CN101700966A - Aspen wood shavings and vermiculite composite thermal insulation materials and preparation method thereof - Google Patents

Aspen wood shavings and vermiculite composite thermal insulation materials and preparation method thereof Download PDF

Info

Publication number
CN101700966A
CN101700966A CN200910310765A CN200910310765A CN101700966A CN 101700966 A CN101700966 A CN 101700966A CN 200910310765 A CN200910310765 A CN 200910310765A CN 200910310765 A CN200910310765 A CN 200910310765A CN 101700966 A CN101700966 A CN 101700966A
Authority
CN
China
Prior art keywords
wood shavings
aspen wood
thermal insulation
insulation materials
composite thermal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN200910310765A
Other languages
Chinese (zh)
Other versions
CN101700966B (en
Inventor
何灵芝
宋希元
崔立东
曾春雷
张长武
毕克新
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
HEILONGJIANG INSTITUTE OF WOOD SCIENCE
Original Assignee
HEILONGJIANG INSTITUTE OF WOOD SCIENCE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by HEILONGJIANG INSTITUTE OF WOOD SCIENCE filed Critical HEILONGJIANG INSTITUTE OF WOOD SCIENCE
Priority to CN2009103107654A priority Critical patent/CN101700966B/en
Publication of CN101700966A publication Critical patent/CN101700966A/en
Application granted granted Critical
Publication of CN101700966B publication Critical patent/CN101700966B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/10Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/12Condensation polymers of aldehydes or ketones
    • C04B26/127Urea formaldehyde condensation polymers
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/10Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/12Condensation polymers of aldehydes or ketones
    • C04B26/122Phenol-formaldehyde condensation polymers
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/10Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/12Condensation polymers of aldehydes or ketones
    • C04B26/125Melamine-formaldehyde condensation polymers
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00017Aspects relating to the protection of the environment
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00034Physico-chemical characteristics of the mixtures
    • C04B2111/00094Sag-resistant materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/28Fire resistance, i.e. materials resistant to accidental fires or high temperatures
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/34Non-shrinking or non-cracking materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/50Flexible or elastic materials
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

Abstract

The invention provides aspen wood shavings and vermiculite composite thermal insulation materials and a preparation method thereof and relates to composite thermal insulation materials and the preparation method thereof. The invention solves the problem that the current polystyrene foam thermal insulation materials have high cost, low bending resistance strength and difficult recycling. The composite thermal insulation materials in the invention are prepared by aspen wood shavings, vermiculite and adhesive. The preparation method is as follows: throwing the aspen wood shavings into a stirrer for stirring and spraying adhesive when stirring; adding vermiculite and stirring to obtain evenly mixed material; paving the mixed material onto the plate blank; and adopting high-frequency heating and pressurizing to obtain the aspen wood shavings and vermiculite composite thermal insulation materials. The inner bonding strength of the aspen wood shavings and vermiculite composite thermal insulation materials obtained in the invention is greater than or equal to 150 kPa, and the aspen wood shavings and vermiculite composite thermal insulation materials can be recovered and recycled. The invention adopts low-priced aspen wood as raw materials and has the advantages of simple structure, high yield and no environmental pollution.

Description

Aspen wood shavings and vermiculite composite thermal insulation materials and preparation method thereof
Technical field
The present invention relates to a kind of compound insulating material and preparation method thereof.
Background technology
Existing polystyrene foam heat insulation material is bigger at the amount ratio in a lot of fields, and its consumption is also increasing year by year.Though polystyrene foam heat insulation material market amount ratio is bigger, also there are shortcomings such as this height, bending strength low (about 100KPa), recycling are difficult and seriously polluted.
Summary of the invention
Technical problem to be solved by this invention is that existing polystyrene foam heat insulation material cost height, bending strength are low in order to solve, the recycling problem of difficulty, and a kind of Aspen wood shavings and vermiculite composite thermal insulation materials and preparation method thereof are provided.
Aspen wood shavings of the present invention and vermiculite composite thermal insulation materials are made by 20~90 weight part Aspen wood shavings, 10~80 weight part vermiculites and 8~25 weight part tackiness agent by ratio of weight and the number of copies; Described tackiness agent is urea-formaldehyde resin, resol or melamine resin; The granularity of described vermiculite is 1mm~8mm; The screening value of described Aspen wood shavings is 6 orders~80 orders, and water ratio is 2%~15% (mass percent).
The preparation method of Aspen wood shavings of the present invention and vermiculite composite thermal insulation materials is as follows: one, get 20~90 parts of Aspen wood shavings, 10~80 parts of vermiculites and 10~25 parts of tackiness agent by weight; Two, Aspen wood shavings is put in the stirrer and to be stirred 3 minutes~5 minutes, spray paste stick in the time of stirring adds vermiculite then and stirred 1 minute, obtains uniform batch mixing; Three, step 2 gained batch mixing being mated formation into slab, is 0.1kg/cm in unit pressure then 2~15kg/cm 2, frequency is under the condition of 6.7MHz~13.6MHz, with the rate of heating heating of 0.2 ℃~0.5 ℃ of per second 5 minutes~15 minutes, pressurize was 5 minutes again, promptly gets Aspen wood shavings and vermiculite composite thermal insulation materials; Tackiness agent described in the step 1 is urea-formaldehyde resin, resol or melamine resin; The screening value of Aspen wood shavings described in the step 1 is 6 orders~80 orders, and water ratio is 2%~15% (mass percent); The granularity of vermiculite described in the step 1 is 1mm~8mm.
The Aspen wood shavings of gained of the present invention and the thermal conductivity≤0.065W/mK of vermiculite composite thermal insulation materials, internal bond strength 〉=150KPa, flame retardancy B 1Level, linear shrinkage≤5%.The Aspen wood shavings of gained of the present invention and vermiculite composite thermal insulation materials have the advantage of insulation, sound insulation, difficult combustion, high temperature resistant (200 ℃), absorption ray, damping, also has higher intensity, thereby having enlarged the use range of compound insulating material, the Aspen wood shavings and the vermiculite composite thermal insulation materials of gained of the present invention can reclaim, recycle simultaneously.The present invention adopts cheap poplar as starting material, has that method is easy, yield rate is high, the advantage of non-environmental-pollution.
Embodiment
Technical solution of the present invention is not limited to following cited embodiment, also comprises the arbitrary combination between each embodiment.
Embodiment one: Aspen wood shavings and vermiculite composite thermal insulation materials are made by 20~90 weight part Aspen wood shavings, 10~80 weight part vermiculites and 8~25 weight part tackiness agent by ratio of weight and the number of copies in the present embodiment.
The Aspen wood shavings of present embodiment gained and the thermal conductivity≤0.065W/mK of vermiculite composite thermal insulation materials, internal bond strength 〉=150KPa, flame retardancy B 1Level, linear shrinkage≤5%.
Embodiment two: what present embodiment and embodiment one were different is that described tackiness agent is urea-formaldehyde resin, resol or melamine resin.Other is identical with embodiment one.
The Aspen wood shavings of present embodiment gained and the thermal conductivity of vermiculite composite thermal insulation materials are that 0.064W/mK, internal bond strength are 160KPa, flame retardancy B 1Level, linear shrinkage are 4%.
Embodiment three: present embodiment is different with embodiment one or two is that the granularity of described vermiculite is 1mm~8mm.Other is identical with embodiment one or two.
The Aspen wood shavings of present embodiment gained and the thermal conductivity of vermiculite composite thermal insulation materials are that 0.063W/mK, internal bond strength are 170KPa, flame retardancy B 1Level, linear shrinkage are 3%.
Embodiment four: present embodiment and embodiment one to three are different is that Aspen wood shavings and vermiculite composite thermal insulation materials are by ratio of weight and the number of copies by 25~85 weight part Aspen wood shavings, make for, 15~75 weight part vermiculites with for, 10~20 weight part tackiness agent.Other is identical with embodiment one to three.
The Aspen wood shavings of present embodiment gained and the thermal conductivity of vermiculite composite thermal insulation materials are that 0.062W/mK, internal bond strength are 180KPa, flame retardancy B 1Level, linear shrinkage are 2%.
Embodiment five: what present embodiment and embodiment one to three were different is that Aspen wood shavings and vermiculite composite thermal insulation materials are made by 30~80 weight part Aspen wood shavings, 20~70 weight part vermiculites and 12~18 weight part tackiness agent by ratio of weight and the number of copies.Other is identical with embodiment one to three.
The Aspen wood shavings of present embodiment gained and the thermal conductivity of vermiculite composite thermal insulation materials are that 0.061W/mK, internal bond strength are 190KPa, flame retardancy B 1Level, linear shrinkage are 1%.
Embodiment six: what present embodiment and embodiment one to three were different is that Aspen wood shavings and vermiculite composite thermal insulation materials are made by 50 weight part Aspen wood shavings, 50 weight part vermiculites and 15 weight part tackiness agent by ratio of weight and the number of copies.Other is identical with embodiment one to three.
The Aspen wood shavings of present embodiment gained and the thermal conductivity of vermiculite composite thermal insulation materials are that 0.060W/mK, internal bond strength are 200KPa, flame retardancy B 1Level, linear shrinkage are 1.5%.
Embodiment seven: present embodiment and embodiment one to six are different is that the screening value of described Aspen wood shavings is 6 orders~80 orders, and water ratio is 2%~15% (mass percent).Other is identical with embodiment one to six.
The Aspen wood shavings of present embodiment gained and the thermal conductivity of vermiculite composite thermal insulation materials are that 0.059W/mK, internal bond strength are 210KPa, flame retardancy B 1Level, linear shrinkage are 2.5%.
Embodiment eight: the preparation method of Aspen wood shavings and vermiculite composite thermal insulation materials is as follows in the present embodiment: one, get 20~90 parts of Aspen wood shavings, 10~80 parts of vermiculites and 10~25 parts of tackiness agent by weight; Two, Aspen wood shavings is put in the stirrer and to be stirred 3 minutes~5 minutes, spray paste stick in the time of stirring adds vermiculite then and stirred 1 minute, obtains uniform batch mixing; Three, step 2 gained batch mixing being mated formation into thickness is 3 times of slabs to nominal thickness, is 0.1kg/cm in unit pressure then 2~15kg/cm 2, frequency is under the condition of 6.7MHz~13.6MHz, with the rate of heating heating of 0.2 ℃~0.5 ℃ of per second 5 minutes~15 minutes, pressurize was 5 minutes again, promptly gets Aspen wood shavings and vermiculite composite thermal insulation materials.
The Aspen wood shavings of present embodiment gained and the thermal conductivity≤0.065W/mK of vermiculite composite thermal insulation materials, internal bond strength 〉=150KPa, flame retardancy B 1Level, linear shrinkage≤5%.
Embodiment nine: what present embodiment and embodiment eight were different is that the tackiness agent described in the step 1 is urea-formaldehyde resin, resol or melamine resin.Other is identical with embodiment eight.
The Aspen wood shavings of present embodiment gained and the thermal conductivity of vermiculite composite thermal insulation materials are that 0.064W/mK, internal bond strength are 160KPa, flame retardancy B 1Level, linear shrinkage are 4%.
Embodiment ten: present embodiment is different with embodiment eight or nine is that the screening value of Aspen wood shavings described in the step 1 is 6 orders~80 orders, and water ratio is 2%~15% (mass percent).Other is identical with embodiment eight or nine.
The Aspen wood shavings of present embodiment gained and the thermal conductivity of vermiculite composite thermal insulation materials are that 0.063W/mK, internal bond strength are 170KPa, flame retardancy B 1Level, linear shrinkage are 3%.
Embodiment 11: present embodiment and embodiment eight to ten are different is that the granularity of vermiculite described in the step 1 is 1mm~8mm.Other is identical with embodiment eight to ten.
The Aspen wood shavings of present embodiment gained and the thermal conductivity of vermiculite composite thermal insulation materials are that 0.062W/mK, internal bond strength are 180KPa, flame retardancy B 1Level, linear shrinkage are 2%.
Embodiment 12: the preparation method of Aspen wood shavings and vermiculite composite thermal insulation materials is as follows in the present embodiment: one, get 30 parts of Aspen wood shavings, 60 parts of vermiculites and 15 parts of urea-formaldehyde resins by weight; Two, Aspen wood shavings is put in the stirrer and to be stirred 3 minutes, spray urea-formaldehyde resin in the time of stirring, add vermiculite then and stirred 1 minute, obtain uniform batch mixing; Three, step 2 gained batch mixing being mated formation into thickness is 3 times of slabs to nominal thickness, is 0.1kg/cm in unit pressure then 2, frequency is under the condition of 6.7MHz, with the rate of heating heating of 0.2 ℃ of per second 5 minutes, pressurize was 5 minutes again, promptly gets Aspen wood shavings and vermiculite composite thermal insulation materials.
The Aspen wood shavings of present embodiment gained and the thermal conductivity of vermiculite composite thermal insulation materials are that 0.061W/mK, internal bond strength are 190KPa, flame retardancy B 1Level, linear shrinkage are 1%.
Embodiment 13: the preparation method of Aspen wood shavings and vermiculite composite thermal insulation materials is as follows in the present embodiment: one, get 40 parts of Aspen wood shavings, 50 parts of vermiculites and 15 parts of resol by weight; Two, Aspen wood shavings is put in the stirrer and to be stirred 4 minutes, spray resol in the time of stirring, add vermiculite then and stirred 1 minute, obtain uniform batch mixing; Three, step 2 gained batch mixing being mated formation into thickness is 3 times of slabs to nominal thickness, is 12kg/cm in unit pressure then 2, frequency is under the condition of 11MHz, with the rate of heating heating of 0.3 ℃ of per second 10 minutes, pressurize was 5 minutes again, promptly gets Aspen wood shavings and vermiculite composite thermal insulation materials.
The Aspen wood shavings of present embodiment gained and the thermal conductivity of vermiculite composite thermal insulation materials are that 0.060W/mK, internal bond strength are 200KPa, flame retardancy B 1Level, linear shrinkage are 1.5%.
Embodiment 14: the preparation method of Aspen wood shavings and vermiculite composite thermal insulation materials is as follows in the present embodiment: one, get 60 parts of Aspen wood shavings, 60 parts of vermiculites and 20 parts of resol by weight; Two, Aspen wood shavings is put in the stirrer and to be stirred 3.5 minutes, spray resol in the time of stirring, add vermiculite then and stirred 1 minute, obtain uniform batch mixing; Three, step 2 gained batch mixing being mated formation into thickness is 3 times of slabs to nominal thickness, is 14kg/cm in unit pressure then 2, frequency is under the condition of 8MHz, with the rate of heating heating of 0.4 ℃ of per second 8 minutes, pressurize was 5 minutes again, promptly gets Aspen wood shavings and vermiculite composite thermal insulation materials.
The Aspen wood shavings of present embodiment gained and the thermal conductivity of vermiculite composite thermal insulation materials are that 0.059W/mK, internal bond strength are 210KPa, flame retardancy B 1Level, linear shrinkage are 2.5%.
Embodiment 15: the preparation method of Aspen wood shavings and vermiculite composite thermal insulation materials is as follows in the present embodiment: one, get 70 parts of Aspen wood shavings, 80 parts of vermiculites and 25 parts of urea-formaldehyde resins by weight; Two, Aspen wood shavings is put in the stirrer and to be stirred 5 minutes, spray urea-formaldehyde resin in the time of stirring, add vermiculite then and stirred 1 minute, obtain uniform batch mixing; Three, step 2 gained batch mixing being mated formation into thickness is 3 times of slabs to nominal thickness, is 10kg/cm in unit pressure then 2, frequency is under the condition of 10MHz, with the rate of heating heating of 0.5 ℃ of per second 15 minutes, pressurize was 5 minutes again, promptly gets Aspen wood shavings and vermiculite composite thermal insulation materials.
The Aspen wood shavings of present embodiment gained and the thermal conductivity of vermiculite composite thermal insulation materials are that 0.063W/mK, internal bond strength are 180KPa, flame retardancy B 1Level, linear shrinkage are 2.5%.
Embodiment 16: the preparation method of Aspen wood shavings and vermiculite composite thermal insulation materials is as follows in the present embodiment: one, get 30 parts of Aspen wood shavings, 55 parts of vermiculites and 19 parts of melamine resins by weight; Two, Aspen wood shavings is put in the stirrer and to be stirred 4.5 minutes, spray melamine resin in the time of stirring, add vermiculite then and stirred 1 minute, obtain uniform batch mixing; Three, step 2 gained batch mixing being mated formation into thickness is 3 times of slabs to nominal thickness, is 0.8kg/cm in unit pressure then 2, frequency is under the condition of 8MHz, with the rate of heating heating of 0.4 ℃ of per second 12 minutes, pressurize was 5 minutes again, promptly gets Aspen wood shavings and vermiculite composite thermal insulation materials.
The Aspen wood shavings of present embodiment gained and the thermal conductivity of vermiculite composite thermal insulation materials are that 0.062W/mK, internal bond strength are 190KPa, flame retardancy B 1Level, linear shrinkage are 2.2%.
Embodiment 17: the preparation method of Aspen wood shavings and vermiculite composite thermal insulation materials is as follows in the present embodiment: one, get 75 parts of Aspen wood shavings, 56 parts of vermiculites and 16 parts of melamine resins by weight; Two, Aspen wood shavings is put in the stirrer and to be stirred 3 minutes~5 minutes, spray melamine resin in the time of stirring, add vermiculite then and stirred 1 minute, obtain uniform batch mixing; Three, step 2 gained batch mixing being mated formation into thickness is 3 times of slabs to nominal thickness, is 6kg/cm in unit pressure then 2, frequency is under the condition of 7.3MHz, with the rate of heating heating of 0.3 ℃ of per second 13 minutes, pressurize was 5 minutes again, promptly gets Aspen wood shavings and vermiculite composite thermal insulation materials.
The Aspen wood shavings of present embodiment gained and the thermal conductivity of vermiculite composite thermal insulation materials are that 0.061W/mK, internal bond strength are 200KPa, flame retardancy B 1Level, linear shrinkage are 2.8%.

Claims (8)

1. Aspen wood shavings and vermiculite composite thermal insulation materials is characterized in that Aspen wood shavings and vermiculite composite thermal insulation materials made by 20~90 weight part Aspen wood shavings, 10~80 weight part vermiculites and 8~25 weight part tackiness agent by ratio of weight and the number of copies.
2. Aspen wood shavings according to claim 1 and vermiculite composite thermal insulation materials is characterized in that described tackiness agent is urea-formaldehyde resin, resol or melamine resin.
3. Aspen wood shavings according to claim 1 and 2 and vermiculite composite thermal insulation materials, the granularity that it is characterized in that described vermiculite is 1mm~8mm.
4. Aspen wood shavings according to claim 1 and 2 and vermiculite composite thermal insulation materials, the screening value that it is characterized in that described Aspen wood shavings are 6 orders~80 orders, and water ratio is 2%~15%.
5. the preparation method of described Aspen wood shavings of claim 1 and vermiculite composite thermal insulation materials is characterized in that the preparation method of Aspen wood shavings and vermiculite composite thermal insulation materials is as follows: one, get 20~90 parts of Aspen wood shavings, 10~80 parts of vermiculites and 10~25 parts of tackiness agent by weight; Two, Aspen wood shavings is put in the stirrer and to be stirred 3 minutes~5 minutes, spray paste stick in the time of stirring adds vermiculite then and stirred 1 minute, obtains uniform batch mixing; Three, step 2 gained batch mixing is mated formation into slab, be that 0.1kg/cm2~15kg/cm2, frequency are under the condition of 6.7MHz~13.6MHz in unit pressure then, rate of heating with 0.2 ℃~0.5 ℃ of per second heated 5 minutes~15 minutes, pressurize is 5 minutes again, promptly gets Aspen wood shavings and vermiculite composite thermal insulation materials.
6. the preparation method of Aspen wood shavings according to claim 5 and vermiculite composite thermal insulation materials is characterized in that the tackiness agent described in the step 1 is urea-formaldehyde resin, resol or melamine resin.
7. according to the preparation method of claim 5 or 6 described Aspen wood shavings and vermiculite composite thermal insulation materials, the screening value that it is characterized in that Aspen wood shavings described in the step 1 is 6 orders~80 orders, and water ratio is 2%~15%.
8. the preparation method of Aspen wood shavings according to claim 7 and vermiculite composite thermal insulation materials, the granularity that it is characterized in that vermiculite described in the step 1 is 1mm~8mm.
CN2009103107654A 2009-12-02 2009-12-02 Preparation method of aspen wood shavings and vermiculite composite thermal insulation materials Expired - Fee Related CN101700966B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2009103107654A CN101700966B (en) 2009-12-02 2009-12-02 Preparation method of aspen wood shavings and vermiculite composite thermal insulation materials

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2009103107654A CN101700966B (en) 2009-12-02 2009-12-02 Preparation method of aspen wood shavings and vermiculite composite thermal insulation materials

Publications (2)

Publication Number Publication Date
CN101700966A true CN101700966A (en) 2010-05-05
CN101700966B CN101700966B (en) 2012-05-02

Family

ID=42155899

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2009103107654A Expired - Fee Related CN101700966B (en) 2009-12-02 2009-12-02 Preparation method of aspen wood shavings and vermiculite composite thermal insulation materials

Country Status (1)

Country Link
CN (1) CN101700966B (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102557529A (en) * 2012-02-27 2012-07-11 尤志萍 Vermiculite composite thermal insulation material
CN104496373A (en) * 2014-11-27 2015-04-08 太仓顺如成建筑材料有限公司 Sound-insulation novel building material
CN105819740A (en) * 2016-03-14 2016-08-03 广东中旗新材料科技有限公司 Self-enhanced ceramic cold glaze and preparation method thereof

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1067639A (en) * 1991-06-10 1993-01-06 山东建筑材料工业学院 Fire-retarding compound board made of plant fabric and raw-vermiculite
CN1088158A (en) * 1992-12-12 1994-06-22 易县科学技术委员会 A kind of light thermal insulation board
RU2283294C2 (en) * 2004-04-07 2006-09-10 Институт химии и химической технологии СО РАН Composition for manufacturing organomineral fertilizer
CN100396459C (en) * 2006-10-27 2008-06-25 吉发 Fire-resistant-chipboard and its manufacturing method

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102557529A (en) * 2012-02-27 2012-07-11 尤志萍 Vermiculite composite thermal insulation material
CN102557529B (en) * 2012-02-27 2013-08-28 尤志萍 Vermiculite composite thermal insulation material
CN104496373A (en) * 2014-11-27 2015-04-08 太仓顺如成建筑材料有限公司 Sound-insulation novel building material
CN105819740A (en) * 2016-03-14 2016-08-03 广东中旗新材料科技有限公司 Self-enhanced ceramic cold glaze and preparation method thereof

Also Published As

Publication number Publication date
CN101700966B (en) 2012-05-02

Similar Documents

Publication Publication Date Title
CN102504557B (en) Low-density wood-plastic composite shaving board and manufacture method thereof
CN103396650B (en) A kind of modified alkyd resin based friction material
CN105108868B (en) The method and particieboard of particieboard are prepared using waste and old indoor heat-treated wood
CN102408672B (en) Production method for cardanol modified phenolic resin
CN103568385A (en) Heat-preservation hard composite carbon fiber felt and preparation method thereof
CN102153718B (en) Heat-resistant phenolic resin and application thereof in production of super-hard material resin mold
CN101700966B (en) Preparation method of aspen wood shavings and vermiculite composite thermal insulation materials
CN101962971B (en) Phenolic foam insulation board for high-strength walls and manufacturing method thereof
CN104985648B (en) Flame-retardant composite board, its preparation method and the application of a kind of particle containing phenol formaldehyde foam
CN107325766A (en) The production technology of the low high moisture resistant chipboard adhesive of aldehyde and its application
CN105295740B (en) The liquid adhesive and wood-based plate processing method of a kind of no aldehyde
CN104070717B (en) Chromatic steel sandwich plate and its preparation method
CN101195232A (en) Rice-wheat haulm plywood and process technique thereof
CN102303433B (en) Production method for multilayer composite flame-retardant fireproof heat insulation board and product
CN108214808B (en) Preparation method of pyrolytic oil phenolic resin ecological bamboo powder brick
CN105255115A (en) Thermosetting resin system composite material capable of being re-molded by being heated and preparation method thereof
CN102555009A (en) High-strength environment-friendly shaving board
CN104212123A (en) Composite alkaline phenolic resin curing agent, preparation method and application
CN103978550B (en) The preparation method of building exterior wall heat preserving template and the building exterior wall heat preserving template of preparation
CN102069525B (en) Process and device for manufacturing thick fiber board by high frequency-contact combined heating mode
CN101775220B (en) Method for preparing electric insulating glue
CN108705646A (en) Rice and kernel straw fire-retardation artificial board and preparation method thereof
CN106751454A (en) A kind of superthin section emery wheel liquid phenolic resin and preparation method thereof
CN103015620A (en) Preparation method of glass fiber reinforced plastic foam sandwich panel
CN105291241A (en) High-strength environment-friendly shaving board

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
C17 Cessation of patent right
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20120502

Termination date: 20121202