CN105801000A - Bulk pattern artificial quartz stone plate and production process thereof - Google Patents

Bulk pattern artificial quartz stone plate and production process thereof Download PDF

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Publication number
CN105801000A
CN105801000A CN201610144066.7A CN201610144066A CN105801000A CN 105801000 A CN105801000 A CN 105801000A CN 201610144066 A CN201610144066 A CN 201610144066A CN 105801000 A CN105801000 A CN 105801000A
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CN
China
Prior art keywords
color
sheet material
bulk type
pigment
inorganic pigment
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Pending
Application number
CN201610144066.7A
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Chinese (zh)
Inventor
周军
胡国强
张韡
蒋陈富
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GUANGDONG BANNER NEW MATERIAL TECHNOLOGY Co Ltd
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GUANGDONG BANNER NEW MATERIAL TECHNOLOGY Co Ltd
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Priority to CN201610144066.7A priority Critical patent/CN105801000A/en
Publication of CN105801000A publication Critical patent/CN105801000A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/04Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/06Acrylates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/10Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/12Condensation polymers of aldehydes or ketones
    • C04B26/122Phenol-formaldehyde condensation polymers
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/10Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/14Polyepoxides
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/10Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/16Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/10Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/18Polyesters; Polycarbonates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/54Substitutes for natural stone, artistic materials or the like
    • C04B2111/542Artificial natural stone

Abstract

The invention discloses a bulk pattern artificial quartz stone plate and a production process thereof.The plate is prepared from a main material with color A and a pattern material with color B.The main material with color A is prepared from a particle raw material with granularity of 0.075-5 mm, quartz powder with granularity of 0.005-0.045 mm, colored pigment, silane coupling agent, unsaturated polyester resin and curing agent.The pattern material with color B is prepared from inorganic pigment or inorganic pigment and quartz powder with granularity of 0.045-0.212 mm, wherein the particle raw material is quartz particles or glass particles or the mixture of quartz particles and glass particles.The pattern material with color B is scattered in the main material with color A, the dry pattern material with color B can be attached to the wet main material with color A to form a color-mixed material, bulk patterns are displayed on the surface of the plate after stirring and pressing, and the larger the stirring frequency is, the more pattern bulks are formed; in addition, the pattern material is simplex inorganic pigment, namely, the mixed material of inorganic pigment and quartz powder, the prepared patterns are good in effect, clear in color and finer, the type and pattern of artificial quartz stone are enriched, production efficiency is high, the reject ratio of the product is effectively decreased, and mass production can be achieved.

Description

A kind of bulk type textured man-made stone diamond stone sheet material and production technology thereof
Technical field
The invention belongs to quartz technical field, specifically, relate to a kind of bulk type textured man-made stone diamond stone sheet material and production technology thereof.
Background technology
In building decoration field, the stone material feature such as by force attractive in appearance with it, graceful, ornamental has become one of primary decoration material.All the time, natural marble figue is abundant, natural, it is subject to extensive use because of its natural decorative effect, texture, but owing to there is resource-constrained, there is aberration in large area paving and radioactivity in various degree exceeds standard, hardness is low, it is easy to the problems such as scratching, limits its omnibearing development to a certain extent.
Artificial quartz in lump is to be main stuffing by quartz sand powder, using unsaturated polyester resin as binding agent, the Novel stone of setting under high pressure temperature state compressing, middle under vacuum condition, it is a kind of "dead" pollution, the environmental protection of repeatable utilization, green building material and ornament materials.
Although artificial quartz in lump rich color is gorgeous, radiationless, wear-resisting, pressure, anti scuffing, anticorrosive, aging resistance, impermeable, but it is because without marmorean native texture and color, makes artificial quartz in lump class can not get big raising.Having the diamond plate of imitating natural marble at present both at home and abroad, but color is relatively stiff, texture is unnatural.Meanwhile, pattern type artificial quartz stone plate is due to complex process, and production efficiency is low, and sheet material color in pressing process easily interpenetrates, and fraction defective is high, thus causing that the supply of material is few, price is high.
Therefore, it is necessary to existing production technology to be carried out upgrading or technological transformation.
Summary of the invention
Instant invention overcomes shortcoming of the prior art, it is provided that a kind of bulk type textured man-made stone diamond stone sheet material and production technology thereof, good product performance, production efficiency is high, and qualification rate is high.
In order to solve above-mentioned technical problem, the present invention is achieved by the following technical solutions:
A kind of bulk type textured man-made stone diamond stone sheet material, including major ingredient A color, decorative pattern material B color, the raw material of described major ingredient A color includes 0.075~5mm particulate material, 0.005~0.045mm silica flour;Colored pigment;Silane coupler;Unsaturated polyester resin;Firming agent;
Component and the proportioning of decorative pattern material B color be: inorganic pigment;Or inorganic pigment and 0.045~0.212mm silica flour;
Wherein, particulate material is quartz particles or glass particle, or the mixture of two kinds.
Further, described major ingredient A color is 98~99.8 parts of total material, and decorative pattern material B color is 0.1~2 part of total material.
Further, described major ingredient A color includes according to percentage by weight: 0.075~5mm particulate material 55%~65%;0.005~0.045mm silica flour 20%~30%;Colored pigment 0.01%~3%;Silane coupler 0.1%~1%;Unsaturated polyester resin 8%~14%;Firming agent 0.8%~1.4%.
Further, according to percentage by weight, component and the proportioning of described decorative pattern material B color be: inorganic pigment 100%;Or inorganic pigment 1%~30%, 0.045~0.212mm silica flour 70%~99%.
Further, described unsaturated polyester resin can also be one or more in epoxy resin, phenolic resin, acrylic resin and polyurethane resin.
Further, described colored pigment is one or more of inorganic pigment or organic pigment or mill base.
Further, described inorganic pigment is the inorganic pigments such as titanium white, medium chrome yellow, iron oxide yellow, iron oxide red, barba hispanica, cadmium red, cadmium yellow, white carbon black, iron oxide black.
Further, described organic pigment is the organic pigments such as red, azophosphine, phthalein viridescent and phthalocyanine blue, and described mill base is the mill bases such as white slurry, black wash, bright red slurry, phthalein viridescent slurry, phthalocyanine blue slurry.
Further, described firming agent is one or more in peroxidating (2 ethyl hexanoic acid) tert-butyl ester, methyl ethyl ketone peroxide, peroxidized t-butyl perbenzoate, dibenzoyl peroxide and fat polyamine.
Further, described silane coupler is one or more in γ-methacryloxypropyl trimethoxy silane, γ-(2,3-epoxy the third oxygen) propyl trimethoxy silicane, N-β (aminoethyl)-γ-aminopropyltriethoxy dimethoxysilane, N-(β-aminoethyl)-gamma-aminopropyl-triethoxy-silane, N-β (aminoethyl)-γ-aminopropyltrimethoxysilane, anilinomethyl triethoxysilane, gamma-aminopropyl-triethoxy-silane, VTES, vinyltrimethoxy silane and γ-chloropropyl triethoxysilane.
The production technology of a kind of bulk type textured man-made stone diamond stone sheet material, comprises the following steps:
(1) each material each component is weighed according to formula;
(2) stirring: the quartz particles of major ingredient A color that 1. step (1) weighed, glass particle, silane coupler premixing in double planetary agitator;The firming agent mixed, decoration colored pigment and unsaturated polyester resin are poured in double planetary agitator and mixed, is subsequently adding silica flour and mixes.Stirring frequency 15~55Hz, mixing time 180~600s;
2. decorative pattern material B colorant rubs material uniformly by manually sieving;
3. color patterned for B material is spread in the A material mixed, low frequency stirring mixing;Stirring frequency 10~30Hz, mixing time 10~80S;
(3) cloth: batch mixing is sent in charge car by distributing belt, then by charge car batch mixing is evenly arranged framed with cloth in;
(4) compacting: after cloth completes, repressed vibration equipment is compressing under the vacuum condition of-0.1Mpa, pressure 50~200t, frequency of vibration 30~55Hz, time 60~600s;
(5) heat cure: after vibration compacting, entering curing apparatus, solidify at the temperature of 80~130 DEG C, hardening time is 30~180 minutes;
(6), after having solidified, room temperature is placed the completely rear sheet material thicknessing machine that enters to be cooled and is determined thickness, is polished then through water mill polissoir.
Compared with prior art, the invention has the beneficial effects as follows:
A kind of bulk type textured man-made stone diamond stone sheet material of the present invention and production technology thereof, the artificial quartz in lump made is handsome in appearance, and pattern is distinct, color is unique, enriches kind and the style of artificial quartz in lump, and production efficiency is high simultaneously, effectively reduce the fraction defective of product, can mass production.
Detailed description of the invention
Hereinafter the preferred embodiments of the present invention are illustrated, it will be appreciated that preferred embodiment described herein is merely to illustrate and explains the present invention, is not intended to limit the present invention.
A kind of bulk type textured man-made stone diamond stone sheet material of the present invention, including major ingredient A color, decorative pattern material B color, major ingredient A color is 99 parts of total material, and decorative pattern material B color is 1 part of total material.
Major ingredient A color includes according to percentage by weight: 0.075~5mm particulate material 63%;0.005~0.045mm silica flour 26%;Colored pigment 1.5%;Silane coupler 0.6%;Unsaturated polyester resin 8%;Firming agent 0.9%.
According to percentage by weight, component and the proportioning of described decorative pattern material B color be: inorganic pigment 25%, 0.045~0.212mm silica flour 75%.
Wherein, particulate material is quartz particles or glass particle, or the mixture of two kinds.
Unsaturated polyester resin can also be one or more in epoxy resin, phenolic resin, acrylic resin and polyurethane resin.
Colored pigment is the multiple of inorganic pigment or organic pigment or mill base, and inorganic pigment is titanium white, medium chrome yellow, iron oxide yellow, iron oxide red or iron oxide black, and organic pigment is red, and phthalein is dark green or phthalocyanine blue, and mill base be white slurry, black wash, bright red slurry, and phthalein viridescent is starched or phthalocyanine blue is starched.
Firming agent is one or more in peroxidating (2 ethyl hexanoic acid) tert-butyl ester, methyl ethyl ketone peroxide, peroxidized t-butyl perbenzoate, dibenzoyl peroxide and fat polyamine.
Silane coupler is one or more in γ-methacryloxypropyl trimethoxy silane, γ-(2,3-epoxy the third oxygen) propyl trimethoxy silicane, N-β (aminoethyl)-γ-aminopropyltriethoxy dimethoxysilane, N-(β-aminoethyl)-gamma-aminopropyl-triethoxy-silane, N-β (aminoethyl)-γ-aminopropyltrimethoxysilane, anilinomethyl triethoxysilane, gamma-aminopropyl-triethoxy-silane, VTES, vinyltrimethoxy silane and γ-chloropropyl triethoxysilane.
The production technology of a kind of bulk type textured man-made stone diamond stone sheet material, comprises the following steps:
(1) each material each component is weighed according to formula;
(2) stirring: the quartz particles of major ingredient A color that 1. step (1) weighed, glass particle, silane coupler premixing in double planetary agitator;The firming agent mixed, decoration colored pigment and unsaturated polyester resin are poured in double planetary agitator and mixed, is subsequently adding silica flour and mixes.Stirring frequency 15~55Hz, mixing time 180~600s;
2. decorative pattern material B colorant rubs material uniformly by manually sieving;
3. color patterned for B material is spread in the A material mixed, low frequency stirring mixing;Stirring frequency 10~30Hz, mixing time 10~80S;
(3) cloth: batch mixing is sent in charge car by distributing belt, then by charge car batch mixing is evenly arranged framed with cloth in;
(4) compacting: after cloth completes, repressed vibration equipment is compressing under the vacuum condition of-0.1Mpa, pressure 50~200t, frequency of vibration 30~55Hz, time 60~600s;
(5) heat cure: after vibration compacting, entering curing apparatus, solidify at the temperature of 80~130 DEG C, hardening time is 30~180 minutes;
(6), after having solidified, room temperature is placed the completely rear sheet material thicknessing machine that enters to be cooled and is determined thickness, is polished then through water mill polissoir.
Last it is noted that these are only the preferred embodiments of the present invention; it is not limited to the present invention; although the present invention being described in detail with reference to embodiment; for a person skilled in the art; technical scheme described in foregoing embodiments still can be modified by it; or wherein portion of techniques feature is carried out equivalent replacement; but all within the spirit and principles in the present invention; any amendment of being made, equivalent replacement, improvement etc., should be included within protection scope of the present invention.

Claims (10)

1. a bulk type textured man-made stone diamond stone sheet material, it is characterised in that: including major ingredient A color, decorative pattern material B color, the raw material of described major ingredient A color includes 0.075~5mm particulate material, 0.005~0.045mm silica flour;Colored pigment;Silane coupler;Unsaturated polyester resin;Firming agent;
Component and the proportioning of decorative pattern material B color be: inorganic pigment;Or inorganic pigment and 0.045~0.212mm silica flour;
Wherein, particulate material is quartz particles or glass particle, or the mixture of two kinds.
2. a kind of bulk type textured man-made stone diamond stone sheet material according to claim 1, it is characterised in that: described major ingredient A color is 98~99.8 parts of total material, and decorative pattern material B color is 0.1~2 part of total material.
3. a kind of bulk type textured man-made stone diamond stone sheet material according to claim 1, it is characterised in that: described major ingredient A color includes according to percentage by weight: 0.075~5mm particulate material 55%~65%;0.005~0.045mm silica flour 20%~30%;Colored pigment 0.01%~3%;Silane coupler 0.1%~1%;Unsaturated polyester resin 8%~14%;Firming agent 0.8%~1.4%.
4. a kind of bulk type textured man-made stone diamond stone sheet material according to claim 1, it is characterised in that: according to percentage by weight, component and the proportioning of described decorative pattern material B color be: inorganic pigment 100%;Or inorganic pigment 1%~30%, 0.045~0.212mm silica flour 70%~99%.
5. a kind of bulk type textured man-made stone diamond stone sheet material according to claim 1, it is characterised in that: described unsaturated polyester resin can also be one or more in epoxy resin, phenolic resin, acrylic resin and polyurethane resin.
6. a kind of bulk type textured man-made stone diamond stone sheet material according to claim 1, it is characterised in that: described colored pigment is one or more of inorganic pigment or organic pigment or mill base.
7. a kind of bulk type textured man-made stone diamond stone sheet material according to claim 6, it is characterized in that: described machine pigment is titanium white, medium chrome yellow, iron oxide yellow, iron oxide red, barba hispanica, cadmium red, cadmium yellow, white carbon black, iron oxide black, described organic pigment is red, azophosphine, phthalein viridescent and phthalocyanine blue, and described mill base is white slurry, black wash, bright red slurry, phthalein viridescent slurry, phthalocyanine blue slurry.
8. a kind of bulk type textured man-made stone diamond stone sheet material according to claim 1, it is characterised in that: described firming agent is one or more in peroxidating (2 ethyl hexanoic acid) tert-butyl ester, methyl ethyl ketone peroxide, peroxidized t-butyl perbenzoate, dibenzoyl peroxide and fat polyamine.
9. a kind of bulk type textured man-made stone diamond stone sheet material according to claim 1, it is characterized in that: described silane coupler is γ-methacryloxypropyl trimethoxy silane, γ-(2, 3-epoxy the third oxygen) propyl trimethoxy silicane, N-β (aminoethyl)-γ-aminopropyltriethoxy dimethoxysilane, N-(β-aminoethyl)-gamma-aminopropyl-triethoxy-silane, N-β (aminoethyl)-γ-aminopropyltrimethoxysilane, anilinomethyl triethoxysilane, gamma-aminopropyl-triethoxy-silane, VTES, one or more in vinyltrimethoxy silane and γ-chloropropyl triethoxysilane.
10. the production technology of a bulk type textured man-made stone diamond stone sheet material, it is characterised in that: comprise the following steps:
(1) each material each component is weighed according to formula;
(2) stirring: the quartz particles of major ingredient A color that 1. step (1) weighed, glass particle, silane coupler premixing in double planetary agitator;The firming agent mixed, decoration colored pigment and unsaturated polyester resin are poured in double planetary agitator and mixed, is subsequently adding silica flour and mixes, stirring frequency 15~55Hz, mixing time 180~600s;
2. decorative pattern material B colorant rubs material uniformly by manually sieving;
3. color patterned for B material is spread in the A material mixed, low frequency stirring mixing;Stirring frequency 10~30Hz, mixing time 10~80S;
(3) cloth: batch mixing is sent in charge car by distributing belt, then by charge car batch mixing is evenly arranged framed with cloth in;
(4) compacting: after cloth completes, repressed vibration equipment is compressing under the vacuum condition of-0.1Mpa, pressure 50~200t, frequency of vibration 30~55Hz, time 60~600s;
(5) heat cure: after vibration compacting, entering curing apparatus, solidify at the temperature of 80~130 DEG C, hardening time is 30~180 minutes;
(6), after having solidified, room temperature is placed the completely rear sheet material thicknessing machine that enters to be cooled and is determined thickness, is polished then through water mill polissoir.
CN201610144066.7A 2016-03-14 2016-03-14 Bulk pattern artificial quartz stone plate and production process thereof Pending CN105801000A (en)

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Application Number Priority Date Filing Date Title
CN201610144066.7A CN105801000A (en) 2016-03-14 2016-03-14 Bulk pattern artificial quartz stone plate and production process thereof

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Application Number Priority Date Filing Date Title
CN201610144066.7A CN105801000A (en) 2016-03-14 2016-03-14 Bulk pattern artificial quartz stone plate and production process thereof

Publications (1)

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CN105801000A true CN105801000A (en) 2016-07-27

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106915921A (en) * 2017-03-22 2017-07-04 佛山市蓝瑞欧特信息服务有限公司 A kind of fire retardant man-made quartzite slate and preparation method thereof
CN106927729A (en) * 2017-01-26 2017-07-07 佛山市高明区新意新石业有限公司 The quartzite slate preparation method and its product of a kind of imitation marble
CN107117867A (en) * 2017-05-19 2017-09-01 广东中旗新材料科技有限公司 A kind of SiO2Grey dawn textured man-made stone diamond stone sheet material and its production technology
CN107117865A (en) * 2017-05-19 2017-09-01 广东中旗新材料科技有限公司 A kind of double-colored fine grained artificial quartz stone plate and its production technology
CN107117868A (en) * 2017-05-19 2017-09-01 广东中旗新材料科技有限公司 A kind of SiO2 grey dawns textured man-made stone diamond stone sheet material and preparation method thereof
CN107129194A (en) * 2017-05-19 2017-09-05 广东中旗新材料科技有限公司 A kind of quartzy stone platform of double-colored decorative pattern and its preparation technology
CN107129192A (en) * 2017-05-19 2017-09-05 广东中旗新材料科技有限公司 A kind of wood grain type textured man-made stone diamond stone sheet material and its production technology

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CN102329100A (en) * 2010-07-12 2012-01-25 周军 Artificial quartz stone checkered plate and process thereof
CN103408250A (en) * 2013-07-29 2013-11-27 广东中旗新材料科技有限公司 Nanocomposite quartz stone board and manufacturing method thereof
CN103408249A (en) * 2013-07-30 2013-11-27 广东中旗新材料科技有限公司 Man-made quartz stone and preparation method thereof
CN104478298A (en) * 2014-11-12 2015-04-01 广东中旗新材料科技有限公司 Lightweighted artificial quartz stone decorative surface material and preparation method thereof
CN104478299A (en) * 2014-11-21 2015-04-01 广东中旗新材料科技有限公司 Double-pattern artificial quartz stone plate and production process thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102329100A (en) * 2010-07-12 2012-01-25 周军 Artificial quartz stone checkered plate and process thereof
CN103408250A (en) * 2013-07-29 2013-11-27 广东中旗新材料科技有限公司 Nanocomposite quartz stone board and manufacturing method thereof
CN103408249A (en) * 2013-07-30 2013-11-27 广东中旗新材料科技有限公司 Man-made quartz stone and preparation method thereof
CN104478298A (en) * 2014-11-12 2015-04-01 广东中旗新材料科技有限公司 Lightweighted artificial quartz stone decorative surface material and preparation method thereof
CN104478299A (en) * 2014-11-21 2015-04-01 广东中旗新材料科技有限公司 Double-pattern artificial quartz stone plate and production process thereof

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106927729A (en) * 2017-01-26 2017-07-07 佛山市高明区新意新石业有限公司 The quartzite slate preparation method and its product of a kind of imitation marble
CN106927729B (en) * 2017-01-26 2019-05-17 佛山市高明区新意新石业有限公司 A kind of the quartzite slate preparation method and its product of imitation marble
CN106915921A (en) * 2017-03-22 2017-07-04 佛山市蓝瑞欧特信息服务有限公司 A kind of fire retardant man-made quartzite slate and preparation method thereof
CN107117867A (en) * 2017-05-19 2017-09-01 广东中旗新材料科技有限公司 A kind of SiO2Grey dawn textured man-made stone diamond stone sheet material and its production technology
CN107117865A (en) * 2017-05-19 2017-09-01 广东中旗新材料科技有限公司 A kind of double-colored fine grained artificial quartz stone plate and its production technology
CN107117868A (en) * 2017-05-19 2017-09-01 广东中旗新材料科技有限公司 A kind of SiO2 grey dawns textured man-made stone diamond stone sheet material and preparation method thereof
CN107129194A (en) * 2017-05-19 2017-09-05 广东中旗新材料科技有限公司 A kind of quartzy stone platform of double-colored decorative pattern and its preparation technology
CN107129192A (en) * 2017-05-19 2017-09-05 广东中旗新材料科技有限公司 A kind of wood grain type textured man-made stone diamond stone sheet material and its production technology

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Application publication date: 20160727