CN108793822A - A kind of artificial quartz plate and preparation method thereof - Google Patents
A kind of artificial quartz plate and preparation method thereof Download PDFInfo
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- CN108793822A CN108793822A CN201810740311.XA CN201810740311A CN108793822A CN 108793822 A CN108793822 A CN 108793822A CN 201810740311 A CN201810740311 A CN 201810740311A CN 108793822 A CN108793822 A CN 108793822A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/12—Condensation polymers of aldehydes or ketones
- C04B26/122—Phenol-formaldehyde condensation polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C67/00—Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00
- B29C67/24—Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00 characterised by the choice of material
- B29C67/242—Moulding mineral aggregates bonded with resin, e.g. resin concrete
- B29C67/243—Moulding mineral aggregates bonded with resin, e.g. resin concrete for making articles of definite length
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/045—Polyalkenes
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/06—Acrylates
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/14—Polyepoxides
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/16—Polyurethanes
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Structural Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
Abstract
The invention belongs to quartz material processing technique fields, more particularly to a kind of artificial quartz plate and preparation method thereof.Stain resistant agents are added on the basis of common synthetic quartz raw material in the present invention, by compression moulding, solidification, fixed thick and polishing treatment, the excellent artificial quartz plate of resistance to soiling is prepared, stain resistant agents of the present invention are pressed together with other raw materials, without subsequently smearing, preparation process is simple, is easy to industrialize.The artificial quartz plate hardness and toughness that the present invention is prepared are relatively high, and surface anti-pollution characteristic is preferable.
Description
Technical field
The invention belongs to quartzy processing technique fields, and in particular to a kind of artificial quartz plate and preparation method thereof.
Background technology
Currently, the stone material in stone material market is roughly divided into, lithotome and artificial stone's two major classes.Lithotome has granite
(various in style), marble etc., artificial stone have hilllock stone, quartz (also known as brilliant hilllock stone), microlite etc..Quartz is to use day
A kind of new polymeric materials that so quartz (particle and fine powder), resin and pigment are mixed and processed.Quartz designs and varieties are more,
Good decorating effect, hardness are high, wearability is good, pollution resistance is strong, anticorrosive, environmentally friendly, radiationless, high temperature resistant is indeformable, intensity is high, tough
Good, the easy connection of property.Compared to lithotome, quartz has the unique advantages such as nontoxic and pollution-free, rich in color；Compared to artificial
Hilllock stone, quartz have the advantages such as toughness height, high temperature resistant.Because have the advantages that lithotome and artificial hilllock stone it is incomparable and
Speciality, quartz has become the new lover in stone material market, widely used by construction market.Artificial quartz stone plate and artificial marble
Plank is compared, and has the characteristics that curvature is high, compressive strength is high, Mohs' hardness is high, water absorption rate is low, gradually by domestic and international vast use
Family is liked, and cabinet, bathroom, office and the ground of megastore, wall decoration and household industry are widely applied to.
But the shrinkage of existing Engineered stone products is higher, and ageing resistance and ultra-violet radiation resisting function are poor, production
Product under the strong light of long term outdoor using be easy to happen aging, colour changed into yellow, embrittlement, physical property and chemical property decline etc. asks
Topic so existing Engineered stone products can only be used as interior architecture ornament materials, and can not be used as outdoor architecture ornament materials to make
With seriously constraining the popularization and application of Engineered stone products.
Invention content
The object of the present invention is to provide a kind of artificial quartz plate and preparation method thereof, the present invention is in common synthetic quartz
Stain resistant agents are added on the basis of raw material, by compression moulding, solidification, fixed thick and polishing treatment, it is excellent that resistance to soiling is prepared
Artificial quartz plate, stain resistant agents of the present invention are pressed together with other raw materials, are smeared without follow-up, preparation process letter
It is single.
The technical scheme is that：
A kind of artificial quartz plate, component include quartz sand, silica flour, glass particle, resin, curing agent, coupling agent,
Colorant and stain resistant agents.
Preferably, above-mentioned people each group in quartzy plank is grouped into：Quartz sand 30-35 parts by weight, silica flour 25-30 weights
Measure part, glass particle 10-15 parts by weight, resin 10-15 parts by weight, curing agent 4-8 parts by weight, coupling agent 3-6 parts by weight, colorant
1.5-3.5 parts by weight, stain resistant agents 2.5-5.5 parts by weight.
Preferably, above-mentioned resin is epoxy resin, phenolic resin, acryl resin, polyurethane resin, acrylic acid tree
At least one of fat, polybutadiene or chloro unsaturated polyester resin.
Preferably, above-mentioned curing agent is azobisisoheptonitrile, cyclohexanone peroxide, peroxidating (2 ethyl hexanoic acid) tertiary fourth
At least one of ester, methyl ethyl ketone peroxide, peroxidized t-butyl perbenzoate, dibenzoyl peroxide and fat polyamine.
Preferably, above-mentioned coupling agent is at least one of silane coupling agent, aluminate coupling agent and titanate coupling agent.
Preferably, above-mentioned colorant be titanium dioxide, iron oxide yellow powder, iron oxide red, iron black powder, chrome green powder and Lan Shuizhong at least one
Kind.
Preferably, above-mentioned stain resistant agents are fluorine zirconic acid or polyvinyl alcohol.
The preparation method of above-mentioned artificial quartz plate, includes the following steps：
(1) by the quartz sand of the 80-120 mesh of 30-35 parts by weight, the 800-1000 mesh of 25-30 parts by weight silica flour and
It is uniformly mixing to obtain material one after the glass particle mixing of 10-15 parts by weight；
(2) 10-15 parts by weight resin, 4-8 parts by weight curing agent and 3-6 parts by weight coupling agents are added in material one,
It is uniformly mixing to obtain material two；
(3) 1.5-3.5 weight part of pigment and 2.5-5.5 parts by weight stain resistant agents are added in material two, are stirred evenly
To material three；
(4) material three is tiled onto making sheet mould, compression moulding under vacuum；
(5) by the material solidification after compression moulding, fixed thickness, then surface polishing treatment is carried out, obtains artificial quartz plate.
Preferably, in step (5), the cured temperature is 80~100 DEG C, and the time is 30~60 minutes.
Beneficial effects of the present invention are as follows：
Stain resistant agents are added on the basis of common synthetic quartz raw material in the present invention, by compression moulding, solidification, it is fixed thick and
Polishing treatment, is prepared the excellent artificial quartz plate of resistance to soiling, and stain resistant agents of the present invention are suppressed together with other raw materials
Molding is smeared without follow-up, and preparation process is simple, is easy to industrialize.Artificial quartz plate hardness that the present invention is prepared and
Toughness is relatively high, and surface anti-pollution characteristic is preferable.
Specific implementation mode
With reference to embodiment, technical scheme of the present invention is described in further detail, but do not constituted pair
Any restrictions of the present invention.
Embodiment 1
A kind of artificial quartz plate, component include the quartz of the quartz sand of 32 parts by weight, 80 mesh, 28 parts by weight, 800 mesh
Powder, 12 parts by weight of glass particles, 13 parts by weight epoxy resin and acryl resin, 6 parts by weight curing agent azobisisoheptonitrile and
Cyclohexanone peroxide, 5 parts by weight silane coupling agents and aluminate coupling agent, 1.5 parts by weight titanium dioxides and chrome green powder and 2.5 weights
Measure part stain resistant agents fluorine zirconic acid.
The preparation method of the artificial quartz plate includes the following steps：
(1) by the quartz sand of 80 mesh of 32 parts by weight, the glass of the silica flour and 12 parts by weight of 800 mesh of 28 parts by weight
It is uniformly mixing to obtain material one after grain mixing；
(2) by 13 parts by weight epoxy resin and acryl resin, 6 parts by weight curing agent azobisisoheptonitrile and peroxidating ring
Hexanone and 5 parts by weight silane coupling agents and aluminate coupling agent are added in material one, are uniformly mixing to obtain material two；
(3) 1.5 parts by weight titanium dioxides and chrome green powder and 2.5 parts by weight stain resistant agents fluorine zirconic acids are added in material two, are stirred
It mixes and uniformly obtains material three；
(4) material three is tiled onto making sheet mould, compression moulding under vacuum；
(5) material after compression moulding is cured 50 minutes at 80 DEG C, after stacking cooling, send to fixed thick polishing machine and carry out
Fixed thickness, to get artificial quartz stone plate after the processing of surface sanding and polishing.
Embodiment 2
A kind of artificial quartz plate, component include the quartz of the quartz sand of 34 parts by weight, 100 mesh, 27 parts by weight, 800 mesh
Powder, 14 parts by weight of glass particles, 11 parts by weight of phenolic resin, acryl resin and acrylic resin, 5 parts by weight curing agent peroxides
Change t-butyl perbenzoate and cyclohexanone peroxide, 4 parts by weight silane coupling agents and titanate coupling agent, 2 parts by weight iron oxide yellow powder and
Iron oxide red and 3 parts by weight stain resistant agents polyvinyl alcohol.
The preparation method of the artificial quartz plate includes the following steps：
(1) by the quartz sand of 100 mesh of 34 parts by weight, the glass of the silica flour and 14 parts by weight of 800 mesh of 27 parts by weight
It is uniformly mixing to obtain material one after particle mixing；
(2) by 11 parts by weight of phenolic resin, acryl resin and acrylic resin, 5 parts by weight curing agent benzoyl peroxide first
Tert-butyl acrylate and cyclohexanone peroxide and 4 parts by weight silane coupling agents and titanate coupling agent are added in material one, and stirring is equal
It is even to obtain material two；
(3) 2 parts by weight iron oxide yellow powder and iron oxide red and 3 parts by weight stain resistant agents polyvinyl alcohol are added in material two, are stirred
Uniformly obtain material three；
(4) material three is tiled onto making sheet mould, compression moulding under vacuum；
(5) material after compression moulding is cured 45 minutes at 100 DEG C, stack it is cooling after, send to fixed thick polishing machine into
The fixed thickness of row, to get artificial quartz stone plate after the processing of surface sanding and polishing.
Embodiment 3
A kind of artificial quartz plate, component include the quartz of the quartz sand of 31 parts by weight, 120 mesh, 26 parts by weight, 1000 mesh
Powder, 15 parts by weight of glass particles, 12 parts by weight epoxy resin, polybutadiene and chloro unsaturated polyester resin, 5 parts by weight
Curing agent peroxidating (2 ethyl hexanoic acid) tert-butyl ester and dibenzoyl peroxide, 4 parts by weight silane coupling agents, aluminate coupling agent
With metatitanic acid coupling agent, 2.5 parts by weight iron oxide black powder and 4.5 parts by weight stain resistant agents polyvinyl alcohol.
The preparation method of the artificial quartz plate includes the following steps：
(1) by the quartz sand of 120 mesh of 31 parts by weight, the glass of the silica flour and 15 parts by weight of 1000 mesh of 26 parts by weight
It is uniformly mixing to obtain material one after particle mixing；
(2) by 12 parts by weight epoxy resin, polybutadiene and chloro unsaturated polyester resin, 5 parts by weight curing agent
Peroxidating (2 ethyl hexanoic acid) tert-butyl ester and dibenzoyl peroxide and 4 parts by weight silane coupling agents, aluminate coupling agent and titanium
Sour coupling agent is added in material one, is uniformly mixing to obtain material two；
(3) 2.5 parts by weight iron oxide black powder and 4.5 parts by weight stain resistant agents polyvinyl alcohol are added in material two, are stirred evenly
Obtain material three；
(4) material three is tiled onto making sheet mould, compression moulding under vacuum；
(5) material after compression moulding is cured 60 minutes at 95 DEG C, after stacking cooling, send to fixed thick polishing machine and carry out
Fixed thickness, to get artificial quartz stone plate after the processing of surface sanding and polishing.
The above embodiment is a preferred embodiment of the present invention, but embodiments of the present invention are not by above-described embodiment
Limitation, it is other it is any without departing from the spirit and principles of the present invention made by changes, modifications, substitutions, combinations, simplifications,
Equivalent substitute mode is should be, is included within the scope of the present invention.
Claims (9)
1. a kind of artificial quartz plate, which is characterized in that the component in the artificial quartz plate include quartz sand, silica flour,
Glass particle, resin, curing agent, coupling agent, colorant and stain resistant agents.
2. a kind of artificial quartz plate according to claim 1, which is characterized in that each component in the artificial quartz plate
Group becomes：Quartz sand 30-35 parts by weight, silica flour 25-30 parts by weight, glass particle 10-15 parts by weight, resin 10-15 weight
Part, curing agent 4-8 parts by weight, coupling agent 3-6 parts by weight, colorant 1.5-3.5 parts by weight, stain resistant agents 2.5-5.5 parts by weight.
3. a kind of artificial quartz plate according to claim 1, which is characterized in that the resin is epoxy resin, phenol
In urea formaldehyde, acryl resin, polyurethane resin, acrylic resin, polybutadiene and chloro unsaturated polyester resin
It is at least one.
4. a kind of artificial quartz plate according to claim 1, which is characterized in that the curing agent is two different heptan of azo
Nitrile, cyclohexanone peroxide, peroxidating (2 ethyl hexanoic acid) tert-butyl ester, methyl ethyl ketone peroxide, peroxidized t-butyl perbenzoate, peroxide
Change at least one of dibenzoyl and fat polyamine.
5. a kind of artificial quartz plate according to claim 1, which is characterized in that the coupling agent be silane coupling agent,
At least one of aluminate coupling agent and titanate coupling agent.
6. a kind of artificial quartz plate according to claim 1, which is characterized in that the colorant be titanium dioxide, iron oxide yellow powder,
At least one of iron oxide red, iron black powder, chrome green powder and Lan Shui.
7. a kind of artificial quartz plate according to claim 1, which is characterized in that the stain resistant agents are fluorine zirconic acid or gather
Vinyl alcohol.
8. the preparation method of any artificial quartz plate in claim 1 to 7, which is characterized in that include the following steps：
(1) by the quartz sand of the 80-120 mesh of 30-35 parts by weight, the silica flour and 10-15 of the 800-1000 mesh of 25-30 parts by weight
It is uniformly mixing to obtain material one after the glass particle mixing of parts by weight；
(2) 10-15 parts by weight resin, 4-8 parts by weight curing agent and 3-6 parts by weight coupling agents are added in material one, are stirred
Uniformly obtain material two；
(3) 1.5-3.5 weight part of pigment and 2.5-5.5 parts by weight stain resistant agents are added in material two, are uniformly mixing to obtain object
Material three；
(4) material three is tiled onto making sheet mould, compression moulding under vacuum；
(5) by the material solidification after compression moulding, fixed thickness, then surface polishing treatment is carried out, obtains artificial quartz plate.
9. a kind of preparation method of synthetic quartz according to claim 8, which is characterized in that in step (5), the solidification
Temperature be 80~100 DEG C, the time be 30~60 minutes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810740311.XA CN108793822A (en) | 2018-07-07 | 2018-07-07 | A kind of artificial quartz plate and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810740311.XA CN108793822A (en) | 2018-07-07 | 2018-07-07 | A kind of artificial quartz plate and preparation method thereof |
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| CN108793822A true CN108793822A (en) | 2018-11-13 |
Family
ID=64075651
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| CN201810740311.XA Pending CN108793822A (en) | 2018-07-07 | 2018-07-07 | A kind of artificial quartz plate and preparation method thereof |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109516717A (en) * | 2018-11-02 | 2019-03-26 | 漳州市吉涵新型建材有限公司 | A kind of quartz plate preparation process |
| CN110451849A (en) * | 2019-08-02 | 2019-11-15 | 黄永西 | A kind of artificial stone formula and preparation method thereof |
| CN112299876A (en) * | 2020-07-20 | 2021-02-02 | 广东欧文莱陶瓷有限公司 | Process for preparing leather surface of artificial quartz stone plate |
| CN114315235A (en) * | 2022-01-13 | 2022-04-12 | 山东康洁利新材料有限公司 | Production method of artificial quartz stone stain-resistant plate |
| CN114477884A (en) * | 2022-02-15 | 2022-05-13 | 肇庆市帝帆新型材料有限公司 | Artificial stone and preparation method thereof |
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| CN104478293A (en) * | 2014-12-15 | 2015-04-01 | 田忠和 | Synthetic quartzite plate and preparation method thereof |
| CN104478290A (en) * | 2014-12-15 | 2015-04-01 | 田忠和 | Anti-aging artificial quartz stone panel and preparation method thereof |
| CN104496271A (en) * | 2014-12-15 | 2015-04-08 | 田忠和 | Artificial quartzite plate and manufacturing method thereof |
| CN107555843A (en) * | 2017-09-27 | 2018-01-09 | 佛山市欧泊石业有限公司 | A kind of artificial quartz stone plate |
| CN107555842A (en) * | 2017-09-27 | 2018-01-09 | 佛山市欧泊石业有限公司 | A kind of new artificial quartz stone plate |
| CN107628767A (en) * | 2017-10-26 | 2018-01-26 | 石家庄多邦晶岗石有限公司 | A kind of method for preparing artificial quartz in lump and its manufactured artificial quartz in lump |
| CN107805002A (en) * | 2017-11-06 | 2018-03-16 | 佛山市欧泊石业有限公司 | A kind of preparation method of resistant artificial quartz stone plate |
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| CN104478293A (en) * | 2014-12-15 | 2015-04-01 | 田忠和 | Synthetic quartzite plate and preparation method thereof |
| CN104478290A (en) * | 2014-12-15 | 2015-04-01 | 田忠和 | Anti-aging artificial quartz stone panel and preparation method thereof |
| CN104496271A (en) * | 2014-12-15 | 2015-04-08 | 田忠和 | Artificial quartzite plate and manufacturing method thereof |
| CN107555843A (en) * | 2017-09-27 | 2018-01-09 | 佛山市欧泊石业有限公司 | A kind of artificial quartz stone plate |
| CN107555842A (en) * | 2017-09-27 | 2018-01-09 | 佛山市欧泊石业有限公司 | A kind of new artificial quartz stone plate |
| CN107628767A (en) * | 2017-10-26 | 2018-01-26 | 石家庄多邦晶岗石有限公司 | A kind of method for preparing artificial quartz in lump and its manufactured artificial quartz in lump |
| CN107805002A (en) * | 2017-11-06 | 2018-03-16 | 佛山市欧泊石业有限公司 | A kind of preparation method of resistant artificial quartz stone plate |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109516717A (en) * | 2018-11-02 | 2019-03-26 | 漳州市吉涵新型建材有限公司 | A kind of quartz plate preparation process |
| CN110451849A (en) * | 2019-08-02 | 2019-11-15 | 黄永西 | A kind of artificial stone formula and preparation method thereof |
| CN112299876A (en) * | 2020-07-20 | 2021-02-02 | 广东欧文莱陶瓷有限公司 | Process for preparing leather surface of artificial quartz stone plate |
| CN112299876B (en) * | 2020-07-20 | 2022-03-11 | 广东欧文莱陶瓷有限公司 | Process for preparing leather surface of artificial quartz stone plate |
| CN114315235A (en) * | 2022-01-13 | 2022-04-12 | 山东康洁利新材料有限公司 | Production method of artificial quartz stone stain-resistant plate |
| CN114477884A (en) * | 2022-02-15 | 2022-05-13 | 肇庆市帝帆新型材料有限公司 | Artificial stone and preparation method thereof |
| CN114477884B (en) * | 2022-02-15 | 2023-01-24 | 肇庆市帝帆新型材料有限公司 | Artificial stone and preparation method thereof |
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Application publication date: 20181113 |
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| RJ01 | Rejection of invention patent application after publication |