CN103288405B - Flexible decorative sheet and manufacturing method thereof - Google Patents
Flexible decorative sheet and manufacturing method thereof Download PDFInfo
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- CN103288405B CN103288405B CN201310191117.8A CN201310191117A CN103288405B CN 103288405 B CN103288405 B CN 103288405B CN 201310191117 A CN201310191117 A CN 201310191117A CN 103288405 B CN103288405 B CN 103288405B
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- 238000004519 manufacturing process Methods 0.000 title claims abstract description 16
- 239000000463 material Substances 0.000 claims abstract description 31
- 239000000839 emulsion Substances 0.000 claims abstract description 29
- 229920000058 polyacrylate Polymers 0.000 claims abstract description 25
- 239000002994 raw material Substances 0.000 claims abstract description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000000835 fiber Substances 0.000 claims abstract description 8
- 239000000049 pigment Substances 0.000 claims abstract description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 18
- 238000003756 stirring Methods 0.000 claims description 17
- 239000006004 Quartz sand Substances 0.000 claims description 13
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 12
- 239000007787 solid Substances 0.000 claims description 12
- 239000003365 glass fiber Substances 0.000 claims description 10
- 238000007711 solidification Methods 0.000 claims description 9
- 230000008023 solidification Effects 0.000 claims description 9
- 235000013312 flour Nutrition 0.000 claims description 8
- 238000004513 sizing Methods 0.000 claims description 8
- 239000002002 slurry Substances 0.000 claims description 8
- 239000004575 stone Substances 0.000 claims description 8
- 239000000725 suspension Substances 0.000 claims description 8
- 239000000945 filler Substances 0.000 claims description 7
- 239000004927 clay Substances 0.000 claims description 3
- 239000002893 slag Substances 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 2
- 229920001296 polysiloxane Polymers 0.000 claims description 2
- 239000004568 cement Substances 0.000 abstract description 16
- 239000000843 powder Substances 0.000 abstract description 7
- 230000032683 aging Effects 0.000 abstract description 6
- 239000005871 repellent Substances 0.000 abstract description 5
- 230000002940 repellent Effects 0.000 abstract description 5
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract description 2
- 239000011707 mineral Substances 0.000 abstract description 2
- 229920000642 polymer Polymers 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 7
- 239000002689 soil Substances 0.000 description 7
- JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 6
- 229960005191 ferric oxide Drugs 0.000 description 6
- 238000010298 pulverizing process Methods 0.000 description 6
- 238000009825 accumulation Methods 0.000 description 5
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- 229920001577 copolymer Polymers 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000002023 wood Substances 0.000 description 4
- 239000000919 ceramic Substances 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 2
- 235000013339 cereals Nutrition 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 239000011468 face brick Substances 0.000 description 2
- 235000011868 grain product Nutrition 0.000 description 2
- -1 iron powder compound Chemical class 0.000 description 2
- 239000010985 leather Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000004321 preservation Methods 0.000 description 2
- 239000010802 sludge Substances 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 229910001051 Magnalium Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 241001300078 Vitrea Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- JHLNERQLKQQLRZ-UHFFFAOYSA-N calcium silicate Chemical compound [Ca+2].[Ca+2].[O-][Si]([O-])([O-])[O-] JHLNERQLKQQLRZ-UHFFFAOYSA-N 0.000 description 1
- 229910052918 calcium silicate Inorganic materials 0.000 description 1
- 235000012241 calcium silicate Nutrition 0.000 description 1
- ARHMMDOXGIIARL-UHFFFAOYSA-N calcium;dihydroxy(dioxido)silane Chemical compound [Ca+2].O[Si](O)([O-])[O-] ARHMMDOXGIIARL-UHFFFAOYSA-N 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000320 mechanical mixture Substances 0.000 description 1
- 229910001719 melilite Inorganic materials 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000001062 red colorant Substances 0.000 description 1
- 238000005057 refrigeration Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 238000001356 surgical procedure Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000010257 thawing Methods 0.000 description 1
- 238000002560 therapeutic procedure Methods 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Landscapes
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Laminated Bodies (AREA)
Abstract
The invention discloses a flexible decorative sheet and a manufacturing method thereof. The flexible decorative sheet disclosed by the invention is composed of the following raw materials by mass percent: 30-60% of blast furnace mineral powder, 7-20% of acrylic polymer emulsion, 0.1-2% of fibre, 0.1-5% of water repellent, 0-3% of pigment, and the balance of filling material. According to the invention, the use amounts of cement and polymer emulsion are greatly reduced, so that the cost is greatly reduced; and the flexible decorative sheet disclosed by the invention has the characteristics of being excellent in ageing-resistant performance, good in fireproof performance and saltpetering-resistant.
Description
Technical field
The invention belongs to building material field, particularly relate to a kind of Flexible decorative sheet and manufacture method thereof.
Background technology
Due to Ceramic Tiles as exterior wall finish material particularly high-rise outer wall outer heat preservation system finishing material there is unsurmountable potential safety hazard, the use of current most domestic territorial restrictions Ceramic Tiles on exterior wall.Flexible sheet material is light owing to having quality, has certain flexibility, is the desirable finishing material of high-rise outer heat preservation system.The Flexible decorative sheet reported at present mainly contains three types: the flexible sheet material of the flexible face brick class be made up of true mineral varnish raw material, the flexible sheet material be made up of earth and cement based.Flexible face brick is ageing-resistant, anti-pollution characteristic is difficult to meet market demands, and fire protecting performance does not reach A level yet; The flexible sheet material that earth is made is better ageing-resistant, but fire protecting performance does not reach A level yet, and cement-based flexible sheet material is difficult to the common fault overcoming cement-based material " accumulation of salt in the surface soil ", although more existing company develops the product of several suppression accumulation of salt in the surface soil, but it is expensive, in actual applications, effect neither be good especially.
For to meet the need of market and can large-scale popularization in actual applications, develop cheap, the anti-accumulation of salt in the surface soil, the external wall of high-rise building Surgery therapy sheet material that ageing-resistant and fire protecting performance is excellent becomes the problem that need solve at present.
Summary of the invention
The object of the present invention is to provide a kind of Flexible decorative sheet.
Another object of the present invention is to the manufacture method that a kind of Flexible decorative sheet is provided.
For solving the problem, the technical solution adopted in the present invention is:
A kind of Flexible decorative sheet, its raw material is made up of following mass percent component: blast furnace iron powder 30 ~ 60%, acrylate polymer emulsion 7 ~ 20%, fiber 0.1 ~ 2%, hydrophober 0.2 ~ 5%, pigment 0 ~ 3%, and surplus is filler.
Preferably, this Flexible decorative sheet, its raw material is made up of following mass percent component: blast furnace iron powder 30 ~ 50%, acrylate polymer emulsion 7 ~ 20%, fiber 0.1 ~ 2%, hydrophober 0.2 ~ 2%, pigment 0 ~ 2%, and surplus is filler.
Preferably, blast furnace iron powder is granulated blast-furnace shrend super finely ground slag.
Preferably, the specific area of blast furnace iron powder is not less than 410m
2/ kg.Blast furnace iron powder can adopt commercially available S95 and other blast furnace iron powder of higher level.
Preferably, the solid content of acrylate polymer emulsion is 45 ~ 55%.As solid content reduces, then the corresponding increase of emulsion used in amounts.
Preferably, fiber is at least one in glass fibre, vinal.
Preferably, filler is at least one in quartz sand, stone flour, pitchers powder, clay.
Preferably, hydrophober is silicone based hydrophober.Poorer than barrier properties after cement solidification after blast furnace iron powder solidification, therefore, adding hydrophober can reduce water absorption rate, strengthens barrier properties.
Preferably, pigment iron oxide serial pigment.
The manufacture method of above-mentioned Flexible decorative sheet, comprises the following steps:
1) filler is pulverized rear and blast furnace iron powder, fiber, pigment Homogeneous phase mixing, obtain siccative;
2) hydrophober is added to the water, is stirred into suspension, siccative is added wherein, stir, then add acrylate polymer emulsion, stir into uniform sizing material
3) by slurry apply, pour into or be squeezed on mould, normal temperature or 50 ~ 150 DEG C solidification after
Demoulding, obtains Flexible decorative sheet.
Preferably, the addition of water is 10 ~ 40% of raw material gross weight.
The invention has the beneficial effects as follows:
Granulation shrend blast furnace iron powder is that quick refrigeration liquid molten steel slag obtains through grinding, and wherein major part is glass state material, and the Vitrea degree of polymerization is very low, has activity, when the specific area of breeze reaches 410m
2during/more than Kg, its activity increases greatly.Except a large amount of vitreum, also containing calcium magnalium melilite and the crystalline solid such as the monocalcium silicate seldom measured and dicalcium silicate in breeze, therefore, breeze has self faint hydraulicity.Blast furnace iron powder compound facing sheet material of the present invention, when adding a small amount of acrylate copolymer as crosslinking agent, can completely by specific area more than 410m
2the blast furnace iron powder of/Kg, as inorganic coagulation material, forms water-tolerant, facing material that case hardness is high, also reduces cost simultaneously after solidification.The most important accumulation of salt in the surface soil phenomenon being that of avoiding traditional cements base flexible sheet material.Replace cement based system with breeze, the use amount of acrylate copolymer can be reduced, make its ageing-resistant performance more excellent.
In addition, when needing effects on surface to carry out secondary glazing treatment, Flexible decorative sheet of the present invention, compared with cement-based flexible sheet material, has better glaze adsorptivity, makes color more firm.
When containing identical amount acrylate copolymer, Flexible decorative sheet of the present invention is flexible better, more freeze-thawing resistant.
Flexible decorative sheet of the present invention, the blast furnace iron powder of employing belongs to discarded object, utilizes blast furnace iron powder to carry out the high ornament materials of production added value, can reach the object turned waste into wealth.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is further illustrated, but be not limited thereto.
The percentage used in following examples, if no special instructions, all refers to mass percent.Enforcement makes acrylate polymer emulsion in you be Guangzhou meter Run height Chemical Co., Ltd. M-8504.
Embodiment 1
A kind of Flexible decorative sheet, its raw material is made up of following mass percent component: S95 breeze 30%, acrylate polymer emulsion (solid content 45%) 20%, hydrophober (the hydrophober B5 that Ao Da chemical plant, Dongguan produces) 0.1%, glass fibre 0.1%, surplus is quartz sand.
The manufacture method of above-mentioned Flexible decorative sheet, comprises the steps:
1) quartz sand powder is broken to 100 ~ 200 orders, the quartz sand after pulverizing is mixed with S95 breeze, glass fibre, obtains siccative;
2) hydrophober is added in the water of raw material gross weight 10%, be stirred into suspension, siccative is added wherein, stir, then add acrylate polymer emulsion, stir into uniform sizing material;
3) be squeezed in by slurry on the grained mould of tool, thick 3mm, 60 DEG C of solidification rear demouldings, obtain the imitative wood grain product of Flexible decorative sheet.
Embodiment 2
A kind of Flexible decorative sheet, its raw material is made up of following mass percent component: S95 breeze 35%, acrylate polymer emulsion (solid content 48%) 16%, vinal 0.5%, hydrophober (organosilicon moisture repellent 1042 that Wa Ke company produces) 0.2%, surplus is stone flour.
The manufacture method of above-mentioned Flexible decorative sheet, comprises the steps:
1) stone flour is crushed to 100 ~ 200 orders, the stone flour after pulverizing is mixed with S95 breeze, vinal, obtains siccative;
2) hydrophober is added in the water of raw material gross weight 15%, be stirred into suspension, siccative is added wherein, stir, then add acrylate polymer emulsion, stir into uniform sizing material;
3) slurry is squeezed on the grained mould of tool, thick 4mm, normal temperature cure rear demoulding, obtains the imitative wood grain product of Flexible decorative sheet.
Embodiment 3
A kind of Flexible decorative sheet, its raw material is made up of following mass percent component: S105 breeze 40%, acrylate polymer emulsion (solid content 48%) 14%, glass fibre 1%, iron oxide red 0.5%, hydrophober (organosilicon moisture repellent 1042 that Wa Ke company produces) 0.5%, surplus are pitchers.The manufacture method of above-mentioned Flexible decorative sheet, comprises the steps:
1) pitchers is crushed to 100 ~ 200 orders, the pitchers after pulverizing is mixed with S105 breeze, glass fibre, obtains siccative;
2) hydrophober is added in the water of raw material gross weight 20%, be stirred into suspension, siccative is added wherein, stir, then add acrylate polymer emulsion, stir into uniform sizing material;
3) be squeezed in by slurry on the mould with ox-hide line, thick 3mm, 150 DEG C of solidification rear demouldings, obtain the leather texture imitation product of Flexible decorative sheet.
Embodiment 4
A kind of Flexible decorative sheet, its raw material is made up of following mass percent component: S95 breeze 45%, acrylate polymer emulsion (solid content 50%) 10%, glass fibre 0.3%, hydrophober (the hydrophober B5 that Ao Da chemical plant, Dongguan produces) 0.8%, iron oxide yellow 0.5%, surplus is quartz sand.
The manufacture method of above-mentioned Flexible decorative sheet, comprises the steps:
1) quartz sand powder is broken to 100 ~ 200 orders, the quartz sand after pulverizing and clay is mixed with S95 breeze, glass fibre, obtains siccative;
2) hydrophober is added in the water of raw material gross weight 25%, be stirred into suspension, siccative is added wherein, stir, then add acrylate polymer emulsion, stir into uniform sizing material;
3) be squeezed in by slurry on the mould with ox-hide line, thick 3mm, 150 DEG C of solidification rear demouldings, obtain the leather texture imitation product of Flexible decorative sheet.
Embodiment 5
A kind of Flexible decorative sheet, its raw material is made up of following mass percent component: S95 breeze 50%, acrylate polymer emulsion (solid content 52%) 9%, vinal 1.0%, ferric oxide red colorant 1.5%, hydrophober (Wa Ke company produce organosilicon moisture repellent 1042) 1.0%, quartz sand and the pitchers powder of surplus to be mass ratio be 1:1.
The manufacture method of above-mentioned Flexible decorative sheet, comprises the steps:
1) quartz sand and pitchers powder are crushed to 100 ~ 200 orders, the quartz sand after pulverizing are mixed with S95 breeze, vinal, obtains siccative;
2) hydrophober is added in the water of raw material gross weight 28%, be stirred into suspension, siccative is added wherein, stir, then add acrylate polymer emulsion, stir into uniform sizing material;
3) be coated in by slurry on light face mould tool, thick 2.5mm, 100 DEG C of solidification rear demouldings, obtain light face product.
Embodiment 6
A kind of Flexible decorative sheet, its raw material is made up of following mass percent component: S95 breeze 50%, acrylate polymer emulsion (solid content 50%) 7%, iron oxide black 1.8%, vinal 1.4%, hydrophober (organosilicon moisture repellent 6683 that DOW CORNING is produced) 2%, surplus is stone flour.
The manufacture method of above-mentioned Flexible decorative sheet, its manufacture method is as follows:
1) stone flour is broken to 100 ~ 200 orders, the stone flour after pulverizing is mixed with S95 breeze, vinal, obtains siccative;
2) hydrophober is added in the water of raw material gross weight 30%, be stirred into suspension, siccative is added wherein, stir, then add acrylate polymer emulsion, stir into uniform sizing material;
3) slurry is coated on the mould with Splitting Tile texture, thick 2mm, 80 DEG C of curing and demolding, obtains imitative Splitting Tile product.
Comparative example 1
Cement-based flexible sheet material, its raw material is made up of following mass percent component: white cement 45%, acrylate polymer emulsion (solid content 45%) 10%, glass fibre 0.3%, hydrophober (the hydrophober B5 that Ao Da chemical plant, Dongguan produces) 0.8%, iron oxide yellow 0.5%, surplus is quartz sand, S95 breeze, with embodiment 4, is only replaced with cement by its preparation method.
Comparative example 2
Cement-based flexible sheet material, its raw material is made up of following mass percent component: white cement 45%, acrylate polymer emulsion (solid content 45%) 12%, glass fibre 0.3%, hydrophober (the hydrophober B5 that Ao Da chemical plant, Dongguan produces) 0.5%, iron oxide yellow 0.5%, surplus is quartz sand, its preparation method is with embodiment 4, S95 breeze is replaced with cement, improves acrylate polymer emulsion content simultaneously.
Comparative example 3
The flexibly wall brick made with modification earth and acrylate polymer emulsion in patent " elastomer product of modifying common soil and production method thereof " ZL200910226004.0.Its acrylic acid scope is at 20%-70%, and embodiment 10 is modification yellow mud powder 71%, and acrylic ester high molecular type copolymer emulsion 20%, water 9%, mechanical mixture stirs into uniform composite sludge.Be coated on by composite sludge in the template with woven design or wood grain or bag, coating thickness is 1.6mm, and baking temperature is 280C, and after moisture evaporation is dry, molding, forming thickness is the yellow woven design of 1.6mm or the compound mud ground wal ceramic tile of wood grain or bag.
The cement-based flexible sheet material of the Flexible decorative sheet of embodiment 1 ~ 6 gained and comparative example 1 ~ 3, Modified soil flexible sheet material are carried out Performance Detection, and testing result is in table 1.As seen from table, Flexible decorative sheet of the present invention is compared with comparative example 1, and when same acrylic emulsion content, comparative example 1 intensity difference, is highly brittle, easily splits, and the present invention uses blast furnace iron powder to replace cement, and manufactured goods are flexible better.And can the accumulation of salt in the surface soil be avoided.Compared with comparative example 3, the present invention has better fire protecting performance and ageing-resistant performance.
The performance test results of table 1 each embodiment blast furnace iron powder composite decoration sheet material
Claims (7)
1. a Flexible decorative sheet, its raw material is made up of following mass percent component: blast furnace iron powder 30 ~ 60%, acrylate polymer emulsion 7 ~ 20%, fiber 0.1 ~ 2%, hydrophober 0.1 ~ 5%, pigment 0 ~ 3%, and surplus is filler; The specific area of described blast furnace iron powder is not less than 410m
2/ kg;
The manufacture method of described Flexible decorative sheet, comprises the following steps:
1) filler is pulverized rear and blast furnace iron powder, fiber, pigment Homogeneous phase mixing, obtain siccative;
2) hydrophober is added to the water, is stirred into suspension, siccative is added wherein, stir, then add acrylate polymer emulsion, stir into uniform sizing material;
3) applied, pour into or be squeezed on mould by slurry, normal temperature or 50 ~ 150 DEG C of solidification rear demouldings, obtain Flexible decorative sheet.
2. Flexible decorative sheet according to claim 1, is characterized in that: blast furnace iron powder is granulated blast-furnace shrend super finely ground slag.
3. Flexible decorative sheet according to claim 1 and 2, is characterized in that: the solid content of acrylate polymer emulsion is 45 ~ 55%.
4. Flexible decorative sheet according to claim 1 and 2, is characterized in that: filler is at least one in quartz sand, stone flour, pitchers, clay.
5. Flexible decorative sheet according to claim 1 and 2, is characterized in that: hydrophober is silicone based hydrophober.
6. Flexible decorative sheet according to claim 1 and 2, is characterized in that: fiber is at least one in glass fibre, vinal.
7. Flexible decorative sheet according to claim 1 and 2, is characterized in that: the addition of water is 10 ~ 40% of raw material gross weight.
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310191117.8A CN103288405B (en) | 2013-05-21 | 2013-05-21 | Flexible decorative sheet and manufacturing method thereof |
| US14/427,799 US10155694B2 (en) | 2013-05-21 | 2013-09-23 | Composite blast furnace mineral powder and synthetic material made from same |
| PCT/CN2013/084013 WO2014187052A1 (en) | 2013-05-21 | 2013-09-23 | Composite blast furnace mineral powder and synthetic material made from same |
| US16/185,135 US11352295B2 (en) | 2013-05-21 | 2018-11-09 | Composite blast furnace mineral powder and synthetic material made from same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310191117.8A CN103288405B (en) | 2013-05-21 | 2013-05-21 | Flexible decorative sheet and manufacturing method thereof |
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| Publication Number | Publication Date |
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| CN103288405A CN103288405A (en) | 2013-09-11 |
| CN103288405B true CN103288405B (en) | 2015-03-25 |
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| CN201310191117.8A Active CN103288405B (en) | 2013-05-21 | 2013-05-21 | Flexible decorative sheet and manufacturing method thereof |
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Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10155694B2 (en) | 2013-05-21 | 2018-12-18 | Guangdong Phomi Mcm Co., Ltd. | Composite blast furnace mineral powder and synthetic material made from same |
| CN105439500B (en) * | 2015-12-11 | 2018-02-06 | 上海古猿人石材有限公司 | A kind of environment-friendly type flexible clay facing tile prepared using modified waste residue and preparation method thereof |
| CN106045422A (en) * | 2016-06-08 | 2016-10-26 | 石磊 | Manufacturing method of flexible decorative sheet |
| CN107311505B (en) * | 2017-06-09 | 2019-11-19 | 广东福美软瓷有限公司 | A kind of composite material of modified industry inorganic powder and the inorganic powder containing modified industry |
| CN107814525A (en) * | 2017-11-27 | 2018-03-20 | 广西福美新材料有限公司 | A kind of antistatic flexible floor and preparation method thereof |
| CN108909082A (en) * | 2018-06-20 | 2018-11-30 | 广东福美软瓷有限公司 | A kind of reflective insulation Flexible decorative sheet and its manufacturing method |
| CN108863217A (en) * | 2018-07-10 | 2018-11-23 | 合沐佳成都新材料有限公司 | A kind of inorganic porcelain tendre and preparation method thereof |
| CN110724468B (en) * | 2019-10-25 | 2020-10-27 | 东阳市琰安建筑工程有限公司 | Preparation process of self-adhesive multilayer composite flexible decorative sheet |
| CN111677218B (en) * | 2020-06-15 | 2021-07-13 | 山东斯蒙特新材料有限公司 | Preparation process of decorative plate containing polyurethane heat-insulating layer |
| CN114213923A (en) * | 2021-09-02 | 2022-03-22 | 万卓（江苏）新材料有限公司 | High-scratch-resistance flame-retardant flexible stone-like material and preparation method thereof |
| CN115353322A (en) * | 2022-08-11 | 2022-11-18 | 华润水泥技术研发有限公司 | Flexible stone-like decorative sheet and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103104046A (en) * | 2013-02-01 | 2013-05-15 | 万华节能科技集团股份有限公司 | Building wall insulation composite board and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103104046A (en) * | 2013-02-01 | 2013-05-15 | 万华节能科技集团股份有限公司 | Building wall insulation composite board and preparation method thereof |
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