CN104529246A - Antibacterial and fireproof artificial quartzite board and preparation method thereof - Google Patents
Antibacterial and fireproof artificial quartzite board and preparation method thereof Download PDFInfo
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- CN104529246A CN104529246A CN201410775369.XA CN201410775369A CN104529246A CN 104529246 A CN104529246 A CN 104529246A CN 201410775369 A CN201410775369 A CN 201410775369A CN 104529246 A CN104529246 A CN 104529246A
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Abstract
The invention discloses an antibacterial and fireproof artificial quartzite board and a preparation method thereof. The antibacterial and fireproof artificial quartzite board is composed of the following components in parts by weight: 30-80 parts of 8-100-mesh quartzite, 30-60 parts of 325-mesh quartz powder, 5-15 parts of cullet, 5-10 parts of shell, 5-15 parts of 50-100-mesh quartzitic sandstone powder, 5-15 parts of 30-50-mesh tourmaline, 5-10 parts of unsaturated resin, 0.3-0.5 part of additives and 0.3-0.8 part of pigment. According to the invention, tourmaline and quartzitic sandstone are added in the preparation process to improve the antibacterial performance and the fireproof performance of the artificial quartzite board, meanwhile, the antibacterial and fireproof artificial quartzite board disclosed by the invention is broad in market prospect, simple in preparation method and is suitable for industrial production.
Description
Technical field
The invention belongs to material of construction preparing technical field, specifically, refer to a kind of antibacterial, fireproof artificial quartz stone sheet material and preparation method thereof.
Background technology
Artificial quartz in lump is the synthesis stone manufactured by artificial means, there is high strength, high rigidity, high temperature resistant, protection against corrosion, the unrivaled advantage of lithotome such as anti-aging, easy to clean, wear-resisting, radiationless, these advantages allow artificial quartz in lump become the upstart of architectural decoration, are widely applied to cabinet, bathroom, the ground of office and megastore, wall decoration and household industry.But artificial quartz stone plate fire resistance is not in the market good, do not have anti-microbial effect yet, limits artificial quartz in lump in wider application, urgently to be resolved hurrily.
Summary of the invention
Technical problem to be solved by this invention is not enough for prior art, a kind of antibacterial, fireproof artificial quartz stone sheet material and preparation method thereof is provided, the artificial quartz stone plate fire resistance adopting the present invention to prepare is high, and has anti-microbial effect, expands the range of application of artificial quartz in lump.
The technical scheme that the present invention solves the problems of the technologies described above is as follows: antibacterial, fireproof artificial quartz stone sheet material, be made up of the component of following parts by weight: 8 ~ 100 order quartzites 30 ~ 80 parts, 325 order silica powders 30 ~ 60 parts, glass cullet 5 ~ 15 parts, 5 ~ 10 parts, shell, 50 ~ 100 5 ~ 15 parts, order white afrodite powder, 30 ~ 50 5 ~ 15 parts, order tourmalinite, unsaturated polyester 5 ~ 10 parts, auxiliary agent 0.3 ~ 0.5 part, pigment 0.3 ~ 0.8 part.
On the basis of technique scheme, the present invention can also do following improvement.
Further, be made up of the component of following parts by weight: 8 ~ 100 order quartzites 65 parts, 325 order silica powders 45 parts, glass cullet 10 parts, 8 parts, shell, 50 ~ 100 10 parts, order white afrodite powder, 30 ~ 50 8 parts, order tourmalinite, unsaturated polyester 8 parts, auxiliary agent 0.4 part, pigment 0.5 part.
Further, described unsaturated polyester is one or more in epoxy resin, resol, acryl resin and urethane resin.
Further, described auxiliary agent is the mixture of silane coupling agent and peroxide-2-ethyl hexanoic acid tert-butyl, and the part by weight of described silane coupling agent and peroxide-2-ethyl hexanoic acid tert-butyl is 3:1.
Further, described pigment be titanium dioxide, iron oxide yellow powder, iron oxide red, iron black powder, chrome green powder, Lan Shuizhong one or more.
Antibacterial, fireproof artificial quartz stone preparation of plates method, comprise following processing step: the component taking following parts by weight: 8 ~ 100 order quartzites 30 ~ 80 parts, 325 order silica powders 30 ~ 60 parts, glass cullet 5 ~ 15 parts, 5 ~ 10 parts, shell, 50 ~ 100 5 ~ 15 parts, order white afrodite powder, 30 ~ 50 5 ~ 15 parts, order tourmalinite, unsaturated polyester 5 ~ 10 parts, auxiliary agent 0.3 ~ 0.5 part, pigment 0.3 ~ 0.8 part, by above-mentioned each component Homogeneous phase mixing, the material mixed evenly is tiled on making sheet mould, then making sheet mould is sent into vacuum chamber, vacuumize, vibratory compaction, send into curing oven solidification again, sheet material after solidification is come out of the stove the demoulding, after stacking cooling, delivering to surely thick polishing machine carries out surely thick, after surface finish polished finish, artificial quartz in lump can be obtained.
On the basis of technique scheme, the present invention can also do following improvement.
Further, the temperature of described solidification is 90 ~ 95 DEG C, and the time is 30 ~ 40 minutes.
Further, pressure during described vibratory compaction is 2.5 ~ 3.5MPa, and molding time is 2 ~ 3 minutes.
The invention has the beneficial effects as follows:
(1) antibacterial: tourmalinite is ring texture silicate minerals, there is the special performances such as piezoelectricity, pyroelectric, far-infrared radiation and anion releasing, the present invention with the addition of tourmalinite in the feed, effectively can increase the germ resistance of artificial quartz stone plate, and antibiotic effect is for a long time special.
(2) prevent fires: the highest refractory temperature of white afrodite powder all reaches more than 1700 DEG C, it can improve refractory temperature, prolongation fire resistance period, the increase ultimate compression strength of artificial quartz stone plate of the present invention.
(3) wide market of the present invention, preparation method is simple, is suitable for suitability for industrialized production.
Embodiment
Be described principle of the present invention and feature below in conjunction with specific embodiment, example, only for explaining the present invention, is not intended to limit scope of the present invention.
Embodiment 1:
Take 8 ~ 100 order quartzite 30kg, 325 order silica powder 60kg, glass cullet 5kg, shell 10kg, 50 ~ 100 order white afrodite powder 5kg, 30 ~ 50 order tourmalinite 15kg, epoxy resin 5kg, part by weight is the γ-methacryloxypropyl trimethoxy silane (KH570) of 3:1 and the 0.5kg of peroxide-2-ethyl hexanoic acid tert-butyl mixture, pigment 0.3kg, and described pigment is made up of according to mass ratio 15:1 titanium dioxide and Lan Shui; By above-mentioned each component Homogeneous phase mixing, the material mixed evenly is tiled on making sheet mould, then making sheet mould is sent into vacuum chamber, when when vacuumizing, air pressure reaches-0.1MPa, under 2.5 ~ 3.5MPa pressure vibrate 2 ~ 3 minutes shaping, then send into curing oven solidification, solidification value 90 ~ 95 DEG C, time is 30 ~ 40 minutes, sheet material after solidification is come out of the stove the demoulding, after stacking cooling, delivers to surely thick polishing machine and carries out surely thick, " white shell plate " artificial quartz in lump after surface finish polished finish, can be obtained.
Embodiment 2:
Take 8 ~ 100 order quartzite 80kg, 325 order silica powder 30kg, glass cullet 15kg, shell 5kg, 50 ~ 100 order white afrodite powder 15kg, 30 ~ 50 order tourmalinite 5kg, resol 10kg, part by weight is the γ-aminopropyl triethoxysilane (KH550) of 3:1 and the 0.3kg of peroxide-2-ethyl hexanoic acid tert-butyl mixture, pigment 0.8kg, and described pigment is made up of according to mass ratio 1421:40:1:3:178 titanium dioxide, iron oxide yellow powder, iron oxide red, iron black powder and Lan Shui; By above-mentioned each component Homogeneous phase mixing, the material mixed evenly is tiled on making sheet mould, then making sheet mould is sent into vacuum chamber, when when vacuumizing, air pressure reaches-0.1MPa, under 2.5 ~ 3.5MPa pressure vibrate 2 ~ 3 minutes shaping, then send into curing oven solidification, solidification value 90 ~ 95 DEG C, time is 30 ~ 40 minutes, sheet material after solidification is come out of the stove the demoulding, after stacking cooling, delivers to surely thick polishing machine and carries out surely thick, " pale yellow shell plate " artificial quartz in lump after surface finish polished finish, can be obtained.
Embodiment 3:
Take 8 ~ 100 order quartzite 65kg, 325 order silica powder 45kg, glass cullet 10kg, shell 8kg, 50 ~ 100 order white afrodite powder 10kg, 30 ~ 50 order tourmalinite 8kg, urethane resin 8kg, part by weight is the γ-glycidyl ether oxygen propyl trimethoxy silicane of 3:1 and the 0.4kg of peroxide-2-ethyl hexanoic acid tert-butyl mixture, pigment 0.5kg, and described pigment is made up of according to mass ratio 980:1:2:3:118 titanium dioxide, iron oxide yellow powder, iron black powder, chrome green powder and Lan Shui; By above-mentioned each component Homogeneous phase mixing, the material mixed evenly is tiled on making sheet mould, then making sheet mould is sent into vacuum chamber, when when vacuumizing, air pressure reaches-0.1MPa, under 2.5 ~ 3.5MPa pressure vibrate 2 ~ 3 minutes shaping, send into curing oven solidification again, solidification value 90 ~ 95 DEG C, time is 30 ~ 40 minutes, sheet material after solidification is come out of the stove the demoulding, after stacking cooling, delivers to surely thick polishing machine and carries out surely thick, " spring's colours fill the garden shell plate " artificial quartz in lump after surface finish polished finish, can be obtained.
The foregoing is only preferred embodiment of the present invention, not in order to limit the present invention, within the spirit and principles in the present invention all, any amendment done, equivalent replacement, improvement etc., all should be included within protection scope of the present invention.
Claims (8)
1. antibacterial, fireproof artificial quartz stone sheet material, it is characterized in that, be made up of the component of following parts by weight: 8 ~ 100 order quartzites 30 ~ 80 parts, 325 order silica powders 30 ~ 60 parts, glass cullet 5 ~ 15 parts, 5 ~ 10 parts, shell, 50 ~ 100 5 ~ 15 parts, order white afrodite powder, 30 ~ 50 5 ~ 15 parts, order tourmalinite, unsaturated polyester 5 ~ 10 parts, auxiliary agent 0.3 ~ 0.5 part, pigment 0.3 ~ 0.8 part.
2. antibacterial, fireproof artificial quartz stone sheet material according to claim 1, it is characterized in that, be made up of the component of following parts by weight: 8 ~ 100 order quartzites 65 parts, 325 order silica powders 45 parts, glass cullet 10 parts, 8 parts, shell, 50 ~ 100 10 parts, order white afrodite powder, 30 ~ 50 8 parts, order tourmalinite, unsaturated polyester 8 parts, auxiliary agent 0.4 part, pigment 0.5 part.
3. antibacterial, fireproof artificial quartz stone sheet material according to claim 1 and 2, is characterized in that, described unsaturated polyester is one or more in epoxy resin, resol, acryl resin and urethane resin.
4. antibacterial, fireproof artificial quartz stone sheet material according to claim 1 and 2, it is characterized in that, described auxiliary agent is the mixture of silane coupling agent and peroxide-2-ethyl hexanoic acid tert-butyl, and the part by weight of described silane coupling agent and peroxide-2-ethyl hexanoic acid tert-butyl is 3:1.
5. antibacterial, fireproof artificial quartz stone sheet material according to claim 1 and 2, is characterized in that, described pigment be titanium dioxide, iron oxide yellow powder, iron oxide red, iron black powder, chrome green powder, Lan Shuizhong one or more.
6. antibacterial, fireproof artificial quartz stone preparation of plates method, it is characterized in that, comprise following processing step: the component taking following parts by weight: 8 ~ 100 order quartzites 30 ~ 80 parts, 325 order silica powders 30 ~ 60 parts, glass cullet 5 ~ 15 parts, 5 ~ 10 parts, shell, 50 ~ 100 5 ~ 15 parts, order white afrodite powder, 30 ~ 50 5 ~ 15 parts, order tourmalinite, unsaturated polyester 5 ~ 10 parts, auxiliary agent 0.3 ~ 0.5 part, pigment 0.3 ~ 0.8 part, by above-mentioned each component Homogeneous phase mixing, the material mixed evenly is tiled on making sheet mould, then making sheet mould is sent into vacuum chamber, vacuumize, vibratory compaction, send into curing oven solidification again, sheet material after solidification is come out of the stove the demoulding, after stacking cooling, delivering to surely thick polishing machine carries out surely thick, after surface finish polished finish, artificial quartz in lump can be obtained.
7. antibacterial, fireproof artificial quartz stone preparation of plates method according to claim 6, it is characterized in that, pressure during described vibratory compaction is 2.5 ~ 3.5MPa, and molding time is 2 ~ 3 minutes.
8. antibacterial, fireproof artificial quartz stone preparation of plates method according to claim 6, is characterized in that, the temperature of described solidification is 90 ~ 95 DEG C, and the time is 30 ~ 40 minutes.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107619215A (en) * | 2017-10-02 | 2018-01-23 | 镇江市星耀智能装备有限公司 | A kind of preparation method of high performance artificial slabstone |
| CN107721374A (en) * | 2017-11-07 | 2018-02-23 | 桂林奥尼斯特节能环保科技有限责任公司 | A kind of antibacterial, fireproof artificial quartz stone sheet material and preparation method thereof |
| CN109081635A (en) * | 2018-08-14 | 2018-12-25 | 贵州美诚凯辉电器制造有限公司 | A kind of environmental protection containing Tourmaline takes dim panel material and preparation method thereof |
| CN109181191A (en) * | 2018-07-12 | 2019-01-11 | 宁波蒙曼生物科技有限公司 | A kind of flame-proof antibiotic artificial slabstone and its preparation and application |
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| WO1989011457A1 (en) * | 1988-05-27 | 1989-11-30 | Schultze Kraft Andreas | Process for producing artificial stones, and their use |
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| CN101337805A (en) * | 2008-08-25 | 2009-01-07 | 张璐 | Artificial quartz in lump and fabrication technology thereof |
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| CN102584115A (en) * | 2011-12-20 | 2012-07-18 | 汪洋 | Fireproof material, preparation method thereof and fireproof door |
| CN103204660A (en) * | 2013-03-20 | 2013-07-17 | 安徽瑞翔石英制品有限公司 | High-hardness artificial quartz stone plate and production process thereof |
| CN103553435A (en) * | 2013-10-14 | 2014-02-05 | 桂林理工大学 | Preparation method of quartz synthetic stone slab |
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| WO1989011457A1 (en) * | 1988-05-27 | 1989-11-30 | Schultze Kraft Andreas | Process for producing artificial stones, and their use |
| JPH02199049A (en) * | 1989-01-26 | 1990-08-07 | Matsushita Electric Works Ltd | Artificial stone and production thereof |
| CN101337805A (en) * | 2008-08-25 | 2009-01-07 | 张璐 | Artificial quartz in lump and fabrication technology thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107619215A (en) * | 2017-10-02 | 2018-01-23 | 镇江市星耀智能装备有限公司 | A kind of preparation method of high performance artificial slabstone |
| CN107721374A (en) * | 2017-11-07 | 2018-02-23 | 桂林奥尼斯特节能环保科技有限责任公司 | A kind of antibacterial, fireproof artificial quartz stone sheet material and preparation method thereof |
| CN109181191A (en) * | 2018-07-12 | 2019-01-11 | 宁波蒙曼生物科技有限公司 | A kind of flame-proof antibiotic artificial slabstone and its preparation and application |
| CN109081635A (en) * | 2018-08-14 | 2018-12-25 | 贵州美诚凯辉电器制造有限公司 | A kind of environmental protection containing Tourmaline takes dim panel material and preparation method thereof |
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Application publication date: 20150422 |