CN105819740A - Self-enhanced ceramic cold glaze and preparation method thereof - Google Patents

Self-enhanced ceramic cold glaze and preparation method thereof Download PDF

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Publication number
CN105819740A
CN105819740A CN201610143659.1A CN201610143659A CN105819740A CN 105819740 A CN105819740 A CN 105819740A CN 201610143659 A CN201610143659 A CN 201610143659A CN 105819740 A CN105819740 A CN 105819740A
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China
Prior art keywords
lustre
pearly
glaze
stone plate
dye grain
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CN201610143659.1A
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Chinese (zh)
Inventor
周军
胡国强
张韡
蒋陈富
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GUANGDONG BANNER NEW MATERIAL TECHNOLOGY Co Ltd
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GUANGDONG BANNER NEW MATERIAL TECHNOLOGY Co Ltd
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Priority to CN201610143659.1A priority Critical patent/CN105819740A/en
Publication of CN105819740A publication Critical patent/CN105819740A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/04Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/06Acrylates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/10Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/12Condensation polymers of aldehydes or ketones
    • C04B26/122Phenol-formaldehyde condensation polymers
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/10Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/14Polyepoxides
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/10Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/16Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/10Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/18Polyesters; Polycarbonates

Abstract

The invention provides a self-enhanced ceramic cold glaze and a preparation method thereof. The cold glaze is prepared by the following steps: preparing the following raw materials: phosphate/polyphosphates, meta-kaolin, silicon dioxide, zinc oxide, sodium silicate, an alkaline compound, and water, mixing raw materials according to a certain ratio, evenly stirring the mixture by a mechanical stirrer to form slurry, evenly painting the slurry on a blank, which needs to be decorated, and drying the blank at a room temperature or low temperature (40 to 100 DEG C). The glaze, which is obtained by the provided formula and preparation method, can be used to repair the glaze of blanks made of various porcelains. The glaze and the blank interface are well combined together. The glaze has excellent mechanical properties, the compressive strength can reach 150 MPa or more, the surface of the glaze is smooth, the color is white-grey and transparent, no defect exist on the surface, and the market needs can be met. Compared with the conventional glaze production technology, the provided preparation method has the advantages of simple technology, energy saving, environment-friendliness, low cost, and easy operation.

Description

A kind of pearly-lustre dye grain artificial quartz stone plate and preparation method thereof
Technical field
The invention belongs to quartz technical field, specifically, relate to a kind of pearly-lustre dye grain artificial quartz stone plate and preparation method thereof.
Background technology
Artificial quartz in lump is to be main stuffing by quartz sand powder, using unsaturated polyester resin as binding agent, under vacuum condition, high pressure is compressing, the Novel stone of setting under the condition of high temperature, and it is a kind of "dead" pollution, the environmental protection of repeatable utilization, green building material and ornament materials.Quartz product with the artificial quartz in lump product of monochrome type, dual color version is in the majority in the market.Monochromatic artificial quartz in lump product color is dull, and majority of case will carry out modular design with using varicolored plain quarz stone, has both limited the popularization of quartz, also result in the waste of material.
Along with the raising of people's aesthetic level, increasing client is more likely to select the quartzite slate of double-colored even polychrome type to decorate household.For a long time, dual color version quartz due to complex process, production efficiency is low, and sheet material color in pressing process easily interpenetrates, and fraction defective is high, thus causes the supply of material few, and price is high.
It is therefore desirable to existing production technology is carried out upgrading or technological transformation.
Summary of the invention
Instant invention overcomes shortcoming of the prior art, it is provided that a kind of pearly-lustre dye grain artificial quartz stone plate and preparation method thereof, product design is attractive in appearance, and production efficiency is high, and qualification rate is high.
In order to solve above-mentioned technical problem, the present invention is achieved by the following technical solutions:
A kind of pearly-lustre dye grain artificial quartz stone plate, its raw material includes: 0.075~5mm particulate material, 0.07~0.7mm decorate coloured pearl essence, 0.005~0.045mm silica flour, colored pigment, silane coupler, unsaturated polyester resin, firming agent, accelerator.
Wherein, particulate material is quartz particles or glass particle, or the mixture of two kinds.
Further, according to percentage by weight, 0.045~5mm particulate material 40%~64%, 0.07~0.7mm pearly-lustre dye grain 1%~15%;0.005~0.045mm silica flour 20%~30%;Colored pigment 0.01%~3%;Silane coupler 0.1%~1%;Unsaturated polyester resin 8%~14%;Firming agent 0.8%~1.4%.
Further, according to percentage by weight, pearly-lustre dye grain: 0.68~5mm glass particle 70%~90%, 0.15~0.68mm quartz granule 5%~15%, 0.07~0.7mm decorates coloured pearl essence 1%~5%, unsaturated polyester resin 1%~5%, silane coupler 0.1%~1%, firming agent 0.015%~0.075%, accelerator 0.01%~0.05%.
Further, described colored pigment is one or more of inorganic pigment or organic pigment or mill base.
Further, described inorganic pigment is the inorganic pigments such as titanium white, medium chrome yellow, iron oxide yellow, iron oxide red, barba hispanica, cadmium red, cadmium yellow, white carbon black, iron oxide black, described organic pigment is the organic pigments such as red, azophosphine, phthalein viridescent and phthalocyanine blue, and described mill base is the mill bases such as white slurry, black wash, bright red slurry, phthalein viridescent slurry, phthalocyanine blue slurry.
Further, one or more during described unsaturated polyester resin can also be epoxy resin, phenolic resin, acrylic resin and polyurethane resin.
Further, one or more during described firming agent is peroxidating (2 ethyl hexanoic acid) tert-butyl ester, methyl ethyl ketone peroxide, peroxidized t-butyl perbenzoate, dibenzoyl peroxide and fat polyamine.
Further, described silane coupler is one or more in γ-methacryloxypropyl trimethoxy silane, γ-(2,3-epoxy the third oxygen) propyl trimethoxy silicane, N-β (aminoethyl)-γ-aminopropyltriethoxy dimethoxysilane, N-(β-aminoethyl)-gamma-aminopropyl-triethoxy-silane, N-β (aminoethyl)-γ-aminopropyltrimethoxysilane, anilinomethyl triethoxysilane, gamma-aminopropyl-triethoxy-silane, VTES, vinyltrimethoxy silane and γ-chloropropyl triethoxysilane.
Further, described accelerator is cobalt naphthenate, cobalt iso-octoate, zinc Isoocatanoate, DMA, N, N-diethylaniline, vanadium phosphate one or more.
The preparation method of a kind of pearly-lustre dye grain artificial quartz stone plate, comprises the following steps:
(2) each component is weighed according to formula.
(2) preparation of pearly-lustre dye grain: 1. the premixing in double planetary agitator of the glass particle weighed, silane coupler is obtained a material;Unsaturated polyester resin, firming agent, accelerator, the coloured pearl essence of decoration are obtained b material in agitator premixing;Again b material is poured in the double planetary agitator of a material and mix, then add quartz particles and mix.
2. heat cure: enter curing apparatus, solidifies at a temperature of 80~130 DEG C, and hardening time is for for 60~90 minutes.
3. sieve: quartz particles sieve is gone, obtain pearly-lustre dye grain.
(3) stirring: by the quartz particles weighed, glass particle, silane coupler premixing in double planetary agitator;The firming agent mixed, decoration colored pigment and unsaturated polyester resin are poured in double planetary agitator and mixed, is subsequently adding silica flour and mixes, finally add pearly-lustre dye grain and mix.Stirring frequency 15~55Hz, mixing time 180~600s.
(4) cloth: material step (3) mixed is sent into beater and broken up further, after breaing up, cloth in electronic measurement enters material distributing machine.
(5) compacting: after cloth completes, repressed vibration equipment is compressing under the vacuum condition of-0.1Mpa, pressure 50~200t, frequency of vibration 30~55Hz, the time 60~600s;
(6) heat cure: after vibration compacting, entering curing apparatus, solidify at a temperature of 80~130 DEG C, hardening time is 30~180 minutes;
(7), after having solidified, room temperature is placed the rear sheet material thicknessing machine that enters to be cooled and is determined thickness, then is polished through water mill polissoir.
Compared with prior art, the invention has the beneficial effects as follows:
A kind of pearly-lustre dye grain artificial quartz stone plate of the present invention, it is handsome in appearance, and pattern is distinct, and color is unique, enriches kind and the style of artificial quartz in lump, and production efficiency is high simultaneously, effectively reduces the fraction defective of product, can mass production.
Detailed description of the invention
Hereinafter the preferred embodiments of the present invention are illustrated, it will be appreciated that preferred embodiment described herein is merely to illustrate and explains the present invention, is not intended to limit the present invention.
A kind of pearly-lustre dye grain artificial quartz stone plate of the present invention, its raw material includes: 0.075~5mm particulate material, 0.07~0.7mm decorate coloured pearl essence, 0.005~0.045mm silica flour, colored pigment, silane coupler, unsaturated polyester resin, firming agent, accelerator.
Wherein, particulate material is quartz particles or glass particle, or the mixture of two kinds.
0.045~5mm particulate material 55%, 0.07~0.7mm pearly-lustre dye grain 12%;0.005~0.045mm silica flour 21%;Colored pigment 1.5%;Silane coupler 0.5%;Unsaturated polyester resin 9%;Firming agent 1%.
Pearly-lustre dye grain: 0.68~5mm glass particle 82%, 0.15~0.68mm quartz granule 10%, 0.07~0.7mm decorates coloured pearl essence 4%, unsaturated polyester resin 3.72%, silane coupler 0.2%, firming agent 0.05%, accelerator 0.03%.
Colored pigment is one or more of inorganic pigment or organic pigment or mill base.
Inorganic pigment is titanium white, medium chrome yellow, iron oxide yellow, iron oxide red, iron oxide black, and organic pigment is red, phthalein viridescent or phthalocyanine blue, and mill base is white slurry, black wash, bright red slurry, phthalein viridescent slurry or phthalocyanine blue slurry.
Unsaturated polyester resin can also be one or more in epoxy resin, phenolic resin, acrylic resin and polyurethane resin.
Firming agent is one or more in peroxidating (2 ethyl hexanoic acid) tert-butyl ester, methyl ethyl ketone peroxide, peroxidized t-butyl perbenzoate, dibenzoyl peroxide and fat polyamine.
Silane coupler is one or more in γ-methacryloxypropyl trimethoxy silane, γ-(2,3-epoxy the third oxygen) propyl trimethoxy silicane, N-β (aminoethyl)-γ-aminopropyltriethoxy dimethoxysilane, N-(β-aminoethyl)-gamma-aminopropyl-triethoxy-silane, N-β (aminoethyl)-γ-aminopropyltrimethoxysilane, anilinomethyl triethoxysilane, gamma-aminopropyl-triethoxy-silane, VTES, vinyltrimethoxy silane and γ-chloropropyl triethoxysilane.
Accelerator is cobalt naphthenate, cobalt iso-octoate, zinc Isoocatanoate, DMA, N, N-diethylaniline, vanadium phosphate one or more.
The preparation method of a kind of pearly-lustre dye grain artificial quartz stone plate, comprises the following steps:
(3) each component is weighed according to formula.
(2) preparation of pearly-lustre dye grain: 1. the premixing in double planetary agitator of the glass particle weighed, silane coupler is obtained a material;Unsaturated polyester resin, firming agent, accelerator, the coloured pearl essence of decoration are obtained b material in agitator premixing;Again b material is poured in the double planetary agitator of a material and mix, then add quartz particles and mix.
2. heat cure: enter curing apparatus, solidifies at a temperature of 80~130 DEG C, and hardening time is 60~90 minutes.
3. sieve: quartz particles sieve is gone, obtain pearly-lustre dye grain.
(3) stirring: by the quartz particles weighed, glass particle, silane coupler premixing in double planetary agitator;The firming agent mixed, decoration colored pigment and unsaturated polyester resin are poured in double planetary agitator and mixed, is subsequently adding silica flour and mixes, finally add pearly-lustre dye grain and mix.Stirring frequency 15~55Hz, mixing time 180~600s.
(4) cloth: material step (3) mixed is sent into beater and broken up further, after breaing up, cloth in electronic measurement enters material distributing machine.
(5) compacting: after cloth completes, repressed vibration equipment is compressing under the vacuum condition of-0.1Mpa, pressure 50~200t, frequency of vibration 30~55Hz, the time 60~600s;
(6) heat cure: after vibration compacting, entering curing apparatus, solidify at a temperature of 80~130 DEG C, hardening time is 30~180 minutes;
(7), after having solidified, room temperature is placed the rear sheet material thicknessing machine that enters to be cooled and is determined thickness, then is polished through water mill polissoir.
Last it is noted that these are only the preferred embodiments of the present invention; it is not limited to the present invention; although the present invention being described in detail with reference to embodiment; for a person skilled in the art; technical scheme described in foregoing embodiments still can be modified by it; or wherein portion of techniques feature is carried out equivalent; but all within the spirit and principles in the present invention; the any modification, equivalent substitution and improvement etc. made, should be included within the scope of the present invention.

Claims (10)

1. a pearly-lustre dye grain artificial quartz stone plate, it is characterised in that: its raw material includes: 0.075~5mm particulate material, 0.07~0.7mm decorate coloured pearl essence, 0.005~0.045mm silica flour, colored pigment, silane coupler, unsaturated polyester resin, firming agent, accelerator;
Wherein, particulate material is quartz particles or glass particle, or the mixture of two kinds.
A kind of pearly-lustre dye grain artificial quartz stone plate, it is characterised in that: according to percentage by weight, 0.045~5mm particulate material 40%~64%, 0.07~0.7mm pearly-lustre dye grain 1%~15%;0.005~0.045mm silica flour 20%~30%;Colored pigment 0.01%~3%;Silane coupler 0.1%~1%;Unsaturated polyester resin 8%~14%;Firming agent 0.8%~1.4%.
A kind of pearly-lustre dye grain artificial quartz stone plate, it is characterized in that: according to percentage by weight, described pearly-lustre dye grain: 0.68~5mm glass particle 75%~90%, 0.15~0.68mm quartz granule 5%~15%, 0.07~0.7mm decorates coloured pearl essence 1%~5%, unsaturated polyester resin 1%~5%, silane coupler 0.1%~1%, firming agent 0.015%~0.075%, accelerator 0.01%~0.05%.
A kind of pearly-lustre dye grain artificial quartz stone plate, it is characterised in that: described colored pigment is one or more of inorganic pigment or organic pigment or mill base.
A kind of pearly-lustre dye grain artificial quartz stone plate, it is characterized in that: described inorganic pigment is titanium white, medium chrome yellow, iron oxide yellow, iron oxide red, barba hispanica, cadmium red, cadmium yellow, white carbon black, iron oxide black, described organic pigment is red, azophosphine, phthalein viridescent and phthalocyanine blue, and described mill base is white slurry, black wash, bright red slurry, phthalein viridescent slurry, phthalocyanine blue slurry.
A kind of pearly-lustre dye grain artificial quartz stone plate, it is characterised in that: described unsaturated polyester resin can also be one or more in epoxy resin, phenolic resin, acrylic resin and polyurethane resin.
A kind of pearly-lustre dye grain artificial quartz stone plate, it is characterised in that: described firming agent is one or more in peroxidating (2 ethyl hexanoic acid) tert-butyl ester, methyl ethyl ketone peroxide, peroxidized t-butyl perbenzoate, dibenzoyl peroxide and fat polyamine.
8. the preparation method of a pearly-lustre dye grain artificial quartz stone plate, it is characterized in that: described silane coupler is γ-methacryloxypropyl trimethoxy silane, γ-(2, 3-epoxy the third oxygen) propyl trimethoxy silicane, N-β (aminoethyl)-γ-aminopropyltriethoxy dimethoxysilane, N-(β-aminoethyl)-gamma-aminopropyl-triethoxy-silane, N-β (aminoethyl)-γ-aminopropyltrimethoxysilane, anilinomethyl triethoxysilane, gamma-aminopropyl-triethoxy-silane, VTES, one or more in vinyltrimethoxy silane and γ-chloropropyl triethoxysilane.
9. the preparation method of pearly-lustre dye grain artificial quartz stone plate, it is characterised in that: described accelerator is cobalt naphthenate, cobalt iso-octoate, zinc Isoocatanoate, DMA, N, N-diethylaniline, vanadium phosphate one or more.
10. the preparation method of a pearly-lustre dye grain artificial quartz stone plate, it is characterised in that: comprise the following steps:
(1) each component is weighed according to formula;
(2) preparation of pearly-lustre dye grain: 1. the premixing in double planetary agitator of the glass particle weighed, silane coupler is obtained a material;Unsaturated polyester resin, firming agent, accelerator, the coloured pearl essence of decoration are obtained b material in agitator premixing;Again b material is poured in the double planetary agitator of a material and mix, then add quartz particles and mix;
2. heat cure: enter curing apparatus, solidifies at a temperature of 80~130 DEG C, and hardening time is for for 60~90 minutes;
3. sieve: quartz particles sieve is gone, obtain pearly-lustre dye grain;
(3) stirring: by the quartz particles weighed, glass particle, silane coupler premixing in double planetary agitator;The firming agent mixed, decoration colored pigment and unsaturated polyester resin are poured in double planetary agitator and mixed, is subsequently adding silica flour and mixes, finally add pearly-lustre dye grain and mix, stirring frequency 15~55Hz, mixing time 180~600s;
(4) cloth: material step (3) mixed is sent into beater and broken up further, after breaing up, cloth in electronic measurement enters material distributing machine;
(5) compacting: after cloth completes, repressed vibration equipment is compressing under the vacuum condition of-0.1Mpa, pressure 50~200t, frequency of vibration 30~55Hz, the time 60~600s;
(6) heat cure: after vibration compacting, entering curing apparatus, solidify at a temperature of 80~130 DEG C, hardening time is 30~180 minutes;
(7), after having solidified, room temperature is placed the rear sheet material thicknessing machine that enters to be cooled and is determined thickness, then is polished through water mill polissoir.
CN201610143659.1A 2016-03-14 2016-03-14 Self-enhanced ceramic cold glaze and preparation method thereof Pending CN105819740A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106866033A (en) * 2017-03-17 2017-06-20 广东必图新材料科技股份有限公司 A kind of artificial quartz in lump leopard card and preparation method thereof
CN106866034A (en) * 2017-03-22 2017-06-20 佛山市蓝瑞欧特信息服务有限公司 A kind of fluorescent artificial stone diamond stone sheet material and preparation method thereof
CN106866030A (en) * 2017-03-22 2017-06-20 佛山市蓝瑞欧特信息服务有限公司 A kind of water-fast artificial quartz in lump and preparation method thereof
CN111847987A (en) * 2020-08-04 2020-10-30 广东原创新材料科技有限公司 Whole-body pearl artificial stone and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101700966A (en) * 2009-12-02 2010-05-05 黑龙江省木材科学研究所 Aspen wood shavings and vermiculite composite thermal insulation materials and preparation method thereof
CN102491681A (en) * 2011-12-06 2012-06-13 湖南文象炭基环保材料股份有限公司 Preparation method of carbon-based plate
CN104478299A (en) * 2014-11-21 2015-04-01 广东中旗新材料科技有限公司 Double-pattern artificial quartz stone plate and production process thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101700966A (en) * 2009-12-02 2010-05-05 黑龙江省木材科学研究所 Aspen wood shavings and vermiculite composite thermal insulation materials and preparation method thereof
CN102491681A (en) * 2011-12-06 2012-06-13 湖南文象炭基环保材料股份有限公司 Preparation method of carbon-based plate
CN104478299A (en) * 2014-11-21 2015-04-01 广东中旗新材料科技有限公司 Double-pattern artificial quartz stone plate and production process thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106866033A (en) * 2017-03-17 2017-06-20 广东必图新材料科技股份有限公司 A kind of artificial quartz in lump leopard card and preparation method thereof
CN106866034A (en) * 2017-03-22 2017-06-20 佛山市蓝瑞欧特信息服务有限公司 A kind of fluorescent artificial stone diamond stone sheet material and preparation method thereof
CN106866030A (en) * 2017-03-22 2017-06-20 佛山市蓝瑞欧特信息服务有限公司 A kind of water-fast artificial quartz in lump and preparation method thereof
CN111847987A (en) * 2020-08-04 2020-10-30 广东原创新材料科技有限公司 Whole-body pearl artificial stone and preparation method thereof

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