CN102390953B - Raw material of antibacterial superhard artificial quartz stone plate, artificial quartz stone plate and preparation method thereof - Google Patents

Raw material of antibacterial superhard artificial quartz stone plate, artificial quartz stone plate and preparation method thereof Download PDF

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Publication number
CN102390953B
CN102390953B CN 201110231100 CN201110231100A CN102390953B CN 102390953 B CN102390953 B CN 102390953B CN 201110231100 CN201110231100 CN 201110231100 CN 201110231100 A CN201110231100 A CN 201110231100A CN 102390953 B CN102390953 B CN 102390953B
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stone plate
quartz stone
artificial quartz
raw
parts
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CN102390953A (en
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张文
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New Cloud Stone (yunfu) Co Ltd
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New Cloud Stone (yunfu) Co Ltd
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Abstract

The invention discloses a raw material of an antibacterial superhard artificial quartz stone plate, comprising the following components in parts by weight: 7-8 parts of modified unsaturated resin, 0.42-0.52 part of assistant, 45-65 parts of calcined quartz sand with particle size smaller than or equal to 6mm, 8-10 parts of tourmaline of20-80 meshes, 0-12 parts of 80-mesh quartz sand, 24-27 parts of 325-mesh quartz powder and 0.01-0.1 part of pigment. The invention also discloses an artificial quartz stone plate made of the raw material and a preparation method thereof. In the invention, a certain quantity of tourmaline and calcined quartz stone is added in the production process of the quartz stone plate so that the produced plate not only is high in hardness, good in wear resistance, not easy to scrape and long in service life, but also has an antibacterial effect.

Description

Antibiotic, exceptional hardness artificial quartz stone plate raw material, artificial quartz stone plate and preparation method thereof
Technical field
The present invention relates to rostone and preparation method thereof, be specifically related to a kind of antibiotic, exceptional hardness artificial quartz stone plate raw material, artificial quartz stone plate and preparation method thereof.
Background technology
The artificial slabstone in existing building finishing material market, safety, low-carbon (LC), environmental protection, high hardness wear-resisting etc. have become the selected key factor of people.At present, the artificial quartz in lump stone slab hardness ratio on the market is lower, wears no resistance, also exist easily to scratch, and the problems such as easy fragmentation, nor have anti-microbial effect.
Summary of the invention
The present invention is in order to overcome the shortcoming and defect that exists in the above-mentioned prior art, provides a kind of exceptional hardness, wear resistance good, and has artificial quartz stone plate raw material, artificial quartz stone plate of anti-microbial effect and preparation method thereof.
In order to solve the problems of the technologies described above, the present invention realizes by following technical scheme:
A kind of artificial quartz stone plate raw material, a kind of artificial quartz stone plate raw material, component by following weight part forms: modification modified unsaturated resin 7-8 part, auxiliary agent 0.42-0.52 part, particle diameter is less than or equal to calcining quartz sand 45-65 part of 6mm, 20-80 order tourmalinite 8-10 part, 80 order quartz sand 0-12 parts, 325 order silica powder 24-27 parts, pigment 0.01-0.1 part.
Preferably, described calcining quartz sand is that quartz sand forms through 1500 ℃ of-1900 ℃ of high-temperature calcinations.
Preferably, described auxiliary agent is the mixture of silane coupling agent and peroxide-2-ethyl hexanoic acid tert-butyl, and the part by weight of described silane coupling agent and peroxide-2-ethyl hexanoic acid tert-butyl is 4: 1.
The artificial quartz stone plate that is prepared by the artificial quartz stone plate raw material.
A kind of preparation method of artificial quartz in lump comprises the steps: that above-mentioned each component evenly mixes, and the material that mixes is sent in the material distributing machine cloth system template die, then the making sheet mould is sent into vacuum chamber, vacuumize, vibratory compaction, send into again curing oven, namely make artificial quartz stone plate.
Preferably, the temperature of described curing is 85 ℃-95 ℃, and the time is 40-45 minute.
Preferably, the pressure during described vibratory compaction is 1.8-3MPa, and molding time is 2-3 minute.
Compared with prior art, the invention has the beneficial effects as follows:
(1) antibiotic.Tourmalinite has unique physical and chemical performance such as piezoelectricity and pyroelectricity, can produce electromagnetic radiation and the negative oxygen ion of far infrared band, has function antibiotic, deodorizing.The present invention adds 8-10% 20-80 order tourmalinite in raw material, can effectively increase the germ resistance of sheet material, and antibiotic effect is for a long time special.
(2) exceptional hardness.Calcining quartz sand of the present invention is to form through 1500 ℃ of-1900 ℃ of high-temperature calcinations, and its original oxidation, weathering material are burnt, and makes its density better fused, is a kind of superhard material.In raw material, add the 45-66% particle diameter less than or equal to 6mm calcining quartz sand, increased substantially sheet material hardness, make it more wear-resisting, be difficult for scratching, increasing work-ing life.
Embodiment
Embodiment 1
The artificial quartz stone plate raw material is comprised of the raw material of following weight:
Modified unsaturated resin 8kg, weight ratio is 4: 1 γ-(2,3-epoxy the third oxygen) propyl trimethoxy silicane and peroxide-2-ethyl hexanoic acid tert-butyl mixture 0.48kg, 20-80 order tourmalinite 10kg, particle diameter is less than or equal to the calcining quartz sand 45.47kg of 6mm, 80 order quartz sand 12kg, 325 order silica powder 24kg, blue pigments 0.05kg.
Above-mentioned each component raw material is added after stirrer stirs 3 minutes, in its fabric system template die, then be conveyed into vacuum chamber, when vacuumizing air pressure reach-during 0.1Mpa, vibration moulding in 2-3 minute is conveyed into baking oven again under 1.8-3Mpa pressure, and oven temperature remains under 85 ℃ of-95 ℃ of states and carries out 40-45 minute curing, treat the sheet material cooling after finishing, the fixed thick sanding and polishing of hair plates is namely made " turquoise diamond stone " artificial quartz stone plate.
It is 300mm that the above-mentioned artificial quartz stone plate that makes and conventional products cut into length, wide 150mm, and the sheet material of high 20mm is done the properties test.Survey dry compressive strength with microcomputer screen display universal hydraulic testing machine; Survey dry flexural strength with microcomputer controlled electronic universal tester; Measure radioactivity with gamma energy spectrometer.Test result is as shown in the table:
By contrast experiment's data of above table as can be known, artificial quartz stone plate of the present invention has added after tourmalinite and the calcining quartz sand, and quartzite slate of the present invention all is improved with respect to the various aspects of performance of existing sheet material.
Embodiment 2
The artificial quartz stone plate raw material is comprised of the raw material of following weight:
Modified unsaturated resin 7kg, weight ratio is 4: 1 γ-(2,3-epoxy the third oxygen) propyl trimethoxy silicane and peroxide-2-ethyl hexanoic acid tert-butyl mixture 0.42kg, 80 order tourmalinite 8kg, particle diameter is less than or equal to the calcining quartz sand 59.5kg of 6mm, 325 order silica powder 25kg, black pigment 0.08kg.
Above-mentioned each component raw material is added after stirrer stirs 3 minutes, in its fabric system template die, then be conveyed into vacuum chamber, when vacuumizing air pressure reach-during 0.1Mpa, vibration moulding in 2-3 minute is conveyed into baking oven again under 1.8-3Mpa pressure, and oven temperature remains under 85 ℃ of-95 ℃ of states and carries out 40-45 minute curing, treat the sheet material cooling after finishing, the fixed thick sanding and polishing of hair plates is namely made " black pearl " artificial quartz stone plate.
It is 300mm that the above-mentioned artificial quartz stone plate that makes and conventional products cut into length, wide 150mm, and the sheet material of high 20mm is done the properties test.Survey dry compressive strength with microcomputer screen display universal hydraulic testing machine; Survey dry flexural strength with microcomputer controlled electronic universal tester; Measure radioactivity with gamma energy spectrometer.Test result is as shown in the table:
By contrast experiment's data of above table as can be known, artificial quartz stone plate of the present invention has added after tourmalinite and the calcining quartz sand, and quartzite slate of the present invention all is improved with respect to the various aspects of performance of existing sheet material.
Embodiment 3
The artificial quartz stone plate raw material is comprised of the raw material of following weight:
Modified unsaturated resin 8kg, weight ratio is 4: 1 γ-(2,3-epoxy the third oxygen) propyl trimethoxy silicane and peroxide-2-ethyl hexanoic acid tert-butyl mixture 0.42kg, 80 order tourmalinite 8kg, particle diameter is less than or equal to 2mm calcining quartz sand 65.31kg, 325 order silica powder 27kg, black pigment 0.01kg.
Above-mentioned each component raw material is added after stirrer stirs 3 minutes, in its fabric system template die, then be conveyed into vacuum chamber, when vacuumizing air pressure reach-during 0.1Mpa, vibration moulding in 2-3 minute is conveyed into baking oven again under 1.8-3Mpa pressure, and oven temperature remains under 85 ℃ of-95 ℃ of states and carries out 40-45 minute curing, treat the sheet material cooling after finishing, the fixed thick sanding and polishing of hair plates is namely made " ash fiber crops " artificial quartz stone plate.
It is 300mm that the above-mentioned artificial quartz stone plate that makes and conventional products cut into length, wide 150mm, and the sheet material of high 20mm is done the properties test.Survey dry compressive strength with microcomputer screen display universal hydraulic testing machine; Survey dry flexural strength with microcomputer controlled electronic universal tester; Measure radioactivity with gamma energy spectrometer.Test result is as shown in the table:
By contrast experiment's data of above table as can be known, artificial quartz stone plate of the present invention has added after tourmalinite and the calcining quartz sand, and quartzite slate of the present invention all is improved with respect to the various aspects of performance of existing sheet material.
Embodiment 4
The artificial quartz stone plate raw material is comprised of the raw material of following weight:
Modified unsaturated resin 7.5kg, weight ratio is 4: 1 γ-(2,3-epoxy the third oxygen) propyl trimethoxy silicane and peroxide-2-ethyl hexanoic acid tert-butyl mixture 0.48kg, 20-80 order tourmalinite 10kg, particle diameter is less than or equal to 2mm calcining quartz sand 54.97kg, 325 order silica powder 27kg, red pigment 0.05kg.
Above-mentioned each component raw material is added after stirrer stirs 3 minutes, in its fabric system template die, then be conveyed into vacuum chamber, when vacuumizing air pressure reach-during 0.1Mpa, vibration moulding in 2-3 minute is conveyed into baking oven again under 1.8-3Mpa pressure, and oven temperature remains under 85 ℃ of-95 ℃ of states and carries out 40-45 minute curing, treat the sheet material cooling after finishing, the fixed thick sanding and polishing of hair plates is namely made " Chinese red " artificial quartz stone plate.
It is 300mm that the above-mentioned artificial quartz stone plate that makes and conventional products cut into length, wide 150mm, and the sheet material of high 20mm is done the properties test.Survey dry compressive strength with microcomputer screen display universal hydraulic testing machine; Survey dry flexural strength with microcomputer controlled electronic universal tester; Measure radioactivity with gamma energy spectrometer.Test result is as shown in the table:
By contrast experiment's data of above table as can be known, artificial quartz stone plate of the present invention has added after tourmalinite and the calcining quartz sand, and quartzite slate of the present invention all is improved with respect to the various aspects of performance of existing sheet material.
Above-described embodiment is better embodiment of the present invention; but embodiments of the present invention are not restricted to the described embodiments; other any do not deviate from change, the decoration done under spirit of the present invention and the principle, substitutes, combination, simplify; all should be the substitute mode of equivalence, be included within protection scope of the present invention.

Claims (5)

1. artificial quartz stone plate raw material, component by following weight part forms: modified unsaturated resin 7-8 part, auxiliary agent 0.42-0.52 part, particle diameter is less than or equal to calcining quartz sand 45-65 part of 6mm, 20-80 order tourmalinite 8-10 part, 80 order quartz sand 0-12 parts, 325 order silica powder 24-27 parts, pigment 0.01-0.1 part; Described calcining quartz sand is that quartz sand forms through 1500 ℃ of-1900 ℃ of high-temperature calcinations, described auxiliary agent is the mixture of silane coupling agent and peroxide-2-ethyl hexanoic acid tert-butyl, and the part by weight of described silane coupling agent and peroxide-2-ethyl hexanoic acid tert-butyl is 4:1.
2. the artificial quartz stone plate that is prepared by artificial quartz stone plate raw material claimed in claim 1.
3. the preparation method of an artificial quartz stone plate, it is characterized in that comprising the steps: each component claimed in claim 1 is evenly mixed, the material that mixes is sent in the material distributing machine cloth system template die, then the making sheet mould is sent into vacuum chamber, vacuumize, curing oven is sent in vibratory compaction again, namely makes artificial quartz stone plate.
4. the preparation method of artificial quartz stone plate according to claim 3, it is characterized in that: the temperature of described curing is 85 ℃-95 ℃, and the time is 40-45 minute.
5. the preparation method of artificial quartz stone plate according to claim 3, it is characterized in that: the pressure during described vibratory compaction is 1.8-3MPa, molding time is 2-3 minute.
CN 201110231100 2011-08-12 2011-08-12 Raw material of antibacterial superhard artificial quartz stone plate, artificial quartz stone plate and preparation method thereof Active CN102390953B (en)

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CN103739235B (en) * 2013-12-18 2016-04-06 广州戈兰迪高分子材料有限公司 A kind of Crack-resistant quartz stone plate and manufacture method thereof
CN103922640A (en) * 2014-04-01 2014-07-16 安庆市凯立金刚石科技有限公司 Artificial quartz raw material and forming production process thereof
CN104478273A (en) * 2014-12-15 2015-04-01 田忠和 Fireproof artificial quartz stone sheet and manufacturing method thereof
CN104529248A (en) * 2014-12-15 2015-04-22 田忠和 Artificial quartz stone panel and preparation method thereof
CN104529245A (en) * 2014-12-15 2015-04-22 田忠和 Fireproof manmade quartz stone slab with superhardness and manufacturing method of fireproof manmade quartz stone slab
CN104478292A (en) * 2014-12-15 2015-04-01 田忠和 Artificial quartz stone sheet and preparation method thereof
CN104529244A (en) * 2014-12-15 2015-04-22 田忠和 Anti-aging and antibacterial artificial quartzite board and manufacturing method thereof
CN104496273A (en) * 2014-12-15 2015-04-08 田忠和 Artificial quartzite plate and manufacturing method thereof
CN104529246A (en) * 2014-12-15 2015-04-22 田忠和 Antibacterial and fireproof artificial quartzite board and preparation method thereof
CN104529247A (en) * 2014-12-15 2015-04-22 田忠和 Super-hardness and antibacterial artificial quartzite plate and manufacture method thereof
CN104529240B (en) * 2015-01-12 2016-06-08 广州市奥维装饰材料有限公司 Quartzite slate and preparation method thereof
CN106810106A (en) * 2015-11-30 2017-06-09 衡阳市雅典娜石英石有限公司 A kind of antibacterial quartz and preparation method thereof
CN105801004A (en) * 2016-04-21 2016-07-27 太仓市建兴石英玻璃厂 Preparation method of health-care man-made quartz stone plate
CN105884260A (en) * 2016-04-21 2016-08-24 太仓市建兴石英玻璃厂 Healthcare artificial quartzite board
CN106145768A (en) * 2016-06-24 2016-11-23 安徽弗仕通实业有限公司 A kind of spontaneous heating antibacterial artificial quartz
CN107586059A (en) * 2017-10-02 2018-01-16 镇江市星耀智能装备有限公司 A kind of compound additive for being used to prepare artificial slabstone
CN110228963A (en) * 2019-07-09 2019-09-13 云浮市盈拓石业有限公司 A kind of novel artificial quartzite plate

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CN2271695Y (en) * 1996-07-20 1997-12-31 刘景潮 Square quartz calciner
CN101195537A (en) * 2007-06-08 2008-06-11 汪滔 Material capable of generating negative ion far-infrared antimicrobial ceramic product and uses thereof
CN102030497A (en) * 2010-11-01 2011-04-27 新云石业(云浮)有限公司 Quartzite material, artificial quartzite plate and manufacturing process thereof

Patent Citations (3)

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Publication number Priority date Publication date Assignee Title
CN2271695Y (en) * 1996-07-20 1997-12-31 刘景潮 Square quartz calciner
CN101195537A (en) * 2007-06-08 2008-06-11 汪滔 Material capable of generating negative ion far-infrared antimicrobial ceramic product and uses thereof
CN102030497A (en) * 2010-11-01 2011-04-27 新云石业(云浮)有限公司 Quartzite material, artificial quartzite plate and manufacturing process thereof

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