CN104556838A - Anti-aging super-hardness artificial quartz stone plate and manufacturing method thereof - Google Patents
Anti-aging super-hardness artificial quartz stone plate and manufacturing method thereof Download PDFInfo
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- CN104556838A CN104556838A CN201410778404.3A CN201410778404A CN104556838A CN 104556838 A CN104556838 A CN 104556838A CN 201410778404 A CN201410778404 A CN 201410778404A CN 104556838 A CN104556838 A CN 104556838A
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Abstract
The invention discloses an anti-aging super-hardness artificial quartz stone plate and a manufacturing method thereof. The artificial quartz stone plate comprises the following components in parts by weight: 30-90 parts of 6-80-mesh calcined quartz stone, 30-70 parts of 325-mesh quartz powder, 5-15 parts of glass cullet, 5-10 parts of unsaturated polyester resin, 0.1-2 parts of an antioxidant, 0.3-2 parts of a silane coupling agent, 0.3-2 parts of a curing agent and 0.1-1 part of pigment. Due to adoption of calcined quartz stone, the hardness of the artificial quartz stone plate is improved, so that the quartz stone plate is wear-resistant and difficult to scratch; and meanwhile, the antioxidant is added into the preparation process, so that the aging resistance of the artificial quartz stone plate is improved.
Description
Technical field
The invention belongs to material of construction preparing technical field, specifically, refer to a kind of anti-aging, exceptional hardness artificial quartz stone plate and manufacture method thereof.
Background technology
Artificial quartz in lump is as the substitute of lithotome, have high strength, high rigidity, high temperature resistant, protection against corrosion, anti-aging, easy to clean, wear-resisting, material is consummate, the unrivaled advantage of lithotome such as radiationless, now be widely used in the daily life of industrial production and the people, as the decorative material material of floor tile, metope etc.
But the artificial quartz in lump that prior art manufactures, exist density unevenness, hardness low, easily tie powder ball, yielding, easily aging, easily enter look, color and pattern single, not there is the defects such as anti-microbial effect, limit its larger application on a large scale, urgently to be resolved hurrily.
Summary of the invention
Technical problem to be solved by this invention is not enough for prior art, a kind of anti-aging, exceptional hardness artificial quartz stone plate and manufacture method thereof are provided, adopt that the artificial quartz stone plate resistance of aging prepared of the present invention is strong, hardness is high, physicals and chemical property good, and long service life.
The technical scheme that the present invention solves the problems of the technologies described above is as follows: anti-aging, exceptional hardness artificial quartz stone plate, be made up of the component of following parts by weight: 6 ~ 80 30 ~ 90 parts, order calcining quartz stones, 325 order silica powders 30 ~ 70 parts, glass cullet 5 ~ 15 parts, unsaturated polyester 5 ~ 10 parts, 0.1 ~ 2 part, oxidation inhibitor, silane coupling agent 0.3 ~ 2 part, 0.3 ~ 2 part, solidifying agent, pigment 0.1 ~ 1 part.
On the basis of technique scheme, the present invention can also do following improvement.
Further, be made up of the component of following parts by weight: 6 ~ 80 70 parts, order calcining quartz stones, 325 order silica powders 50 parts, glass cullet 10 parts, unsaturated polyester 8 parts, 1 part, oxidation inhibitor, silane coupling agent 0.5 part, 1 part, solidifying agent, pigment 0.5 part.
Further, described calcining quartz stone is that quartzite forms through 1600 ~ 1800 DEG C of high-temperature calcinations.
Further, described unsaturated polyester is one or more in epoxy resin, resol, acryl resin and urethane resin.
Further, described oxidation inhibitor is one or more in oxidation inhibitor 1222, AT-76, antioxidant 2246-S, AT-59, oxidation inhibitor 1035, oxidation inhibitor 1098, oxidation inhibitor 3125, TPP, TNPP, AT-168, oxidation inhibitor 245, GA-80, oxidation inhibitor 858, antioxidant 1010.
Further, described silane coupling agent is the one in γ-methacryloxypropyl trimethoxy silane, γ-aminopropyl triethoxysilane, γ-glycidyl ether oxygen propyl trimethoxy silicane, vinyl three ('beta '-methoxy oxyethyl group) silane, vinyltriethoxysilane or γ-divinyl triammonium base propyl-triethoxysilicane.
Further, described solidifying agent is the one in peroxide-2-ethyl hexanoic acid tert-butyl, peroxidized t-butyl perbenzoate or benzoyl peroxide.
Further, described pigment be titanium dioxide, iron oxide yellow powder, iron oxide red, iron black powder, chrome green powder, Lan Shuizhong one or more.
Anti-aging, the manufacture method of exceptional hardness artificial quartz stone plate, comprise following processing step: the component taking following parts by weight: 6 ~ 80 30 ~ 90 parts, order calcining quartz stones, 325 order silica powders 30 ~ 70 parts, glass cullet 5 ~ 15 parts, unsaturated polyester 5 ~ 10 parts, 0.1 ~ 2 part, oxidation inhibitor, silane coupling agent 0.3 ~ 2 part, 0.3 ~ 2 part, solidifying agent, pigment 0.1 ~ 1 part, by above-mentioned each component Homogeneous phase mixing, the material mixed evenly is tiled on making sheet mould, then making sheet mould is sent into vacuum chamber, vacuumize, vibratory compaction, pressure during vibratory compaction is 2.5 ~ 3.5MPa, molding time is 2 ~ 3 minutes, send into curing oven solidification again, the temperature of solidification is 85 ~ 95 DEG C, time is 30 ~ 45 minutes, sheet material after solidification is come out of the stove the demoulding, after stacking cooling, delivering to surely thick polishing machine carries out surely thick, after surface finish polished finish, artificial quartz in lump can be obtained.
The invention has the beneficial effects as follows:
(1) anti-aging: in raw material of the present invention, to the addition of oxidation inhibitor, improve the oxidation-resistance of artificial quartz stone plate of the present invention and the ability of antiultraviolet, there is use widely.
(2) exceptional hardness: calcining quartz sand of the present invention is through 1600 ~ 1800 DEG C of high-temperature calcinations and forms, it was oxidized originally, weathering material is burnt, and making its density better fused, is a kind of superhard material.Add calcining quartz stone in the feed, improve the hardness of artificial quartz stone plate, make that it is more wear-resisting, not easily scratch, increase work-ing life.
(3) manufacture method of the present invention is simple, is suitable for suitability for industrialized production.
Embodiment
Be described principle of the present invention and feature below in conjunction with specific embodiment, example, only for explaining the present invention, is not intended to limit scope of the present invention.
Embodiment 1:
Take 6 ~ 80 order calcining quartz stone 30kg, 325 order silica powder 70kg, glass cullet 5kg, epoxy resin 10kg, oxidation inhibitor AT-76:0.1kg, silane coupling agent γ-methacryloxypropyl trimethoxy silane (KH570) 2kg, peroxide-2-ethyl hexanoic acid tert-butyl 0.3kg, pigment 1kg, described pigment is made up of according to mass ratio 15:1 titanium dioxide and Lan Shui; By above-mentioned each component Homogeneous phase mixing, the material mixed evenly is tiled on making sheet mould, then making sheet mould is sent into vacuum chamber, when when vacuumizing, air pressure reaches-0.1MPa, under 2.5 ~ 3.5MPa pressure vibrate 2 ~ 3 minutes shaping, then send into curing oven solidification, solidification value 85 ~ 95 DEG C, time is 30 ~ 45 minutes, sheet material after solidification is come out of the stove the demoulding, after stacking cooling, delivers to surely thick polishing machine and carries out surely thick, after surface finish polished finish, " white board " artificial quartz in lump can be obtained.
Embodiment 2:
Take 6 ~ 80 order calcining quartz stone 90kg, 325 order silica powder 30kg, glass cullet 15kg, resol 5kg, antioxidant 2246-S:2kg, silane coupling agent γ-aminopropyl triethoxysilane (KH550) 0.3kg, peroxidized t-butyl perbenzoate 2kg, pigment 0.1kg, described pigment is made up of according to mass ratio 312:6:25:1:28 titanium dioxide, iron oxide yellow powder, iron oxide red, iron black powder and Lan Shui; By above-mentioned each component Homogeneous phase mixing, the material mixed evenly is tiled on making sheet mould, then making sheet mould is sent into vacuum chamber, when when vacuumizing, air pressure reaches-0.1MPa, under 2.5 ~ 3.5MPa pressure vibrate 2 ~ 3 minutes shaping, then send into curing oven solidification, solidification value 85 ~ 95 DEG C, time is 30 ~ 45 minutes, sheet material after solidification is come out of the stove the demoulding, after stacking cooling, delivers to surely thick polishing machine and carries out surely thick, " shallow steel gray plate " artificial quartz in lump after surface finish polished finish, can be obtained.
Embodiment 3:
Take 6 ~ 80 order calcining quartz stone 70kg, 325 order silica powder 50kg, glass cullet 10kg, epoxy resin 8kg, oxidation inhibitor TPP:1kg, silane coupling agent γ-glycidyl ether oxygen propyl trimethoxy silicane 0.5kg, benzoyl peroxide 1kg, pigment 0.5kg, described pigment is made up of according to mass ratio 980:1:2:3:118 titanium dioxide, iron oxide yellow powder, iron black powder, chrome green powder and Lan Shui; By above-mentioned each component Homogeneous phase mixing, the material mixed evenly is tiled on making sheet mould, then making sheet mould is sent into vacuum chamber, when when vacuumizing, air pressure reaches-0.1MPa, under 2.5 ~ 3.5MPa pressure vibrate 2 ~ 3 minutes shaping, then send into curing oven solidification, solidification value 85 ~ 95 DEG C, time is 30 ~ 45 minutes, sheet material after solidification is come out of the stove the demoulding, after stacking cooling, delivers to surely thick polishing machine and carries out surely thick, after surface finish polished finish, " spring's colours fill the garden " artificial quartz in lump can be obtained.
The foregoing is only preferred embodiment of the present invention, not in order to limit the present invention, within the spirit and principles in the present invention all, any amendment done, equivalent replacement, improvement etc., all should be included within protection scope of the present invention.
Claims (9)
1. anti-aging, exceptional hardness artificial quartz stone plate, it is characterized in that, be made up of the component of following parts by weight: 6 ~ 80 30 ~ 90 parts, order calcining quartz stones, 325 order silica powders 30 ~ 70 parts, glass cullet 5 ~ 15 parts, unsaturated polyester 5 ~ 10 parts, 0.1 ~ 2 part, oxidation inhibitor, silane coupling agent 0.3 ~ 2 part, 0.3 ~ 2 part, solidifying agent, pigment 0.1 ~ 1 part.
2. anti-aging, exceptional hardness artificial quartz stone plate according to claim 1, it is characterized in that, be made up of the component of following parts by weight: 6 ~ 80 70 parts, order calcining quartz stones, 325 order silica powders 50 parts, glass cullet 10 parts, unsaturated polyester 8 parts, 1 part, oxidation inhibitor, silane coupling agent 0.5 part, 1 part, solidifying agent, pigment 0.5 part.
3. anti-aging, exceptional hardness artificial quartz stone plate according to claim 1 and 2, is characterized in that, described calcining quartz stone is that quartzite forms through 1600 ~ 1800 DEG C of high-temperature calcinations.
4. anti-aging, exceptional hardness artificial quartz stone plate according to claim 1 and 2, is characterized in that, described unsaturated polyester is one or more in epoxy resin, resol, acryl resin and urethane resin.
5. anti-aging, exceptional hardness artificial quartz stone plate according to claim 1 and 2, it is characterized in that, described oxidation inhibitor is one or more in oxidation inhibitor 1222, AT-76, antioxidant 2246-S, AT-59, oxidation inhibitor 1035, oxidation inhibitor 1098, oxidation inhibitor 3125, TPP, TNPP, AT-168, oxidation inhibitor 245, GA-80, oxidation inhibitor 858, antioxidant 1010.
6. anti-aging, exceptional hardness artificial quartz stone plate according to claim 1 and 2, it is characterized in that, described silane coupling agent is the one in γ-methacryloxypropyl trimethoxy silane, γ-aminopropyl triethoxysilane, γ-glycidyl ether oxygen propyl trimethoxy silicane, vinyl three ('beta '-methoxy oxyethyl group) silane, vinyltriethoxysilane or γ-divinyl triammonium base propyl-triethoxysilicane.
7. anti-aging, exceptional hardness artificial quartz stone plate according to claim 1 and 2, is characterized in that, described solidifying agent is the one in peroxide-2-ethyl hexanoic acid tert-butyl, peroxidized t-butyl perbenzoate or benzoyl peroxide.
8. anti-aging, exceptional hardness artificial quartz stone plate according to claim 1 and 2, is characterized in that, described pigment be titanium dioxide, iron oxide yellow powder, iron oxide red, iron black powder, chrome green powder, Lan Shuizhong one or more.
9. anti-aging, the manufacture method of exceptional hardness artificial quartz stone plate, it is characterized in that, comprise following processing step: the component taking following parts by weight: 6 ~ 80 30 ~ 90 parts, order calcining quartz stones, 325 order silica powders 30 ~ 70 parts, glass cullet 5 ~ 15 parts, unsaturated polyester 5 ~ 10 parts, 0.1 ~ 2 part, oxidation inhibitor, silane coupling agent 0.3 ~ 2 part, 0.3 ~ 2 part, solidifying agent, pigment 0.1 ~ 1 part, by above-mentioned each component Homogeneous phase mixing, the material mixed evenly is tiled on making sheet mould, then making sheet mould is sent into vacuum chamber, vacuumize, vibratory compaction, pressure during vibratory compaction is 2.5 ~ 3.5MPa, molding time is 2 ~ 3 minutes, send into curing oven solidification again, the temperature of solidification is 85 ~ 95 DEG C, time is 30 ~ 45 minutes, sheet material after solidification is come out of the stove the demoulding, after stacking cooling, delivering to surely thick polishing machine carries out surely thick, after surface finish polished finish, artificial quartz in lump can be obtained.
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106116264A (en) * | 2016-06-24 | 2016-11-16 | 安徽弗仕通实业有限公司 | A kind of resistant to corrosion artificial quartz in lump |
| CN106116251A (en) * | 2016-06-24 | 2016-11-16 | 安徽弗仕通实业有限公司 | A kind of impact resistance artificial quartz in lump |
| CN106145774A (en) * | 2016-06-24 | 2016-11-23 | 安徽弗仕通实业有限公司 | A kind of flame-proof explosion-proof artificial quartz in lump |
| CN106220144A (en) * | 2016-08-05 | 2016-12-14 | 佛山市寰田陶瓷有限公司 | A kind of wear-resistant ceramic brick and preparation method thereof |
| CN106833002A (en) * | 2015-12-07 | 2017-06-13 | 徐文寿 | The manufacture method of the antibiotic colored quartz basin of resin base complex abrasion-proof |
| CN107892507A (en) * | 2017-11-07 | 2018-04-10 | 桂林奥尼斯特节能环保科技有限责任公司 | A kind of superhard artificial quartz stone plate and preparation method thereof |
| CN108483995A (en) * | 2018-05-28 | 2018-09-04 | 嘉兴涌锦服饰有限公司 | A kind of production method of artificial quartz stone plate |
| CN111548052A (en) * | 2020-05-06 | 2020-08-18 | 广东河源住方高分子材料有限公司 | Artificial quartz stone plate and preparation method thereof |
-
2014
- 2014-12-15 CN CN201410778404.3A patent/CN104556838A/en active Pending
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106833002A (en) * | 2015-12-07 | 2017-06-13 | 徐文寿 | The manufacture method of the antibiotic colored quartz basin of resin base complex abrasion-proof |
| CN106116264A (en) * | 2016-06-24 | 2016-11-16 | 安徽弗仕通实业有限公司 | A kind of resistant to corrosion artificial quartz in lump |
| CN106116251A (en) * | 2016-06-24 | 2016-11-16 | 安徽弗仕通实业有限公司 | A kind of impact resistance artificial quartz in lump |
| CN106145774A (en) * | 2016-06-24 | 2016-11-23 | 安徽弗仕通实业有限公司 | A kind of flame-proof explosion-proof artificial quartz in lump |
| CN106220144A (en) * | 2016-08-05 | 2016-12-14 | 佛山市寰田陶瓷有限公司 | A kind of wear-resistant ceramic brick and preparation method thereof |
| CN107892507A (en) * | 2017-11-07 | 2018-04-10 | 桂林奥尼斯特节能环保科技有限责任公司 | A kind of superhard artificial quartz stone plate and preparation method thereof |
| CN108483995A (en) * | 2018-05-28 | 2018-09-04 | 嘉兴涌锦服饰有限公司 | A kind of production method of artificial quartz stone plate |
| CN112895496A (en) * | 2018-05-28 | 2021-06-04 | 嘉兴涌锦服饰有限公司 | Manufacturing method of improved artificial quartz stone plate |
| CN111548052A (en) * | 2020-05-06 | 2020-08-18 | 广东河源住方高分子材料有限公司 | Artificial quartz stone plate and preparation method thereof |
| CN111548052B (en) * | 2020-05-06 | 2021-05-04 | 广东河源住方高分子材料有限公司 | Artificial quartz stone plate and preparation method thereof |
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Application publication date: 20150429 |