CN104496272A - Anti-aging artificial quartzite plate and manufacturing method thereof - Google Patents
Anti-aging artificial quartzite plate and manufacturing method thereof Download PDFInfo
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- CN104496272A CN104496272A CN201410775194.2A CN201410775194A CN104496272A CN 104496272 A CN104496272 A CN 104496272A CN 201410775194 A CN201410775194 A CN 201410775194A CN 104496272 A CN104496272 A CN 104496272A
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Abstract
The invention discloses an anti-aging artificial quartzite plate and a manufacturing method thereof. The artificial quartzite plate is composed of the following components in parts by weight: 40-90 parts of 3-80-mesh quartzite, 30-70 parts of 325-mesh quartz powder, 5-15 parts of cullet, 5-10 parts of unsaturated resin, 0.1-2 parts of light stabilizer, 0.1-2 parts of antioxidant, 0.3-2 parts of coupling agent, 0.3-2 parts of curing agent and 0.1-1 part of pigment. The light stabilizer and antioxidant are added in the preparation process to enhance the aging resistance of the anti-aging artificial quartzite plate. The anti-aging artificial quartzite plate has the advantages of favorable physical and chemical properties and long service life. The manufacturing method is simple and is suitable for industrial production.
Description
Technical field
The invention belongs to material of construction preparing technical field, specifically, refer to a kind of anti-aging artificial quartz stone plate and manufacture method thereof.
Background technology
Artificial quartz in lump rises in Spain, cry match sharp stone when 2005 enter China, after artificial quartz in lump is by increasing consumer acceptance, China in 2006 starts someone and researches and develops artificial quartz in lump, within 2007, successively has a lot of producer to be proposed domestic artificial quartz in lump.
But the shrinkability of existing Engineered stone products is higher, and resistance to deterioration and ultra-violet radiation resisting function poor, product uses and degradation problem under aging, its colour changed into yellow, embrittlement, physicals and chemical property easily occurs under long term outdoor high light, so existing Engineered stone products can only as interior architecture finishing material, and cannot use as outdoor architecture finishing material, seriously constrain applying of Engineered stone products.
Summary of the invention
Technical problem to be solved by this invention is not enough for prior art, a kind of anti-aging artificial quartz stone plate and manufacture method thereof are provided, adopt that the artificial quartz stone plate resistance of aging prepared of the present invention is strong, physicals and chemical property good, and long service life.
The technical scheme that the present invention solves the problems of the technologies described above is as follows: anti-aging artificial quartz stone plate, be made up of the component of following parts by weight: 3 ~ 80 order quartzites 40 ~ 90 parts, 325 order silica powders 30 ~ 70 parts, glass cullet 5 ~ 15 parts, unsaturated polyester 5 ~ 10 parts, photostabilizer 0.1 ~ 2 part, 0.1 ~ 2 part, oxidation inhibitor, coupling agent 0.3 ~ 2 part, 0.3 ~ 2 part, solidifying agent, pigment 0.1 ~ 1 part.
On the basis of technique scheme, the present invention can also do following improvement.
Further, be made up of the component of following parts by weight: 3 ~ 80 order quartzites 70 parts, 325 order silica powders 50 parts, glass cullet 10 parts, unsaturated polyester 8 parts, photostabilizer 0.4 part, 0.6 part, oxidation inhibitor, coupling agent 1 part, 0.8 part, solidifying agent, pigment 0.3 part.
Further, described unsaturated polyester is one or more in epoxy resin, resol, acryl resin and urethane resin.
Further, described photostabilizer is any one or several in benzophenone, salicylate class, benzotriazole category, hindered amines, photostabilizer HPT and photostabilizer EPU.
Further, described oxidation inhibitor is one or more in oxidation inhibitor 1222, AT-76, antioxidant 2246-S, AT-59, oxidation inhibitor 1035, oxidation inhibitor 1098, oxidation inhibitor 3125, TPP, TNPP, AT-168, oxidation inhibitor 245, GA-80, oxidation inhibitor 858, antioxidant 1010.
Further, described coupling agent is organo silane coupling agent.
Further, described solidifying agent is the one in peroxide-2-ethyl hexanoic acid tert-butyl, peroxidized t-butyl perbenzoate or benzoyl peroxide.
Further, described pigment be titanium dioxide, iron oxide yellow powder, iron oxide red, iron black powder, chrome green powder, Lan Shuizhong one or more.
The manufacture method of anti-aging artificial quartz stone plate, comprise following processing step: the component taking following parts by weight: 3 ~ 80 order quartzites 40 ~ 90 parts, 325 order silica powders 30 ~ 70 parts, glass cullet 5 ~ 15 parts, unsaturated polyester 5 ~ 10 parts, photostabilizer 0.1 ~ 2 part, 0.1 ~ 2 part, oxidation inhibitor, coupling agent 0.3 ~ 2 part, 0.3 ~ 2 part, solidifying agent, pigment 0.1 ~ 1 part, by above-mentioned each component Homogeneous phase mixing, the material mixed evenly is tiled on making sheet mould, then making sheet mould is sent into vacuum chamber, vacuumize, vibratory compaction, pressure during vibratory compaction is 2.5 ~ 3.5MPa, molding time is 2 ~ 3 minutes, send into curing oven solidification again, the temperature of solidification is 85 ~ 95 DEG C, time is 30 ~ 45 minutes, sheet material after solidification is come out of the stove the demoulding, after stacking cooling, delivering to surely thick polishing machine carries out surely thick, after surface finish polished finish, artificial quartz in lump can be obtained.
The invention has the beneficial effects as follows:
(1) anti-aging: in raw material of the present invention, to the addition of photostabilizer and oxidation inhibitor, improve the oxidation-resistance of artificial quartz stone plate of the present invention and the ability of antiultraviolet, there is use widely.
(2) manufacture method of the present invention is simple, is suitable for suitability for industrialized production.
Embodiment
Be described principle of the present invention and feature below in conjunction with specific embodiment, example, only for explaining the present invention, is not intended to limit scope of the present invention.
Embodiment 1:
Take 3 ~ 100 order quartzite 40kg, 325 order silica powder 70kg, glass cullet 5kg, epoxy resin 10kg, benzophenone light stabilizer 0.1kg, oxidation inhibitor AT-76:2kg, organo silane coupling agent 0.3kg, peroxide-2-ethyl hexanoic acid tert-butyl 2kg, pigment 0.1kg, described pigment is made up of according to mass ratio 15:1 titanium dioxide and Lan Shui; By above-mentioned each component Homogeneous phase mixing, the material mixed evenly is tiled on making sheet mould, then making sheet mould is sent into vacuum chamber, when when vacuumizing, air pressure reaches-0.1MPa, under 2.5 ~ 3.5MPa pressure vibrate 2 ~ 3 minutes shaping, then send into curing oven solidification, solidification value 85 ~ 95 DEG C, time is 30 ~ 45 minutes, sheet material after solidification is come out of the stove the demoulding, after stacking cooling, delivers to surely thick polishing machine and carries out surely thick, after surface finish polished finish, " white board " artificial quartz in lump can be obtained.
Embodiment 2:
Take 3 ~ 100 order quartzite 90kg, 325 order silica powder 30kg, glass cullet 15kg, resol 5kg, photostabilizer HPT:2kg, antioxidant 2246-S:0.1kg, organo silane coupling agent 2kg, peroxidized t-butyl perbenzoate 0.3kg, pigment 1kg, described pigment is made up of according to mass ratio 312:6:25:1:28 titanium dioxide, iron oxide yellow powder, iron oxide red, iron black powder and Lan Shui; By above-mentioned each component Homogeneous phase mixing, the material mixed evenly is tiled on making sheet mould, then making sheet mould is sent into vacuum chamber, when when vacuumizing, air pressure reaches-0.1MPa, under 2.5 ~ 3.5MPa pressure vibrate 2 ~ 3 minutes shaping, then send into curing oven solidification, solidification value 85 ~ 95 DEG C, time is 30 ~ 45 minutes, sheet material after solidification is come out of the stove the demoulding, after stacking cooling, delivers to surely thick polishing machine and carries out surely thick, " shallow steel gray plate " artificial quartz in lump after surface finish polished finish, can be obtained.
Embodiment 3:
Take 3 ~ 100 order quartzite 70kg, 325 order silica powder 50kg, glass cullet 10kg, urethane resin 8kg, photostabilizer EPU:0.4kg, oxidation inhibitor TPP:0.6kg, organo silane coupling agent 1kg, peroxidized t-butyl perbenzoate 0.8kg, pigment 0.3kg, described pigment is made up of according to mass ratio 980:1:2:3:118 titanium dioxide, iron oxide yellow powder, iron black powder, chrome green powder and Lan Shui; By above-mentioned each component Homogeneous phase mixing, the material mixed evenly is tiled on making sheet mould, then making sheet mould is sent into vacuum chamber, when when vacuumizing, air pressure reaches-0.1MPa, under 2.5 ~ 3.5MPa pressure vibrate 2 ~ 3 minutes shaping, then send into curing oven solidification, solidification value 85 ~ 95 DEG C, time is 30 ~ 45 minutes, sheet material after solidification is come out of the stove the demoulding, after stacking cooling, delivers to surely thick polishing machine and carries out surely thick, after surface finish polished finish, " spring's colours fill the garden " artificial quartz in lump can be obtained.
The foregoing is only preferred embodiment of the present invention, not in order to limit the present invention, within the spirit and principles in the present invention all, any amendment done, equivalent replacement, improvement etc., all should be included within protection scope of the present invention.
Claims (9)
1. anti-aging artificial quartz stone plate, it is characterized in that, be made up of the component of following parts by weight: 3 ~ 80 order quartzites 40 ~ 90 parts, 325 order silica powders 30 ~ 70 parts, glass cullet 5 ~ 15 parts, unsaturated polyester 5 ~ 10 parts, photostabilizer 0.1 ~ 2 part, 0.1 ~ 2 part, oxidation inhibitor, coupling agent 0.3 ~ 2 part, 0.3 ~ 2 part, solidifying agent, pigment 0.1 ~ 1 part.
2. anti-aging artificial quartz stone plate according to claim 1, it is characterized in that, be made up of the component of following parts by weight: 3 ~ 80 order quartzites 70 parts, 325 order silica powders 50 parts, glass cullet 10 parts, unsaturated polyester 8 parts, photostabilizer 0.4 part, 0.6 part, oxidation inhibitor, coupling agent 1 part, 0.8 part, solidifying agent, pigment 0.3 part.
3. anti-aging artificial quartz stone plate according to claim 1 and 2, is characterized in that, described unsaturated polyester is one or more in epoxy resin, resol, acryl resin and urethane resin.
4. anti-aging artificial quartz stone plate according to claim 1 and 2, is characterized in that, described photostabilizer is any one or several in benzophenone, salicylate class, benzotriazole category, hindered amines, photostabilizer HPT and photostabilizer EPU.
5. anti-aging artificial quartz stone plate according to claim 1 and 2, it is characterized in that, described oxidation inhibitor is one or more in oxidation inhibitor 1222, AT-76, antioxidant 2246-S, AT-59, oxidation inhibitor 1035, oxidation inhibitor 1098, oxidation inhibitor 3125, TPP, TNPP, AT-168, oxidation inhibitor 245, GA-80, oxidation inhibitor 858, antioxidant 1010.
6. anti-aging artificial quartz stone plate according to claim 1 and 2, is characterized in that, described coupling agent is organo silane coupling agent.
7. anti-aging artificial quartz stone plate according to claim 1 and 2, is characterized in that, described solidifying agent is the one in peroxide-2-ethyl hexanoic acid tert-butyl, peroxidized t-butyl perbenzoate or benzoyl peroxide.
8. anti-aging artificial quartz stone plate according to claim 1 and 2, is characterized in that, described pigment be titanium dioxide, iron oxide yellow powder, iron oxide red, iron black powder, chrome green powder, Lan Shuizhong one or more.
9. the manufacture method of anti-aging artificial quartz stone plate, it is characterized in that, comprise following processing step: the component taking following parts by weight: 3 ~ 80 order quartzites 40 ~ 90 parts, 325 order silica powders 30 ~ 70 parts, glass cullet 5 ~ 15 parts, unsaturated polyester 5 ~ 10 parts, photostabilizer 0.1 ~ 2 part, 0.1 ~ 2 part, oxidation inhibitor, coupling agent 0.3 ~ 2 part, 0.3 ~ 2 part, solidifying agent, pigment 0.1 ~ 1 part, by above-mentioned each component Homogeneous phase mixing, the material mixed evenly is tiled on making sheet mould, then making sheet mould is sent into vacuum chamber, vacuumize, vibratory compaction, pressure during vibratory compaction is 2.5 ~ 3.5MPa, molding time is 2 ~ 3 minutes, send into curing oven solidification again, the temperature of solidification is 85 ~ 95 DEG C, time is 30 ~ 45 minutes, sheet material after solidification is come out of the stove the demoulding, after stacking cooling, delivering to surely thick polishing machine carries out surely thick, after surface finish polished finish, artificial quartz in lump can be obtained.
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| CN201410775194.2A CN104496272A (en) | 2014-12-15 | 2014-12-15 | Anti-aging artificial quartzite plate and manufacturing method thereof |
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| CN201410775194.2A CN104496272A (en) | 2014-12-15 | 2014-12-15 | Anti-aging artificial quartzite plate and manufacturing method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106810114A (en) * | 2015-11-30 | 2017-06-09 | 衡阳市雅典娜石英石有限公司 | A kind of quartz and preparation method thereof |
| CN110128058A (en) * | 2019-05-19 | 2019-08-16 | 福建师范大学福清分校 | A kind of artificial marble and preparation method thereof with discarded terylene textile fabric preparation |
| CN112573861A (en) * | 2021-02-03 | 2021-03-30 | 湖北钊晟新材料科技有限公司 | Quartz stone plate with low expansion coefficient and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1994955A (en) * | 2005-12-26 | 2007-07-11 | 秦升益 | Weatherable water-permeable material and its uses |
| KR20080070345A (en) * | 2007-01-26 | 2008-07-30 | 주식회사 엘지화학 | Artificial marble having various designs and process for preparing the same |
| CN101337805A (en) * | 2008-08-25 | 2009-01-07 | 张璐 | Artificial quartz in lump and fabrication technology thereof |
| CN102476934A (en) * | 2010-11-30 | 2012-05-30 | 肇庆富盛复合材料有限公司 | Environment friendly quartz slab |
| CN103833265A (en) * | 2014-01-23 | 2014-06-04 | 王舒怡 | High-strength man-made quartz plate and preparation method thereof |
-
2014
- 2014-12-15 CN CN201410775194.2A patent/CN104496272A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1994955A (en) * | 2005-12-26 | 2007-07-11 | 秦升益 | Weatherable water-permeable material and its uses |
| KR20080070345A (en) * | 2007-01-26 | 2008-07-30 | 주식회사 엘지화학 | Artificial marble having various designs and process for preparing the same |
| CN101337805A (en) * | 2008-08-25 | 2009-01-07 | 张璐 | Artificial quartz in lump and fabrication technology thereof |
| CN102476934A (en) * | 2010-11-30 | 2012-05-30 | 肇庆富盛复合材料有限公司 | Environment friendly quartz slab |
| CN103833265A (en) * | 2014-01-23 | 2014-06-04 | 王舒怡 | High-strength man-made quartz plate and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 李祥高等: "《精细化学品化学》", 30 April 2013, 华东理工大学出版社 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106810114A (en) * | 2015-11-30 | 2017-06-09 | 衡阳市雅典娜石英石有限公司 | A kind of quartz and preparation method thereof |
| CN110128058A (en) * | 2019-05-19 | 2019-08-16 | 福建师范大学福清分校 | A kind of artificial marble and preparation method thereof with discarded terylene textile fabric preparation |
| CN112573861A (en) * | 2021-02-03 | 2021-03-30 | 湖北钊晟新材料科技有限公司 | Quartz stone plate with low expansion coefficient and preparation method thereof |
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Application publication date: 20150408 |
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