CN106866030A - A kind of water-fast artificial quartz in lump and preparation method thereof - Google Patents
A kind of water-fast artificial quartz in lump and preparation method thereof Download PDFInfo
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- CN106866030A CN106866030A CN201710171976.9A CN201710171976A CN106866030A CN 106866030 A CN106866030 A CN 106866030A CN 201710171976 A CN201710171976 A CN 201710171976A CN 106866030 A CN106866030 A CN 106866030A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/14—Polyepoxides
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- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/06—Acrylates
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/12—Condensation polymers of aldehydes or ketones
- C04B26/122—Phenol-formaldehyde condensation polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4804—Two or more polyethers of different physical or chemical nature
- C08G18/4808—Mixtures of two or more polyetherdiols
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4825—Polyethers containing two hydroxy groups
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4854—Polyethers containing oxyalkylene groups having four carbon atoms in the alkylene group
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/27—Water resistance, i.e. waterproof or water-repellent materials
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/54—Substitutes for natural stone, artistic materials or the like
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/20—Mortars, concrete or artificial stone characterised by specific physical values for the density
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
Abstract
The present invention relates to a kind of water-fast artificial quartz in lump and preparation method thereof, it is made up of the component of following weight portion：20~50 65~75 parts of mesh calcining quartz sand, 20~50 35~46 parts of mesh mica stone flours, 4~10 parts of 20~50 mesh molybdenum disulphide powder, 10~20 parts of unsaturated polyester resin, 10~15 parts of curing agent, 1~5 part of accelerator, 4~6 parts of colorant, 20~30 parts of modified fluorinated polyurethane, 5~10 parts of coupling agent.Artificial quartz in lump waterproof and oilproof prepared by the present invention, being suitable for kitchen etc. needs waterproof and oilproof place to use, and the present invention also has certain antibacterial ability, and surface adhesion force is small, and the globule is difficult to adhere to surface, and cleaning gets up very convenient, and hardness is good, is difficult to scratch.
Description
Technical field
The present invention relates to a kind of artificial quartz in lump and preparation method thereof, more particularly to a kind of water-fast artificial quartz in lump and its system
Preparation Method.
Background technology
Artificial stone is a kind of "dead", pollution-free, repeatable utilization, the architecture indoor novel decorative material of environmental protection
Material.As a kind of strategic novel healthy environment protection product for meeting national sustainable development, domestic city is introduced the eighties in last century
.The artificial stone sold in the market is main using macromolecule resin material as the organic type artificial stone of adhesive, is divided into three
Class：Artificial marble (hereinafter referred to as artificial hilllock stone), artificial quartz in lump and acrylic.Although China artificial stone industry starting compared with
Evening, but by the fast development of more than ten years, it is at the forefront in the world in terms of market scale and application popularization rate.
Artificial quartz in lump is natural with silicate (class) with unsaturated polyester resin or thermoplastic polyester as matrix
The inorganic material such as quartz and/or powder, silica sand, mine tailings (its main component is silica) is main stuffing, through specific
The artificial stone with certain specification size and dimension that technique is processed.Because of its quality hard (Mohs' hardness 5~7), structure
Densification, with the incomparable characteristic such as wear-resisting, pressure-resistant, anticorrosive, impermeable of other ornament materials.Artificial quartz in lump extensively should
For kitchen table top, laboratory table top, windowsill, bar desk, lift port, ground, metope etc..It is higher to material requirements building
Place artificial quartz in lump is also all suitable for.
Traditional artificial quartz in lump not yet reaches relatively good level in glossiness and antifouling property.Especially in pollution resistance
On energy, for showing undesirable on the antifouling property of some obstinate stains and special stain, so as to limit artificial quartz in lump
Extensive use and popularization.
The content of the invention
The present invention seeks in view of the shortcomings of the prior art, be filled out as water-fast using nano-material modified fluorinated polyurethane
Material, artificial quartz in lump prepared by the method both has hydrophobic and oleophobic performance, again the performance such as heat-resisting, against corrosion, wear-resistant of tool.
Specifically, one aspect of the present invention provides a kind of water-fast artificial quartz in lump, and it is made up of the component of following weight portion：20
~50 65~75 parts of mesh calcining quartz sand, 20~50 35~46 parts of mesh mica stone flours, 4~10 parts of 20~50 mesh molybdenum disulphide powder,
10~20 parts of unsaturated polyester resin, 10~15 parts of curing agent, 1~5 part of accelerator, 4~6 parts of colorant, modified fluorinated polyurethane
20~30 parts, 5~10 parts of coupling agent.
Preferably, the unsaturated polyester resin is the one kind or many in epoxy resin, phenolic resin, acrylic resin
Kind, the accelerator is dibutyl tin laurate, N, N~dimethyl open-chain crown ether, di-2-ethylhexylphosphine oxide phenylenediamine, 8- hydroxyl quinolines
At least one in quinoline.
Preferably, the curing agent is peroxidating (2 ethyl hexanoic acid) tert-butyl ester, methyl ethyl ketone peroxide, perbenzoic acid
One or more in the tert-butyl ester, dibenzoyl peroxide and fat polyamine.The coupling agent is γ-methacryloxy
Propyl trimethoxy silicane, γ-(2,3- the third oxygen of epoxy) propyl trimethoxy silicane, N- β (aminoethyl)-γ-aminopropyltriethoxy
Dimethoxysilane, N- (β-aminoethyl)-gamma-aminopropyl-triethoxy-silane, N- β (aminoethyl)-γ-aminopropyl trimethoxy
Silane, anilinomethyl triethoxysilane, gamma-aminopropyl-triethoxy-silane, VTES, vinyl front three
One or more in TMOS and γ-chloropropyl triethoxysilane.
Further, the preparation method of the modified fluorinated polyurethane is as follows：
Hydrophilicrto polyether polyalcohol is mixed with a kind of composition in aliphatic diisocyanate, two kinds of fluorine-containing monohydric alcohol, will
Gained mixed liquor is put into reactor under nitrogen protection, and aliphatic diisocyanate, fluorine-containing unitary are added at 55~65 DEG C
Remaining a kind of composition and solvent in two kinds of alcohol, stir 2~4 hours at 95~105 DEG C, add chain extender, catalyst and through logical
The ethanol solution of the scattered nano-graphene of fluorine ultrasonic wave, stirs 1~2 hour, reaction 0.5~1 is continued at 50~100 DEG C small
When, obtain modified fluorinated polyurethane nano composite material.
Preferably, the logical fluorine ultrasonic wave dispersion is that nanopowder nano-graphene is added into ethanol solution, in ultrasound
To fluorine gas is passed through in the ethanol containing inorganic nanoparticles while dispersion, so that inorganic nano-particle dispersed 40~60
Minute.
- NCO the bases of described aliphatic diisocyanate are 1 with the mol ratio of-OH bases of PPG:0.5~
0.95；Described aliphatic diisocyanate is 1 with the mol ratio of chain extender:0.5~1；Described aliphatic diisocyanate
It is 1 with the mol ratio of fluorine-containing monohydric alcohol:0.1~0.5.Described Hydrophilicrto polyether polyol molecular weight is 200~4000.It is described
Hydrophilicrto polyether polyalcohol be polyethylene glycol (PEG), polypropylene glycol (PPG), the propylene oxide glycol of polyethylene glycol oxide one.It is described
Fluorine-containing monohydric alcohol for perfluoroalkyl ethanol, containing heteroatomic perfluoroalkyl ethanol；Perfluoroalkyl ethanol molecular formula：C2F5
(CF2CF2)n CH2CH2OH (n=2~6)；Described aliphatic diisocyanate be IPDI (IPDI),
Tetramethylene diisocyanate, hexa-methylene -1,6- diisocyanate (HDI), dicyclohexyl methyl hydride diisocyanate (HMDI)
And its derivative.Described chain extender is hydrophobic long-chain polyether glycols, can be selected from the equal PTMEG of PolyTHF, gather
Polypropylene ether diol, polyoxyethylene oxypropylene copolyether glycol, tetrahydrofuran-expoxy propane binary copolymerization ether glycol or four
Hydrogen furans-propyleneoxide-ethyleneoxide ternary polymerization ether glycol.Described solvent is ethyl acetate, dimethylbenzene, toluene or it is mixed
Bonding solvent.Described catalyst is dibutyl tin laurate (DBTDL) or stannous octoate, and its addition is 0.05~0.1 milli
Rise.
Another aspect of the present invention provides a kind of preparation method of water-fast artificial quartz in lump, comprises the following steps：
(1) 20~50 mesh calcining quartz sand are calcined 1 hour under 800~900 DEG C of high temperature, are then rushed with 5 DEG C of cold water and poured,
They are calcined 1 hour under 900~1000 DEG C of high temperature again, is then cooled to normal temperature；
(2) to addition mica stone flour, molybdenum disulphide powder, unsaturated polyester resin, curing agent, rush in the material of step (1)
Enter agent, colorant, coupling agent and modified fluorinated polyurethane, each component uniformly mixes；
(3) in the material feeding material distributing machine cloth system template die that will be mixed, making sheet mould is then sent into vacuum chamber, takes out true
Sky, vibration moulding is re-fed into curing oven, that is, artificial quartz in lump is obtained.
Preferably, in two stages, first stage solidification temperature is 92~98 DEG C for the solidification, and hardening time is 50 minutes,
Second stage solidification temperature is 80~84 DEG C, and hardening time is 30 minutes.
Advantages of the present invention is as follows：
Artificial quartz in lump waterproof and oilproof prepared by the present invention, being suitable for kitchen etc. needs waterproof and oilproof place to use, and
And the present invention also has certain antibacterial ability, surface adhesion force is small, and the globule is difficult to adhere to surface, and cleaning is got up very square
Just, hardness is good, is difficult to scratch.
Specific embodiment
The technical scheme in the embodiment of the present invention is clearly and completely described below, it is clear that described embodiment
Only a part of embodiment of the invention, rather than whole embodiments.Based on the embodiment in the present invention, the common skill in this area
The every other embodiment that art personnel are obtained on the premise of creative work is not made, belongs to the model of present invention protection
Enclose.
【Embodiment 1】
The preparation of modified fluorinated polyurethane：Add 200 grams of polypropylene glycol (PPG400), 2- perfluors pungent in 1L glass beakers
464 grams of base ethanol, being placed on constant-temperature heating magnetic stirring apparatus mixes content, and constant temperature mixes 1 hour, by gained to 65 DEG C
Mixed liquor loads in reactor under nitrogen protection, adds 444 grams of IPDI (IPDI), ethyl acetate
2000ml, is mixed 2 hours, and the equal PTMEG of PolyTHF (PTMG2000) 2000 is added when being warming up to 100 DEG C or so
Gram, stannous octoate 0.5ml, quick stirring 30 minutes is cooled to 70 DEG C, mixes 1 hour, reduces temperature to 40 DEG C, adds
Average grain diameter is the alcohol dispersion liquid of the nano-graphene of 40nm, and quick dispersed with stirring 60 minutes is cooled to room temperature, is discharged.
【Embodiment 2】
(1) 350g mesh calcining quartz sand is calcined 1 hour under 800-900 DEG C of high temperature, is then rushed with 5 DEG C of cold water and poured, then
They are calcined 1 hour under 900-1000 DEG C of high temperature, normal temperature is then cooled to；
(2) to addition 240g micas stone flour, 325g molybdenum disulphide powders, 115g unsaturated polyester (UP) trees in the material of step (1)
Fat, 150g peroxidized t-butyl perbenzoates, 30g dibutyl tin laurates, 35g cadmium yellows, 60g γ-methacryloxy third
Base trimethoxy silane and the modified fluorinated polyurethane of 250g, each component uniformly mix；
(3) in the material feeding material distributing machine cloth system template die that will be mixed, making sheet mould is then sent into vacuum chamber, takes out true
Sky, vibration moulding is re-fed into curing oven, that is, artificial quartz in lump is obtained.It is described to solidify in two stages, first stage solidification temperature
It it is 92~98 DEG C, hardening time is 50 minutes, second stage solidification temperature is 80~84 DEG C, hardening time is 30 minutes.
【Comparative example 1】
【Comparative example】
Using the identical preparation method of embodiment 2, difference only replaces with the fluorination polyamide prepared by embodiment 1
Polyamide.Common artificial quartz in lump detection data contrast obtained in quartz obtained in the embodiment of the present invention 2 and comparative example 1
Result is as shown in the table：
From the comparative experimental data of above table, artificial quartz in lump of the invention is than common artificial quartz in lump each side
Performance all has greatly improved.
Described above fully discloses specific embodiment of the invention.It is pointed out that being familiar with the field
Scope of any change that technical staff is done to specific embodiment of the invention all without departing from claims of the present invention.
Correspondingly, the scope of claim of the invention is also not limited only to previous embodiment.
Claims (8)
1. a kind of water-fast artificial quartz in lump, it is characterised in that be made up of the component of following weight portion：20~50 mesh calcining quartz sand
65~75 parts, 20~50 35~46 parts of mesh mica stone flours, 4~10 parts of 20~50 mesh molybdenum disulphide powder, unsaturated polyester resin 10
~20 parts, 10~15 parts of curing agent, 1~5 part of accelerator, 4~6 parts of colorant, 20~30 parts of modified fluorinated polyurethane, coupling agent 5
~10 parts.
2. a kind of water-fast artificial quartz in lump according to claim 1, it is characterised in that the unsaturated polyester resin is epoxy
One or more in resin, phenolic resin, acrylic resin, the accelerator is dibutyl tin laurate, N, N- diformazans
At least one in base open-chain crown ether, di-2-ethylhexylphosphine oxide phenylenediamine, 8-hydroxyquinoline.
3. a kind of water-fast artificial quartz in lump according to claim 1, it is characterised in that the curing agent is peroxidating (2- second
Base caproic acid) in the tert-butyl ester, methyl ethyl ketone peroxide, peroxidized t-butyl perbenzoate, dibenzoyl peroxide and fat polyamine
One or more.
4. a kind of water-fast artificial quartz in lump according to claim 1, it is characterised in that the coupling agent is γ-metering system
Acryloxypropylethoxysilane trimethoxy silane, γ-(2,3- the third oxygen of epoxy) propyl trimethoxy silicane, N- β (aminoethyl)-γ-ammonia third
Ylmethyl dimethoxysilane, N- (β-aminoethyl)-gamma-aminopropyl-triethoxy-silane, N- β (aminoethyl)-γ-aminopropyl three
Methoxy silane, anilinomethyl triethoxysilane, gamma-aminopropyl-triethoxy-silane, VTES, ethene
One or more in base trimethoxy silane and γ-chloropropyl triethoxysilane.
5. a kind of water-fast artificial quartz in lump according to claim any one of 1-4, it is characterised in that the modified fluorinated poly- ammonia
The preparation method of ester is as follows：
Hydrophilicrto polyether polyalcohol is mixed with a kind of composition in aliphatic diisocyanate, two kinds of fluorine-containing monohydric alcohol, by gained
Mixed liquor is put into reactor under nitrogen protection, and aliphatic diisocyanate, fluorine-containing monohydric alcohol two are added at 55~65 DEG C
Remaining a kind of composition and solvent in kind, stir 2~4 hours at 95~105 DEG C, add chain extender, catalyst and surpass through logical fluorine
The ethanol solution of the scattered nano-graphene of sound wave, stirs 1~2 hour, continues to react 0.5~1 hour at 50~100 DEG C, obtains
To modified fluorinated polyurethane nano composite material.
6. a kind of water-fast artificial quartz in lump according to claim 5, it is characterised in that the logical fluorine ultrasonic wave dispersion is to receive
Ground rice material nano-graphene is added to ethanol solution, while ultrasonic disperse to the ethanol containing inorganic nanoparticles in be passed through
Fluorine gas, so that dispersed 40~60 minutes of inorganic nano-particle.
7. a kind of preparation method of the water-fast artificial quartz in lump as described in claim any one of 1-6, it is characterised in that including as follows
Step,
(1) 20~50 mesh calcining quartz sand are calcined 1 hour under 800~900 DEG C of high temperature, is then rushed with 5 DEG C of cold water and poured, then will
They are calcined 1 hour under 900~1000 DEG C of high temperature, are then cooled to normal temperature；
(2) to added in the material of step (1) mica stone flour, molybdenum disulphide powder, unsaturated polyester resin, curing agent, accelerator,
Colorant, coupling agent and modified fluorinated polyurethane, each component uniformly mix；
(3) in the material feeding material distributing machine cloth system template die that will be mixed, making sheet mould is then sent into vacuum chamber, is vacuumized,
Vibration moulding, is re-fed into curing oven, that is, artificial quartz in lump is obtained.
8. the preparation method of water-fast artificial quartz in lump according to claim 7, it is characterised in that the solidification in two stages,
First stage solidification temperature is 92~98 DEG C, and hardening time is 50 minutes, and second stage solidification temperature is 80~84 DEG C, during solidification
Between be 30 minutes.
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| CN201710171976.9A CN106866030A (en) | 2017-03-22 | 2017-03-22 | A kind of water-fast artificial quartz in lump and preparation method thereof |
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| CN201710171976.9A CN106866030A (en) | 2017-03-22 | 2017-03-22 | A kind of water-fast artificial quartz in lump and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107244832A (en) * | 2017-07-25 | 2017-10-13 | 宿松圣峰装饰材料有限公司 | A kind of cabinet table surface quartzy stone composite material of scrubbing resistance waterproof |
| CN107311524A (en) * | 2017-07-25 | 2017-11-03 | 宿松圣峰装饰材料有限公司 | One kind is floatd the quartzy stone composite material of window table color inhibition waterproof heat resistant |
Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101585902A (en) * | 2009-06-26 | 2009-11-25 | 湖南大学 | Fluorinated polyurethane nanometer composite material and preparation method thereof |
| CN101717478A (en) * | 2009-11-13 | 2010-06-02 | 清华大学 | Fluorinated polyurethane and preparation method thereof |
| CN102329100A (en) * | 2010-07-12 | 2012-01-25 | 周军 | Artificial quartz stone checkered plate and process thereof |
| CN102659348A (en) * | 2012-04-16 | 2012-09-12 | 武汉石尚高新建材有限公司 | Raw material of artificial quartzite plate and method for preparing artificial quartzite by using the same |
| CN103408249A (en) * | 2013-07-30 | 2013-11-27 | 广东中旗新材料科技有限公司 | Man-made quartz stone and preparation method thereof |
| CN103613325A (en) * | 2013-11-22 | 2014-03-05 | 廖荣刚 | Pattern quartz composite board and production method thereof |
| CN104478297A (en) * | 2014-11-12 | 2015-04-01 | 广东中旗新材料科技有限公司 | Lightweight artificial quartz stone and preparation method thereof |
| CN105152579A (en) * | 2015-08-07 | 2015-12-16 | 珠海色萨利健康石材有限公司 | Stone slab with patterns |
| CN105819740A (en) * | 2016-03-14 | 2016-08-03 | 广东中旗新材料科技有限公司 | Self-enhanced ceramic cold glaze and preparation method thereof |
| CN106116251A (en) * | 2016-06-24 | 2016-11-16 | 安徽弗仕通实业有限公司 | A kind of impact resistance artificial quartz in lump |
| CN106477971A (en) * | 2015-11-30 | 2017-03-08 | 衡阳市雅典娜石英石有限公司 | A kind of fire resisting quartz and preparation method thereof |
-
2017
- 2017-03-22 CN CN201710171976.9A patent/CN106866030A/en not_active Withdrawn
Patent Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101585902A (en) * | 2009-06-26 | 2009-11-25 | 湖南大学 | Fluorinated polyurethane nanometer composite material and preparation method thereof |
| CN101717478A (en) * | 2009-11-13 | 2010-06-02 | 清华大学 | Fluorinated polyurethane and preparation method thereof |
| CN102329100A (en) * | 2010-07-12 | 2012-01-25 | 周军 | Artificial quartz stone checkered plate and process thereof |
| CN102659348A (en) * | 2012-04-16 | 2012-09-12 | 武汉石尚高新建材有限公司 | Raw material of artificial quartzite plate and method for preparing artificial quartzite by using the same |
| CN103408249A (en) * | 2013-07-30 | 2013-11-27 | 广东中旗新材料科技有限公司 | Man-made quartz stone and preparation method thereof |
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Application publication date: 20170620 |