CN104496274A - Fireproof artificial quartz stone plate and manufacturing method thereof - Google Patents
Fireproof artificial quartz stone plate and manufacturing method thereof Download PDFInfo
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- CN104496274A CN104496274A CN201410775640.XA CN201410775640A CN104496274A CN 104496274 A CN104496274 A CN 104496274A CN 201410775640 A CN201410775640 A CN 201410775640A CN 104496274 A CN104496274 A CN 104496274A
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Abstract
The invention discloses a fireproof artificial quartz stone plate and a manufacturing method thereof. The artificial quartz stone plate comprises the following components in parts by weight: 30-80 parts of 6-100-mesh quartz stone, 30-60 parts of 325-mesh quartz powder, 5-15 parts of broken glass, 2-10 parts of shells, 5-10 parts of epoxy resin, 0.3-0.5 part of an adjuvant and 0.3-0.8 part of a pigment. Epoxy resin having a flame-retardant effect is added during the manufacturing process so that the artificial quartz stone plate has long-acting and stable flame retardant properties, the fireproof property is further improved and meanwhile, the manufacturing method is simple, is wide in market prospects and is suitable for industrial production.
Description
Technical field
The invention belongs to material of construction manufacturing technology field, specifically, refer to a kind of fireproof artificial quartz stone sheet material and manufacture method thereof.
Background technology
Artificial quartz in lump rises in Spain, cry match sharp stone when 2005 enter China, after artificial quartz in lump is by increasing consumer acceptance, China in 2006 starts someone and researches and develops artificial quartz in lump, within 2007, successively has a lot of producer to be proposed domestic artificial quartz in lump.
Artificial quartz in lump is the synthesis stone manufactured by artificial means, there is high strength, high rigidity, high temperature resistant, protection against corrosion, the unrivaled advantage of lithotome such as anti-aging, easy to clean, wear-resisting, radiationless, these advantages allow artificial quartz in lump become the upstart of architectural decoration, are widely applied to cabinet, bathroom, the ground of office and megastore, wall decoration and household industry.However, also there is certain drawback in artificial quartz stone plate, such as fire resistance is not good.In artificial quartz in lump production process, general resin content is all more than 6%, because resin is combustiblesubstance, when artificial quartz in lump resin content reaches more than 3%, its product fire resistance is extremely low, and then significantly limit the application of artificial quartz in lump at various complex condition, particularly in the use in large common facility and the high place of fire protection requirement.
Summary of the invention
Technical problem to be solved by this invention is not enough for prior art, provides a kind of fireproof artificial quartz stone sheet material and manufacture method thereof, adopts the artificial quartz stone plate of manufacture of the present invention to have excellent compressive property and fire retardant performance.
The technical scheme that the present invention solves the problems of the technologies described above is as follows: fireproof artificial quartz stone sheet material, be made up of the component of following parts by weight: 6 ~ 100 order quartzites 30 ~ 80 parts, 325 order silica powders 30 ~ 60 parts, glass cullet 5 ~ 15 parts, 2 ~ 10 parts, shell, epoxy resin 5 ~ 10 parts, auxiliary agent 0.3 ~ 0.5 part, pigment 0.3 ~ 0.8 part.
On the basis of technique scheme, the present invention can also do following improvement.
Further, be made up of the component of following parts by weight: 6 ~ 100 order quartzites 65 parts, 325 order silica powders 50 parts, glass cullet 10 parts, 5 parts, shell, epoxy resin 8 parts, auxiliary agent 0.4 part, pigment 0.6 part.
Further, described epoxy resin is one or more in brominated epoxy resin, chloride epoxy resin and phosphorous epoxy resin and nitrogen-containing epoxy thermoset.
Further, described auxiliary agent is the mixture of silane coupling agent and peroxide-2-ethyl hexanoic acid tert-butyl, and the part by weight of described silane coupling agent and peroxide-2-ethyl hexanoic acid tert-butyl is 4:1.
Further, described pigment be titanium dioxide, middle network bloom, iron oxide red, iron black powder, chrome green powder, Lan Shuizhong one or more.
The manufacture method of fireproof artificial quartz stone sheet material, comprise following processing step: the component taking following parts by weight: 6 ~ 100 order quartzites 30 ~ 80 parts, 325 order silica powders 30 ~ 60 parts, glass cullet 5 ~ 15 parts, 2 ~ 10 parts, shell, epoxy resin 5 ~ 10 parts, auxiliary agent 0.3 ~ 0.5 part, pigment 0.3 ~ 0.8 part, by above-mentioned each component Homogeneous phase mixing, the material mixed evenly is tiled on making sheet mould, then making sheet mould is sent into moulding press in vacuum, vibrate, add pressure and carry out shaping, send into curing oven solidification again, i.e. obtained artificial quartz stone plate.
On the basis of technique scheme, the present invention can also do following improvement.
Further, the temperature of described solidification is 90 ~ 95 DEG C, and the time is 30 ~ 40 minutes.
Further, pressure during described vibratory compaction is 2.5 ~ 3.5MPa, and molding time is 2 ~ 3 minutes.
The invention has the beneficial effects as follows:
(1) prevent fires: the present invention adopts the epoxy resin with flame retardant efficiency, makes artificial quartz stone plate have long-acting, stable flame retardant properties, and then also improves its fire resistance.
(2) manufacture method of the present invention is simple, and wide market, is suitable for suitability for industrialized production.
Embodiment
Be described principle of the present invention and feature below in conjunction with specific embodiment, example, only for explaining the present invention, is not intended to limit scope of the present invention.
Embodiment 1:
Take 6 ~ 100 order quartzite 30kg, 325 order silica powder 60kg, glass cullet 5kg, shell 10kg, brominated epoxy resin 5kg, part by weight is the γ-methacryloxypropyl trimethoxy silane (KH570) of 4:1 and the 0.5kg of peroxide-2-ethyl hexanoic acid tert-butyl mixture, pigment 0.3kg, and described pigment is made up of according to mass ratio 15:1 titanium dioxide and Lan Shui; By above-mentioned each component Homogeneous phase mixing, the material mixed evenly is tiled on making sheet mould, then making sheet mould is sent into moulding press, when when vacuumizing, air pressure reaches-0.1MPa, under 2.5 ~ 3.5MPa pressure vibrate 2 ~ 3 minutes shaping, then send into curing oven solidification, solidification value 90 ~ 95 DEG C, time is 30 ~ 40 minutes, i.e. obtained " white shell plate " artificial quartz stone plate.
Embodiment 2:
Take 6 ~ 100 order quartzite 80kg, 325 order silica powder 30kg, glass cullet 15kg, shell 2kg, chloride epoxy resin 10kg, part by weight is the γ-aminopropyl triethoxysilane (KH550) of 4:1 and the 0.3kg of peroxide-2-ethyl hexanoic acid tert-butyl mixture, pigment 0.8kg, and described pigment is made up of according to mass ratio 312:6:25:1:28 titanium dioxide, middle network bloom, iron oxide red, iron black powder and Lan Shui; By above-mentioned each component Homogeneous phase mixing, the material mixed evenly is tiled on making sheet mould, then making sheet mould is sent into moulding press, when when vacuumizing, air pressure reaches-0.1MPa, under 2.5 ~ 3.5MPa pressure vibrate 2 ~ 3 minutes shaping, then send into curing oven solidification, solidification value 90 ~ 95 DEG C, time is 30 ~ 40 minutes, i.e. obtained " light gray shell plate " artificial quartz stone plate.
Embodiment 3:
Take 6 ~ 100 order quartzite 65kg, 325 order silica powder 50kg, glass cullet 10kg, shell 5kg, phosphorous epoxy resin 8kg, part by weight is the γ-glycidyl ether oxygen propyl trimethoxy silicane of 4:1 and the 0.4kg of peroxide-2-ethyl hexanoic acid tert-butyl mixture, pigment 0.6kg, and described pigment is made up of according to mass ratio 300:30:1:2:27 titanium dioxide, middle network bloom, iron black powder, chrome green powder and Lan Shui; By above-mentioned each component Homogeneous phase mixing, the material mixed evenly is tiled on making sheet mould, then making sheet mould is sent into moulding press, when when vacuumizing, air pressure reaches-0.1MPa, under 2.5 ~ 3.5MPa pressure vibrate 2 ~ 3 minutes shaping, then send into curing oven solidification, solidification value 90 ~ 95 DEG C, time is 30 ~ 40 minutes, i.e. obtained " gorgeous yellow shell plate " artificial quartz stone plate.
The foregoing is only preferred embodiment of the present invention, not in order to limit the present invention, within the spirit and principles in the present invention all, any amendment done, equivalent replacement, improvement etc., all should be included within protection scope of the present invention.
Claims (8)
1. fireproof artificial quartz stone sheet material, is characterized in that, is made up of the component of following parts by weight: 6 ~ 100 order quartzites 30 ~ 80 parts, 325 order silica powders 30 ~ 60 parts, glass cullet 5 ~ 15 parts, 2 ~ 10 parts, shell, epoxy resin 5 ~ 10 parts, auxiliary agent 0.3 ~ 0.5 part, pigment 0.3 ~ 0.8 part.
2. fireproof artificial quartz stone sheet material according to claim 1, is characterized in that, is made up of the component of following parts by weight: 6 ~ 100 order quartzites 65 parts, 325 order silica powders 50 parts, glass cullet 10 parts, 5 parts, shell, epoxy resin 8 parts, auxiliary agent 0.4 part, pigment 0.6 part.
3. fireproof artificial quartz stone sheet material according to claim 1 and 2, is characterized in that, described epoxy resin is one or more in brominated epoxy resin, chloride epoxy resin and phosphorous epoxy resin and nitrogen-containing epoxy thermoset.
4. fireproof artificial quartz stone sheet material according to claim 1 and 2, it is characterized in that, described auxiliary agent is the mixture of silane coupling agent and peroxide-2-ethyl hexanoic acid tert-butyl, and the part by weight of described silane coupling agent and peroxide-2-ethyl hexanoic acid tert-butyl is 4:1.
5. fireproof artificial quartz stone sheet material according to claim 1 and 2, is characterized in that, described pigment be titanium dioxide, middle network bloom, iron oxide red, iron black powder, chrome green powder, Lan Shuizhong one or more.
6. the manufacture method of fireproof artificial quartz stone sheet material, it is characterized in that, comprise following processing step: the component taking following parts by weight: 6 ~ 100 order quartzites 30 ~ 80 parts, 325 order silica powders 30 ~ 60 parts, glass cullet 5 ~ 15 parts, 2 ~ 10 parts, shell, epoxy resin 5 ~ 10 parts, auxiliary agent 0.3 ~ 0.5 part, pigment 0.3 ~ 0.8 part, by above-mentioned each component Homogeneous phase mixing, the material mixed evenly is tiled on making sheet mould, then making sheet mould is sent into moulding press in vacuum, vibration, adding pressure carries out shaping, send into curing oven solidification again, i.e. obtained artificial quartz stone plate.
7. the manufacture method of fireproof artificial quartz stone sheet material according to claim 6, is characterized in that, the temperature of described solidification is 90 ~ 95 DEG C, and the time is 30 ~ 40 minutes.
8. the manufacture method of fireproof artificial quartz stone sheet material according to claim 6, is characterized in that, pressure during described vibratory compaction is 2.5 ~ 3.5MPa, and molding time is 2 ~ 3 minutes.
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| CN201410775640.XA CN104496274A (en) | 2014-12-15 | 2014-12-15 | Fireproof artificial quartz stone plate and manufacturing method thereof |
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| CN201410775640.XA CN104496274A (en) | 2014-12-15 | 2014-12-15 | Fireproof artificial quartz stone plate and manufacturing method thereof |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105924035A (en) * | 2016-06-30 | 2016-09-07 | 禹州市远大塑料电器有限责任公司 | Quartz stone plate and preparation process thereof |
| CN106116248A (en) * | 2016-06-30 | 2016-11-16 | 禹州市远大塑料电器有限责任公司 | A kind of quartz cabinet face and preparation technology thereof |
| CN106186817A (en) * | 2016-06-30 | 2016-12-07 | 禹州市远大塑料电器有限责任公司 | A kind of fire prevention quartzite slate and preparation technology thereof |
| CN106186816A (en) * | 2016-06-30 | 2016-12-07 | 禹州市远大塑料电器有限责任公司 | A kind of environment protection type sheet material and preparation technology thereof |
| CN107445559A (en) * | 2017-09-11 | 2017-12-08 | 东莞环球经典新型材料有限公司 | One kind fire prevention UV resistant artificial slabstone and preparation method thereof |
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| KR20080070345A (en) * | 2007-01-26 | 2008-07-30 | 주식회사 엘지화학 | Artificial marble having various designs and process for preparing the same |
| CN101337805A (en) * | 2008-08-25 | 2009-01-07 | 张璐 | Artificial quartz in lump and fabrication technology thereof |
| CN102584115A (en) * | 2011-12-20 | 2012-07-18 | 汪洋 | Fireproof material, preparation method thereof and fireproof door |
| CN103204660A (en) * | 2013-03-20 | 2013-07-17 | 安徽瑞翔石英制品有限公司 | High-hardness artificial quartz stone plate and production process thereof |
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| KR20080070345A (en) * | 2007-01-26 | 2008-07-30 | 주식회사 엘지화학 | Artificial marble having various designs and process for preparing the same |
| CN101337805A (en) * | 2008-08-25 | 2009-01-07 | 张璐 | Artificial quartz in lump and fabrication technology thereof |
| CN102584115A (en) * | 2011-12-20 | 2012-07-18 | 汪洋 | Fireproof material, preparation method thereof and fireproof door |
| CN103204660A (en) * | 2013-03-20 | 2013-07-17 | 安徽瑞翔石英制品有限公司 | High-hardness artificial quartz stone plate and production process thereof |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105924035A (en) * | 2016-06-30 | 2016-09-07 | 禹州市远大塑料电器有限责任公司 | Quartz stone plate and preparation process thereof |
| CN106116248A (en) * | 2016-06-30 | 2016-11-16 | 禹州市远大塑料电器有限责任公司 | A kind of quartz cabinet face and preparation technology thereof |
| CN106186817A (en) * | 2016-06-30 | 2016-12-07 | 禹州市远大塑料电器有限责任公司 | A kind of fire prevention quartzite slate and preparation technology thereof |
| CN106186816A (en) * | 2016-06-30 | 2016-12-07 | 禹州市远大塑料电器有限责任公司 | A kind of environment protection type sheet material and preparation technology thereof |
| CN107445559A (en) * | 2017-09-11 | 2017-12-08 | 东莞环球经典新型材料有限公司 | One kind fire prevention UV resistant artificial slabstone and preparation method thereof |
| CN107445559B (en) * | 2017-09-11 | 2020-04-24 | 东莞环球经典新型材料有限公司 | Fireproof ultraviolet-resistant artificial stone plate and preparation method thereof |
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Application publication date: 20150408 |