CN104529245A - Fireproof manmade quartz stone slab with superhardness and manufacturing method of fireproof manmade quartz stone slab - Google Patents
Fireproof manmade quartz stone slab with superhardness and manufacturing method of fireproof manmade quartz stone slab Download PDFInfo
- Publication number
- CN104529245A CN104529245A CN201410775207.6A CN201410775207A CN104529245A CN 104529245 A CN104529245 A CN 104529245A CN 201410775207 A CN201410775207 A CN 201410775207A CN 104529245 A CN104529245 A CN 104529245A
- Authority
- CN
- China
- Prior art keywords
- powder
- parts
- quartz stone
- order
- manmade
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a fireproof manmade quartz stone slab with superhardness and a manufacturing method of the fireproof manmade quartz stone slab. The manmade quartz stone slab is manufactured from the following components in parts by weight: 30-80 parts of 6-80-mesh calcined quartz stones, 30-60 parts of 325-mesh quartz powder, 5-10 parts of cullet, 10-20 parts of 50-100-mesh red-silica powder or quartzitic sandstone powder, 5-15 parts of 100-150-mesh kyanite powder or andalusite powder or sillimanite powder, 1-10 parts of 100-200-mesh zirconium silicate or yttria-stabilized zirconia powder, 5-10 parts of unsaturated resins, 0.3-0.5 part of auxiliary, and 0.3-0.8 part of pigment. According to the fireproof manmade quartz stone slab, the red-silica powder, quartzitic sandstone powder, kyanite powder or andalusite powder or sillimanite powder, and zirconium silicate or yttria-stabilized zirconia powder is added in a manufacturing process, so that the compressive property and the fireproof flame retardant performance of the manmade quartz stone slab are improved; meanwhile, by using the calcined quartz stones, the hardness of the manmade quartz stone slab is improved, so that the fireproof manmade quartz stone slab with superhardness is relatively wearproof, difficult to scratch and long in service life.
Description
Technical field
The invention belongs to material of construction manufacturing technology field, specifically, refer to a kind of fire prevention, exceptional hardness artificial quartz stone plate and manufacture method thereof.
Background technology
Artificial quartz stone plate is compared with artificial marble sheet material, there is the features such as sinuousness is high, compressive strength is high, Mohs' hardness is high, water-intake rate is low, gradually like by domestic and international users, be widely applied to cabinet, bathroom, the ground of office and megastore, wall decoration and household industry.But artificial quartz stone plate hardness ratio is in the market lower, wears no resistance, fire resistance is not good, limits artificial quartz in lump in wider application, urgently to be resolved hurrily.
Summary of the invention
Technical problem to be solved by this invention is not enough for prior art, and provide a kind of fire prevention, exceptional hardness artificial quartz stone plate and manufacture method thereof, the artificial quartz stone plate fire retardant performance adopting the present invention to manufacture is excellent, hardness is high, wear resistance good.
The technical scheme that the present invention solves the problems of the technologies described above is as follows: fire prevention, exceptional hardness artificial quartz stone plate, be made up of the component of following parts by weight: 6 ~ 100 30 ~ 80 parts, order calcining quartz stones, 325 order silica powders 30 ~ 60 parts, glass cullet 5 ~ 10 parts, 50 ~ 100 order red beach powder or 10 ~ 20 parts, white afrodite powder, 100 ~ 150 order aquamaine stone flours or andaluzite powder or 5 ~ 15 parts, sillimanite powder, 100 ~ 200 order zirconium silicate powders or 1 ~ 10 part, yttrium stable zirconium oxide powder, unsaturated polyester 5 ~ 10 parts, auxiliary agent 0.3 ~ 0.5 part, pigment 0.3 ~ 0.8 part.
On the basis of technique scheme, the present invention can also do following improvement.
Further, be made up of the component of following parts by weight: 6 ~ 80 65 parts, order calcining quartz stones, 325 order silica powders 45 parts, glass cullet 8 parts, 50 ~ 100 order red beach powder or 12 parts, white afrodite powder, 100 ~ 150 order aquamaine stone flours or andaluzite powder or 8 parts, sillimanite powder, 100 ~ 200 order zirconium silicate powders or 5 parts, yttrium stable zirconium oxide powder, unsaturated polyester 8 parts, auxiliary agent 0.4 part, pigment 0.5 part.
Further, described calcining quartz stone is that quartzite forms through 1600 ~ 1800 DEG C of high-temperature calcinations.
Further, described unsaturated polyester is one or more in epoxy resin, resol, acryl resin and urethane resin.
Further, described auxiliary agent is the mixture of silane coupling agent and peroxide-2-ethyl hexanoic acid tert-butyl, and the part by weight of described silane coupling agent and peroxide-2-ethyl hexanoic acid tert-butyl is 4:1.
Further, described pigment be titanium dioxide, middle network bloom, iron oxide red, iron black powder, chrome green powder, phenolphthalein blue powder, Lan Shuizhong one or more.
Fire prevention, the manufacture method of exceptional hardness artificial quartz stone plate, comprise following processing step: the component taking following parts by weight: 6 ~ 80 30 ~ 80 parts, order calcining quartz stones, 325 order silica powders 30 ~ 60 parts, glass cullet 5 ~ 10 parts, 50 ~ 100 order red beach powder or 10 ~ 20 parts, white afrodite powder, 100 ~ 150 order aquamaine stone flours or andaluzite powder or 5 ~ 15 parts, sillimanite powder, 100 ~ 200 order zirconium silicate powders or 1 ~ 10 part, yttrium stable zirconium oxide powder, unsaturated polyester 5 ~ 10 parts, auxiliary agent 0.3 ~ 0.5 part, pigment 0.3 ~ 0.8 part, by above-mentioned each component Homogeneous phase mixing, the material mixed evenly is tiled on making sheet mould, then making sheet mould is sent into moulding press in vacuum, vibration, adding pressure carries out shaping, send into curing oven solidification again, i.e. obtained artificial quartz stone plate.
On the basis of technique scheme, the present invention can also do following improvement.
Further, described shaping time pressure be 2.5 ~ 3.5MPa, molding time is 2 ~ 3 minutes.
Further, the temperature of described solidification is 90 ~ 95 DEG C, and the time is 30 ~ 40 minutes.
The invention has the beneficial effects as follows:
(1) fire prevention, resistance to compression: the highest refractory temperature of red beach powder and white afrodite powder all reaches more than 1700 DEG C.Aquamaine stone flour, andaluzite powder, sillimanite powder are also good refractory materialss, and they can improve refractory temperature, prolongation fire resistance period, the increase ultimate compression strength of artificial quartz stone plate of the present invention.The fusing point of zirconium silicate powder is 2500 DEG C, and hardness is 7.5 ~ 8.0, and the fusing point of same yttrium stable zirconium oxide powder and hardness are also very high, and they can play the effect improving refractory temperature, increase ultimate compression strength.
(2) exceptional hardness: calcining quartz sand of the present invention is through 1600 ~ 1800 DEG C of high-temperature calcinations and forms, it was oxidized originally, weathering material is burnt, and making its density better fused, is a kind of superhard material.Add calcining quartz stone in the feed, improve the hardness of artificial quartz stone plate, make that it is more wear-resisting, not easily scratch, increase work-ing life.
(3) manufacture method of the present invention is simple, and wide market, is suitable for suitability for industrialized production.
Embodiment
Be described principle of the present invention and feature below in conjunction with specific embodiment, example, only for explaining the present invention, is not intended to limit scope of the present invention.
Embodiment 1:
Take 6 ~ 80 order calcining quartz stone 30kg, 325 order silica powder 60kg, glass cullet 5kg, 50 ~ 100 order red beach powder 20kg, 100 ~ 150 order sillimanite powder 5kg, 100 ~ 200 order zirconium silicate powder 10kg, epoxy resin 5kg, part by weight is the γ-methacryloxypropyl trimethoxy silane (KH570) of 4:1 and the 0.5kg of peroxide-2-ethyl hexanoic acid tert-butyl mixture, pigment 0.3kg, and described pigment is made up of according to mass ratio 18:1 titanium dioxide and Lan Shui; By above-mentioned each component Homogeneous phase mixing, the material mixed evenly is tiled on making sheet mould, then making sheet mould is sent into moulding press, when when vacuumizing, air pressure reaches-0.1MPa, under 2.5 ~ 3.5MPa pressure vibrate 2 ~ 3 minutes shaping, then send into curing oven solidification, solidification value 90 ~ 95 DEG C, time is 30 ~ 40 minutes, i.e. obtained " white board " artificial quartz stone plate.
Embodiment 2:
Take 6 ~ 80 order calcining quartz stone 80kg, 325 order silica powder 30kg, glass cullet 10kg, 50 ~ 100 order white afrodite powder 10kg, 100 ~ 150 order aquamaine stone flour 15kg, 100 ~ 200 order yttrium stable zirconium oxide powder 1kg, resol 10kg, part by weight is the γ-aminopropyl triethoxysilane (KH550) of 4:1 and the 0.3kg of peroxide-2-ethyl hexanoic acid tert-butyl mixture, pigment 0.8kg, described pigment is made up of according to mass ratio 312:6:25:1:28 titanium dioxide, iron oxide yellow powder, iron black powder, phenolphthalein blue powder and Lan Shui; By above-mentioned each component Homogeneous phase mixing, the material mixed evenly is tiled on making sheet mould, then making sheet mould is sent into moulding press, when when vacuumizing, air pressure reaches-0.1MPa, under 2.5 ~ 3.5MPa pressure vibrate 2 ~ 3 minutes shaping, then send into curing oven solidification, solidification value 90 ~ 95 DEG C, time is 30 ~ 40 minutes, i.e. obtained " light gray plate " artificial quartz stone plate.
Embodiment 3:
Take 6 ~ 80 order calcining quartz stone 65kg, 325 order silica powder 45kg, glass cullet 8kg, 50 ~ 100 order white afrodite powder 12kg, 100 ~ 150 order andaluzite powder 8kg, 100 ~ 200 order zirconium silicate powder 5kg, urethane resin 8kg, part by weight is the γ-glycidyl ether oxygen propyl trimethoxy silicane of 4:1 and the 0.4kg of peroxide-2-ethyl hexanoic acid tert-butyl mixture, pigment 0.5kg, described pigment is made up of according to mass ratio 300:30:1:2:27 titanium dioxide, middle network bloom, iron black powder, chrome green powder and Lan Shui; By above-mentioned each component Homogeneous phase mixing, the material mixed evenly is tiled on making sheet mould, then making sheet mould is sent into moulding press, when when vacuumizing, air pressure reaches-0.1MPa, under 2.5 ~ 3.5MPa pressure vibrate 2 ~ 3 minutes shaping, then send into curing oven solidification, solidification value 90 ~ 95 DEG C, time is 30 ~ 40 minutes, i.e. obtained " gorgeous yellow plate " artificial quartz stone plate.
The foregoing is only preferred embodiment of the present invention, not in order to limit the present invention, within the spirit and principles in the present invention all, any amendment done, equivalent replacement, improvement etc., all should be included within protection scope of the present invention.
Claims (9)
1. fire prevention, exceptional hardness artificial quartz stone plate, it is characterized in that, be made up of the component of following parts by weight: 6 ~ 80 30 ~ 80 parts, order calcining quartz stones, 325 order silica powders 30 ~ 60 parts, glass cullet 5 ~ 10 parts, 50 ~ 100 order red beach powder or 10 ~ 20 parts, white afrodite powder, 100 ~ 150 order aquamaine stone flours or andaluzite powder or 5 ~ 15 parts, sillimanite powder, 100 ~ 200 order zirconium silicate powders or 1 ~ 10 part, yttrium stable zirconium oxide powder, unsaturated polyester 5 ~ 10 parts, auxiliary agent 0.3 ~ 0.5 part, pigment 0.3 ~ 0.8 part.
2. fire prevention according to claim 1, exceptional hardness artificial quartz stone plate, it is characterized in that, be made up of the component of following parts by weight: 6 ~ 80 65 parts, order calcining quartz stones, 325 order silica powders 45 parts, glass cullet 8 parts, 50 ~ 100 order red beach powder or 12 parts, white afrodite powder, 100 ~ 150 order aquamaine stone flours or andaluzite powder or 8 parts, sillimanite powder, 100 ~ 200 order zirconium silicate powders or 5 parts, yttrium stable zirconium oxide powder, unsaturated polyester 8 parts, auxiliary agent 0.4 part, pigment 0.5 part.
3. fire prevention according to claim 1 and 2, exceptional hardness artificial quartz stone plate, is characterized in that, described calcining quartz stone is that quartzite forms through 1600 ~ 1800 DEG C of high-temperature calcinations.
4. fire prevention according to claim 1 and 2, exceptional hardness artificial quartz stone plate, is characterized in that, described unsaturated polyester is one or more in epoxy resin, resol, acryl resin and urethane resin.
5. fire prevention according to claim 1 and 2, exceptional hardness artificial quartz stone plate, it is characterized in that, described auxiliary agent is the mixture of silane coupling agent and peroxide-2-ethyl hexanoic acid tert-butyl, and the part by weight of described silane coupling agent and peroxide-2-ethyl hexanoic acid tert-butyl is 4:1.
6. fire prevention according to claim 1 and 2, exceptional hardness artificial quartz stone plate, is characterized in that, described pigment be titanium dioxide, middle network bloom, iron oxide red, iron black powder, chrome green powder, phenolphthalein blue powder, Lan Shuizhong one or more.
7. prevent fires, the manufacture method of exceptional hardness artificial quartz stone plate, it is characterized in that, comprise following processing step: the component taking following parts by weight: 6 ~ 80 30 ~ 80 parts, order calcining quartz stones, 325 order silica powders 30 ~ 60 parts, glass cullet 5 ~ 10 parts, 50 ~ 100 order red beach powder or 10 ~ 20 parts, white afrodite powder, 100 ~ 150 order aquamaine stone flours or andaluzite powder or 5 ~ 15 parts, sillimanite powder, 100 ~ 200 order zirconium silicate powders or 1 ~ 10 part, yttrium stable zirconium oxide powder, unsaturated polyester 5 ~ 10 parts, auxiliary agent 0.3 ~ 0.5 part, pigment 0.3 ~ 0.8 part, by above-mentioned each component Homogeneous phase mixing, the material mixed evenly is tiled on making sheet mould, then making sheet mould is sent into moulding press in vacuum, vibration, adding pressure carries out shaping, send into curing oven solidification again, i.e. obtained artificial quartz stone plate.
8. the manufacture method of fire prevention according to claim 7, exceptional hardness artificial quartz stone plate, is characterized in that, described shaping time pressure be 2.5 ~ 3.5MPa, molding time is 2 ~ 3 minutes.
9. the manufacture method of fire prevention according to claim 7, exceptional hardness artificial quartz stone plate, is characterized in that, the temperature of described solidification is 90 ~ 95 DEG C, and the time is 30 ~ 40 minutes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410775207.6A CN104529245A (en) | 2014-12-15 | 2014-12-15 | Fireproof manmade quartz stone slab with superhardness and manufacturing method of fireproof manmade quartz stone slab |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410775207.6A CN104529245A (en) | 2014-12-15 | 2014-12-15 | Fireproof manmade quartz stone slab with superhardness and manufacturing method of fireproof manmade quartz stone slab |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104529245A true CN104529245A (en) | 2015-04-22 |
Family
ID=52844934
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410775207.6A Pending CN104529245A (en) | 2014-12-15 | 2014-12-15 | Fireproof manmade quartz stone slab with superhardness and manufacturing method of fireproof manmade quartz stone slab |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104529245A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106145774A (en) * | 2016-06-24 | 2016-11-23 | 安徽弗仕通实业有限公司 | A kind of flame-proof explosion-proof artificial quartz in lump |
| CN106145810A (en) * | 2016-06-24 | 2016-11-23 | 安徽弗仕通实业有限公司 | A kind of artificial stone of resistance to water logging and preparation method thereof |
| CN106186822A (en) * | 2016-06-30 | 2016-12-07 | 禹州市远大塑料电器有限责任公司 | A kind of wear-resisting quartzite slate and preparation technology thereof |
| CN106477971A (en) * | 2015-11-30 | 2017-03-08 | 衡阳市雅典娜石英石有限公司 | A kind of fire resisting quartz and preparation method thereof |
| CN107892507A (en) * | 2017-11-07 | 2018-04-10 | 桂林奥尼斯特节能环保科技有限责任公司 | A kind of superhard artificial quartz stone plate and preparation method thereof |
| CN109320171A (en) * | 2018-12-07 | 2019-02-12 | 袁建辉 | A kind of high rigidity artificial stone material and preparation method |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH09255880A (en) * | 1996-03-22 | 1997-09-30 | Takahashi Seisakusho:Kk | Biodegradable plastic composition |
| CN101337805A (en) * | 2008-08-25 | 2009-01-07 | 张璐 | Artificial quartz in lump and fabrication technology thereof |
| CN102390953A (en) * | 2011-08-12 | 2012-03-28 | 新云石业（云浮）有限公司 | Raw material of antibacterial superhard artificial quartz stone plate, artificial quartz stone plate and preparation method thereof |
| CN102584115A (en) * | 2011-12-20 | 2012-07-18 | 汪洋 | Fireproof material, preparation method thereof and fireproof door |
-
2014
- 2014-12-15 CN CN201410775207.6A patent/CN104529245A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH09255880A (en) * | 1996-03-22 | 1997-09-30 | Takahashi Seisakusho:Kk | Biodegradable plastic composition |
| CN101337805A (en) * | 2008-08-25 | 2009-01-07 | 张璐 | Artificial quartz in lump and fabrication technology thereof |
| CN102390953A (en) * | 2011-08-12 | 2012-03-28 | 新云石业（云浮）有限公司 | Raw material of antibacterial superhard artificial quartz stone plate, artificial quartz stone plate and preparation method thereof |
| CN102584115A (en) * | 2011-12-20 | 2012-07-18 | 汪洋 | Fireproof material, preparation method thereof and fireproof door |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106477971A (en) * | 2015-11-30 | 2017-03-08 | 衡阳市雅典娜石英石有限公司 | A kind of fire resisting quartz and preparation method thereof |
| CN106145774A (en) * | 2016-06-24 | 2016-11-23 | 安徽弗仕通实业有限公司 | A kind of flame-proof explosion-proof artificial quartz in lump |
| CN106145810A (en) * | 2016-06-24 | 2016-11-23 | 安徽弗仕通实业有限公司 | A kind of artificial stone of resistance to water logging and preparation method thereof |
| CN106186822A (en) * | 2016-06-30 | 2016-12-07 | 禹州市远大塑料电器有限责任公司 | A kind of wear-resisting quartzite slate and preparation technology thereof |
| CN107892507A (en) * | 2017-11-07 | 2018-04-10 | 桂林奥尼斯特节能环保科技有限责任公司 | A kind of superhard artificial quartz stone plate and preparation method thereof |
| CN109320171A (en) * | 2018-12-07 | 2019-02-12 | 袁建辉 | A kind of high rigidity artificial stone material and preparation method |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104478292A (en) | Artificial quartz stone sheet and preparation method thereof | |
| CN104529245A (en) | Fireproof manmade quartz stone slab with superhardness and manufacturing method of fireproof manmade quartz stone slab | |
| CN104496273A (en) | Artificial quartzite plate and manufacturing method thereof | |
| CN104478215A (en) | Super-hardness artificial quartz stone plate and manufacturing method thereof | |
| CN104556838A (en) | Anti-aging super-hardness artificial quartz stone plate and manufacturing method thereof | |
| CN103396040B (en) | Artificial solid plane materiel and manufacturing method thereof | |
| CN104478289A (en) | Fireproof and pressure-resistant artificial quartz stone plate and preparation method thereof | |
| CN102390953B (en) | Raw material of antibacterial superhard artificial quartz stone plate, artificial quartz stone plate and preparation method thereof | |
| CN104478293A (en) | Synthetic quartzite plate and preparation method thereof | |
| CN104291734B (en) | A kind of artificial stone-like material and preparation method thereof | |
| CN104496271A (en) | Artificial quartzite plate and manufacturing method thereof | |
| CN103288405B (en) | Flexible decorative sheet and manufacturing method thereof | |
| CN104529248A (en) | Artificial quartz stone panel and preparation method thereof | |
| CN104529244A (en) | Anti-aging and antibacterial artificial quartzite board and manufacturing method thereof | |
| CN104478290A (en) | Anti-aging artificial quartz stone panel and preparation method thereof | |
| CN105621949A (en) | Artificial quartz stone slabs and preparation method thereof | |
| CN105819748A (en) | High strength artificial quartz stone sheet and preparation method thereof | |
| CN104496274A (en) | Fireproof artificial quartz stone plate and manufacturing method thereof | |
| CN105732078A (en) | Preparation method for colored foamed ceramic sheet material by utilizing polished waste slag | |
| CN104529246A (en) | Antibacterial and fireproof artificial quartzite board and preparation method thereof | |
| CN104529247A (en) | Super-hardness and antibacterial artificial quartzite plate and manufacture method thereof | |
| CN104478291A (en) | Pressure-proof antibacterial artificial quartz stone plate and preparation method thereof | |
| CN104529249A (en) | Man-made quartz stone plate and preparation method thereof | |
| CN104016629B (en) | Blue bricks modelled after an antique and manufacture method thereof | |
| CN106699205B (en) | Sol-combined blast furnace lining wet-process spray coating and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20150422 |
|
| RJ01 | Rejection of invention patent application after publication |