Chemische Fabrik Gmbh Verfahren zur herstellung polymerer pentabrombenzylacrylate
US6028156A (en) * 1996-01-16 2000-02-22 Bromine Compounds, Ltd. Process for the preparation of poly-(halobenzyl acrylate)

Also Published As

Publication number Publication date
WO2014061010A1 (en) 2014-04-24
US9493584B2 (en) 2016-11-15
EP2909245A1 (en) 2015-08-26
CN104903367A (zh) 2015-09-09
JP6625185B2 (ja) 2019-12-25
JP2015532350A (ja) 2015-11-09
JP6472751B2 (ja) 2019-02-20
KR20150083837A (ko) 2015-07-20
JP2019035083A (ja) 2019-03-07
US20150259440A1 (en) 2015-09-17

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