CN105819747A - Artificial quartz stone sheet material with linear patterns and production technology thereof - Google Patents

Artificial quartz stone sheet material with linear patterns and production technology thereof Download PDF

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Publication number
CN105819747A
CN105819747A CN201610143665.7A CN201610143665A CN105819747A CN 105819747 A CN105819747 A CN 105819747A CN 201610143665 A CN201610143665 A CN 201610143665A CN 105819747 A CN105819747 A CN 105819747A
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China
Prior art keywords
color
sheet material
pigment
decorative pattern
inorganic pigment
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Pending
Application number
CN201610143665.7A
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Chinese (zh)
Inventor
周军
胡国强
张韡
蒋陈富
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GUANGDONG BANNER NEW MATERIAL TECHNOLOGY Co Ltd
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GUANGDONG BANNER NEW MATERIAL TECHNOLOGY Co Ltd
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Priority to CN201610143665.7A priority Critical patent/CN105819747A/en
Publication of CN105819747A publication Critical patent/CN105819747A/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02—Macromolecular compounds
    • C04B26/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02—Macromolecular compounds
    • C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/12—Condensation polymers of aldehydes or ketones
    • C04B26/122—Phenol-formaldehyde condensation polymers
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02—Macromolecular compounds
    • C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/14—Polyepoxides
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02—Macromolecular compounds
    • C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/16—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02—Macromolecular compounds
    • C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/18—Polyesters; Polycarbonates

Abstract

The invention discloses an artificial quartz stone sheet material with linear patterns and a production technology thereof. The sheet material comprises a main material with an A color and a pattern material with a B color. The main material comprises a granular raw material with a size of 0.075 to 5 mm, quartz powder with a size of 0.005 to 0.045 mm; color pigment, a silane coupling agent, unsaturated polyester resin, and a curing agent. The pattern material comprises an inorganic pigment, or comprises an inorganic pigment and quartz powder with a size of 0.045 to 0.212 mm. The granular raw material is quartz particles or glass particles. The artificial quartz stone, which is produced by mixing two materials, has the advantages of beauty, distinctive patterns, and unique color. The species and patterns of artificial quartz stone are enriched, at the same time, the production efficiency is high, the reject rate is effectively reduced, and the sheet material can be massively produced.

Description

A kind of linear textured man-made stone diamond stone sheet material and production technology thereof
Technical field
The invention belongs to quartz technical field, specifically, relate to a kind of linear textured man-made stone diamond stone sheet material and production technology thereof.
Background technology
In building decoration field, the stone material feature such as by force attractive in appearance with it, graceful, ornamental has become one of primary decoration material.All the time, natural marble figue is abundant, natural, extensively applied because of its natural decorative effect, texture, but owing to there is resource-constrained, there is aberration in large area paving and radioactivity in various degree exceeds standard, the problems such as hardness is low, easy scratching, limit its omnibearing development to a certain extent.
Artificial quartz in lump is to be main stuffing by quartz sand powder, using unsaturated polyester resin as binding agent, the Novel stone of setting under high pressure temperature state compressing, middle under vacuum condition, it is a kind of "dead" pollution, the environmental protection of repeatable utilization, green building material and ornament materials.
Although artificial quartz in lump rich color is gorgeous, radiationless, wear-resisting, pressure, anti scuffing, anticorrosive, aging resistance, impermeable, but owing to not having marmorean native texture and color, artificial quartz in lump class is made to can not get big raising.Having the diamond plate of imitating natural marble the most both at home and abroad, but color is the most stiff, texture is unnatural.Meanwhile, pattern type artificial quartz stone plate is due to complex process, and production efficiency is low, and sheet material color in pressing process easily interpenetrates, and fraction defective is high, thus causes the supply of material few, and price is high.
Therefore, it is necessary to existing production technology is carried out upgrading or technological transformation.
Summary of the invention
Instant invention overcomes shortcoming of the prior art, it is provided that a kind of linear textured man-made stone diamond stone sheet material with natural stone texture and production technology thereof, good product performance, production efficiency is high, and qualification rate is high.
In order to solve above-mentioned technical problem, the present invention is achieved by the following technical solutions:
A kind of linear textured man-made stone diamond stone sheet material, including major ingredient A color, decorative pattern material B color,
The raw material of described major ingredient A color includes 0.075～5mm particulate material, 0.005～0.045mm silica flour；Colored pigment；Silane coupler；Unsaturated polyester resin；Firming agent；
Component and the proportioning of decorative pattern material B color be: inorganic pigment；Or inorganic pigment, 0.045～0.212mm silica flour；
Wherein, particulate material is quartz particles or glass particle, or the mixture of two kinds.
Further, described major ingredient A color is 98～99.8 parts of total material, and decorative pattern material B color is 0.1～2 part of total material.
Further, described major ingredient A color includes according to percentage by weight: 0.075～5mm particulate material 55%～65%；0.005～0.045mm silica flour 20%～30%；Colored pigment 0.01%～3%；Silane coupler 0.1%～1%；Unsaturated polyester resin 8%～14%；Firming agent 0.8%～1.4%.
Further, according to percentage by weight, component and the proportioning of described decorative pattern material B color be: inorganic pigment 100%；Or inorganic pigment 1%～30%, 0.045～0.212mm silica flour 70%～99%.
Further, one or more during described unsaturated polyester resin can also be epoxy resin, phenolic resin, acrylic resin and polyurethane resin.
Further, described colored pigment is one or more of inorganic pigment or organic pigment or mill base.
Further, described inorganic pigment is the inorganic pigments such as titanium white, medium chrome yellow, iron oxide yellow, iron oxide red, barba hispanica, cadmium red, cadmium yellow, white carbon black, iron oxide black, described organic pigment is the organic pigments such as red, azophosphine, phthalein viridescent and phthalocyanine blue, and described mill base is the mill bases such as white slurry, black wash, bright red slurry, phthalein viridescent slurry, phthalocyanine blue slurry.
Further, one or more during described firming agent is peroxidating (2 ethyl hexanoic acid) tert-butyl ester, methyl ethyl ketone peroxide, peroxidized t-butyl perbenzoate, dibenzoyl peroxide and fat polyamine.
Further, described silane coupler is one or more in γ-methacryloxypropyl trimethoxy silane, γ-(2,3-epoxy the third oxygen) propyl trimethoxy silicane, N-β (aminoethyl)-γ-aminopropyltriethoxy dimethoxysilane, N-(β-aminoethyl)-gamma-aminopropyl-triethoxy-silane, N-β (aminoethyl)-γ-aminopropyltrimethoxysilane, anilinomethyl triethoxysilane, gamma-aminopropyl-triethoxy-silane, VTES, vinyltrimethoxy silane and γ-chloropropyl triethoxysilane.
The production technology of a kind of linear textured man-made stone diamond stone sheet material, comprises the following steps:
(1) each material each component is weighed according to formula；
(2) stirring: the quartz particles of major ingredient A color that 1. step (1) weighed, glass particle, silane coupler premixing in double planetary agitator；The firming agent mixed, decoration colored pigment and unsaturated polyester resin are poured in double planetary agitator and mixed, is subsequently adding silica flour and mixes.Stirring frequency 15～55Hz, mixing time 180～600s；
2. decorative pattern material B colorant rubs material uniformly by manually sieving；
(3) distributing mode 1: in the compound during 1. color patterned for B material is spread to；Batch mixing is sent in charge car by distributing belt, then is evenly arranged by batch mixing framed with cloth interior by charge car；
Distributing mode 2: batch mixing is sent in charge car by distributing belt, then batch mixing is evenly arranged framed with cloth interior by charge car, meanwhile the color patterned material of B is fallen within the compound that belt transmits by the vibration screen vibrosieve of vibrating distributor；The mace of rotation additionally according to lines Len req, can be set up for breaing up decorative pattern material；
(4) compacting: after cloth completes, repressed vibration equipment is compressing under the vacuum condition of-0.1Mpa, pressure 50～200t, frequency of vibration 30～55Hz, the time 60～600s；
(5) heat cure: after vibration compacting, entering curing apparatus, solidify at a temperature of 80～130 DEG C, hardening time is 30～180 minutes；
(6), after having solidified, room temperature is placed the rear sheet material thicknessing machine that enters to be cooled and is determined thickness, then is polished through water mill polissoir.
Compared with prior art, the invention has the beneficial effects as follows:
A kind of linear textured man-made stone diamond stone sheet material of the present invention and production technology thereof, the artificial quartz in lump made is handsome in appearance, and pattern is distinct, color is unique, enriches kind and the style of artificial quartz in lump, and production efficiency is high simultaneously, effectively reduce the fraction defective of product, can mass production.
Detailed description of the invention
Hereinafter the preferred embodiments of the present invention are illustrated, it will be appreciated that preferred embodiment described herein is merely to illustrate and explains the present invention, is not intended to limit the present invention.
A kind of linear textured man-made stone diamond stone sheet material of the present invention, including major ingredient A color, decorative pattern material B color.
Major ingredient A color includes according to percentage by weight: 0.075～5mm particulate material 63%；0.005～0.045mm silica flour 26%；Colored pigment 1.5%；Silane coupler 0.6%；Unsaturated polyester resin 8%；Firming agent 0.9%.
According to percentage by weight, component and the proportioning of decorative pattern material B color be: inorganic pigment 100%；Or inorganic pigment 25%, 0.045～0.212mm silica flour 75%；
Wherein, particulate material is quartz particles or glass particle, or the mixture of two kinds.
Major ingredient A color is 99 parts of total material, and decorative pattern material B color is 1 part of total material.
Unsaturated polyester resin can also be one or more in epoxy resin, phenolic resin, acrylic resin and polyurethane resin.
Colored pigment is one or more of inorganic pigment or organic pigment or mill base.
Inorganic pigment is titanium white, medium chrome yellow, iron oxide yellow, iron oxide red or iron oxide black, and organic pigment is red, phthalein viridescent or phthalocyanine blue, and mill base is white slurry, black wash, bright red slurry, phthalein viridescent slurry or phthalocyanine blue slurry.
Firming agent is one or more in peroxidating (2 ethyl hexanoic acid) tert-butyl ester, methyl ethyl ketone peroxide, peroxidized t-butyl perbenzoate, dibenzoyl peroxide and fat polyamine.
Silane coupler is one or more in γ-methacryloxypropyl trimethoxy silane, γ-(2,3-epoxy the third oxygen) propyl trimethoxy silicane, N-β (aminoethyl)-γ-aminopropyltriethoxy dimethoxysilane, N-(β-aminoethyl)-gamma-aminopropyl-triethoxy-silane, N-β (aminoethyl)-γ-aminopropyltrimethoxysilane, anilinomethyl triethoxysilane, gamma-aminopropyl-triethoxy-silane, VTES, vinyltrimethoxy silane and γ-chloropropyl triethoxysilane.
The production technology of a kind of linear textured man-made stone diamond stone sheet material, comprises the following steps:
(1) each material each component is weighed according to formula；
(2) stirring: the quartz particles of major ingredient A color that 1. step (1) weighed, glass particle, silane coupler premixing in double planetary agitator；The firming agent mixed, decoration colored pigment and unsaturated polyester resin are poured in double planetary agitator and mixed, is subsequently adding silica flour and mixes.Stirring frequency 15～55Hz, mixing time 180～600s；
2. decorative pattern material B colorant rubs material uniformly by manually sieving；
(3) distributing mode 1: in the compound during 1. color patterned for B material is spread to；Batch mixing is sent in charge car by distributing belt, then is evenly arranged by batch mixing framed with cloth interior by charge car；
Distributing mode 2: batch mixing is sent in charge car by distributing belt, then batch mixing is evenly arranged framed with cloth interior by charge car, meanwhile the color patterned material of B is fallen within the compound that belt transmits by the vibration screen vibrosieve of vibrating distributor；The mace of rotation additionally according to lines Len req, can be set up for breaing up decorative pattern material；
(4) compacting: after cloth completes, repressed vibration equipment is compressing under the vacuum condition of-0.1Mpa, pressure 50～200t, frequency of vibration 30～55Hz, the time 60～600s；
(5) heat cure: after vibration compacting, entering curing apparatus, solidify at a temperature of 80～130 DEG C, hardening time is 30～180 minutes；
(6), after having solidified, room temperature is placed the rear sheet material thicknessing machine that enters to be cooled and is determined thickness, then is polished through water mill polissoir.
Last it is noted that these are only the preferred embodiments of the present invention; it is not limited to the present invention; although the present invention being described in detail with reference to embodiment; for a person skilled in the art; technical scheme described in foregoing embodiments still can be modified by it; or wherein portion of techniques feature is carried out equivalent; but all within the spirit and principles in the present invention; the any modification, equivalent substitution and improvement etc. made, should be included within the scope of the present invention.

Claims (10)

1. a linear textured man-made stone diamond stone sheet material, it is characterised in that: include major ingredient A color, decorative pattern material B color,
The raw material of described major ingredient A color includes 0.075～5mm particulate material, 0.005～0.045mm silica flour；Colored pigment；Silane coupler；Unsaturated polyester resin；Firming agent；
Component and the proportioning of decorative pattern material B color be: inorganic pigment；Or inorganic pigment, 0.045～0.212mm silica flour；
Wherein, particulate material is quartz particles or glass particle, or the mixture of two kinds.
A kind of linear textured man-made stone diamond stone sheet material, it is characterised in that: described major ingredient A color is 98～99.8 parts of total material, and decorative pattern material B color is 0.1～2 part of total material.
A kind of linear textured man-made stone diamond stone sheet material, it is characterised in that: described major ingredient A color includes according to percentage by weight: 0.075～5mm particulate material 55%～65%；0.005～0.045mm silica flour 20%～30%；Colored pigment 0.01%～3%；Silane coupler 0.1%～1%；Unsaturated polyester resin 8%～14%；Firming agent 0.8%～1.4%.
A kind of linear textured man-made stone diamond stone sheet material, it is characterised in that: according to percentage by weight, component and the proportioning of described decorative pattern material B color be: inorganic pigment 100%；Or inorganic pigment 1%～30%, 0.045～0.212mm silica flour 70%～99%.
A kind of linear textured man-made stone diamond stone sheet material, it is characterised in that: described unsaturated polyester resin can also be one or more in epoxy resin, phenolic resin, acrylic resin and polyurethane resin.
A kind of linear textured man-made stone diamond stone sheet material, it is characterised in that: described colored pigment is one or more of inorganic pigment or organic pigment or mill base.
A kind of linear textured man-made stone diamond stone sheet material, it is characterized in that: described inorganic pigment is the inorganic pigments such as titanium white, medium chrome yellow, iron oxide yellow, iron oxide red, barba hispanica, cadmium red, cadmium yellow, white carbon black, iron oxide black, described organic pigment is red, azophosphine, phthalein viridescent and phthalocyanine blue, and described mill base is white slurry, black wash, bright red slurry, phthalein viridescent slurry, phthalocyanine blue slurry.
A kind of linear textured man-made stone diamond stone sheet material, it is characterised in that: described firming agent is one or more in peroxidating (2 ethyl hexanoic acid) tert-butyl ester, methyl ethyl ketone peroxide, peroxidized t-butyl perbenzoate, dibenzoyl peroxide and fat polyamine.
A kind of linear textured man-made stone diamond stone sheet material, it is characterized in that: described silane coupler is γ-methacryloxypropyl trimethoxy silane, γ-(2, 3-epoxy the third oxygen) propyl trimethoxy silicane, N-β (aminoethyl)-γ-aminopropyltriethoxy dimethoxysilane, N-(β-aminoethyl)-gamma-aminopropyl-triethoxy-silane, N-β (aminoethyl)-γ-aminopropyltrimethoxysilane, anilinomethyl triethoxysilane, gamma-aminopropyl-triethoxy-silane, VTES, one or more in vinyltrimethoxy silane and γ-chloropropyl triethoxysilane.
A kind of production technology of linear textured man-made stone diamond stone sheet material, it is characterised in that: comprise the following steps:
(1) each material each component is weighed according to formula；
(2) stirring: the quartz particles of major ingredient A color that 1. step (1) weighed, glass particle, silane coupler premixing in double planetary agitator；The firming agent mixed, decoration colored pigment and unsaturated polyester resin are poured in double planetary agitator and mixed, is subsequently adding silica flour and mixes, stirring frequency 15～55Hz, mixing time 180～600s；
2. decorative pattern material B colorant rubs material uniformly by manually sieving；
(3) distributing mode 1: in the compound during 1. color patterned for B material is spread to；Batch mixing is sent in charge car by distributing belt, then is evenly arranged by batch mixing framed with cloth interior by charge car；
Distributing mode 2: batch mixing is sent in charge car by distributing belt, then batch mixing is evenly arranged framed with cloth interior by charge car, meanwhile the color patterned material of B is fallen within the compound that belt transmits by the vibration screen vibrosieve of vibrating distributor；The mace of rotation additionally according to lines Len req, can be set up for breaing up decorative pattern material；
(4) compacting: after cloth completes, repressed vibration equipment is compressing under the vacuum condition of-0.1Mpa, pressure 50～200t, frequency of vibration 30～55Hz, the time 60～600s；
(5) heat cure: after vibration compacting, entering curing apparatus, solidify at a temperature of 80～130 DEG C, hardening time is 30～180 minutes；
(6), after having solidified, room temperature is placed the rear sheet material thicknessing machine that enters to be cooled and is determined thickness, then is polished through water mill polissoir.
CN201610143665.7A 2016-03-14 2016-03-14 Artificial quartz stone sheet material with linear patterns and production technology thereof Pending CN105819747A (en)

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106927729A (en) * 2017-01-26 2017-07-07 佛山市高明区新意新石业有限公司 The quartzite slate preparation method and its product of a kind of imitation marble
CN107117867A (en) * 2017-05-19 2017-09-01 广东中旗新材料科技有限公司 A kind of SiO2Grey dawn textured man-made stone diamond stone sheet material and its production technology
CN107117865A (en) * 2017-05-19 2017-09-01 广东中旗新材料科技有限公司 A kind of double-colored fine grained artificial quartz stone plate and its production technology
CN107117868A (en) * 2017-05-19 2017-09-01 广东中旗新材料科技有限公司 A kind of SiO2 grey dawns textured man-made stone diamond stone sheet material and preparation method thereof
CN107129193A (en) * 2017-05-19 2017-09-05 广东中旗新材料科技有限公司 A kind of OK a karaoke club card tower textured man-made stone diamond stone sheet material and its production technology
CN107129192A (en) * 2017-05-19 2017-09-05 广东中旗新材料科技有限公司 A kind of wood grain type textured man-made stone diamond stone sheet material and its production technology
CN109651768A (en) * 2018-12-13 2019-04-19 北京华祥瑞野营装备有限公司 A kind of preparation method for simulating Triton block
CN109928672A (en) * 2019-04-08 2019-06-25 肇庆爱博新材料科技有限公司 A kind of preparation method of imitative rosy clouds moire synthetic quartz plate
CN112521052A (en) * 2020-12-21 2021-03-19 新云石业（云浮）有限公司 Preparation method of environment-friendly quartz stone plate

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Publication number Priority date Publication date Assignee Title
CN101337805A (en) * 2008-08-25 2009-01-07 张璐 Artificial quartz in lump and fabrication technology thereof
CN102329100A (en) * 2010-07-12 2012-01-25 周军 Artificial quartz stone checkered plate and process thereof
CN104478299A (en) * 2014-11-21 2015-04-01 广东中旗新材料科技有限公司 Double-pattern artificial quartz stone plate and production process thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101337805A (en) * 2008-08-25 2009-01-07 张璐 Artificial quartz in lump and fabrication technology thereof
CN102329100A (en) * 2010-07-12 2012-01-25 周军 Artificial quartz stone checkered plate and process thereof
CN104478299A (en) * 2014-11-21 2015-04-01 广东中旗新材料科技有限公司 Double-pattern artificial quartz stone plate and production process thereof

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106927729A (en) * 2017-01-26 2017-07-07 佛山市高明区新意新石业有限公司 The quartzite slate preparation method and its product of a kind of imitation marble
CN106927729B (en) * 2017-01-26 2019-05-17 佛山市高明区新意新石业有限公司 A kind of the quartzite slate preparation method and its product of imitation marble
CN107117867A (en) * 2017-05-19 2017-09-01 广东中旗新材料科技有限公司 A kind of SiO2Grey dawn textured man-made stone diamond stone sheet material and its production technology
CN107117865A (en) * 2017-05-19 2017-09-01 广东中旗新材料科技有限公司 A kind of double-colored fine grained artificial quartz stone plate and its production technology
CN107117868A (en) * 2017-05-19 2017-09-01 广东中旗新材料科技有限公司 A kind of SiO2 grey dawns textured man-made stone diamond stone sheet material and preparation method thereof
CN107129193A (en) * 2017-05-19 2017-09-05 广东中旗新材料科技有限公司 A kind of OK a karaoke club card tower textured man-made stone diamond stone sheet material and its production technology
CN107129192A (en) * 2017-05-19 2017-09-05 广东中旗新材料科技有限公司 A kind of wood grain type textured man-made stone diamond stone sheet material and its production technology
CN109651768A (en) * 2018-12-13 2019-04-19 北京华祥瑞野营装备有限公司 A kind of preparation method for simulating Triton block
CN109651768B (en) * 2018-12-13 2021-06-29 北京华祥瑞野营装备有限公司 Preparation method of simulated trinitrotoluene medicine block
CN109928672A (en) * 2019-04-08 2019-06-25 肇庆爱博新材料科技有限公司 A kind of preparation method of imitative rosy clouds moire synthetic quartz plate
CN109928672B (en) * 2019-04-08 2021-07-30 肇庆爱博新材料科技有限公司 Preparation method of artificial quartz plate with imitated nepheline patterns
CN112521052A (en) * 2020-12-21 2021-03-19 新云石业（云浮）有限公司 Preparation method of environment-friendly quartz stone plate

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Application publication date: 20160803