CN107759133A - A kind of anti-aging artificial quartz stone plate and preparation method thereof - Google Patents
A kind of anti-aging artificial quartz stone plate and preparation method thereof Download PDFInfo
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- CN107759133A CN107759133A CN201711083166.4A CN201711083166A CN107759133A CN 107759133 A CN107759133 A CN 107759133A CN 201711083166 A CN201711083166 A CN 201711083166A CN 107759133 A CN107759133 A CN 107759133A
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- antioxidant
- artificial quartz
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/14—Polyepoxides
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/06—Acrylates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/12—Condensation polymers of aldehydes or ketones
- C04B26/122—Phenol-formaldehyde condensation polymers
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/16—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/54—Substitutes for natural stone, artistic materials or the like
- C04B2111/542—Artificial natural stone
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
Abstract
The invention discloses a kind of anti-aging artificial quartz stone plate and preparation method thereof, belong to construction material preparing technical field.The artificial quartz stone plate, it is made up of the component of following parts by weight：0.2~0.6 part of 10~80 20~80 parts of mesh quartzs, 20~40 parts of 325 mesh silica flour, 5~9 parts of cullet, 5~10 parts of unsaturated-resin, 0.2~1 part of antioxidant, 0.5~2 part of coupling agent, 5~15 parts of medical stone powder, 6~16 parts of mica powder, 0.3~2 part of curing agent and pigment.The anti-aging artificial quartz stone plate of the present invention, antioxidant being added, improves the ageing resistace of artificial quartz stone plate, physical property and chemical property are good, and service life is grown, meanwhile, preparation method of the invention is simple, suitable for industrialized production.
Description
Technical field
The invention belongs to construction material preparing technical field, specifically, refers to a kind of anti-aging artificial quartz stone plate
And preparation method thereof.
Background technology
Artificial quartz stone plate has high flexibility, compressive strength height, Mohs' hardness compared with artificial marble sheet material
High, the features such as water absorption rate is low, gradually liked by domestic and international users, be widely applied to cabinet, bathroom, office and big
Ground, wall decoration and the household industry in type market.But the shrinkage of existing Engineered stone products is higher, and ageing resistance
Poor with ultra-violet radiation resisting function, product uses easily generation aging, its colour changed into yellow, embrittlement, thing under the strong light of long term outdoor
Rationality can and chemical property the problems such as declining, so existing Engineered stone products can only be used as interior architecture ornament materials, and nothing
Method uses as outdoor architecture ornament materials, seriously constrains the popularization and application of Engineered stone products.
The content of the invention
An object of the present invention, it is to provide a kind of anti-aging artificial quartz stone plate.The anti-aging artificial stone of the present invention
Diamond stone sheet material, antioxidant being added, improves the ageing resistace of artificial quartz stone plate, physical property and chemical property are good,
And service life is grown
The technical scheme that the present invention solves above-mentioned technical problem is as follows：A kind of anti-aging artificial quartz stone plate, by following
The component composition of parts by weight：10~80 20~80 parts of mesh quartzs, 20~40 parts of 325 mesh silica flour, 5~9 parts of cullet, no
5~10 parts of saturated resin, 0.2~1 part of antioxidant, 0.5~2 part of coupling agent, 5~15 parts of medical stone powder, 6~16 parts of mica powder,
0.2~0.6 part of 0.3~2 part of curing agent and pigment.
On the basis of above-mentioned technical proposal, the present invention can also do following improvement.
Further, it is made up of the component of following parts by weight：It is 10~80 50 parts of mesh quartzs, 30 parts of 325 mesh silica flour, broken
7 parts of glass, 7 parts of unsaturated-resin, 0.6 part of antioxidant, 1 part of coupling agent, 10 parts of medical stone powder, 11 parts of mica powder, curing agent 1.2
0.4 part of part and pigment.
Further, the unsaturated-resin is one in epoxy resin, phenolic resin, acryl resin and polyurethane resin
Kind is a variety of.
Further, the antioxidant be antioxidant 1222, it is AT-76, antioxidant 2246-S, AT-59, antioxidant 1035, anti-
In oxygen agent 1098, antioxidant 3125, TPP, TNPP, AT-168, antioxidant 245, GA-80, antioxidant 858, antioxidant 1010
It is one or more of.
Further, the coupling agent is organo silane coupling agent.
Further, the curing agent is peroxide -2-ethyl hexanoic acid tert-butyl, peroxidized t-butyl perbenzoate or peroxidating
One kind in benzoyl.
Further, the pigment is titanium dioxide, iron oxide yellow powder, iron oxide red, iron black powder, chrome green powder, Lan Shuizhong one kind or more
Kind.
The second object of the present invention, it is to provide the preparation method of above-mentioned artificial quartz stone plate.The preparation method of the present invention
Simple and environmentally-friendly saving, cost is low, suitable for industrialized production.
The technical scheme that the present invention solves above-mentioned technical problem is as follows：A kind of preparation side of anti-aging artificial quartz stone plate
Method, comprise the technical steps that：
Weigh the component of following parts by weight：It is 10~80 20~80 parts of mesh quartzs, 20~40 parts of 325 mesh silica flour, broken
5~9 parts of glass, 5~10 parts of unsaturated-resin, 0.2~1 part of antioxidant, 0.5~2 part of coupling agent, 5~15 parts of medical stone powder, cloud
0.2~0.6 part of 6~16 parts of female powder, 0.3~2 part of curing agent and pigment, above-mentioned each component are uniformly mixed, the thing that will be mixed
Expect it is evenly laid out making sheet mould is then sent into vacuum chamber, vacuumized, vibration moulding on making sheet mould, be re-fed into curing oven solidification,
Sheet material after solidification is come out of the stove the demoulding, after stacking cooling, is delivered to fixed thick polishing machine and is carried out fixed thickness, after the processing of surface sanding and polishing, i.e.,
Obtain the anti-aging artificial quartz stone plate.
On the basis of above-mentioned technical proposal, the present invention can also do following improvement.
Further, the pressure during vibration moulding is 2~4MPa, and molding time is 3~5 minutes.
Further, the temperature of the solidification is 85~95 DEG C, and the time is 35~45 minutes.
The beneficial effects of the invention are as follows：
(1) it is anti-aging：Antioxidant is with the addition of in the raw material of the present invention, improves the antioxygen of artificial quartz stone plate of the present invention
The ability of the property changed and antiultraviolet, has wider use.
(2) preparation method of the present invention is simple, suitable for industrialized production.
Embodiment
The principle and feature of the present invention are described below in conjunction with specific embodiment, example is served only for explaining this hair
It is bright, it is not intended to limit the scope of the present invention.
Embodiment 1：
The anti-aging artificial quartz stone plate of the present embodiment, is made up of the component of following weight：10~80 mesh quartzs
20kg, 325 mesh silica flour 40kg, cullet 5kg, epoxy resin 10kg, antioxidant 12220.2kg, organo silane coupling agent
2kg, medical stone powder 5kg, mica powder 16kg, peroxide -2-ethyl hexanoic acid tert-butyl 0.3kg and titanium dioxide 0.6kg.
The preparation method of the anti-aging artificial quartz stone plate of the present embodiment, is comprised the technical steps that：
Weigh the component of following weight：10~80 mesh quartz 20kg, 325 mesh silica flour 40kg, cullet 5kg, epoxy
Resin 10kg, antioxidant 12220.2kg, organo silane coupling agent 2kg, medical stone powder 5kg, mica powder 16kg, peroxidating -2- second
Base hecanoic acid t-butyl ester 0.3kg and titanium dioxide 0.6kg, above-mentioned each component is uniformly mixed, and is arrived the material mixed is evenly laid out
On making sheet mould, making sheet mould is then sent into vacuum chamber, vacuumized, when air pressure reaches -0.1MPa when vacuumizing, under 2MPa pressure
Vibration is molded for 5 minutes, is re-fed into curing oven solidification, 85 DEG C of solidification temperature, the time is 45 minutes, and the sheet material after solidification is come out of the stove de-
Mould, after stacking cooling, deliver to fixed thick polishing machine and carry out fixed thickness, after the processing of surface sanding and polishing, produce the anti-aging artificial stone
Diamond stone sheet material.
Embodiment 2：
The anti-aging artificial quartz stone plate of the present embodiment, is made up of the component of following weight：10~80 mesh quartzs
50kg, 325 mesh silica flour 30kg, cullet 7kg, epoxy resin 7kg, antioxidant 2246-S0.6kg, organo silane coupling agent
1kg, medical stone powder 10kg, mica powder 11kg, peroxidized t-butyl perbenzoate 1.2kg and iron oxide yellow powder 0.4kg.
The preparation method of the anti-aging artificial quartz stone plate of the present embodiment, is comprised the technical steps that：
Weigh the component of following weight：10~80 mesh quartz 50kg, 325 mesh silica flour 30kg, cullet 7kg, epoxy
Resin 7kg, antioxidant 2246-S 0.6kg, organo silane coupling agent 1kg, medical stone powder 10kg, mica powder 11kg, benzoyl peroxide
T-butyl formate 1.2kg and iron oxide yellow powder 0.4kg, above-mentioned each component is uniformly mixed, and the material mixed is evenly laid out to system
On template die, making sheet mould is then sent into vacuum chamber, vacuumizes, when air pressure reaches -0.1MPa when vacuumizing, is shaken under 3MPa pressure
It is molded within dynamic 4 minutes, is re-fed into curing oven solidification, 90 DEG C of solidification temperature, the time is 40 minutes, and the sheet material after solidification is come out of the stove the demoulding,
After stacking cooling, deliver to fixed thick polishing machine and carry out fixed thickness, after the processing of surface sanding and polishing, produce the anti-aging artificial quartz in lump
Sheet material.
Embodiment 3：
The anti-aging artificial quartz stone plate of the present embodiment, is made up of the component of following weight：10~80 mesh quartzs
80kg, 325 mesh silica flour 20kg, cullet 9kg, epoxy resin 5kg, antioxidant 1010 1kg, organo silane coupling agent 0.5kg,
Medical stone powder 15kg, mica powder 6kg, benzoyl peroxide 2kg and chrome green powder 0.2kg.
The preparation method of the anti-aging artificial quartz stone plate of the present embodiment, is comprised the technical steps that：
Weigh the component of following weight：10~80 mesh quartz 80kg, 325 mesh silica flour 20kg, cullet 9kg, epoxy
Resin 5kg, antioxidant 1010 1kg, organo silane coupling agent 0.5kg, medical stone powder 15kg, mica powder 6kg, benzoyl peroxide
2kg and chrome green powder 0.2kg, above-mentioned each component is uniformly mixed, and the material mixed is evenly laid out on making sheet mould, then will
Making sheet mould is sent into vacuum chamber, vacuumizes, and when air pressure reaches -0.1MPa when vacuumizing, vibrates 3 minutes and is molded under 4MPa pressure,
Curing oven solidification, 95 DEG C of solidification temperature are re-fed into, the time is 35 minutes, and the sheet material after solidification is come out of the stove the demoulding, is stacked after cooling down, is sent
Fixed thickness is carried out to fixed thick polishing machine, after the processing of surface sanding and polishing, produces the anti-aging artificial quartz stone plate.
Anti-aging artificial quartz stone plate obtained by embodiment 1-3 is subjected to conventional products performance detection, its testing result is such as
Table 1, examination criteria are：JC908-2002.
The properties of product of anti-aging artificial quartz stone plate obtained by the embodiment 1-3 of table 1
As can be seen here, antioxidant is with the addition of in raw material of the invention, improves the antioxygen of artificial quartz stone plate of the present invention
The ability of the property changed and antiultraviolet, has wider use.
The foregoing is only presently preferred embodiments of the present invention, be not intended to limit the invention, it is all the present invention spirit and
Within principle, any modification, equivalent substitution and improvements made etc., it should be included in the scope of the protection.
Claims (10)
1. a kind of anti-aging artificial quartz stone plate, it is characterised in that be made up of the component of following parts by weight：10~80 mesh stones
20~80 parts of diamond stone, 20~40 parts of 325 mesh silica flour, 5~9 parts of cullet, 5~10 parts of unsaturated-resin, antioxidant 0.2~1
Part, 0.5~2 part of coupling agent, 5~15 parts of medical stone powder, 6~16 parts of mica powder, 0.3~2 part of curing agent and pigment 0.2~0.6
Part.
2. a kind of anti-aging artificial quartz stone plate according to claim 1, it is characterised in that by following parts by weight
Component forms：10~80 50 parts of mesh quartzs, 30 parts of 325 mesh silica flour, 7 parts of cullet, 7 parts of unsaturated-resin, antioxidant 0.6
Part, 1 part of coupling agent, 10 parts of medical stone powder, 11 parts of mica powder, 1.2 parts of curing agent and 0.4 part of pigment.
A kind of 3. anti-aging artificial quartz stone plate according to claim 1 or 2, it is characterised in that the unsaturated tree
Fat is the one or more in epoxy resin, phenolic resin, acryl resin and polyurethane resin.
4. a kind of anti-aging artificial quartz stone plate according to claim 1 or 2, it is characterised in that the antioxidant is
Antioxidant 1222, AT-76, antioxidant 2246-S, AT-59, antioxidant 1035, antioxidant 1098, antioxidant 3125, TPP,
One or more in TNPP, AT-168, antioxidant 245, GA-80, antioxidant 858, antioxidant 1010.
5. a kind of anti-aging artificial quartz stone plate according to claim 1 or 2, it is characterised in that the coupling agent is
Organo silane coupling agent.
6. a kind of anti-aging artificial quartz stone plate according to claim 1 or 2, it is characterised in that the curing agent is
One kind in peroxide -2-ethyl hexanoic acid tert-butyl, peroxidized t-butyl perbenzoate or benzoyl peroxide.
7. a kind of anti-aging artificial quartz stone plate according to claim 1 or 2, it is characterised in that the pigment is titanium
White powder, iron oxide yellow powder, iron oxide red, iron black powder, chrome green powder, Lan Shuizhong one or more.
8. a kind of preparation method of anti-aging artificial quartz stone plate, it is characterised in that comprise the technical steps that：
Weigh the component of following parts by weight：10~80 20~80 parts of mesh quartzs, 20~40 parts of 325 mesh silica flour, cullet 5
~9 parts, 5~10 parts of unsaturated-resin, 0.2~1 part of antioxidant, 0.5~2 part of coupling agent, 5~15 parts of medical stone powder, mica powder 6
0.2~0.6 part of~16 parts, 0.3~2 part of curing agent and pigment, above-mentioned each component is uniformly mixed, and the material mixed is uniform
Tile onto making sheet mould, making sheet mould is then sent into vacuum chamber, vacuumized, vibration moulding, curing oven solidification is re-fed into, after solidification
Sheet material come out of the stove the demoulding, after stacking cooling, deliver to fixed thick polishing machine and carry out fixed thickness, after the processing of surface sanding and polishing, produce described
Anti-aging artificial quartz stone plate.
9. the preparation method of a kind of anti-aging artificial quartz stone plate according to claim 8, it is characterised in that described to shake
Pressure during dynamic shaping is 2~4MPa, and molding time is 3~5 minutes.
10. the preparation method of a kind of anti-aging artificial quartz stone plate according to claim 8, it is characterised in that described
The temperature of solidification is 85~95 DEG C, and the time is 35~45 minutes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711083166.4A CN107759133A (en) | 2017-11-07 | 2017-11-07 | A kind of anti-aging artificial quartz stone plate and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711083166.4A CN107759133A (en) | 2017-11-07 | 2017-11-07 | A kind of anti-aging artificial quartz stone plate and preparation method thereof |
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| CN107759133A true CN107759133A (en) | 2018-03-06 |
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| CN201711083166.4A Pending CN107759133A (en) | 2017-11-07 | 2017-11-07 | A kind of anti-aging artificial quartz stone plate and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109305772A (en) * | 2018-11-02 | 2019-02-05 | 广东雄杰建材有限公司 | A kind of low cost artificial quartz stone plate and preparation method thereof |
| CN112573861A (en) * | 2021-02-03 | 2021-03-30 | 湖北钊晟新材料科技有限公司 | Quartz stone plate with low expansion coefficient and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104478290A (en) * | 2014-12-15 | 2015-04-01 | 田忠和 | Anti-aging artificial quartz stone panel and preparation method thereof |
-
2017
- 2017-11-07 CN CN201711083166.4A patent/CN107759133A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104478290A (en) * | 2014-12-15 | 2015-04-01 | 田忠和 | Anti-aging artificial quartz stone panel and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109305772A (en) * | 2018-11-02 | 2019-02-05 | 广东雄杰建材有限公司 | A kind of low cost artificial quartz stone plate and preparation method thereof |
| CN112573861A (en) * | 2021-02-03 | 2021-03-30 | 湖北钊晟新材料科技有限公司 | Quartz stone plate with low expansion coefficient and preparation method thereof |
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Application publication date: 20180306 |
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