CN104478290A - Anti-aging artificial quartz stone panel and preparation method thereof - Google Patents
Anti-aging artificial quartz stone panel and preparation method thereof Download PDFInfo
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- CN104478290A CN104478290A CN201410775884.8A CN201410775884A CN104478290A CN 104478290 A CN104478290 A CN 104478290A CN 201410775884 A CN201410775884 A CN 201410775884A CN 104478290 A CN104478290 A CN 104478290A
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Abstract
The invention discloses an anti-aging artificial quartz stone panel and a preparation method thereof. The anti-aging artificial quartz stone panel is prepared from the following components in parts by weight: 50-80 parts of 3-80-mesh quartz stone, 30-60 parts of 325-mesh quartz powder, 5-10 parts of glass cullet, 5-10 parts of unsaturated resin, 0.1-2 parts of an antioxidant, 0.3-2 parts of a coupling agent, 0.3-2 parts of a curing agent and 0.1-1 part of a pigment. The anti-aging artificial quartz stone panel has the advantages that antioxidant is added in a preparation process, so that anti-aging property of the artificial quartz stone panel is improved, physical and chemical properties of the artificial quartz stone panel are good, and service life is long; meanwhile, the preparation method of the anti-aging artificial quartz stone panel is simple, so that the anti-aging artificial quartz stone panel is applicable to industrial production.
Description
Technical field
The invention belongs to material of construction preparing technical field, specifically, refer to a kind of anti-aging artificial quartz stone plate and preparation method thereof.
Background technology
Artificial quartz stone plate is compared with artificial marble sheet material, there is the features such as sinuousness is high, compressive strength is high, Mohs' hardness is high, water-intake rate is low, gradually like by domestic and international users, be widely applied to cabinet, bathroom, the ground of office and megastore, wall decoration and household industry.But the shrinkability of existing Engineered stone products is higher, and resistance to deterioration and ultra-violet radiation resisting function poor, product uses and degradation problem under aging, its colour changed into yellow, embrittlement, physicals and chemical property easily occurs under long term outdoor high light, so existing Engineered stone products can only as interior architecture finishing material, and cannot use as outdoor architecture finishing material, seriously constrain applying of Engineered stone products.
Summary of the invention
Technical problem to be solved by this invention is not enough for prior art, a kind of anti-aging artificial quartz stone plate and preparation method thereof is provided, adopt that the artificial quartz stone plate resistance of aging prepared of the present invention is strong, physicals and chemical property good, and long service life.
The technical scheme that the present invention solves the problems of the technologies described above is as follows: anti-aging artificial quartz stone plate, be made up of the component of following parts by weight: 3 ~ 80 order quartzites 50 ~ 80 parts, 325 order silica powders 30 ~ 60 parts, glass cullet 5 ~ 10 parts, unsaturated polyester 5 ~ 10 parts, 0.1 ~ 2 part, oxidation inhibitor, coupling agent 0.3 ~ 2 part, 0.3 ~ 2 part, solidifying agent, pigment 0.1 ~ 1 part.
On the basis of technique scheme, the present invention can also do following improvement.
Further, be made up of the component of following parts by weight: 3 ~ 80 order quartzites 65 parts, 325 order silica powders 45 parts, glass cullet 8 parts, unsaturated polyester 8 parts, 0.5 part, oxidation inhibitor, coupling agent 1 part, 0.8 part, solidifying agent, pigment 0.3 part.
Further, described unsaturated polyester is one or more in epoxy resin, resol, acryl resin and urethane resin.
Further, described oxidation inhibitor is one or more in oxidation inhibitor 1222, AT-76, antioxidant 2246-S, AT-59, oxidation inhibitor 1035, oxidation inhibitor 1098, oxidation inhibitor 3125, TPP, TNPP, AT-168, oxidation inhibitor 245, GA-80, oxidation inhibitor 858, antioxidant 1010.
Further, described coupling agent is organo silane coupling agent.
Further, described solidifying agent is the one in peroxide-2-ethyl hexanoic acid tert-butyl, peroxidized t-butyl perbenzoate or benzoyl peroxide.
Further, described pigment be titanium dioxide, iron oxide yellow powder, iron oxide red, iron black powder, chrome green powder, Lan Shuizhong one or more.
The preparation method of anti-aging artificial quartz stone plate, comprise following processing step: the component taking following parts by weight: 3 ~ 80 order quartzites 50 ~ 80 parts, 325 order silica powders 30 ~ 60 parts, glass cullet 5 ~ 10 parts, unsaturated polyester 5 ~ 10 parts, 0.1 ~ 2 part, oxidation inhibitor, coupling agent 0.3 ~ 2 part, 0.3 ~ 2 part, solidifying agent, pigment 0.1 ~ 1 part, by above-mentioned each component Homogeneous phase mixing, the material mixed evenly is tiled on making sheet mould, then making sheet mould is sent into vacuum chamber, vacuumize, vibratory compaction, send into curing oven solidification again, sheet material after solidification is come out of the stove the demoulding, after stacking cooling, delivering to surely thick polishing machine carries out surely thick, after surface finish polished finish, artificial quartz in lump can be obtained.
On the basis of technique scheme, the present invention can also do following improvement.
Further, pressure during described vibratory compaction is 2.5 ~ 3.5MPa, and molding time is 2 ~ 3 minutes.
Further, the temperature of described solidification is 85 ~ 95 DEG C, and the time is 30 ~ 45 minutes.
The invention has the beneficial effects as follows:
(1) anti-aging: in raw material of the present invention, to the addition of oxidation inhibitor, improve the oxidation-resistance of artificial quartz stone plate of the present invention and the ability of antiultraviolet, there is use widely.
(2) preparation method of the present invention is simple, is suitable for suitability for industrialized production.
Embodiment
Be described principle of the present invention and feature below in conjunction with specific embodiment, example, only for explaining the present invention, is not intended to limit scope of the present invention.
Embodiment 1:
Take 3 ~ 100 order quartzite 50kg, 325 order silica powder 60kg, glass cullet 5kg, epoxy resin 10kg, oxidation inhibitor 1222:0.1kg, organo silane coupling agent 2kg, peroxide-2-ethyl hexanoic acid tert-butyl 0.3kg, pigment 1kg, described pigment is made up of according to mass ratio 18:1 titanium dioxide and Lan Shui; By above-mentioned each component Homogeneous phase mixing, the material mixed evenly is tiled on making sheet mould, then making sheet mould is sent into vacuum chamber, when when vacuumizing, air pressure reaches-0.1MPa, under 2.5 ~ 3.5MPa pressure vibrate 2 ~ 3 minutes shaping, then send into curing oven solidification, solidification value 85 ~ 95 DEG C, time is 30 ~ 45 minutes, sheet material after solidification is come out of the stove the demoulding, after stacking cooling, delivers to surely thick polishing machine and carries out surely thick, after surface finish polished finish, " white board " artificial quartz in lump can be obtained.
Embodiment 2:
Take 3 ~ 100 order quartzite 80kg, 325 order silica powder 30kg, glass cullet 10kg, resol 5kg, oxidation inhibitor 1098:2kg, organo silane coupling agent 0.3kg, peroxidized t-butyl perbenzoate 2kg, pigment 0.1kg, described pigment is made up of according to mass ratio 1076:47:1:310:125 titanium dioxide, iron oxide yellow powder, iron black powder, chrome green powder and Lan Shui; By above-mentioned each component Homogeneous phase mixing, the material mixed evenly is tiled on making sheet mould, then making sheet mould is sent into vacuum chamber, when when vacuumizing, air pressure reaches-0.1MPa, under 2.5 ~ 3.5MPa pressure vibrate 2 ~ 3 minutes shaping, then send into curing oven solidification, solidification value 85 ~ 95 DEG C, time is 30 ~ 45 minutes, sheet material after solidification is come out of the stove the demoulding, after stacking cooling, delivers to surely thick polishing machine and carries out surely thick, " pale yellow plate " artificial quartz in lump after surface finish polished finish, can be obtained.
Embodiment 3:
Take 3 ~ 100 order quartzite 65kg, 325 order silica powder 45kg, glass cullet 8kg, urethane resin 8kg, oxidation inhibitor 245:0.5kg, organo silane coupling agent 1kg, peroxidized t-butyl perbenzoate 0.8kg, pigment 0.3kg, described pigment is made up of according to mass ratio 980:1:2:3:118 titanium dioxide, iron oxide yellow powder, iron black powder, chrome green powder and Lan Shui; By above-mentioned each component Homogeneous phase mixing, the material mixed evenly is tiled on making sheet mould, then making sheet mould is sent into vacuum chamber, when when vacuumizing, air pressure reaches-0.1MPa, under 2.5 ~ 3.5MPa pressure vibrate 2 ~ 3 minutes shaping, then send into curing oven solidification, solidification value 85 ~ 95 DEG C, time is 30 ~ 45 minutes, sheet material after solidification is come out of the stove the demoulding, after stacking cooling, delivers to surely thick polishing machine and carries out surely thick, after surface finish polished finish, " spring's colours fill the garden " artificial quartz in lump can be obtained.
The foregoing is only preferred embodiment of the present invention, not in order to limit the present invention, within the spirit and principles in the present invention all, any amendment done, equivalent replacement, improvement etc., all should be included within protection scope of the present invention.
Claims (10)
1. anti-aging artificial quartz stone plate, it is characterized in that, be made up of the component of following parts by weight: 3 ~ 80 order quartzites 50 ~ 80 parts, 325 order silica powders 30 ~ 60 parts, glass cullet 5 ~ 10 parts, unsaturated polyester 5 ~ 10 parts, 0.1 ~ 2 part, oxidation inhibitor, coupling agent 0.3 ~ 2 part, 0.3 ~ 2 part, solidifying agent, pigment 0.1 ~ 1 part.
2. anti-aging artificial quartz stone plate according to claim 1, it is characterized in that, be made up of the component of following parts by weight: 3 ~ 80 order quartzites 65 parts, 325 order silica powders 45 parts, glass cullet 8 parts, unsaturated polyester 8 parts, 0.5 part, oxidation inhibitor, coupling agent 1 part, 0.8 part, solidifying agent, pigment 0.3 part.
3. anti-aging artificial quartz stone plate according to claim 1 and 2, is characterized in that, described unsaturated polyester is one or more in epoxy resin, resol, acryl resin and urethane resin.
4. anti-aging artificial quartz stone plate according to claim 1 and 2, it is characterized in that, described oxidation inhibitor is one or more in oxidation inhibitor 1222, AT-76, antioxidant 2246-S, AT-59, oxidation inhibitor 1035, oxidation inhibitor 1098, oxidation inhibitor 3125, TPP, TNPP, AT-168, oxidation inhibitor 245, GA-80, oxidation inhibitor 858, antioxidant 1010.
5. anti-aging artificial quartz stone plate according to claim 1 and 2, is characterized in that, described coupling agent is organo silane coupling agent.
6. anti-aging artificial quartz stone plate according to claim 1 and 2, is characterized in that, described solidifying agent is the one in peroxide-2-ethyl hexanoic acid tert-butyl, peroxidized t-butyl perbenzoate or benzoyl peroxide.
7. anti-aging artificial quartz stone plate according to claim 1 and 2, is characterized in that, described pigment be titanium dioxide, iron oxide yellow powder, iron oxide red, iron black powder, chrome green powder, Lan Shuizhong one or more.
8. the preparation method of anti-aging artificial quartz stone plate, it is characterized in that, comprise following processing step: the component taking following parts by weight: 3 ~ 80 order quartzites 50 ~ 80 parts, 325 order silica powders 30 ~ 60 parts, glass cullet 5 ~ 10 parts, unsaturated polyester 5 ~ 10 parts, 0.1 ~ 2 part, oxidation inhibitor, coupling agent 0.3 ~ 2 part, 0.3 ~ 2 part, solidifying agent, pigment 0.1 ~ 1 part, by above-mentioned each component Homogeneous phase mixing, the material mixed evenly is tiled on making sheet mould, then making sheet mould is sent into vacuum chamber, vacuumize, vibratory compaction, send into curing oven solidification again, sheet material after solidification is come out of the stove the demoulding, after stacking cooling, delivering to surely thick polishing machine carries out surely thick, after surface finish polished finish, artificial quartz in lump can be obtained.
9. the preparation method of anti-aging artificial quartz stone plate according to claim 8, is characterized in that, pressure during described vibratory compaction is 2.5 ~ 3.5MPa, and molding time is 2 ~ 3 minutes.
10. the preparation method of anti-aging artificial quartz stone plate according to claim 8, is characterized in that, the temperature of described solidification is 85 ~ 95 DEG C, and the time is 30 ~ 45 minutes.
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107759133A (en) * | 2017-11-07 | 2018-03-06 | 桂林奥尼斯特节能环保科技有限责任公司 | A kind of anti-aging artificial quartz stone plate and preparation method thereof |
| CN108793822A (en) * | 2018-07-07 | 2018-11-13 | 河源市极致知管信息科技有限公司 | A kind of artificial quartz plate and preparation method thereof |
| CN111548052A (en) * | 2020-05-06 | 2020-08-18 | 广东河源住方高分子材料有限公司 | Artificial quartz stone plate and preparation method thereof |
| CN111978011A (en) * | 2020-08-29 | 2020-11-24 | 泉州艺峰股份有限公司 | Quartz plate and preparation method thereof |
| CN112573861A (en) * | 2021-02-03 | 2021-03-30 | 湖北钊晟新材料科技有限公司 | Quartz stone plate with low expansion coefficient and preparation method thereof |
| KR20210074675A (en) * | 2019-12-12 | 2021-06-22 | (주)엘지하우시스 | Artificial marble and method for manufacturing thereof |
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| CN101328039A (en) * | 2008-08-04 | 2008-12-24 | 覃庆峰 | Artificial stone panel and manufacturing method thereof |
| CN101337805A (en) * | 2008-08-25 | 2009-01-07 | 张璐 | Artificial quartz in lump and fabrication technology thereof |
| CN101665340A (en) * | 2005-12-26 | 2010-03-10 | 北京仁创科技集团有限公司 | Weather resistance permeable material and application thereof |
| CN103204660A (en) * | 2013-03-20 | 2013-07-17 | 安徽瑞翔石英制品有限公司 | High-hardness artificial quartz stone plate and production process thereof |
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| JPH02199049A (en) * | 1989-01-26 | 1990-08-07 | Matsushita Electric Works Ltd | Artificial stone and production thereof |
| CN101665340A (en) * | 2005-12-26 | 2010-03-10 | 北京仁创科技集团有限公司 | Weather resistance permeable material and application thereof |
| CN101328039A (en) * | 2008-08-04 | 2008-12-24 | 覃庆峰 | Artificial stone panel and manufacturing method thereof |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107759133A (en) * | 2017-11-07 | 2018-03-06 | 桂林奥尼斯特节能环保科技有限责任公司 | A kind of anti-aging artificial quartz stone plate and preparation method thereof |
| CN108793822A (en) * | 2018-07-07 | 2018-11-13 | 河源市极致知管信息科技有限公司 | A kind of artificial quartz plate and preparation method thereof |
| KR20210074675A (en) * | 2019-12-12 | 2021-06-22 | (주)엘지하우시스 | Artificial marble and method for manufacturing thereof |
| KR102641983B1 (en) * | 2019-12-12 | 2024-02-27 | (주)엘엑스하우시스 | Artificial marble and method for manufacturing thereof |
| CN111548052A (en) * | 2020-05-06 | 2020-08-18 | 广东河源住方高分子材料有限公司 | Artificial quartz stone plate and preparation method thereof |
| CN111548052B (en) * | 2020-05-06 | 2021-05-04 | 广东河源住方高分子材料有限公司 | Artificial quartz stone plate and preparation method thereof |
| CN111978011A (en) * | 2020-08-29 | 2020-11-24 | 泉州艺峰股份有限公司 | Quartz plate and preparation method thereof |
| CN111978011B (en) * | 2020-08-29 | 2022-03-25 | 泉州艺峰股份有限公司 | Quartz plate and preparation method thereof |
| CN112573861A (en) * | 2021-02-03 | 2021-03-30 | 湖北钊晟新材料科技有限公司 | Quartz stone plate with low expansion coefficient and preparation method thereof |
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Application publication date: 20150401 |