CN104529247A - Super-hardness and antibacterial artificial quartzite plate and manufacture method thereof - Google Patents
Super-hardness and antibacterial artificial quartzite plate and manufacture method thereof Download PDFInfo
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- CN104529247A CN104529247A CN201410778388.8A CN201410778388A CN104529247A CN 104529247 A CN104529247 A CN 104529247A CN 201410778388 A CN201410778388 A CN 201410778388A CN 104529247 A CN104529247 A CN 104529247A
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Abstract
The invention discloses a super-hardness and antibacterial artificial quartzite plate and a manufacture method thereof. The artificial quartzite plate disclosed by the invention is composed of the following components in parts by weight: 30-90 parts of 6-80-mesh calcined quartzite, 20-60 parts of 325-mesh quartz powder, 5-15 parts of cullet, 5-10 parts of shell, 5-20 parts of 30-50-mesh tourmaline, 5-10 parts of unsaturated resin, 0.1-5 parts of a silane coupling agent, 0.1-5 parts of a curing agent and 0.3-0.8 part of pigment. By means of adoption of the calcined quartzite, the hardness of the artificial quartzite plate is increased; therefore, the artificial quartzite plate is more wearable, difficult to scratch and long in service life; and simultaneously, because the tourmaline is added, the antibacterial property of the artificial quartzite plate disclosed by the invention can be improved.
Description
Technical field
The invention belongs to material of construction manufacturing technology field, specifically, refer to a kind of exceptional hardness, antibacterial artificial quartzite sheet material and manufacture method thereof.
Background technology
Artificial quartz in lump is as the substitute of lithotome, have high strength, high rigidity, high temperature resistant, protection against corrosion, anti-aging, easy to clean, wear-resisting, material is consummate, the unrivaled advantage of lithotome such as radiationless, now be widely used in the daily life of industrial production and the people, as the decorative material material of floor tile, metope etc.
But the artificial quartz in lump that prior art manufactures, exist density unevenness, hardness low, easily tie powder ball, yielding, easily aging, easily enter look, color and pattern single, not there is the defects such as anti-microbial effect, limit its larger application on a large scale, urgently to be resolved hurrily.
Summary of the invention
Technical problem to be solved by this invention is not enough for prior art, provides a kind of exceptional hardness, antibacterial artificial quartzite sheet material and manufacture method thereof, and the artificial quartz stone plate hardness adopting the present invention to manufacture is high, wear resisting property good, anti-microbial property good.
The technical scheme that the present invention solves the problems of the technologies described above is as follows: exceptional hardness, antibacterial artificial quartzite sheet material, be made up of the component of following parts by weight: 6 ~ 80 30 ~ 90 parts, order calcining quartz stones, 325 order silica powders 20 ~ 60 parts, glass cullet 5 ~ 15 parts, 5 ~ 10 parts, shell, 30 ~ 50 5 ~ 20 parts, order tourmalinite, unsaturated polyester 5 ~ 10 parts, silane coupling agent 0.1 ~ 5 part, 0.1 ~ 5 part, solidifying agent, pigment 0.3 ~ 0.8 part.
On the basis of technique scheme, the present invention can also do following improvement.
Further, be made up of the component of following parts by weight: 6 ~ 80 70 parts, order calcining quartz stones, 325 order silica powders 40 parts, glass cullet 10 parts, 8 parts, shell, 30 ~ 50 15 parts, order tourmalinite, unsaturated polyester 8 parts, silane coupling agent 2 parts, 2 parts, solidifying agent, pigment 0.5 part.
Further, described calcining quartz stone is that quartzite forms through 1600 ~ 1800 DEG C of high-temperature calcinations.
Further, described unsaturated polyester is one or more in epoxy resin, resol, acryl resin and urethane resin.
Further, described silane coupling agent is the one in γ-methacryloxypropyl trimethoxy silane, γ-aminopropyl triethoxysilane, γ-glycidyl ether oxygen propyl trimethoxy silicane, vinyl three ('beta '-methoxy oxyethyl group) silane, vinyltriethoxysilane or γ-divinyl triammonium base propyl-triethoxysilicane.
Further, described solidifying agent is the one in peroxide-2-ethyl hexanoic acid tert-butyl, peroxidized t-butyl perbenzoate or benzoyl peroxide.
Further, described pigment be titanium dioxide, iron oxide yellow powder, iron oxide red, iron black powder, chrome green powder, Lan Shuizhong one or more.
Exceptional hardness, the manufacture method of antibacterial artificial quartzite sheet material, comprise following processing step: the component taking following parts by weight: 6 ~ 80 30 ~ 90 parts, order calcining quartz stones, 325 order silica powders 20 ~ 60 parts, glass cullet 5 ~ 15 parts, 5 ~ 10 parts, shell, 30 ~ 50 5 ~ 20 parts, order tourmalinite, unsaturated polyester 5 ~ 10 parts, silane coupling agent 0.1 ~ 5 part, 0.1 ~ 5 part, solidifying agent, pigment 0.3 ~ 0.8 part, by above-mentioned each component Homogeneous phase mixing, the material mixed evenly is tiled on making sheet mould, then making sheet mould is sent into moulding press in vacuum, vibration, adding pressure carries out shaping, send into curing oven solidification again, i.e. obtained artificial quartz stone plate.
On the basis of technique scheme, the present invention can also do following improvement.
Further, described shaping time pressure be 2.5 ~ 3.5MPa, molding time is 2 ~ 3 minutes.
Further, the temperature of described solidification is 90 ~ 95 DEG C, and the time is 30 ~ 40 minutes.
The invention has the beneficial effects as follows:
(1) exceptional hardness: calcining quartz stone of the present invention is through 1600 ~ 1800 DEG C of high-temperature calcinations and forms, it was oxidized originally, weathering material is burnt, and making its density better fused, is a kind of exceptional hardness, anti-biotic material.Add calcining quartz stone in the feed, improve the hardness of artificial quartz stone plate, make that it is more wear-resisting, not easily scratch, increase work-ing life.
(2) antibacterial: tourmalinite is ring texture silicate minerals, there is the special performances such as piezoelectricity, pyroelectric, far-infrared radiation and anion releasing, the present invention with the addition of tourmalinite in the feed, effectively can increase the germ resistance of artificial quartz stone plate, and antibiotic effect is for a long time special.
(3) manufacture method of the present invention is simple, and wide market, is suitable for suitability for industrialized production.
Embodiment
Be described principle of the present invention and feature below in conjunction with specific embodiment, example, only for explaining the present invention, is not intended to limit scope of the present invention.
Embodiment 1:
Take 6 ~ 80 order calcining quartz stone 30kg, 325 order silica powder 60kg, glass cullet 5kg, shell 10kg, 30 ~ 50 order tourmalinite 5kg, epoxy resin 10kg, silane coupling agent γ-methacryloxypropyl trimethoxy silane (KH570) 0.1kg, peroxide-2-ethyl hexanoic acid tert-butyl 5kg, pigment 0.3kg, described pigment is made up of according to mass ratio 15:1 titanium dioxide and Lan Shui; By above-mentioned each component Homogeneous phase mixing, the material mixed evenly is tiled on making sheet mould, then making sheet mould is sent into moulding press, when when vacuumizing, air pressure reaches-0.1MPa, under 2.5 ~ 3.5MPa pressure vibrate 2 ~ 3 minutes shaping, then send into curing oven solidification, solidification value 90 ~ 95 DEG C, time is 30 ~ 40 minutes, i.e. obtained " white shell plate " artificial quartz stone plate.
Embodiment 2:
Take 6 ~ 80 order calcining quartz stone 90kg, 325 order silica powder 20kg, glass cullet 15kg, shell 5kg, 30 ~ 50 order tourmalinite 20kg, resol 5kg, silane coupling agent γ-aminopropyl triethoxysilane (KH550) 5kg, peroxidized t-butyl perbenzoate 0.1kg, pigment 0.8kg, described pigment is titanium dioxide, iron oxide yellow powder, blue powder, iron black powder, Lan Shuizhong form according to mass ratio 560:6:1:3:37; By above-mentioned each component Homogeneous phase mixing, the material mixed evenly is tiled on making sheet mould, then making sheet mould is sent into moulding press, when when vacuumizing, air pressure reaches-0.1MPa, under 2.5 ~ 3.5MPa pressure vibrate 2 ~ 3 minutes shaping, then send into curing oven solidification, solidification value 90 ~ 95 DEG C, time is 30 ~ 40 minutes, i.e. obtained " shallow steel gray shell plate " artificial quartz stone plate.
Embodiment 3:
Take 6 ~ 80 order calcining quartz stone 70kg, 325 order silica powder 40kg, glass cullet 10kg, shell 8kg, 30 ~ 50 order tourmalinite 15kg, urethane resin 8kg, silane coupling agent γ-glycidyl ether oxygen propyl trimethoxy silicane 2kg, benzoyl peroxide 2kg, pigment 0.5kg, described pigment is made up of according to mass ratio 606:1:2:36 titanium dioxide, blue powder, iron oxide yellow powder and Lan Shui; By above-mentioned each component Homogeneous phase mixing, the material mixed evenly is tiled on making sheet mould, then making sheet mould is sent into moulding press, when when vacuumizing, air pressure reaches-0.1MPa, under 2.5 ~ 3.5MPa pressure vibrate 2 ~ 3 minutes shaping, then send into curing oven solidification, solidification value 90 ~ 95 DEG C, time is 30 ~ 40 minutes, i.e. obtained " light blue shell plate " artificial quartz stone plate.
The foregoing is only preferred embodiment of the present invention, not in order to limit the present invention, within the spirit and principles in the present invention all, any amendment done, equivalent replacement, improvement etc., all should be included within protection scope of the present invention.
Claims (10)
1. exceptional hardness, antibacterial artificial quartzite sheet material, it is characterized in that, be made up of the component of following parts by weight: 6 ~ 80 30 ~ 90 parts, order calcining quartz stones, 325 order silica powders 20 ~ 60 parts, glass cullet 5 ~ 15 parts, 5 ~ 10 parts, shell, 30 ~ 50 5 ~ 20 parts, order tourmalinite, unsaturated polyester 5 ~ 10 parts, silane coupling agent 0.1 ~ 5 part, 0.1 ~ 5 part, solidifying agent, pigment 0.3 ~ 0.8 part.
2. exceptional hardness according to claim 1, antibacterial artificial quartzite sheet material, it is characterized in that, be made up of the component of following parts by weight: 6 ~ 80 70 parts, order calcining quartz stones, 325 order silica powders 40 parts, glass cullet 10 parts, 8 parts, shell, 30 ~ 50 15 parts, order tourmalinite, unsaturated polyester 8 parts, silane coupling agent 2 parts, 2 parts, solidifying agent, pigment 0.5 part.
3. exceptional hardness according to claim 1 and 2, antibacterial artificial quartzite sheet material, is characterized in that, described calcining quartz stone is that quartzite forms through 1600 ~ 1800 DEG C of high-temperature calcinations.
4. exceptional hardness according to claim 1 and 2, antibacterial artificial quartzite sheet material, is characterized in that, described unsaturated polyester is one or more in epoxy resin, resol, acryl resin and urethane resin.
5. exceptional hardness according to claim 1 and 2, antibacterial artificial quartzite sheet material, it is characterized in that, described silane coupling agent is the one in γ-methacryloxypropyl trimethoxy silane, γ-aminopropyl triethoxysilane, γ-glycidyl ether oxygen propyl trimethoxy silicane, vinyl three ('beta '-methoxy oxyethyl group) silane, vinyltriethoxysilane or γ-divinyl triammonium base propyl-triethoxysilicane.
6. exceptional hardness according to claim 1 and 2, antibacterial artificial quartzite sheet material, is characterized in that, described solidifying agent is the one in peroxide-2-ethyl hexanoic acid tert-butyl, peroxidized t-butyl perbenzoate or benzoyl peroxide.
7. exceptional hardness according to claim 1 and 2, antibacterial artificial quartzite sheet material, is characterized in that, described pigment be titanium dioxide, iron oxide yellow powder, iron oxide red, iron black powder, chrome green powder, Lan Shuizhong one or more.
8. exceptional hardness, the manufacture method of antibacterial artificial quartzite sheet material, it is characterized in that, comprise following processing step: the component taking following parts by weight: 6 ~ 80 30 ~ 90 parts, order calcining quartz stones, 325 order silica powders 20 ~ 60 parts, glass cullet 5 ~ 15 parts, 5 ~ 10 parts, shell, 30 ~ 50 5 ~ 20 parts, order tourmalinite, unsaturated polyester 5 ~ 10 parts, silane coupling agent 0.1 ~ 5 part, 0.1 ~ 5 part, solidifying agent, pigment 0.3 ~ 0.8 part, by above-mentioned each component Homogeneous phase mixing, the material mixed evenly is tiled on making sheet mould, then making sheet mould is sent into moulding press in vacuum, vibration, adding pressure carries out shaping, send into curing oven solidification again, i.e. obtained artificial quartz stone plate.
9. the manufacture method of exceptional hardness according to claim 8, antibacterial artificial quartzite sheet material, is characterized in that, described shaping time pressure be 2.5 ~ 3.5MPa, molding time is 2 ~ 3 minutes.
10. the manufacture method of exceptional hardness according to claim 8, antibacterial artificial quartzite sheet material, is characterized in that, the temperature of described solidification is 90 ~ 95 DEG C, and the time is 30 ~ 40 minutes.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106116251A (en) * | 2016-06-24 | 2016-11-16 | 安徽弗仕通实业有限公司 | A kind of impact resistance artificial quartz in lump |
| CN106495641A (en) * | 2016-10-29 | 2017-03-15 | 常州亚环环保科技有限公司 | A kind of preparation method of automatically cleaning composite artificial shone material |
| CN106810106A (en) * | 2015-11-30 | 2017-06-09 | 衡阳市雅典娜石英石有限公司 | A kind of antibacterial quartz and preparation method thereof |
| CN106810121A (en) * | 2015-11-30 | 2017-06-09 | 衡阳市雅典娜石英石有限公司 | A kind of environmentally friendly quartz and preparation method thereof |
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| CN106810106A (en) * | 2015-11-30 | 2017-06-09 | 衡阳市雅典娜石英石有限公司 | A kind of antibacterial quartz and preparation method thereof |
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Application publication date: 20150422 |